EP3853904B1 - Nouveau procédé de gravure avec formation in situ de couche de protection - Google Patents
Nouveau procédé de gravure avec formation in situ de couche de protection Download PDFInfo
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- EP3853904B1 EP3853904B1 EP19914915.4A EP19914915A EP3853904B1 EP 3853904 B1 EP3853904 B1 EP 3853904B1 EP 19914915 A EP19914915 A EP 19914915A EP 3853904 B1 EP3853904 B1 EP 3853904B1
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- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02118—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer carbon based polymeric organic or inorganic material, e.g. polyimides, poly cyclobutene or PVC
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0334—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/0337—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0334—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/0338—Process specially adapted to improve the resolution of the mask
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31105—Etching inorganic layers
- H01L21/31111—Etching inorganic layers by chemical means
- H01L21/31116—Etching inorganic layers by chemical means by dry-etching
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/50—EEPROM devices comprising charge-trapping gate insulators characterised by the boundary region between the core and peripheral circuit regions
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02115—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material being carbon, e.g. alpha-C, diamond or hydrogen doped carbon
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- H—ELECTRICITY
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- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02109—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
- H01L21/02112—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
- H01L21/02118—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer carbon based polymeric organic or inorganic material, e.g. polyimides, poly cyclobutene or PVC
- H01L21/0212—Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer carbon based polymeric organic or inorganic material, e.g. polyimides, poly cyclobutene or PVC the material being fluoro carbon compounds, e.g.(CFx) n, (CHxFy) n or polytetrafluoroethylene
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/02104—Forming layers
- H01L21/02107—Forming insulating materials on a substrate
- H01L21/02225—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer
- H01L21/0226—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process
- H01L21/02263—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase
- H01L21/02271—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition
- H01L21/02274—Forming insulating materials on a substrate characterised by the process for the formation of the insulating layer formation by a deposition process deposition from the gas or vapour phase deposition by decomposition or reaction of gaseous or vapour phase compounds, i.e. chemical vapour deposition in the presence of a plasma [PECVD]
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B43/23—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B43/27—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
Definitions
- a semiconductor memory such as a NAND memory
- the semiconductor memory can function as a data storage component in the integrated circuit.
- critical dimensions of the semiconductor memory shrink to the limits of common memory cell technologies, designers have been looking to techniques for stacking multiple planes of memory cells to achieve greater storage capacity, and achieve lower costs per bit.
- a 3D-NAND memory device is an exemplary device of stacking multiple planes of memory cells to achieve greater storage capacity, and to achieve lower costs per bit.
- 3D-NAND technology migrates towards high density and high capacity, especially from 64L to 128L architecture, the number of devices, and the number of mask layers to make the devices have increased significantly.
- Each of the mask layers can mean an increased manufacturing cost and an increased manufacturing time.
- increased mask layers introduce process complexity, especially in a dry etching process and a photolithographic process.
- Document US 6 989 317 Bl discloses e.g. a trench etching method for etching trenches of different depths which are self-aligned to one another.
- Document JP 2011 060958 A discloses e.g.
- Document US 2007/0287293 A1 e.g. discloses a fabrication method of a semiconductor device, and more particularly, to a method for fabricating a semiconductor device that prevents a plate from being punched during an etching for forming a metal interconnection
- document US 2015/0263029 A1 e.g. discloses a method to fabricate a semiconductor memory device includes a substrate including a cell region and peripheral region, wherein the cell region is equipped with a photolithographic reference mark pattern and includes a memory cell array region and a staircase shaped connection region connected to memory cells of the memory cell array region.
- the inventive concepts relate to a novel etching process.
- a first mask layer is normally required to form the first pattern
- a second mask layer is required to form the second pattern.
- the first and the second patterns of the microstructure are formed via a single mask layer.
- the first pattern can be formed by an etching process and then protected by an in-situ formed protective (or polymeric) layer.
- the etching process subsequently complete formation of the second pattern in the microstructure.
- the protective layer and the mask layer are removed thereafter.
- the disclosure provides a novel etching process that has a low cost and less process complexity by forming patterns with different dimensions in a single mask layer.
- a method for processing a wafer is provided.
- the method is defined in appended claim 1, with dependent claims defining additional features.
- the mask that is formed on the microstructure includes the first pattern with a first critical dimension.
- the mask also includes second pattern of the mask over the second region with a second critical dimension.
- the first critical dimension is smaller than the second critical dimension.
- the first region of the microstructure is protected by the protective layer during the second etching process.
- the first region of the microstructure comprises at least a channel region and includes a plurality of top channel contacts positioned in a dielectric layer.
- the first etching process transfers the first pattern of the mask into the first region of the microstructure to expose the plurality of top channel contacts and form a plurality of channel contact openings in the dielectric layer.
- the protective layer is formed to fill the plurality of channel contact openings and cover a top surface of the first pattern of the mask.
- the protective layer is further accumulated on a top surface of the first pattern of the mask and is uniformly formed along side portions and bottom portions of the trenches in the second region of the microstructure.
- the protective layer is formed by a processing gas that includes carbon element, hydrogen element, or fluorine element. A density, a thickness, and a composition of the protective layer can be adjusted by changing the carbon to hydrogen ratio in the processing gas.
- the second region of the microstructure includes a plurality of word lines.
- the second etching process etches the microstructure to transfer the second pattern of the mask further into the second region of the microstructure to expose the plurality of the word lines.
- first and the second etching processes and the formation of the protective layer are performed in a same processing chamber. In yet another embodiment, the first and the second etching processes are performed in a first processing chamber and the protective layer is formed in a second processing chamber.
- a method for manufacturing a memory structure is provided.
- a mask stack is formed for pattern transfer on a memory structure.
- the memory structure is formed over a substrate and includes at least the channel region as the first region of the microstructure and a word line region as the second region of the microstructure.
- the mask stack has a first pattern that is positioned over the channel region and a second pattern that is positioned over the word line region.
- a first etching process is then performed. The first etching process etches the memory structure according to the first and second patterns formed in the mask stack to transfer the first and second patterns into the channel region and the word line region of the memory structure respectively.
- a plurality of channel contact openings are formed in the channel region by the first etching process.
- a protective layer is formed over the first pattern of the mask stack that is positioned on the channel region of the memory structure.
- a second etching process is performed. The second etching process etches the memory structure and transfers the second pattern of the mask stack further into the word line region of the memory structure.
- a plurality of word line contact openings are formed in the word line region by the second etching process. After the second etching process, the mask stack and the protective layer are removed from the channel region.
- a mask stack is formed for pattern transfer on a 3D-NAND structure.
- the 3D-NAND structure is formed over a substrate and includes the channel region as the first region of the microstructure and a staircase region as the second region of the microstructure.
- the channel region includes a plurality of top channel contacts disposed in a dielectric layer and the staircase region includes a plurality of word lines stacked in a staircase configuration.
- a first and a second patterns are formed in the mask stack. The first pattern is positioned over the channel region and a second pattern is positioned over the staircase region.
- the first pattern has a smaller critical dimension (CD) than the second pattern.
- the 3D-NAND structure is subsequently etched according to the first and second patterns formed in the mask stack to transfer the first and second patterns of the mask stack into the 3D-NAND structure.
- the first pattern of the mask stack is transferred to the channel region to expose the plurality of top channel contacts and form a plurality of channel contact openings in the dielectric layer.
- a protective layer is then formed over the first pattern of the mask stack that is positioned over the channel region of the 3D-NAND structure. The protective layer covers the channel region and further fills the plurality of channel contact openings.
- the 3D-NAND structure is etched to transfer the second pattern of the mask stack further into the staircase region.
- the second pattern of the mask stack is transferred into the staircase region to expose the plurality of the word lines and form a plurality of word line contact openings in the staircase region.
- the mask stack and the protective layer are removed thereafter from the 3D-NAND structure.
- first and second features are formed features may be in direct contact
- additional features may be formed between the first and second features, such that the first and second features may not be in direct contact
- present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
- spatially relative terms such as “beneath,” “below,” “lower,” “above,” “upper” and the like, may be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures.
- the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures.
- the apparatus may be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein may likewise be interpreted accordingly.
- FIG. 1 shows a cross-sectional view of a portion of a 3D-NAND memory device 100 during a semiconductor manufacturing process in accordance with exemplary embodiments of the disclosure.
- the memory device 100 can be divided into two regions: a channel region (or first region) 100b and a staircase region (or second region) 100a.
- a plurality of word lines 104a-120j are sequentially stacked over a substrate 102.
- the plurality of word lines 104 are spaced apart from each other by a plurality of insulating layers 106a-106j.
- the word lines 104 and the insulating layer 106 are stacked in a staircase configuration, where a word line 104a and an insulating layer 106a have a smallest length, and a word line 104j and an insulating layer 106j have a largest length, as shown in FIG. 1 . While shown with ten word lines, it should be understood that any number of word lines can be used.
- the substrate 102 may be a bulk silicon wafer heavily doped with a N-type dopant or a P-type dopant to form a N-well or P-well, respectively.
- the word lines 104 illustrated in FIG. 1 are formed using sacrificial layers that are made of SiN. The sacrificial layers can be removed and replaced with a high K layer and a metal layer. The high K layer can be made of aluminum oxide and the metal layer can be made of tungsten (W), for example.
- the word line 104 can have a thickness in a range from 10 nm to 100 nm, according to manufacturing requirements.
- the insulating layer 106 can be made of SiO with a thickness from 5 nm to 50 nm.
- a first dielectric layer 108 is deposited over the staircase that is formed by the word lines 104 and insulating layers 106 in the staircase region 100a.
- a second dielectric layer 110 is formed on the first dielectric layer 108.
- a mask stack 112 is deposited that includes a first pattern 126 and a second pattern 124.
- the second pattern 124 is positioned in the staircase region 100a.
- the second pattern 124 can have a cylindrical shape that includes side portions and a bottom portion to expose the second dielectric layer 110.
- the first dielectric layer 108 can be made of SiO with a thickness in a range from 4 um to 8 um.
- the second dielectric layer 110 can also be made of SiO with a thickness in a range from 50 nm to 300 nm, depending on the technology requirements.
- the mask stack 112 can includes an amorphous carbon layer, a dielectric anti-reflection coating (DARC) layer, a bottom anti-reflective coating (BARC) layer, and a photo resist layer, depending on the manufacturing requirements.
- DARC dielectric anti-reflection coating
- BARC bottom anti-reflective coating
- a plurality of channel structure 136a-136f are included in the channel region 100b of the memory device 100.
- the channel structures 136 pass through the plurality of word lines 104 and the insulating layers 106.
- the channel structures 136 can have a cylindrical shape with sidewalls and a bottom region. Of course, other shapes are possible.
- the channel structures 136 are formed along a direction perpendicular to the substrate 102, and electrically coupled with the substrate 102 via bottom channel contacts 114.
- a channel structure 136a is electrically coupled with the substrate 102 via a bottom channel structure 114a, as shown in FIG. 1 .
- the channel structures 136 further include channel dielectric regions 116, channel layers 118, channel insulating layers 120, and top channel contacts 122.
- the channel structure 136a has a channel dielectric region 116a, a channel layer 118a, a channel insulating layer 120a, and a top channel contact 122a.
- the channel structures 136 extends out from the first dielectric layer 108 and are encapsulated by the second dielectric layer 110.
- the first pattern 126 of the mask stack 112 is positioned over the channel region 110b.
- the first pattern 126 can have a cylindrical shape that includes side portions and a bottom portion to expose the second dielectric layer 110.
- the first pattern 126 can have a smaller critical dimension (CD) than the second pattern 124.
- the patterns 124 and 126 can be formed according to any suitable technique, such as a lithography process (e.g., photolithography or e-beam lithography) which may further include photoresist coating (e.g., spin-on coating), soft baking, mask aligning, exposure, post-exposure baking, photoresist developing, rinsing, drying (e.g., spin-drying and/or hard baking), and the like.
- a lithography process e.g., photolithography or e-beam lithography
- photoresist coating e.g., spin-on coating
- soft baking mask aligning
- exposure post-exposure baking
- photoresist developing e.g., rinsing
- drying e.g., spin-drying and/or hard baking
- FIGS. 2A/2B an expanded cross-sectional and top down views of the channel structure 136a are illustrated.
- FIG. 2A is an expanded cross-sectional view of the channel structure 136a
- FIG. 2B is an expanded top down view of the channel structure 136a.
- the cross-sectional view in FIG. 2A is obtained from a plane same as the vertical plane containing line A-A' in FIG. 2B . Dashed lines in FIG. 2B indicate a perspective view.
- the channel dielectric region 116a further includes a barrier layer 144a, a charge trapping layer 142a, and a tunneling layer 140a.
- the barrier layer 144a is formed along the sidewalls of the channel structure 136a and over the bottom channel contact 114a.
- the barrier layer 144a is in direct contact with the word lines 104 and the insulating layers 106.
- the charge trapping layer 142a is formed along the barrier layer 144a and over the bottom channel contact 114a.
- the tunneling layer 140a is formed along the charge trapping layer 142a and over the bottom channel contact 114a.
- the channel structure 136a further includes a channel layer 118a formed along the tunneling layer 140a and over the bottom channel contact 114a.
- a channel insulating layer 120a is formed over the channel layer 118a to fill the channel structure 136a.
- the barrier layer 144a is made of SiO. In another embodiment, the barrier layer 144a can include multiple layers, such as SiO and AlO. In an embodiment of FIGS. 2A/2B , the charge trapping layer 142a is made of SiN. In another embodiment, the charge trapping layer 142a can include a multi-layer configuration, such as a SiN/SiON/SiN multi-layer configuration. In some embodiments, the tunneling layer 140a can include a multi-layer configuration, such as a SiO/SiON/SiO multi-layer configuration. In an embodiment of FIGS. 2A/2B , the channel layer 118a is made of polysilicon via a furnace low pressure chemical vapor deposition (CVD) process.
- CVD chemical vapor deposition
- the channel structure 136a can have a cylindrical shape.
- the present disclosure is not limited thereto, and the channel structures 136 may be formed in other shapes, such as a square pillar-shape, an oval pillar-shape, or any other suitable shapes.
- a first etching process is performed.
- the first etching process etches the memory device 100 according to the first pattern 126 and second pattern 124 formed in the mask stack 112.
- the first etching process transfers the first pattern 126 and second pattern 124 of the mask stack 112 into the channel region 100b and staircase region 100a of the memory device 100, respectively.
- a plurality of first openings 128a-128j are formed in the staircase region 100a where the first openings 128 extend into the second dielectric layer 110.
- the first openings 128 can have a cylindrical shape that includes side portions and a bottom portion to extend into the second dielectric layer 110.
- a plurality of channel contact openings 130a-130j are formed in the channel region.
- the channel contact openings 130 can have a cylindrical shape that includes side portions and a bottom portion to extend into the second dielectric layer 110 and further expose the top channel contacts 122.
- a channel contact opening 120a extends into the second dielectric layer 110 and exposes the top channel contact 122a, as shown in FIG. 3 .
- the first openings 128 formed in the staircase region 100a can have a CD from 100 nm to 300 nm, and the channel contact openings 130 formed in the channel region 100b can have a CD from 20 nm to 80 nm, according to the design requirements.
- the first etching process may include RIE (reactive ion etching) etching, ICP (inductively coupled plasma) etching, CCP (capacitive coupled plasma) etching, MERIE (magnetically enhanced reactive ion etching) etching, plasma etching, and/or other etching methods.
- RIE reactive ion etching
- ICP inductively coupled plasma
- CCP capacitive coupled plasma
- MERIE magnetically enhanced reactive ion etching
- the processing gases can be selected in that the processing gases can have a good etching selectivity between the second dielectric layer 110 (e.g., SiO) and the top channel contact 122 (e.g., polysilicon).
- Various processing gases can be selected in the first etching process, such as CF 4 , CHF 3 , CH 2 F 2 , C 4 F 8 , C 5 F 8 , SF 6 , NF 3 , or other suitable gases.
- a CCP etching is applied.
- a processing gas such as CF 4 can be introduced into the etching chamber.
- the CF 4 dissociates to form free F (fluorine) radicals in an etching plasma generated in the etching chamber.
- the free F radicals further react with the SiO to form volatile by-product SiF4.
- O 2 can be added into the CF 4 gas to increase the F free radical production and hence increases the etch rate as well as makes the etch profile more isotropic.
- the first etching process can have a processing temperature in a range from 30 °C to 70 °C, a processing pressure from 10 mTorr to 80 mTorr, and a processing time less than 2 minutes.
- a protective (or polymeric) layer 132 can be formed over the first and second patterns of the mask stack 112.
- a film preferably forms in a microstructure with a relative larger size (opening) than in a microstructure with a relative smaller size (opening). Since the second pattern 124 have a bigger CD than the first pattern 126, the protective layer 132 can have a higher deposition rate in the second pattern 124.
- the protective layer 132 can accumulate over the first pattern 126 of the mask stack 112 that is positioned over the channel region 100b. According to the invention, the protective layer 132 fills the channel contact openings 130 and is further accumulated on a top surface of the pattern of the mask stack 112.
- the protective layer 132 is uniformly formed along side portions of the second pattern 124, side portions of the first openings 128, and over bottom portions of the first openings 128.
- the protective layer 132 can further cover a top surface of the mask stack 112, as shown in FIG. 4 .
- the protective layer 132 can be a polymer that is formed in a same etching chamber to perform the first etching process.
- the protective layer 132 can be formed by applying suitable processing gases, such as C 4 F 6 , C 4 F 8 , CHF 3 , CH 2 F 2 .
- the processing gases are polymer-forming gases having a relatively low fluorine/carbon (F/C) ratio.
- F/C fluorine/carbon
- the F7C ratio of the polymer-forming gas is below 3, and more preferably the F7C ratio of the polymer-forming gas is at most about 2.
- Suitable polymer-forming gases can be (hydro) fluorocarbon gases that include Freon 134 (CHF 2 -CHF 2 ), octafluorocyclobutane (C 4 F 8 ) and trifluoromethane (CHF 3 ).
- Process conditions of forming the protective layer can be different from process conditions of performing the first etching process.
- the processing gas to form the protective layer 132 can have a higher C to F ratio than the processing gas to perform the first etching process.
- a processing gas containing hydrogen is preferred to form the protective layer because the processing gas containing hydrogen tends to be polymerizing.
- a bias voltage coupled to the substrate 102 can be smaller during formation of the protective layer comparing to a bias voltage coupled to the substrate 102 during the first etching process.
- a composition, a density, and a thickness of the protective layer 132 can be adjusted by changing the C to F ratio of the processing gases, a processing pressure, and a processing time. For example, an increasing C to F ratio increases polymerization.
- the protective layer 132 can include hydrocarbon, fluorocarbon, chlorofluorocarbons (CFCs), or other carbonaceous compounds via dissociation of the processing gases in a deposition plasma generated in the etching chamber.
- An exemplary processing temperature to form the protective layer can be in a range from 10 °C to 70 °C, an exemplary processing pressure can be between 10 mTorr and 80 mTorr, and an exemplary processing time can be less than 3 minutes.
- the protective layer 132 can be formed in a different processing chamber rather in the etching chamber, such as a CVD chamber or a diffusion chamber.
- the protective layer 132 can be formed by applying a chemical vapor deposition (CVD), a hot wire CVD, a parylene polymerization, a plasma enhanced CVD, a plasma assisted CVD, a plasma CVD, a plasma polymerization or a diffusion process.
- CVD chemical vapor deposition
- a hot wire CVD a hot wire CVD
- a parylene polymerization a plasma enhanced CVD
- a plasma assisted CVD a plasma assisted CVD
- a plasma CVD a plasma polymerization or a diffusion process.
- a second etching process is performed.
- the second etching process etches the memory device 100 and transfers the second pattern of the mask stack 112 further into the staircase region of the memory device 100.
- the first openings 128 extend through the second dielectric layer 110 and extend into the first dielectric layer 108.
- the first openings 128 further extend through the insulating layers 106 and land on the word lines 104.
- the second etching process is completed, the first openings 128 become second openings 134.
- Each of the second openings 134 has side portions and a bottom portion to expose a respective word line.
- the second openings 134 can have a cylindrical shape, a square pillar-shape, an oval pillar-shape, or other suitable shapes.
- a portion of the protective layer 132 that covers the first openings 128 can be removed by an etching plasma generated in the second etching process.
- a remaining of the protective layer 132 over the first pattern 126 of the mask stack 112 becomes 132'.
- the channel region 100b can be protected by the remaining portion 132' of the protective layer 132 formed over the channel region 100b during the second etching process.
- suitable processing gases and process conditions can be selected to help forming additional protective layer over the first pattern of the mask stack 112 in the channel region 100b during the second etching process.
- the protective layer 132' can include a remaining portion of protective layer 132 over the first pattern of the mask stack 112 in the channel region 110b and an additional portion formed during the second etching process.
- the remaining portion of the protective layer 132 is covered by the additional portion formed during the second etching process.
- Suitable processing gases can be selected in the second etching process to achieve good etching selectivity between the first/second dielectric layers (e.g., SiO) and the word lines (e.g., SiN).
- the processing gases of the second etching process can include CF 4 , C 4 F 8 , C 5 F 8 , SF 6 , NF 3 , or other suitable gases.
- a processing time can also be precisely controlled through an end point detecting technique.
- the second etching process can have a processing temperature in a range from 30 °C to 70 °C, a processing pressure from 10 mTorr to 80 mTorr, and a processing time more than 15 minutes.
- a plasma ashing can be applied to remove the mask stack 112 and the remaining protective layer 132'.
- the plasma ashing can be an in-situ process performed in the etching chamber, or an ex-situ process performed in a strip/ash tool.
- an O 2 gas plus a forming gas i.e., 3-20% H 2 in N 2
- the plasma ashing can have a temperature between 100 °C to 300 °C, a power from 2000 W to 4000 W, and a pressure from 50 Torr to 200 Torr.
- the second openings 134 becomes word line contact openings 136
- the channel contact openings 130 becomes the bit line contact openings 138.
- the word line contact openings 136 pass through the second dielectric layer 110, extend into the second dielectric layer 108, pass through the insulating layers 106, and land on the word lines 104.
- Each of the word line contact openings 136 can have a cylindrical shape and expose a respective word line 104.
- the bit line contact openings 138 are formed in the second dielectric layers 110 and expose the top channel contacts 122.
- the bit line contact openings 138 can have a cylindrical shape as well.
- the word line contact openings 136 can have a CD from 100 nm to 300 nm and a depth from 4 um to 8 um, and the bit line contact openings can have a CD from 20 nm to 80 nm and a depth from 0.1 um to 0.4 um, according to the design requirements.
- FIG. 7 is a flowchart of a process 700 for manufacturing a 3D NAND memory device in accordance with some embodiments of the present disclosure.
- the process 700 begins at step 704 where a plurality of patterns are formed over a 3D NAND memory device.
- the patterns have a first pattern positioned over a channel region of the memory device, and a second pattern positioned over a staircase region of the memory device.
- the first pattern has a smaller CD than the second pattern.
- step 304 can be performed as illustrated with reference to FIG. 1 .
- step 706 a first etching process is performed to transfer the first pattern and the second pattern into the channel region and staircase region, respectively.
- the first etching process forms a plurality of bit line contact openings in the channel region. Each of the bit line contact openings exposes a respective top channel contact in the channel region.
- the first etching process transfers the second pattern into the staircase region of the memory device to form a plurality of word line trenches.
- step 706 can be performed as illustrated with reference to FIG. 3 .
- a protective layer is formed to accumulate over the bit line contact openings in the channel region.
- the protective layer further fills the bit line contact openings. Due to a microloading effect, the protective layer further uniformly covers the word line trenches formed in the staircase region of the memory device.
- the protective layer can be a polymer that is formed in a same etching chamber to perform the first etching process.
- the protective layer 132 can be formed by applying suitable processing gases, such as C 4 F 6 , C 4 F 8 , CHF 3 , CH 2 F 2 . Process conditions of forming the protective layer are different from process conditions of performing the first etching process.
- the protective layer 132 can include hydrocarbon, fluorocarbon, chlorofluorocarbons (CFCs), or other carbonaceous compounds via dissociation of the processing gases in a deposition plasma generated in the etching chamber.
- the protective layer 132 can be formed in a different processing chamber rather in the etching chamber, such as a CVD processing chamber or a diffusion chamber.
- the protective layer can be formed by applying a chemical vapor deposition (CVD), a hot wire CVD, a parylene polymerization, a plasma enhanced CVD, a plasma assisted CVD, a plasma CVD, a plasma polymerization or a diffusion process.
- step 708 can be performed as illustrated with reference to FIG. 4 .
- step 710 a second etching process is performed.
- the second etching process etches the memory device and transfers the second pattern of the mask stack further into the staircase region of the memory device.
- the channel region is protected by the protective layer, and the word line trenches extend further into the staircase region of the memory device.
- the word line trenches become word line contact openings.
- the word line contact openings extend into the staircase of the memory device and exposes word lines of the memory device.
- step 710 can be performed as illustrated with reference to FIG. 5 .
- a plasma ashing can be applied to remove the mask stack and the protective layer.
- the plasma ashing can be an in-situ process performed in the etching chamber, or an ex-situ process performed in a strip/ash tool.
- an O 2 gas plus a forming gas i.e., 3-20% H 2 in N 2 ) can be applied to remove the mask stack and the remaining protective layer.
- interconnect structures e.g., metallization layers having conductive lines and/or vias
- Such interconnect structures electrically connect the semiconductor device 100 with other contact structures and/or active devices to form functional circuits. Additional device features such as passivation layers, input/output structures, and the like may also be formed.
- a related etching process needs more than one mask layers that increase cost and process complexity.
- the first and the second patterns of the memory device are formed via a single mask layer.
- the first pattern can be formed by an etching process and then protected by an in-situ formed protective (or polymer) layer.
- the etching process subsequently completes formation of the second pattern in the microstructure.
- the protective layer and the mask layer are removed thereafter.
- the disclosure provides a novel etching process that has a low cost and less process complexity by forming patterns with different dimensions in a single mask layer.
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Claims (12)
- Procédé de traitement d'un wafer, comprenant:former un masque (112) sur une microstructure (100), le masque (1123) ayant un premier motif (126) positionné sur une première zone (100b) de la microstructure (100) et un second motif (124) positionné sur une deuxième zone (100a) de la microstructure (100);exécuter un premier processus de gravure, le premier processus de gravure gravant la microstructure (100) conformément aux premier et second motifs formés dans le masque (112) pour transférer les premier et second motifs (126, 124) du masque (112) respectivement dans les première et deuxième zones (100b, 100a) de la microstructure (100);former une couche protectrice (132) sur le premier motif (126) du masque (112) positionnée sur la première zone (100b) de la microstructure (100) à la suite du premier processus de gravure;effectuer un deuxième processus de gravure, le deuxième processus de gravure gravant la microstructure (100) et en outre transférant le deuxième motif (124) du masque (112) dans la deuxième zone (100a) de la microstructure (100); etenlever le masque (112) et la couche protectrice (132) de la microstructure (100), la première zone (100b) de la microstructure (100) étant protégée par la couche protectrice (132) pendant le second processus de gravure, dans lequel la première zone (100b) de la microstructure (100) comprend au moins une zone de canal et comprend une pluralité de contacts de canal supérieurs (122) à l'intérieur d'une couche diélectrique (110),dans lequel l'exécution du premier processus de gravure comprend en outre:transférer le premier motif (126) du masque (112) dans la première zone (100b) afin d'exposer la pluralité de contacts de canal supérieurs (122) et de former une pluralité d'ouvertures de contact de canal (130) dans la couche diélectrique (110); ettransférer le deuxième motif (124) du masque (112) dans la deuxième zone (100a) pour former une pluralité de tranchées dans la couche diélectrique (110), les tranchées comprenant des parties latérales et des parties de fond;et dans lequel la formation de la couche protectrice (132) sur le premier motif (126) du masque (112) comprend:
former la couche protectrice (132) pour remplir la pluralité d'ouvertures de contact de canal (130), la couche protectrice (132) étant en outre accumulée sur une surface supérieure du premier motif (126) du masque (112) et étant formée uniformément le long de parties latérales et de parties de fond des tranchées dans la seconde zone (100a) de la microstructure (100). - Procédé selon la revendication 1, dans lequel la formation du masque (112) sur la microstructure (100) comprend :Former le premier motif (126) du masque (112) sur la première zone (126) ayant une première dimension critique; etformer le deuxième motif (124) du masque (112) sur la deuxième zone (124) ayant une deuxième dimension critique,la première dimension critique étant notamment inférieure à la deuxième dimension critique.
- Procédé selon l'une des revendications 1 à 2, dans lequel la formation de la couche protectrice (132) sur le premier motif (126) du masque (112) comprend l'introduction d'un gaz de traitement pour former la couche protectrice (132), et dans lequel le gaz de traitement contient au moins un élément parmi un élément carboné, un élément hydrogène ou un élément fluor.
- Procédé selon l'une des revendications 1 à 3, dans lequel la formation d'une couche protectrice (132) comprend en outre la formation d'une couche de polymère sur le premier motif (126) du masque positionné sur la première zone (100b) de la microstructure (100).
- Procédé selon l'une des revendications 1 à 4, dans lequel la deuxième zone (100a) de la microstructure (100) comprend une pluralité de lignes de mots (104),
dans lequel, en particulier, la mise en oeuvre du deuxième processus de gravure comprend en outre le transfert du deuxième motif (124) du masque (112) dans la deuxième zone (100a) de la microstructure (100) afin d'exposer la pluralité de lignes de mots (104). - Procédé selon l'une des revendications 1 à 5, dans lequel l'enlèvement du masque (112) et de la couche protectrice (132) de la microstructure (100) comprend l'introduction d'un gaz réactif pour enlever le masque (112) et la couche protectrice (132), le gaz réactif contenant au moins un élément parmi un élément d'oxygène, un élément d'hydrogène ou un élément d'azote.
- Procédé selon l'une des revendications 1 à 6, comprenant en outre:graver les première et deuxième zones (100b, 100a) de la microstructure (100) dans une chambre de gravure, respectivement selon les premier et deuxième motifs (126, 124) dans le masque (112);former la couche protectrice (132) sur le premier motif (126) du masque (112) positionné sur la première zone (100b) de la microstructure (100) dans la chambre de gravure pour protéger la première zone (100b);g etgraver la deuxième zone (100a) de la microstructure (100) dans la chambre de gravure selon le deuxième motif (124) dans le masque (112).
- Procédé selon l'une des revendications 1 à 6, dans lequel les premier et deuxième processus de gravure sont réalisés dans une première chambre de traitement et la couche de protection est formée dans une deuxième chambre de traitement.
- Procédé selon la revendication 1, notamment pour la fabrication d'un dispositif de mémoire,dans lequel la microstructure est une structure de mémoire (100) formée sur un substrat (102) et comprenant au moins la zone de canal (100b) en tant que première zone de la microstructure et une zone de ligne de mot (100a) en tant que deuxième zone de la microstructure, dans lequel l'exécution du deuxième processus de gravure comprend la formation d'une pluralité d'ouvertures de contact de ligne de mot (136) dans la zone de ligne de mot (100a) par le second processus de gravure; etdans lequel l'enlèvement du masque (112) et de la couche protectrice (132) de la microstructure (100) comprend l'enlèvement du masque et de la couche protectrice de la zone de canal.
- Procédé selon la revendication 9, dans lequel les premier et deuxième processus de gravure et la formation de la couche protectrice sont effectués dans la même chambre de traitement, ou
dans lequel les premier et deuxième processus de gravure sont réalisés dans une première chambre de traitement et la couche protectrice est formée dans une deuxième chambre de traitement. - Procédé selon la revendication 9 ou 10, dans lequel la couche protectrice contient au moins un élément parmi un élément de carbone, un élément d'hydrogène ou un élément de fluor.
- Procédé selon la revendication 1, en particulier pour la fabrication d'un dispositif de mémoire NAND 3D,dans lequel la microstructure est une structure NAND 3D (100) formée sur un substrat (102) et comprenant la zone de canal (100b) en tant que première zone de la microstructure et une zone en escalier (100a) en tant que deuxième zone de la microstructure, la zone en escalier (100a) comprenant une pluralité de lignes de mots (104) empilées dans une configuration en escalier, le masque (112) étant un empilement de masques (112) comprenant une ou plusieurs couches;dans lequel le premier motif (126) dans le masque (112) a une dimension critique (CD) plus petite que le second motif (124);dans lequel, dans le second processus de gravure, le procédé comprend la gravure de la structure NAND 3D (100) pour transférer en outre le second motif (124) du masque (112) dans la zone en escalier (100a), le second motif (124) du masque (112) étant transféré dans la zone en escalier (100a) pour exposer la pluralité de lignes de mots (104) et former une pluralité d'ouvertures de contact de lignes de mots (136) dans la zone en escalier (100a); etdans lequel les premier et deuxième processus de gravure et la formation de la couche protectrice (132) sont de préférence effectués dans la même chambre de traitement.
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- 2019-02-11 CN CN201980000316.1A patent/CN109952645B/zh active Active
- 2019-02-11 JP JP2021530278A patent/JP7235864B2/ja active Active
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- 2019-03-27 US US16/365,734 patent/US11062913B2/en active Active
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US11062913B2 (en) | 2021-07-13 |
JP7235864B2 (ja) | 2023-03-08 |
TWI681551B (zh) | 2020-01-01 |
EP3853904A1 (fr) | 2021-07-28 |
US20200258757A1 (en) | 2020-08-13 |
US20210287914A1 (en) | 2021-09-16 |
KR20210083323A (ko) | 2021-07-06 |
JP2022511446A (ja) | 2022-01-31 |
US11631592B2 (en) | 2023-04-18 |
EP3853904A4 (fr) | 2022-05-25 |
WO2020163979A1 (fr) | 2020-08-20 |
CN109952645B (zh) | 2022-03-15 |
CN109952645A (zh) | 2019-06-28 |
KR102629727B1 (ko) | 2024-01-25 |
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