EP3026082A1 - Composition de résine thermoplastique présentant une excellente résistance chimique et une transparence, procédé pour sa préparation, et produit moulé la comprenant - Google Patents
Composition de résine thermoplastique présentant une excellente résistance chimique et une transparence, procédé pour sa préparation, et produit moulé la comprenant Download PDFInfo
- Publication number
- EP3026082A1 EP3026082A1 EP15784546.2A EP15784546A EP3026082A1 EP 3026082 A1 EP3026082 A1 EP 3026082A1 EP 15784546 A EP15784546 A EP 15784546A EP 3026082 A1 EP3026082 A1 EP 3026082A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- compound
- resin composition
- graft copolymer
- thermoplastic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 18
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 29
- 239000000126 substance Substances 0.000 title abstract description 32
- -1 methacrylate alkyl ester compound Chemical class 0.000 claims abstract description 139
- 229920005989 resin Polymers 0.000 claims abstract description 93
- 239000011347 resin Substances 0.000 claims abstract description 93
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 78
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 77
- 229920002614 Polyether block amide Polymers 0.000 claims abstract description 26
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 24
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 34
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 27
- 229920001971 elastomer Polymers 0.000 claims description 13
- 239000005060 rubber Substances 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- 238000004898 kneading Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 10
- 229920006026 co-polymeric resin Polymers 0.000 claims description 8
- 239000002537 cosmetic Substances 0.000 claims description 7
- 239000003814 drug Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 5
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 4
- 239000012963 UV stabilizer Substances 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 150000001993 dienes Chemical class 0.000 claims description 3
- 239000003017 thermal stabilizer Substances 0.000 claims description 3
- VTPNYMSKBPZSTF-UHFFFAOYSA-N 1-ethenyl-2-ethylbenzene Chemical compound CCC1=CC=CC=C1C=C VTPNYMSKBPZSTF-UHFFFAOYSA-N 0.000 claims description 2
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 claims description 2
- TVONJMOVBKMLOM-UHFFFAOYSA-N 2-methylidenebutanenitrile Chemical compound CCC(=C)C#N TVONJMOVBKMLOM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000126 latex Polymers 0.000 abstract description 19
- 239000004816 latex Substances 0.000 abstract description 16
- 229940127554 medical product Drugs 0.000 abstract description 11
- 238000003860 storage Methods 0.000 abstract description 9
- 229920001169 thermoplastic Polymers 0.000 abstract description 4
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 30
- 238000002360 preparation method Methods 0.000 description 22
- 230000003247 decreasing effect Effects 0.000 description 21
- 229920001577 copolymer Polymers 0.000 description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- 239000004615 ingredient Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000012467 final product Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000008188 pellet Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- FRQQKWGDKVGLFI-UHFFFAOYSA-N 2-methylundecane-2-thiol Chemical compound CCCCCCCCCC(C)(C)S FRQQKWGDKVGLFI-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 4
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 4
- 239000004926 polymethyl methacrylate Substances 0.000 description 4
- 229920006352 transparent thermoplastic Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000010559 graft polymerization reaction Methods 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 229920006146 polyetheresteramide block copolymer Polymers 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 2
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000000598 endocrine disruptor Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002500 ions Chemical group 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/18—Homopolymers or copolymers of nitriles
- C08L33/20—Homopolymers or copolymers of acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20140132857 | 2014-10-02 | ||
KR1020150078514 | 2015-06-03 | ||
PCT/KR2015/005733 WO2016052832A1 (fr) | 2014-10-02 | 2015-06-08 | Composition de résine thermoplastique présentant une excellente résistance chimique et une transparence, procédé pour sa préparation, et produit moulé la comprenant |
Publications (3)
Publication Number | Publication Date |
---|---|
EP3026082A1 true EP3026082A1 (fr) | 2016-06-01 |
EP3026082A4 EP3026082A4 (fr) | 2017-03-29 |
EP3026082B1 EP3026082B1 (fr) | 2018-02-28 |
Family
ID=55630834
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15784546.2A Active EP3026082B1 (fr) | 2014-10-02 | 2015-06-08 | Composition de résine thermoplastique présentant une excellente résistance chimique et une transparence, procédé pour sa préparation, et produit moulé la comprenant |
Country Status (4)
Country | Link |
---|---|
US (1) | US9840618B2 (fr) |
EP (1) | EP3026082B1 (fr) |
CN (1) | CN105658725B (fr) |
WO (1) | WO2016052832A1 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3339367A1 (fr) * | 2016-12-23 | 2018-06-27 | Lotte Advanced Materials Co., Ltd. | Composition de résine thermoplastique résistant aux rayonnements ionisants et article la comprenant |
US20180179314A1 (en) * | 2016-12-22 | 2018-06-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic Resin Composition and Article Manufactured Using the Same |
EP3342818A1 (fr) * | 2016-12-30 | 2018-07-04 | Lotte Advanced Materials Co., Ltd. | Composition de résine thermoplastique et article moulé ainsi produit |
US10472490B2 (en) | 2016-10-25 | 2019-11-12 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article produced thereform |
US10472510B2 (en) | 2016-12-30 | 2019-11-12 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article manufactured using the same |
US10544278B2 (en) | 2016-11-02 | 2020-01-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article produced therefrom |
US11124643B2 (en) | 2016-12-27 | 2021-09-21 | Lotte Chemical Corporation | Thermoplastic resin composition and molded article manufactured therefrom |
US11365304B2 (en) | 2016-12-23 | 2022-06-21 | Lotte Chemical Corporation | Foaming resin composition, preparation method therefor, and foam using same |
US11505674B2 (en) | 2017-11-08 | 2022-11-22 | Lotte Chemical Corporation | Thermoplastic resin composition and molded article produced from same |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102068650B1 (ko) | 2017-01-24 | 2020-01-21 | 주식회사 엘지화학 | 그라프트 공중합체, 이의 제조방법, 이를 포함하는 열가소성 수지 조성물 및 성형품 |
KR102417536B1 (ko) * | 2017-11-01 | 2022-07-05 | 현대자동차주식회사 | 휠 러스트 커버용 열가소성 투명 수지 조성물 및 이의 제조방법 |
WO2020251215A1 (fr) * | 2019-06-13 | 2020-12-17 | 주식회사 엘지화학 | Composition de résine thermoplastique |
KR102474481B1 (ko) | 2019-06-13 | 2022-12-07 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
US20220340747A1 (en) * | 2020-07-23 | 2022-10-27 | Lg Chem, Ltd. | Thermoplastic resin composition and molded article thereof |
TW202212386A (zh) * | 2020-08-11 | 2022-04-01 | 南韓商Lg化學股份有限公司 | 透明熱塑性樹脂及彼之製備方法 |
EP4011971B1 (fr) * | 2020-10-16 | 2024-04-03 | LG Chem, Ltd. | Composition de résine thermoplastique, son procédé de préparation, et produit moulé la comprenant |
JP7417736B2 (ja) * | 2020-10-22 | 2024-01-18 | エルジー・ケム・リミテッド | 熱可塑性樹脂組成物及びそれから製造された成形品 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6673873B1 (en) * | 1999-08-25 | 2004-01-06 | Cyro Industries | Electrostatic-dissipative multipolymer compositions |
US20050032984A1 (en) * | 2001-10-29 | 2005-02-10 | Jeong-Su Choi | Acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency and preparation thereof |
EP1778785A1 (fr) * | 2004-08-19 | 2007-05-02 | LG Chem Ltd. | Compositions de resines thermoplastiques transparentes et leur procede de preparation |
US20100222511A1 (en) * | 2004-03-31 | 2010-09-02 | Techno Polymer Co., Ltd. | Thermoplastic resin composition and resin molding |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6284109A (ja) | 1985-10-09 | 1987-04-17 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物の製造方法 |
US5891962A (en) | 1994-09-20 | 1999-04-06 | Mitsui Chemicals, Inc. | Transparent, rubber-modified styrene resin and production process thereof |
EP0703525B1 (fr) | 1994-09-22 | 2001-12-05 | Aisin Aw Co., Ltd. | Affichage au toucher pour un système d'entrée d'information |
JPH08199008A (ja) | 1995-01-27 | 1996-08-06 | Densen Sogo Gijutsu Center | 低煙・低毒性難燃ポリオレフィンコンパゥンド |
JP3879204B2 (ja) | 1997-11-17 | 2007-02-07 | 石川島播磨重工業株式会社 | 排煙脱硫装置の吸収塔循環ポンプ起動・停止時における吸収剤スラリー流量制御方法及び装置 |
KR100376052B1 (ko) * | 2000-12-12 | 2003-03-15 | 제일모직주식회사 | 영구제전성 투명 열가소성 수지 조성물 |
KR100423873B1 (ko) * | 2001-01-04 | 2004-03-24 | 주식회사 엘지화학 | 압출쉬트용 투명수지 조성물의 제조방법 |
KR100779159B1 (ko) * | 2005-08-30 | 2007-11-28 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 그 제조방법 |
KR100792122B1 (ko) * | 2005-12-19 | 2008-01-04 | 주식회사 엘지화학 | 고경도 열가소성 투명 abs 수지 조성물 |
-
2015
- 2015-06-08 US US14/786,951 patent/US9840618B2/en active Active
- 2015-06-08 EP EP15784546.2A patent/EP3026082B1/fr active Active
- 2015-06-08 WO PCT/KR2015/005733 patent/WO2016052832A1/fr active Application Filing
- 2015-06-08 CN CN201580000726.8A patent/CN105658725B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6673873B1 (en) * | 1999-08-25 | 2004-01-06 | Cyro Industries | Electrostatic-dissipative multipolymer compositions |
US20050032984A1 (en) * | 2001-10-29 | 2005-02-10 | Jeong-Su Choi | Acrylonitrile-butadiene-styrene copolymer transparent resin having superior chemical resistance and transparency and preparation thereof |
US20100222511A1 (en) * | 2004-03-31 | 2010-09-02 | Techno Polymer Co., Ltd. | Thermoplastic resin composition and resin molding |
EP1778785A1 (fr) * | 2004-08-19 | 2007-05-02 | LG Chem Ltd. | Compositions de resines thermoplastiques transparentes et leur procede de preparation |
Non-Patent Citations (1)
Title |
---|
See also references of WO2016052832A1 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10472490B2 (en) | 2016-10-25 | 2019-11-12 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article produced thereform |
US10544278B2 (en) | 2016-11-02 | 2020-01-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article produced therefrom |
US20180179314A1 (en) * | 2016-12-22 | 2018-06-28 | Lotte Advanced Materials Co., Ltd. | Thermoplastic Resin Composition and Article Manufactured Using the Same |
US10787532B2 (en) * | 2016-12-22 | 2020-09-29 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article manufactured using the same |
EP3339367A1 (fr) * | 2016-12-23 | 2018-06-27 | Lotte Advanced Materials Co., Ltd. | Composition de résine thermoplastique résistant aux rayonnements ionisants et article la comprenant |
US10815368B2 (en) | 2016-12-23 | 2020-10-27 | Lotte Advanced Materials Co., Ltd. | Ionizing radiation resistant thermoplastic resin composition and article comprising the same |
US11365304B2 (en) | 2016-12-23 | 2022-06-21 | Lotte Chemical Corporation | Foaming resin composition, preparation method therefor, and foam using same |
US11124643B2 (en) | 2016-12-27 | 2021-09-21 | Lotte Chemical Corporation | Thermoplastic resin composition and molded article manufactured therefrom |
EP3342818A1 (fr) * | 2016-12-30 | 2018-07-04 | Lotte Advanced Materials Co., Ltd. | Composition de résine thermoplastique et article moulé ainsi produit |
US10377892B2 (en) | 2016-12-30 | 2019-08-13 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and molded article produced therefrom |
US10472510B2 (en) | 2016-12-30 | 2019-11-12 | Lotte Advanced Materials Co., Ltd. | Thermoplastic resin composition and article manufactured using the same |
US11505674B2 (en) | 2017-11-08 | 2022-11-22 | Lotte Chemical Corporation | Thermoplastic resin composition and molded article produced from same |
Also Published As
Publication number | Publication date |
---|---|
WO2016052832A1 (fr) | 2016-04-07 |
EP3026082B1 (fr) | 2018-02-28 |
CN105658725A (zh) | 2016-06-08 |
CN105658725B (zh) | 2018-01-19 |
US20170198132A1 (en) | 2017-07-13 |
EP3026082A4 (fr) | 2017-03-29 |
US9840618B2 (en) | 2017-12-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3026082B1 (fr) | Composition de résine thermoplastique présentant une excellente résistance chimique et une transparence, procédé pour sa préparation, et produit moulé la comprenant | |
EP3118258B1 (fr) | Composition de résine thermoplastique, procédé de préparation associé, et produit moulé la comprenant | |
KR101902060B1 (ko) | 내화학성 및 투명성이 우수한 열가소성 수지 조성물, 이의 제조방법 및 이를 포함하는 성형품 | |
KR100852580B1 (ko) | 향상된 특성이 조합된 abs 조성물 | |
EP1778785B1 (fr) | Compositions de resines thermoplastiques transparentes et leur procede de preparation | |
KR100852581B1 (ko) | 향상된 특성이 조합된 abs 조성물 | |
JP4907438B2 (ja) | 機械的物性に優れた光拡散性樹脂組成物 | |
EP3848414B1 (fr) | Composition de résine thermoplastique | |
EP3875534A1 (fr) | Composition de résine thermoplastique | |
EP0271349B1 (fr) | Composition de résine thermoplastique | |
EP3686244B1 (fr) | Composition de résine résistant à la chaleur | |
EP3287492B1 (fr) | Composition de résine thermoplastique et article moulé fabriqué avec celle-ci | |
JP4603653B2 (ja) | 熱可塑性樹脂組成物 | |
KR20190051560A (ko) | 열가소성 수지 조성물 | |
EP3363863B1 (fr) | Résine transparente thermoplastique et son procédé de préparation | |
KR100623009B1 (ko) | 내후성 및 내충격성이 향상된 열가소성 수지의 제조 방법 | |
KR20200042558A (ko) | 열가소성 투명 수지, 이를 포함하는 열가소성 투명 수지 조성물, 이들의 제조방법 및 성형품 | |
JP2007023098A (ja) | 熱可塑性樹脂組成物およびその成形品 | |
EP4011971B1 (fr) | Composition de résine thermoplastique, son procédé de préparation, et produit moulé la comprenant | |
CN107207684B (zh) | 透明热塑性树脂及其制备方法 | |
EP4011973A1 (fr) | Composition de résine thermoplastique et article moulé de celle-ci | |
KR102288289B1 (ko) | 열가소성 수지 조성물 | |
EP3187529A1 (fr) | Composition de résine thermoplastique et produit ainsi formé | |
EP4011957A1 (fr) | Composition de résine thermoplastique | |
EP4011974A1 (fr) | Composition de résine thermoplastique, son procédé de préparation et produit moulé fabriqué à partir de cette dernière |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20151103 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
AX | Request for extension of the european patent |
Extension state: BA ME |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 20170227 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C08L 77/00 20060101ALI20170221BHEP Ipc: C08L 55/02 20060101ALI20170221BHEP Ipc: C08J 5/00 20060101ALI20170221BHEP Ipc: C08F 2/02 20060101ALI20170221BHEP Ipc: C08F 279/02 20060101ALI20170221BHEP Ipc: C08F 2/44 20060101ALI20170221BHEP Ipc: C08L 25/14 20060101ALI20170221BHEP Ipc: C08L 33/12 20060101ALI20170221BHEP Ipc: C08G 69/40 20060101ALI20170221BHEP Ipc: C08L 51/04 20060101AFI20170221BHEP Ipc: C08L 33/04 20060101ALI20170221BHEP |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
DAV | Request for validation of the european patent (deleted) | ||
DAX | Request for extension of the european patent (deleted) | ||
INTG | Intention to grant announced |
Effective date: 20171024 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 974084 Country of ref document: AT Kind code of ref document: T Effective date: 20180315 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602015008470 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 4 |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20180228 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 974084 Country of ref document: AT Kind code of ref document: T Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180528 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180528 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180529 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602015008470 Country of ref document: DE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
26N | No opposition filed |
Effective date: 20181129 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20180630 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180608 Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180630 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180608 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180608 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20190608 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190608 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180228 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20180228 Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20150608 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180628 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230522 Year of fee payment: 9 Ref country code: DE Payment date: 20230522 Year of fee payment: 9 |