EP3411464B1 - Waschmittelzusammensetzungen zur reinigung in der kosmetischen und pharmazeutischen industrie - Google Patents

Waschmittelzusammensetzungen zur reinigung in der kosmetischen und pharmazeutischen industrie Download PDF

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Publication number
EP3411464B1
EP3411464B1 EP17707631.2A EP17707631A EP3411464B1 EP 3411464 B1 EP3411464 B1 EP 3411464B1 EP 17707631 A EP17707631 A EP 17707631A EP 3411464 B1 EP3411464 B1 EP 3411464B1
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Prior art keywords
detergent composition
fatty alcohols
composition
use according
chosen
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English (en)
French (fr)
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EP3411464A1 (de
Inventor
Gaétan Rauwel
Jacques Criquelion
Stéphane TERRIER
Bertrand Letartre
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Ecolab USA Inc
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Ecolab USA Inc
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/10—Cleaning involving contact with liquid with additional treatment of the liquid or of the object being cleaned, e.g. by heat, by electricity or by vibration
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3409—Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines

Definitions

  • the present invention relates to the use of detergent compositions for cleaning manufacturing equipment, packaging or any other equipment used in the manufacture or packaging of hydrophobic cosmetic or pharmaceutical preparations.
  • the invention also relates to such detergent compositions as such.
  • Manufacturing and packaging equipment as well as any other equipment used in the manufacture and packaging of cosmetic and pharmaceutical products are generally cleaned using a dynamic system with turbulence.
  • dynamic systems include in particular "cleaning in place” (CIP, in English “clean in place” or CIP), soaking with strong agitation, washing in a closed circuit via washing balls, cleaning in washer and cleaning in washing cabin.
  • These cleaning systems require specific non-foaming detergents to prevent the formation of foam due to the turbulence created in the system.
  • These detergents are generally strongly alkaline and therefore contain significant amounts of alkali hydroxide as well as surfactants and sequestering and antiflocculation agents.
  • the European patent application EP 1,200,544 describes for example an alkaline detergent for the elimination of residues containing pigments appearing during the manufacture or packaging of pharmaceutical or cosmetic products.
  • This detergent contains surfactants, in particular nonionic such as alkoxylated fatty alcohols, alkylpolyglucosides and / or alkoxylated fatty amines, and a combination of polyaspartic acid and gluconic acid or of their salts as complexing agents.
  • this detergent does not allow the removal of highly hydrophobic residues from production and packaging facilities. which represents a major drawback today due to the fact that cosmetic products such as for example foundations, mascaras, lipsticks are more and more hydrophobic and rich in pigments, in particular in oxides such as for example in titanium oxide.
  • a detergent composition for removing stains of oxidized grease adhering to the surfaces of floors, walls and kitchen implements containing a nonionic surfactant based on an amine oxide.
  • a nonionic surfactant based on an amine oxide improves the detergent power and at the same time acts as a solubilizing agent for the water-insoluble organic solvent also contained in the detergent composition.
  • this document also teaches that when the content of the amine oxide surfactant is less than 20% by weight, the detergency is insufficient to remove stains of oxidized fat or persistent stains of denatured fat.
  • a detergent composition which is based on the combination of a non-ionic surfactant, a co-surfactant and a specifically chosen organic alkaline agent. for its ability to effectively remove a wide range of hydrophobic residues typically encountered in the manufacture and packaging of cosmetic and pharmaceutical preparations.
  • residues can for example be finished products, such as foundations, sunscreens, lipsticks, mascaras, toothpastes, etc., semi-finished products such as bases for foundation, creams, etc. or raw materials such as for example gels and silicones, volatile or not, containing modified clays such as hectorite and its derivatives.
  • This specific combination of a nonionic surfactant, a co-surfactant and an organic alkaline agent makes it possible to effectively remove even extremely hydrophobic residues, containing or not containing pigments, from manufacturing and packaging facilities. as well as any other material used in the manufacture or packaging of cosmetic or pharmaceutical preparations. These other materials include in particular stainless steel buckets, spatulas, transfer and suction pipes, transfer and suction pumps, dosing nozzles, filling nozzles for packaging lines.
  • a detergent based on this combination specific removes a wide range of different residues such as foundation, lipsticks, waterproof mascaras, toothpastes, extremely hydrophobic raw materials containing pigments such as for example modified clays such as hectorite and its derivatives, in particular bentones.
  • the alkoxylated nonionic surfactant chosen from alkoxylated fatty alcohols is a mixture of several alkoxylated fatty alcohols. Such a mixture contains ethoxylated, propoxylated, butoxylated and optionally pentoxylated fatty alcohols.
  • the alkoxylated fatty alcohol (s) are alkoxylated branched C5 to C11 fatty alcohols.
  • a preferred nonionic surfactant of the invention contains a mixture of ethoxylated, propoxylated, butoxylated and optionally pentoxylated branched C5 to C11 fatty alcohols.
  • the short branched chain confers a high critical micellar concentration (CMC), thus limiting the formation of micelles at low doses (availability of surfactants for detergency), the hydrophilic part, composed of d oxide units.
  • CMC critical micellar concentration
  • the hydrophilic part composed of d oxide units.
  • the steric hindrance resulting from the presence of butylene oxide contributes to stabilizing this surfactant in an acaline medium.
  • These surfactants combine a high wetting power with a very low foaming effect and are also biodegradable.
  • nonionic surfactants which are particularly suitable for the present invention are the alkoxylated fatty alcohols sold by the company BASF (Ludwigshafen, Germany) under the name Plurafac® LF, in particular Plurafac® LF 305, Plurafac® LF 120 and Plurafac® LF 711.
  • the alkoxylated nonionic surfactant is advantageously contained in the detergent composition in an amount of 3 to 20%, preferably 5 to 15%, more preferably 5 to 10% and more preferably still about 10% by weight relative to the total weight of the composition.
  • the non-aromatic co-surfactant is chosen from amine-oxides, alkylsulphates and alkylsulphonates.
  • the amine oxides include in particular C10 to C16 alkyl dimethyl amine oxides.
  • a preferred amine oxide is N, N-dimethyl decyl amine oxide, sold for example under the name Ammonyx® DO40 by the company Stepan (Stepan Europe, Voreppe, France).
  • For the alkylsulphates and alkylsulphonates they may in particular be sodium, potassium or ammonium, preferably sodium, sulphates and sulphonates.
  • Alkyl sulphates include in particular C 6 to C 10 alkyl sulphates.
  • alkylsulfate is 2-ethylhexylsulfate, sold under the name EMPICOL® 0585 / U (Huntsman).
  • Alkylsulfonates include in particular C6 to C8 alkylsulfonates.
  • An example of such a commercial alkylsulfonate is BIO-TERGE® PAS-7S marketed by the company Stepan (Stepan Europe, Voreppe, France).
  • the non-aromatic co-surfactant is contained in the detergent composition in an amount of 1 to 15%, preferably 3 to 10%, more preferably 3 to 6% and more preferably still about 6% by weight relative to the total weight of the composition.
  • an organic alkaline agent chosen from amino alcohols, excluding monoethanolamine, has the advantage of providing a reserve of alkalinity without damaging materials sensitive to corrosion or exhibiting a strong tendency to carbonation.
  • an organic alkaline agent chosen from amino alcohols, excluding monoethanolamine, has the advantage of providing a reserve of alkalinity without damaging materials sensitive to corrosion or exhibiting a strong tendency to carbonation.
  • chosen from triethanolamine and 2-amino-2-methyl-1-propanol more preferably the aminoalcohol is triethanolamine.
  • the organic alkaline agent chosen from amino alcohols is advantageously contained in the detergent composition in an amount of 5 to 50%, preferably 10 to 40% and more preferably still from 15 to 30% by weight relative to the total weight of the product. composition.
  • the detergent composition used in accordance with the invention may further comprise an aromatic hydrotrope.
  • This hydrotropic agent aromatic can for example be chosen from xylenesulphonates, toluenesulphonates and cumenesulphonates. They can in particular be sodium, potassium or ammonium sulphonates, preferably sodium. Xylenesulphonates being preferred since they make it possible to monitor the concentration of the detergent, in particular in the rinsing water, by HPLC. Those skilled in the art will know how to adapt the amount of aromatic hydrotrope as a function in particular of the amounts of organic alkaline agent and of alkoxylated nonionic surfactants employed.
  • the detergent composition used in accordance with the invention may further comprise an alkali hydroxide.
  • the detergent composition comprises less than 5%, more preferably less than 3% and more preferably still less than 2% by weight of alkali hydroxide relative to the total weight of the detergent composition.
  • the alkaline hydroxide can in particular be chosen from sodium hydroxide and potassium hydroxide.
  • the detergent composition used in accordance with the invention may further comprise other adjuvants such as, for example, third solvents, such as propylene glycol or ethylene glycol, and / or antiflocculant agents.
  • the antiflocculant agents can for example be phosphonic acids and their alkali metal salts (phosphonates), such as, for example, 1-hydroxy-ethane-1,1-diphosphonic acid, aminotrismethylene-phosphonic acid, ethylenediaminotetramethylene-phosphonic acid, phosphonobutanetricarboxylic acid, diethylenetriamine penta (methylene phosphonic acid; or homo-, co- or terpolymers based on acrylic acid or alkali metal salts thereof (polyacrylates).
  • phosphonic acids and their alkali metal salts phosphonates
  • phosphonates such as, for example, 1-hydroxy-ethane-1,1-diphosphonic acid, aminotrismethylene-phosphonic acid, ethylenediaminotetramethylene-phosphonic
  • the ready-to-use detergent composition generally has a pH of 7 to 13, preferably 8 to 12.
  • the detergent composition contains neither polyaspartic acid nor gluconic acid or one of their salts.
  • the detergent composition is advantageously used at a temperature of 40 to 85 ° C, preferably from 55 to 70 ° C, more preferably from 60 to 70 ° C and more preferably around 65 ° C.
  • the detergent composition is used in a dynamic cleaning system with turbulence.
  • the dynamic cleaning system with turbulence is chosen from cleaning in place, soaking with agitation, washing in a closed circuit via washing balls, cleaning in a washer and cleaning in the washing cabin.
  • the present invention also relates to the detergent composition used in the use according to the invention as described above.
  • This composition may be in the form of a concentrate to be diluted with water, preferably softened, demineralized or osmosed, before use or in the form of a ready-to-use solution.
  • Figure 4 Photos of whitening toothpaste residues before and after the performance test with KOPHANIOS CIP MAXI PP (Laboratoires Anios) and composition C7 according to the invention.
  • compositions with amine oxide A.1. Compositions with amine oxide
  • Table 1 gives the composition of nine of these compositions, the other two compositions were respectively KOPHANIOS CIP MAXI PP (Laboratoires Anios, Hellemmes, France) and the detergent of Example 3 of the patent application EP 1,200,544 .
  • compositions with alkylsulfate or alkylsulfonate are provided with alkylsulfate or alkylsulfonate
  • the detergency is quantified by visual assessment (remaining product, traces, shine, etc.).
  • composition C7 is clearly more efficient than the reference product KOPHANIOS CIP MAXI PP on all the residues tested and composition C9 shows performances of the same level as those of composition C7.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Claims (15)

  1. Verwendung einer Reinigungsmittelzusammensetzung zur Entfernung von hydrophoben Rückständen, gegebenenfalls umfassend Pigmente, von Herstellungseinrichtungen, von Verpackungseinrichtungen oder von irgendeinem anderen Material, das zur Herstellung oder Verpackung von kosmetischen oder pharmazeutischen Präparaten dient, wobei die Reinigungsmittelzusammensetzung umfasst
    - ein nichtionisches Tensid ausgewählt aus den alkoxylierten Fettalkoholen,
    - ein nichtaromatisches Cotensid, ausgewählt aus den Aminoxiden, den Alkylsulfaten und den Alkylsulfonaten, und
    - ein organisches alkalisches Mittel, ausgewählt aus den Aminoalkoholen, ausgenommen Monoethanolamin,
    wobei das nichtionische Tensid eine Mischung aus alkoxylierten Fettalkoholen ist, enthaltend ethoxylierte, propoxylierte und butoxylierte Fettalkohole, und wobei der Gehalt an nichtaromatischem Cotensid in der Reinigungsmittelzusammensetzung in einer Menge von 1 bis 15 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung enthalten ist.
  2. Verwendung nach Anspruch 1, dadurch gekennzeichnet, dass das nichtionische Tensid eine Mischung aus alkoxylierten Fettalkoholen ist, enthaltend ethoxylierte, propoxylierte, butoxylierte und pentoxylierte Fettalkohole.
  3. Verwendung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass das nichtaromatische Cotensid ein Aminoxid, vorzugsweise ein N,N-Dimethyl-C10 bis C16-alkylaminoxid, noch bevorzugter N,N-Dimethyldecylaminoxid ist.
  4. Verwendung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass das aus den Aminoalkoholen ausgewählte organische alkalische Mittel Triethanolamin ist.
  5. Verwendung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Reinigungsmittelzusammensetzung ferner ein aromatisches Hydrotrop umfasst.
  6. Verwendung nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Reinigungsmittelzusammensetzung weniger als 5 Gewichts-% alkalisches Hydroxid bezogen auf das Gesamtgewicht der Reinigungsmittelzusammensetzung umfasst.
  7. Verwendung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass die Reinigungsmittelzusammensetzung bei einer Temperatur von 40 bis 85 °C eingesetzt wird.
  8. Verwendung nach einem der Ansprüche 1 bis 7, bei der die Reinigungsmittelzusammensetzung in einem dynamischen Reinigungssystem mit Turbulenzen eingesetzt wird.
  9. Verwendung nach Anspruch 8, bei der das dynamische Reinigungssystem mit Turbulenzen ausgewählt ist aus der Reinigung an Ort und Stelle, dem Einweichen unter Rühren, dem Waschen in einem geschlossenen Kreislauf über Waschkugeln, der Reinigung in einer Waschmaschine und der Reinigung in einer Waschkabine.
  10. Reinigungsmittelzusammensetzung, umfassend:
    - ein nichtionisches Tensid, ausgewählt aus den alkoxylierten Fettalkoholen,
    - ein nichtaromatisches Cotensid, ausgewählt aus den Aminoxiden, den Alkylsulfaten und den Alkylsulfonaten, und
    - ein organisches alkalisches Mittel, ausgewählt aus den Aminoalkoholen, ausgenommen Monoethanolamin,
    wobei das nichtionische Tensid eine Mischung aus alkoxylierten Fettalkoholen ist, enthaltend ethoxylierte, propoxylierte und butoxylierte Fettalkohole, und wobei der Gehalt an nichtaromatischem Cotensid in der Reinigungsmittelzusammensetzung in einer Menge von 1 bis 15 Gewichts-% bezogen auf das Gesamtgewicht der Zusammensetzung enthalten ist.
  11. Reinigungsmittelzusammensetzung nach Anspruch 10, dadurch gekennzeichnet, dass das nichtionische Tensid eine Mischung aus alkoxylierten Fettalkoholen ist, enthaltend ethoxylierte, propoxylierte, butoxylierte und pentoxylierte Fettalkohole.
  12. Zusammensetzung nach Anspruch 10, dadurch gekennzeichnet, dass das nichtaromatische Cotensid ein Aminooxid, vorzugsweise ein N,N-Dimethyl-C10 bis C16-alkylaminoxid, noch bevorzugter N,N-Dimethyldecylaminoxid ist.
  13. Zusammensetzung nach einem der Ansprüche 10 bis 12, dadurch gekennzeichnet, dass das aus den Aminoalkoholen ausgewählte organische alkalische Mittel Triethanolamin ist.
  14. Zusammensetzung nach einem der Ansprüche 10 bis 13, dadurch gekennzeichnet, dass die Reinigungsmittelzusammensetzung ferner ein aromatisches Hydrotrop umfasst.
  15. Zusammensetzung nach einem der Ansprüche 10 bis 14, dadurch gekennzeichnet, dass die Reinigungsmittelzusammensetzung weniger als 5 Gewichts-% alkalisches Hydroxid bezogen auf das Gesamtgewicht der Reinigungsmittelzusammensetzung umfasst.
EP17707631.2A 2016-02-05 2017-02-03 Waschmittelzusammensetzungen zur reinigung in der kosmetischen und pharmazeutischen industrie Active EP3411464B1 (de)

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PL17707631T PL3411464T3 (pl) 2016-02-05 2017-02-03 Kompozycje detergentowe do czyszczenia w przemyśle kosmetycznym i farmaceutycznym

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FR1650928A FR3047488B1 (fr) 2016-02-05 2016-02-05 Compositions detergentes pour le nettoyage dans l'industrie cosmetique et pharmaceutique.
PCT/FR2017/050254 WO2017134404A1 (fr) 2016-02-05 2017-02-03 Compositions détergentes pour le nettoyage dans l'industrie cosmétique et pharmaceutique

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EP3411464A1 EP3411464A1 (de) 2018-12-12
EP3411464B1 true EP3411464B1 (de) 2020-09-30

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US (3) US11685878B2 (de)
EP (1) EP3411464B1 (de)
JP (2) JP6756841B2 (de)
CN (1) CN109477036B (de)
FR (1) FR3047488B1 (de)
MX (1) MX2018009450A (de)
PL (1) PL3411464T3 (de)
WO (1) WO2017134404A1 (de)

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FR3047488B1 (fr) * 2016-02-05 2020-02-28 Laboratoires Anios Compositions detergentes pour le nettoyage dans l'industrie cosmetique et pharmaceutique.

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US11746305B2 (en) 2023-09-05
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FR3047488B1 (fr) 2020-02-28
JP6756841B2 (ja) 2020-09-16
JP6883134B2 (ja) 2021-06-09
CN109477036B (zh) 2021-10-08
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US20180334638A1 (en) 2018-11-22
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