EP2943075A1 - Film soluble dans l'eau comestible - Google Patents

Film soluble dans l'eau comestible

Info

Publication number
EP2943075A1
EP2943075A1 EP14701878.2A EP14701878A EP2943075A1 EP 2943075 A1 EP2943075 A1 EP 2943075A1 EP 14701878 A EP14701878 A EP 14701878A EP 2943075 A1 EP2943075 A1 EP 2943075A1
Authority
EP
European Patent Office
Prior art keywords
film
water soluble
water
soluble film
soluble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP14701878.2A
Other languages
German (de)
English (en)
Inventor
David M. Lee
Jennifer L. CHILDERS
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monosol LLC
Original Assignee
Monosol LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monosol LLC filed Critical Monosol LLC
Publication of EP2943075A1 publication Critical patent/EP2943075A1/fr
Pending legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/46—Applications of disintegrable, dissolvable or edible materials
    • B65D65/463—Edible packaging materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/26—Cellulose ethers
    • C08L1/28—Alkyl ethers
    • C08L1/286—Alkyl ethers substituted with acid radicals, e.g. carboxymethyl cellulose [CMC]
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A23L27/33—Artificial sweetening agents containing sugars or derivatives
    • A23L27/34—Sugar alcohols
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/262—Cellulose; Derivatives thereof, e.g. ethers
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/288—Synthetic resins, e.g. polyvinylpyrrolidone
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23P—SHAPING OR WORKING OF FOODSTUFFS, NOT FULLY COVERED BY A SINGLE OTHER SUBCLASS
    • A23P20/00—Coating of foodstuffs; Coatings therefor; Making laminated, multi-layered, stuffed or hollow foodstuffs
    • A23P20/20—Making of laminated, multi-layered, stuffed or hollow foodstuffs, e.g. by wrapping in preformed edible dough sheets or in edible food containers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
    • C08K5/1575—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/90—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in food processing or handling, e.g. food conservation

Definitions

  • the present disclosure relates generally to water-soluble films. More particularly, the disclosure relates to edible water-soluble films comprising a mixture of a first water- soluble polymer, a compatibilizer polymer, and a sugar alcohol plasticizer that is a solid at room temperature.
  • Water-soluble films are well known in the art. Water-soluble films have many applications, including non-edible forms, such as packaging materials, and edible forms, wherein the film itself is or makes up an edible article. Edible films are known for uses such as delivery of therapeutic agents, breath freshening agents, and flavors.
  • One aspect of the disclosure is a water-soluble film including a water-soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film is substantially transparent.
  • Another aspect of the disclosure is a water-soluble film including a water-soluble mixture of polyvinyl alcohol, a compatibilizing agent, xylitol and a second sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film at about 2.0 mils thick completely dissolves in less than 50 seconds, preferably less than 40 and most preferably less than 30 at 23 °C, optionally wherein the compatibilizing agent is
  • Still another aspect of the disclosure is a water-soluble film including a water- soluble mixture of polyvinyl alcohol, a compatibilizing agent, xylitol and a second sugar alcohol plasticizer that is a solid at room temperature, wherein the water-soluble film at about 2.0 mils thick completely dissolves in less than 50 seconds, preferably less than 40 and most preferably less than 30 at 23 °C, and wherein the water-soluble film has a tear strength of at least 400 g/mil, optionally wherein the compatibilizing agent is carboxymethyl cellulose.
  • Still another aspect of the disclosure is a water-soluble film including a water- soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the sugar alcohol plasticizer that is a solid at room temperature is included in the mixture in an amount of about 20 phr or less, and is characterized by a heat of fusion of about 247 J/g or less.
  • Still another aspect of the disclosure is a water-soluble film including a water- soluble mixture of polyvinyl alcohol, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the sugar alcohol plasticizer that is a solid at room temperature is included in the mixture in an amount of about 30 phr, for example about 29 phr to about 31 phr or about 25 phr to about 35 phr.
  • the water-soluble films of each aspect can be thermoformed into a pouch.
  • Figure la is a top view of a Mylar template for determining the percent opacity of water-soluble films illustrating the designation of the five sampling areas, according to the Examples below.
  • Figure lb is a top view of the Mylar template of Figure la for determining the percent opacity of water-soluble films, illustrating the placement of the five sampling areas on the Mylar template.
  • Figure 2 is a plot of the tear strength of water-soluble films vs. the weight percent of xylitol included in the water-soluble films according to Example 1.
  • Figure 3 is a plot of the dissolution time of water-soluble films vs. the weight percent of xylitol included in the water-soluble films according to Example 1.
  • Figure 4 is a contour plot of the tear strengths of PVOH based water-soluble films with different loadings of CMC and xylitol according to Example 1.
  • water-soluble films comprising a water-soluble mixture of a first water-soluble polymer, a polymer compatibilizer (for example a cellulose ether polymer or a modified starch), and a sugar alcohol plasticizer that is a solid at room temperature.
  • the water-soluble films are edible.
  • the water-soluble films of one aspect of the disclosure can be particularly advantageous in that they can be designed such that the transparency of the water-soluble film is maintained for long periods of time.
  • the water- soluble films of the disclosure herein can have one or more other, optional advantages including thermoformability (e.g., into packets) and suitable toughness for use as packaging materials.
  • optional edible embodiments can be designed according to the disclosure herein to have suitable robustness, e.g. for use as packaging.
  • water- soluble films according to one class of embodiments of the disclosure can demonstrate unexpectedly advantageous tear strength and further optionally an unexpectedly
  • substantially transparency refers to a water-soluble film that, when cast to a thickness of about 2.0 mm, has a measured opacity of about 37.0% or less, as determined by an X-RITE SP60 Series Sphere Spectrophotometer X-64 colorimeter as described herein, or substantial equivalent, after storing for at least 30 days.
  • enhanced transparency refers to a water-soluble film according to the disclosure herein that, when cast to a thickness of about 2.0 mils, demonstrates an opacity of 37.0% or less, as determined by an X-RITE SP60 Series Sphere Spectrophotometer X-64 colorimeter as described herein, or substantially equivalent, optionally after storing for at least 30 days.
  • vorable solubility refers to a film according to the disclosure herein that, at about 2.0 mils thick, completely dissolves in less than 50 seconds, preferably less than 40 and most preferably less than 30 seconds in water at 23 °C.
  • good tear strength refers to a tear strength of at least 400 g/mil at 23 °C as measured by an Elmdorf Tearing Tester model number 40043, or equivalent.
  • the terms “wt.%” and “wt%” are intended to refer to the composition of the identified element in “dry” (non water) parts by weight of the entire film (when applicable) or parts by weight of the entire composition enclosed within a pouch (when applicable).
  • the term “phr” is intended to refer to the composition of the identified element in parts per one hundred parts water-soluble PVOH resins.
  • Water-soluble films, optional ingredients for use therein, and methods of making the same are well known in the art.
  • the water-soluble film includes polyvinyl alcohol (PVOH).
  • PVOH is a synthetic resin generally prepared by the alcoholysis, usually termed hydrolysis or saponification, of polyvinyl acetate. Fully hydrolyzed PVOH, wherein virtually all the acetate groups have been converted to alcohol groups, is a strongly hydrogen-bonded, highly crystalline polymer which dissolves only in hot water— greater than about 140 °F (60 °C). If a sufficient number of acetate groups are allowed to remain after the hydrolysis of polyvinyl acetate, the PVOH polymer then being known as partially hydrolyzed, it is more weakly hydrogen-bonded and less crystalline and is soluble in cold water— less than about 50 ° F (10 ° C).
  • An intermediate cold/hot water soluble film can include, for example, intermediate partially-hydrolyzed PVOH (e.g. , with degrees of hydrolysis of about 94% to about 98%), and is readily soluble only in warm water— e.g. , rapid dissolution at temperatures of about 40 °C and greater.
  • intermediate partially-hydrolyzed PVOH e.g. , with degrees of hydrolysis of about 94% to about 98%)
  • thermallyzed PVOH e.g. , with degrees of hydrolysis of about 94% to about 98%)
  • the degree of hydrolysis (DH) of the PVOH included in the water-soluble films of the present disclosure can be about 75% to about 99%. As the degree of hydrolysis is reduced, a film made from the resin will have reduced mechanical strength but faster solubility at temperatures below about 20°C. As the degree of hydrolysis increases, a film made from the resin will tend to be mechanically stronger and the thermoformability will tend to decrease.
  • the degree of hydrolysis of the PVOH can be chosen such that the water- solubility of the resin is temperature dependent, and thus the solubility of a film made from the resin, compatibilizer polymer, and additional ingredients is also influenced. In one class of embodiments the film is cold water-soluble.
  • a cold water-soluble film, soluble in water at a temperature of less than 10 °C can include PVOH with a degree of hydrolysis in a range of about 75% to about 90%, or in a range of about 80% to about 90%, or in a range of about 85% to about 90%.
  • the film is hot water-soluble.
  • a hot water-soluble film is advantageous for edible applications such as water- soluble packets enclosing a hot food item, e.g. oatmeal, cocoa, or soup mix.
  • a hot water- soluble film, soluble in water at a temperature of at least about 60 °C can include PVOH with a degree of hydrolysis of at least about 98%.
  • film-forming, water soluble resins for use in addition to or in an alternative to PVOH can include, but are not limited to modified polyvinyl alcohols, polyacrylates, water- soluble acrylate copolymers, polyvinyl pyrrolidone, pullulan, water-soluble natural polymers including, but not limited to, guar gum, xanthan gum, carrageenan, and starch, water-soluble polymer derivatives including, but not limited to, ethoxylated starch and hydroxypropylated starch, copolymers of the forgoing and combinations of any of the foregoing.
  • the water-soluble polymers can be included in the film composition in an amount in a range of about 30 wt.% to about 90 wt.%, for example.
  • the weight ratio of the amount of the water-soluble polymer as compared to the combined amount of all plasticizers, compatibilizing agents, and secondary additives can be in a range of about 0.5 to about 9, about 0.5 to about 5, or about 1 to 3, or about 1 to 2, for example.
  • Water-soluble polymers for use in the films described herein can be characterized by a viscosity in a range of about 3.0 to about 27.0 cP, or about 3.0 cP to about 15 cP, or about 6.0 to about 10.0 cP.
  • the viscosity of a PVOH polymer is determined by measuring a freshly made solution using a Brookfield LV type viscometer with UL adapter as described in British Standard EN ISO 15023-2:2006 Annex E Brookfield Test method. It is international practice to state the viscosity of 4% aqueous polyvinyl alcohol solutions at 20 °C. All viscosities specified herein in cP should be understood to refer to the viscosity of 4% aqueous polyvinyl alcohol solution at 20 °C, unless specified otherwise.
  • the viscosity of a PVOH polymer is correlated with the weight average molecular weig ht (MW) of the same PVOH polymer, and often the viscosity is used as a proxy for Mw .
  • the weight average molecular weight of the water-soluble polymer can be in a range of about 30,000 to about 175,000, or about 30,000 to about 100,000, or about 55,000 to about 80,000.
  • the molecular weight of the water-soluble polymer is in the range of about 55,000 to about 80,000.
  • a water-soluble film according to the disclosure comprising polymers with molecular weights in the range of about 55,000 to about 80,000, demonstrate enhanced transparency properties. If the molecular weight of the water-soluble polymer is too high, the resulting water-soluble film does not maintain substantial transparency.
  • a water-soluble film including a mixture of PVOH (e.g., about 87.7% hydrolyzed) having a 4% solution viscosity of about 8 cps and 10 phr of sorbitol can demonstrate substantial transparency for 30 days. In contrast, a water-soluble film including a mixture of PVOH (about 87.7% hydrolyzed) having a viscosity of 23 cps and 10 phr of sorbitol demonstrates substantial transparency for only 4 days.
  • Water-soluble films of the present disclosure can include a compatibilizing agent for the sugar alcohol plasticizer that is a solid at room temperature.
  • a compatibilizing agent is a component that when included in the water-soluble film in a range of about 15 phr to about 20 phr (a ratio of about 2: 1 to about 1:2 to the sugar alcohol plasticizer that is a solid at room temperature), results in the water-soluble film maintaining transparency at a sugar alcohol loading that would otherwise cause the water-soluble film to lose transparency.
  • a water-soluble film including a compatibilizing agent is able to maintain a ⁇ % opacity of 2.0% or less for a longer time period than an otherwise identical film that does not include the compatibilizing agent.
  • the compatibilizing agent can be included in the water-soluble films of the present disclosure in a range of about 10 phr to about 25 phr, or in a range of about 13 phr to about 22 phr, or in a range of about 15 phr to about 20 phr.
  • the amount of compatibilizing agent included in the water-soluble film is reduced, the water-soluble film tends to lose transparency.
  • the amount of compatibilizing agent included in the water-soluble film becomes more brittle and has slower dissolution times.
  • Suitable compatibilizers include, but are not limited to, cellulose ethers such as methylcellulose, hydroxypropyl methylcellulose, carboxymethyl cellulose, salts thereof, polysaccharides of pectin, polysaccharides of sodium alginate, modified starches such as acid-modified, hydroxypropylated starches (e.g., Pure-Cote B760 or B790 available from Grain Processing Corporation, Muscatine, Iowa), hydroxyethyl starches (e.g., Ethylex 2035 available from Tate & Lyle Ingredients Americas LLC, 2200 E. Eldorado Street, Decater, IL ), and combinations of any of the foregoing.
  • the compatibilizer comprises sodium carboxymethyl cellulose (CMC).
  • CMC carboxymethyl cellulose
  • degree of substitution refers to the number of hydroxyl groups that have been substituted with a sodium
  • the viscosity of a 2% aqueous solution of CMC is in a range of about 20 to about 80 cP, as measured at 25 °C on a Brookfield LVT viscometer.
  • the compatibilizer comprises a hydroxypropylated starch.
  • the hydroxypropylated starch can have a 9.1% moisture content, a pH of about 6.3, an ash content of 0.20 wt.% and a protein content of 0.173 wt.%.
  • the compatibilizing agent comprises a hydroxyethyl starch. The level of ethoxylation can be from about 2 wt.% to about 3 wt.%, for example, as the total weight of the substituent units divided by the total weight of the polymer.
  • Water-soluble films according to the present disclosure further include sugar alcohol plasticizers that are solids at room temperature.
  • Sugar alcohol plasticizers that are solid at room temperature include, but are not limited to, isomalt, maltitol, sorbitol, xylitol, erythritol, adonitol, dulcitol, pentaerythritol, mannitol and combinations thereof. Suitable sugar alcohols are available from Rochem Intl. (Ronkonkoma, NY), Roquette (Lestrem, France), and Sigma-Aldrich Co, LLC (St. Louis, MO).
  • Sugar alcohol plasticizers that are solid at room temperature can be included in the water-soluble films of the present disclosure in an amount in a range of about 5 phr to about 35 phr, or about 5 phr to about 25 phr, or about 10 phr to about 25 phr, or about 10 phr to about 25 phr, for example 10 phr, 15 phr, 20 phr, 25 phr, or 30 phr.
  • a sugar alcohol plasticizer that is a solid at room temperature can be present in the water-soluble films of the present disclosure in an amount such that the ratio of compatibilizing agent to sugar alcohol plasticizer that is a solid at room temperature is in a range of about 2: 1 to 1:2, for example about 2: 1, about 1.9: 1, about 1.8: 1, about 1.7: 1, about 1.6: 1, about 1.5: 1, about 1.4: 1, about 1.3: 1, about 1.2: 1, about 1.1: 1, about 1: 1, about 0.9: 1, about 0.8: 1, about 0.7: 1, about 0.6: 1 and/or about 0.5: 1.
  • the amount of sugar alcohol included in the water-soluble film increases, the transparency of the water-soluble film becomes more negatively affected.
  • the solubility of the water-soluble film becomes negatively affected. That is, for example, at a constant temperature a film of equal thickness will take longer to dissolve.
  • the sugar alcohol plasticizer that is a solid at room temperature comprises two or more sugar alcohol plasticizers that are solids at room temperature.
  • the two or more sugar alcohol plasticizers can be included in the film composition in any relative amounts.
  • the two or more sugar alcohol plasticizers can be included in the film composition in equal amounts, or one of the sugar alcohol plasticizers that is a solid at room temperature can be a minor impurity in another sugar alcohol plasticizer as provided by a commercial supplier.
  • the sugar alcohol plasticizer that is a solid at room temperature will include one that has a relatively high heat of fusion (e.g. above 247 J/g, or abovel92 J/g) and a second one that has a relatively low heat of fusion (e.g. 247 J/g or less, or 192 J/g or less, respectively).
  • the sugar alcohol plasticizer that is a solid at room temperature is selected from the group consisting of isomalt, maltitol, sorbitol, xylitol, adonitol, mannitol, and combinations thereof, and further optionally the ratio of
  • compatibilizing agent to sugar alcohol present in the water-soluble film is about 2: 1.
  • water-soluble film according to this class of embodiments (including the described ratio of compatibilizing agent to sugar alcohol), cast to about 2.0 mils thick, maintained a ⁇ % opacity of 2.0% or less for at least 4 days longer than water-soluble films of a similar composition except with no compatibilizing agent included, or at least 21 days longer, or at least 25 days longer.
  • the sugar alcohol plasticizer that is a solid at room temperature is selected from the group consisting of isomalt, maltitol, sorbitol, xylitol, adonitol, and combinations thereof, and further optionally the ratio of compatibilizing agent to sugar alcohol present in the water-soluble film is less than 2: 1.
  • Water-soluble films according to this class of embodiments (including the described ratio of compatibilizing agent to sugar alcohol), cast to about 2.0 mils thick, were shown to maintain a ⁇ % opacity of 2.0% or less for at least 12 days longer than water-soluble films of a similar composition except with no CMC included, or at least 19 days longer, or at least 23 days longer, or at least 28 days longer.
  • Unacceptable amounts of cloudiness of the water-soluble film results when a water- soluble film has an opacity of 37.2% or more, 37.3% or more, or 37.4% or more. More unexpectedly, the ability of a given compatibilizing agent/sugar alcohol combination to result in a water-soluble film with enhanced transparency (relative to a film with the same sugar alcohol and no compatibilizing agent) can be predicted based on the heat of fusion of the sugar alcohol. In one class of embodiments enhanced transparency is demonstrated when a sugar alcohol plasticizer that is a solid at room temperature characterized by a heat of fusion of about 247 J/g or less is included in a water-soluble film in an amount of about 20 phr or less, with a compatibilizing agent.
  • Suitable sugar alcohol plasticizers that demonstrate enhanced transparency when included in a water-soluble film with a compatibilizing agent in an amount of about 20 phr or less can include, consist essentially of, or can consist of one or more of isomalt, maltitol, sorbitol, adonitol, and xylitol, and combinations thereof.
  • a water-soluble film comprising 10 phr of xylitol, having a heat of fusion of 247 J/g, demonstrated an opacity of 36.6 after 30 days.
  • a water-soluble film comprising 10 phr of pentaerythritol, having a heat of fusion of 289 J/g, demonstrated an opacity of 38.6 after 30 days and had an undesirable cloudiness.
  • enhanced transparency is demonstrated when a sugar alcohol plasticizer that is a solid at room temperature characterized by a heat of fusion of about 247 J/g or less and has at least two adjacent, non sterically hindered hydroxyl groups in a common plane is included in a water soluble film in an amount of about 20 phr or less.
  • the at least two sterically unhindered adjacent hydroxyl groups in a common plane favors the hydrogen bonding of the hydroxyls of the sugar alcohol with the hydroxyls of PVOH.
  • the hydrogen bonding interactions of the sugar alcohol with the PVOH stabilizes the sugar alcohols in the film formulation, allowing for a greater loading of the sugar alcohols characterized by a heat of fusion of 247 J/g or less.
  • enhanced transparency is demonstrated when a sugar alcohol plasticizer that is a solid at room temperature characterized by a heat of fusion of about 192 J/g or less is included in a water-soluble film in an amount of about 25 phr to about 35 phr, or about 30 phr, with a compatibilizing agent.
  • a sugar alcohol plasticizer that is a solid at room temperature characterized by a heat of fusion of about 192 J/g or less is included in a water-soluble film in an amount of about 25 phr to about 35 phr, or about 30 phr, with a compatibilizing agent.
  • compatibilizing agent in an amount of about 25 phr to about 35 phr , or about 30 phr include, but are not limited to, isomalt, sorbitol, and combinations thereof.
  • isomalt for example, it was shown that a water-soluble film comprising 30 phr of sorbitol, having a heat of fusion of 192 J/g demonstrated an opacity of 35.7 after 30 days.
  • a water-soluble film comprising 30 phr of adonitol, having a heat of fusion of 232 J/g had an opacity of 42.4 after 30 days and had an undesirable cloudy appearance.
  • a sugar alcohol plasticizer that is a solid at room temperature characterized by a heat of fusion of about 192 J/g or less and has at least two adjacent, non sterically hindered hydroxyl groups in a common plane is included in a water soluble film in an amount of about 25 phr to about 35 phr, for example 30 phr.
  • the at least two sterically unhindered adjacent hydroxyl groups in a common plane favors the hydrogen bonding of the hydroxyls of the sugar alcohol with the hydroxyls of PVOH.
  • the hydrogen bonding interactions of the sugar alcohol with the PVOH stabilizes the sugar alcohols in the film formulation, allowing for a greater loading of the sugar alcohols characterized by a heat of fusion of 192 J/g or less.
  • the water-soluble film includes a mixture of PVOH, CMC, xylitol, and sorbitol.
  • the CMC to xylitol ratio can be 3: 1, for example, while the ratio of compatibilizing agent to total sugar alcohol plasticizer that is a solid at room temperature is in the range of about 2: 1 to 1:2.
  • a water-soluble film comprising a 3: 1 CMC to xylitol ratio demonstrated both favorable solubility and good tear strength.
  • vorable solubility refers to a film that, at about 2.0 mils thick, completely dissolves in less than 50 seconds, preferably less than 40 and most preferably less than 30 seconds in water at 23 °C.
  • good tear strength refers to a tear strength of at least 400 g/mil as measured by an Elmdorf Tearing Tester model number 40043, or equivalent as described in the Tear Strength Measurements section below.
  • a water-soluble film including a 3: 1 ratio of CMC to xylitol had a faster rate of dissolution than a water-soluble film including a CMC to xylitol ratio in which the xylitol is the major component.
  • the rate of dissolution of the water-soluble film including a 3: 1 ratio of CMC to xylitol was also comparable to the rate at which a water soluble film of the same composition, except with no CMC, dissolves.
  • the rate of dissolution of a water-soluble film comprising CMC and xylitol would be expected to decrease when the amount of CMC in the water-soluble film increased because CMC has a slower rate of dissolution than xylitol.
  • a water-soluble film comprising a 3: 1 ratio of CMC to xylitol demonstrates an increase in tear strength relative to a water-soluble film comprising either CMC or xylitol alone.
  • Both CMC and xylitol are known to independently reduce the tear strength of water-soluble films comprised of PVOH.
  • the inclusion of both components in a water-soluble film would be expected to compound the individual effects, reducing the tear strength of a PVOH based water soluble film comprising to a level between the PVOH tear strength of a water-soluble film with CMC only and the PVOH tear strength of a water- soluble film with only xylitol.
  • the water-soluble films according to the present disclosure may include other optional additive ingredients including, but not limited to, plasticizers that are liquids at room temperature, surfactants, film formers, antiblocking agents, internal release agents and other functional ingredients, for example in amounts suitable for their intended purpose.
  • Water is recognized as a very efficient plasticizer for PVOH and other polymers; however, the volatility of water makes its utility limited since polymer films need to have at least some resistance (robustness) to a variety of ambient conditions including low and high relative humidity.
  • Glycerin is much less volatile than water and has been well established as an effective plasticizer for PVOH and other polymers.
  • Glycerin or other such liquid plasticizers by themselves can cause surface "sweating" and greasiness if the level used in the film formulation is too high. This can lead to problems in a film such as unacceptable feel to the hand of the consumer and even blocking of the film on the roll or in stacks of sheets if the sweating is not mitigated in some manner, such as powdering of the surface. This could be characterized as over plasticization.
  • too little plasticizer is added to the film the film may lack sufficient ductility and flexibility for many end uses, for example to be converted into a final use format such as pouches.
  • Plasticizers that are liquids at room temperature for use in water-soluble films of the present disclosure include, but are not limited to, glycerol, diglycerol, propylene glycol, ethylene glycol, diethyleneglycol, triethylene glycol, tetraethyleneglycol, polyethylene glycols up to MW 400, 2 methyl 1, 3 propane diol, lactic acid and combinations thereof. As less plasticizer is used, the film becomes more brittle, whereas as more plasticizer is used the film loses tensile strength.
  • Plasticizers that are liquids at room temperature can be included in the water-soluble films in an amount in a range of about 25 phr to about 50 phr, or from about 30 phr to about 45 phr, or from about 35 phr to about 40 phr, for example.
  • surfactants for use in water-soluble films are well known in the art.
  • surfactants are included to aid in the dispersion of the polymer solution upon casting.
  • Suitable surfactants for water-soluble films of the present disclosure include, but are not limited to, dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerol and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of glycerol and propylene glycol, and acetylated esters of fatty acids, and combinations thereof.
  • surfactants can be included in the water-soluble films in an amount of less than about 2 phr, for example less than about 1 phr, or less than about 0.5 phr, for example.
  • a class of embodiments of the water-soluble films according to the present disclosure is characterized by the water-soluble film being edible.
  • the water-soluble film being edible.
  • the water-soluble polymers can include, can consist essentially of, or can consist of one or more of PVOH, modified PVOH, water-soluble natural polymers including, but not limited to, guar gum, xanthan gum, carrageenan, and starch, water-soluble polymer derivatives including, but not limited to, ethoxylated starch and hydroxypropylated starch, copolymers of the forgoing, and combinations of the forgoing.
  • the water-soluble polymer is included in the film composition in the lowest amount possible that will still allow the resulting film to demonstrate acceptable tear strength, solubility, tensile strength, elongation at break, and energy to break.
  • Optional ingredients for inclusion in water-soluble films according to the disclosure include one or more of plasticizers that are liquid at room temperature, surfactants, compatibilizers, co-polymers, and co-film formers, for example.
  • Liquid plasticizers can include, consist essentially of, or consist of one or more of glycerol, diglycerol, propylene glycol, low molecular weight polyethylene glycol (e.g., having a liquid consistency, for example having a molecular weight such as 200, 300, and 600), monoacetin, triacetin, triethyl citrate, and 1,3-butanediol.
  • Surfactants can include, consist essentially of, or consist of dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerol and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of glycerol and propylene glycol, and acetylated esters of fatty acids, for example.
  • Film formers can include, consist essentially of, or consist of one or more of pullulan, pectin, starch, gelatin, sodium alginates and modified starches.
  • Components for inclusion in edible water soluble films can be those designated as "Generally Recognized as Safe” (GRAS) by the United States Food and Drug Administration, and/or components with assigned, allowable E-numbers in the European Union, and/or components that are not yet designated as GRAS or E-numbered but have gone through proper testing and have been demonstrated as safe for human consumption in the amounts proposed for use in the film.
  • GRAS Generally Recognized as Safe
  • Water-soluble films according to the present disclosure can be designed by the disclosure herein to demonstrate excellent practical toughness.
  • excellent practical toughness refers to one or more of tensile strength, elongation at break, and energy to break values that fall within the ranges described herein, optionally a combination of all three of tensile strength, elongation at break, and energy to break values.
  • the water-soluble films according to the present disclosure can have a tensile strength of at least about 10 N/mm 2 , or greater than about 12 N/mm 2 , or greater than about 14 N/mm 2 , or greater than about 16 N/mm 2 as measured on a Model 5543
  • the water-soluble films according to this aspect of the invention can have an elongation at break value of at least about 250%, or greater than about 300%, or greater than about 350%, or greater than about 400% as measured on a Model 5543 Instron® Tensile Tester, or equivalent, as described in the Tensile Strength Measurement section below.
  • the water-soluble films according to this aspect of the invention can have an energy to break of at least about 0.5 J/mm 2 , or greater than about 1.0 J/mm 2 , or greater than about 1.23 J/mm 2 as measured on a Model 5543 Instron® Tensile Tester, or equivalent, as described in the Tensile Strength Measurement section below.
  • a water-soluble film according to the disclosure includes PVOH, a CMC compatibilizing agent and a combination of xylitol and sorbitol as the sugar alcohol plasticizer that is a solid at room temperature, with a CMC to sugar alcohol plasticizer ratio of about 1.1: 1.
  • a water-soluble film according to the disclosure includes PVOH, a modified starch compatibilizing agent and a combination of xylitol and sorbitol as the sugar alcohol plasticizer that is a solid at room temperature, with a compatibilizing agent to sugar alcohol plasticizer ratio of about 1.1: 1.
  • Water-soluble films according to this embodiment demonstrate good dissolution time at 23 °C, for example about 31.4 seconds, good tensile strength, for example about 19.6 N/mm , good elongation to break, for example about
  • the water-soluble films can be formed into a water-soluble packet. Packets may be made using any suitable equipment and method, including the various methods already commonly known in the art.
  • the water-soluble film optionally can be drawn into a suitable mold. Heat can be applied to the water-soluble film during the process, to result in a process commonly known as thermoforming. Water-soluble films according to the present disclosure are heat sealable.
  • heat sealable refers to films that when heat sealed at a temperature in a range of about 275 °F to about 300 °F (135 °C to about 150 °C) do not peel apart by hand without tearing the film and do not show any indications of degradation (i.e., browning or bubbling) when heat sealed in a TS-12 Heat Sealer available from Lako Tool & Manufacturing, Inc of Perrysburg, OH, or equivalent, as described in the Heat Seal
  • the heat sealable water-soluble films have a peak load ratio (i.e. a ratio of the seal peak load to the film peak load) of at least about 0.30, at least about 0.32, at least about 0.35, or at least about 0.36 as determined by measurements taken on a Model 5543 Instron® Tensile Tester, or equivalent, as described in the Tensile Strength Measurement section below.
  • Water-soluble films according to the present disclosure are thermoformable. As used herein, "thermoformable" refers to a water soluble film that has an elongation at about 23 °C and 35% relative humidity of at least about 250%, or at least about 300% and is heat stable.
  • a water soluble film comprising a water soluble mixture of a water soluble resin, a compatibilizing agent, and a sugar alcohol plasticizer that is a solid at room temperature, wherein the water soluble film is substantially transparent.
  • a water soluble film comprising a water soluble mixture of a water soluble resin, a compatibilizing agent, xylitol, and a second sugar alcohol plasticizer that is a solid at room temperature, wherein the water soluble film of about 2.0 mils thick dissolves in less than 50 seconds, preferably less than 40 and most preferably less than 30 at 23 °C, and wherein the compatibilizing agent is carboxymethyl cellulose.
  • the sugar alcohol plasticizer that is a solid at room temperature comprises a mixture of xylitol with at least one member of the group consisting of maltitol, sorbitol, and isomalt.
  • a liquid plasticizer selected from the group consisting of glycerol, diglycerol, propylene glycol, ethylene glycol, diethyleneglycol, triethylene glycol, tetraethyleneglycol, polyethylene glycols up to MW 400, 2 methyl 1,3 propane diol and combinations of the forgoing.
  • the surfactant is selected from the group consisting of dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerol and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of glycerol and propylene glycol, and acetylated esters of fatty acids, and combinations of any of the forgoing.
  • the surfactant is selected from the group consisting of dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerol and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of
  • a water soluble packet comprising a film according to any one of the preceding paragraphs.
  • the films were tested for a change in the percent opacity by an X-RITE SP60 Series Sphere Spectrophotometer X-64 colorimeter, available from X-Rite Incorporated, Grand Rapids, Michigan.
  • the spectrophotometer was calibrated using X-Rite Calibration Standard SP62-162 (L*05.17, a* -1.16, B* -0.20).
  • SP62-162 L*05.17, a* -1.16, B* -0.20
  • a 5" by 5" square of Mylar was cut and the average opacity was determined to be 18.61 by the spectrophotometer.
  • Non-powdered moisture barrier gloves were used when handling the film samples to mitigate moisture contamination of the film samples. Moisture contamination may cause unnatural cloudiness in the film.
  • the films were cast to a nominal 2.0 mil gauge. The samples were cast in ambient conditions and initial data was measured in the ambient environment prior to placement in the testing environment of nominally 23 °C +/- 3 °C (73 °F +/- 5 °F), and 50% RH +/- 5% RH.
  • the Opacity test was selected from the spectrophotometer menu.
  • a double Mylar standard (two plies of 4.75 mil Mylar film over white portion of a Leneta chart 7-5/8" X 10 1 ⁇ 4" 2C B#42201) was loaded into the spectrophotometer. For each of the five spots designated on the film sample swatch, a piece of Mylar film was selected for backing and clipped to the back of the sample being measured. The sample was placed over the black portion of the Leneta chart.
  • This method covers the determination of the average force in grams per mil of specimen thickness required to propagate tearing through a specified length of polyvinyl alcohol (PVOH) film.
  • the force in grams required to propagate tearing across a film is measured using a precisely calibrated pendulum device. Acting by gravity, the pendulum swings through an arc, tearing the specimen from a pre-cut slit. The specimen is held stationary on one side and on the other is fixed to the pendulum. The loss of energy of the pendulum swing is indicated by a pointer on a scale. The scale indication is a function of the force required to tear the specimen.
  • This method is of value in ranking relative tearing resistance of PVOH films.
  • the water-soluble films were evaluated on an Elmendorf Tearing Tester Model # 40043, in accordance with MSTM 107RD Standard Test Method for
  • a beaker was filled with 500 mL of distilled water. The water temperature was measured with a thermometer and, if necessary, heated or cooled to maintain temperature at 10 °C or 23 °C. The height of column of water was marked, and a magnetic stirring rod was added to the beaker. The stir speed was adjusted until a vortex
  • the 35 mm slide mount was secured to a 35 mm slide mount holder such that the long end of the slide mount was parallel to the water surface.
  • the depth adjuster of the holder was set so that when dropped, the end of the clamp was 0.6 cm below the surface of the water.
  • One of the short sides of the slide mount was positioned next to the side of the beaker with the other positioned directly over the center of the stirring rod such that the film surface was perpendicular to the flow of the water.
  • Instron® grips utilized in the test may affect the test results. Consequently, the test was conducted utilizing Instron® grips having model number 2702-032 faces, which are rubber coated and 25 mm wide. Values were used directly from the Instron® Bluehill software version 2.25.796.
  • Instron® grips utilized in the test may affect the test results. Consequently, the test was conducted utilizing Instron® grips having model number 2702-032 faces, which are rubber coated and 25 mm wide. Values were used directly from the Instron® Bluehill software version 2.25.796 for the Energy/ Area methodology.
  • Water-soluble films 1-5 were each comprised of 45 wt PVOH, based on the total weight of the film. 20 wt of the films were comprised of a combination of CMC and xylitol. Water-soluble film 6 contained 65 wt PVOH with no CMC or xylitol, as a control film. The relative amounts of CMC and xylitol were varied over films 1-5. 2.0 mil thick water-soluble films were cast according to formulae 1-5, conditioned for 24 hours, and were tested for tear strength, solubility, tensile strength, elongation at break, and energy to break, as described above. The results are reproduced in the table below.
  • Figure 2 is a plot of the tear strengths vs. the wt xylitol included in the water- soluble films.
  • Figure 3 is a plot of dissolution times vs. the wt xylitol included in the water-soluble films.
  • Figure 4 is a contour plot of the tear strengths of PVOH based water- soluble films with different loadings of CMC and xylitol. As expected, the water-soluble film containing PVOH and CMC with no xylitol, film 1, was found to be brittle and dissolve relatively slowly at 23 °C, relative to the control film 6. This film did show some improved dissolution properties at 10 °C.
  • Film 5 the other extreme, containing PVOH and xylitol with no CMC also was found to have decreased tear strength relative to the control film 6, and increased rate of dissolution, as expected.
  • the tear strength was found to be higher than the tear strength of either film 1 or film 5; however as expected, the tear strength was still less than that of the control film 6.
  • film 2 had the fastest rate of dissolution out of all the films except the xylitol-only film (film 5), which had similar rates of dissolution. This is unexpected because in film 2, CMC is the major component of the CMC/xylitol mixture, and the rate of dissolution would be expected to decrease, that is a film of given thickness would be expected to take longer to dissolve with the higher level of CMC.
  • the film containing 10 phr sorbitol (film 9), the film containing 20 phr sorbitol (film 11) and the film containing 30 phr sorbitol (film 13) remained substantially transparent for at least 30 days.
  • Water-soluble films that contained sorbitol demonstrated poor transparency without CMC at even low sorbitol loadings, and the performance was improved with the introduction of CMC into the film, especially at high sorbitol loadings.
  • maltitol is a disaccharide consisting of a linear and a cyclic unit
  • films that included maltitol had similar transparency properties as films that included the linear monosaccharide, sorbitol.
  • the inclusion of CMC in the films that included maltitol resulted in an increase in the number of days that the films remained substantially transparent.
  • Mannitol, (2R,3R,4R,5R)-hexan-l,2,3,4,5,6-hexol is a stereoisomer of sorbitol, (2 l S',3R,4R,5R)-hexan-l,2,3,4,5,6-hexol.
  • water-soluble films that included sorbitol unlike the water-soluble films that included sorbitol (Example 3), water-soluble films that included mannitol only remained substantially transparent for 9 days, regardless of the loading level of mannitol, or the inclusion of CMC.
  • mannitol and sorbitol are both six carbon, linear sugars of equal molecular weight, the heats of fusion of the two sugar alcohol plasticizers that are solids at room temperature are not similar. Sorbitol has a heat of fusion of 192 J/g and mannitol has a heat of fusion of 301 J/g.
  • the films that included CMC were substantially transparent for up to 30 days, 30 days and 14 days at xylitol loadings of 10, 20, and 30 phr, respectively.
  • xylitol is a five carbon sugar alcohol plasticizer
  • the water-soluble films that include xylitol behaved similar to the water-soluble films that contained the six carbon sugar alcohol plasticizer, sorbitol.
  • sorbitol Example 3, the inclusion of CMC in the films that included xylitol resulted in an increase in the number of days that the films remained substantially transparent.
  • Example 7 An edible water-soluble film was prepared with the ingredients identified below in the amounts shown (phr).
  • Example 7 demonstrates an edible water soluble film according to the invention that has good dissolution time, tensile strength, elongation at break and energy to break.
  • Example 7 includes a cellulose ether as a compatibilizing agent.
  • Example 8 An edible water-soluble film was prepared with the ingredients identified below in the amounts shown (phr).
  • Example 8 like Example 7, demonstrates an edible water soluble film according to the invention that has good dissolution time, tensile strength, elongation at break and energy to break.
  • Example 8 includes a modified starch as a compatibilizing agent.
  • Example 9
  • a water-soluble film was prepared with the ingredients identified below in the amounts shown (phr).
  • Water-soluble packets were made from the water-soluble film according to formula 35.
  • the water-soluble film of the packets had an average thickness of 1.52 mils. Oatmeal was enclosed within the packets.
  • the compatibility of the packets with the oatmeal was tested under three test atmospheres for 42 days.
  • the packets were inserted into high density polyethylene (HDPE) jars and capped, and subjected to one of either: ambient temperature and humidity (about 23 °C and about 30 to 50% relative humidity (RH)); 38 °C and about 80% RH; or 38 °C and about 10% RH.
  • HDPE high density polyethylene
  • a water-soluble film was prepared with the ingredients identified below
  • films according to formulae 38, 39, 40, and 21 having the described amounts of dulcitol, erythritol, pentaerythritol or mannitol as the sugar alcohol plasticizer that is a solid at room temperature demonstrated an undesirable cloudiness.
  • films according to formulae 36, 15, 9, 37, and 27 comprising isomalt, maltitol, sorbitol, or adonitol as a sugar alcohol plasticizer that is solid at room temperature demonstrated an acceptable level of transparency.
  • the undesirable films had opacity values of 37.2% or greater while the desirable films had opacity levels of 36.6% or less.
  • Example 10 shows that in films comprising 10 phr of the sugar alcohol plasticizer that is a solid at room temperature, films wherein the sugar alcohol plasticizer had a heat of fusion of about 247 J/g or less were acceptably transparent and films wherein the sugar alcohol plasticizer had a heat of fusion of about 289 J/g or greater at these loading rates had unacceptable cloudiness.
  • a water-soluble film was prepared with the ingredients identified below in the amounts shown (phr). Component Description 11 41 29 42 43 17 23 44 45
  • PVOH 8 cps 88%DH 100 100 100 100 100 100 100 100 100 100 100 100 100 100
  • films according to formulae 11, 41, and 29 comprising xylitol, isomalt or sorbitol as the sugar alcohol plasticizer that is a solid at room temperature demonstrated an acceptable level of transparency.
  • the undesirable films had opacity values of 37.4% or greater while the
  • films wherein the sugar alcohol plasticizer had a heat of fusion of about 247 J/g or less were acceptably transparent, with the exceptions of the films comprising sugar alcohol plasticizers that are a solid at room temperature with heats of fusion below 247 J/g but do not have two adjacent, sterically unhindered, hydroxyl groups in the same plane, maltitol and adonitol, the films being unacceptably cloudy.
  • films wherein the sugar alcohol plasticizer had a heat of fusion of about 289 J/g or greater at these loading rates were unacceptably cloudy in appearance.
  • a water-soluble film was prepared with the ingredients identified below
  • films according to formulae 47, 48, 19, 31, 49, 50, and 25 having the described amounts of dulcitol, pentaerythritol, maltitol, xylitol, erythritol, adonitol or mannitol as the sugar alcohol plasticizer that is a solid demonstrated an undesirable cloudy appearance.
  • films according to formulae 13 and 46 comprising isomalt or sorbitol as the sugar alcohol plasticizer that is a solid at room temperature demonstrated an acceptable level of transparency.
  • the undesirable films had opacity values of 37.3% or greater while the desirable films had opacity levels of 37.0% or less.
  • Example 12 shows that in films comprising 30 phr of the sugar alcohol plasticizer that is a solid at room temperature, films wherein the sugar alcohol plasticizer had a heat of fusion of about 192 J/g or less were acceptably transparent, with the exception of the film comprising a sugar alcohol plasticizer that are a solid at room temperature with a heat of fusion below 192 J/g but does not have two adjacent, sterically unhindered, hydroxyl groups in the same plane, maltitol, the film being unacceptably cloudy. In contrast, films wherein the sugar alcohol plasticizer had a heat of fusion of about 232 J/g or greater at these loading rates were unacceptably cloudy in appearance.
  • a water-soluble film was prepared with the ingredients identified below in the amounts shown (phr). Component Description 51
  • Example 13 shows that when additional processing aids for antiblocking were added that good tear, tensile and solubility properties and acceptable transparency as visually observed were achieved.
  • a water-soluble film was prepared with the ingredients identified below in the amounts shown (phr). Component Description 52
  • Example 14 shows that acceptable peak load ratios are obtained for films that are heat sealed at a temperature in the range of 275 °F to 300 °F (135 °C to 149 °C).

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Abstract

L'invention concerne des films solubles dans l'eau et les paquets résultants comprenant un film soluble dans l'eau, le film soluble dans l'eau comprenant un mélange soluble dans l'eau d'alcool polyvinylique, d'un agent de compatibilisation et d'un plastifiant d'alcool de sucre qui est un solide à la température ambiante, le film soluble dans l'eau étant substantiellement transparent.
EP14701878.2A 2013-01-11 2014-01-10 Film soluble dans l'eau comestible Pending EP2943075A1 (fr)

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US13/740,053 US10829621B2 (en) 2013-01-11 2013-01-11 Edible water-soluble film
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KR20160065205A (ko) 2013-10-07 2016-06-08 모노졸, 엘엘씨 수용성 지연 방출 캡슐, 관련된 방법, 및 관련된 제품
KR20160065973A (ko) 2013-10-07 2016-06-09 모노졸, 엘엘씨 수용성 지연 방출 캡슐, 관련된 방법, 및 관련된 제품
CN105829427A (zh) 2013-12-06 2016-08-03 蒙诺苏尔有限公司 用于水溶性膜的荧光示踪剂、相关方法和相关物品
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CN107108919A (zh) * 2014-10-03 2017-08-29 蒙诺苏尔有限公司 可降解材料和由可降解材料制造的包装
TWI689547B (zh) 2014-10-13 2020-04-01 美商摩諾索公司 具有塑化劑摻合物的水溶性聚乙烯醇膜、相關方法及相關物品
WO2016061069A2 (fr) 2014-10-13 2016-04-21 Monosol, Llc Film à base de polyvinyle et d'alcool soluble dans l'eau, procédés associés et articles associés
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TWI677525B (zh) 2014-10-13 2019-11-21 美商摩諾索公司 水溶性聚乙烯醇摻合物膜、相關方法及相關物品
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US10829621B2 (en) 2020-11-10
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CN105188403B (zh) 2021-02-26
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US20210087365A1 (en) 2021-03-25
US20140199460A1 (en) 2014-07-17
CN112940312A (zh) 2021-06-11
CA2897577A1 (fr) 2014-07-17
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JP6915017B2 (ja) 2021-08-04
TWI653941B (zh) 2019-03-21
WO2014110356A1 (fr) 2014-07-17
JP6604852B2 (ja) 2019-11-13
KR20150130981A (ko) 2015-11-24
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KR20210031782A (ko) 2021-03-22
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