EP2915845B1 - Polyolefin flame-retardant resin composition and molded article - Google Patents

Polyolefin flame-retardant resin composition and molded article Download PDF

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Publication number
EP2915845B1
EP2915845B1 EP14854897.7A EP14854897A EP2915845B1 EP 2915845 B1 EP2915845 B1 EP 2915845B1 EP 14854897 A EP14854897 A EP 14854897A EP 2915845 B1 EP2915845 B1 EP 2915845B1
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Prior art keywords
flame retardant
phosphate
polyolefin
molded product
resin composition
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EP14854897.7A
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German (de)
English (en)
French (fr)
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EP2915845A4 (en
EP2915845A1 (en
Inventor
Hong Jin Kim
Eung Soo Kim
Jong Su Kim
Soo Min Lee
Yoon Young Kim
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LG Chem Ltd
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LG Chem Ltd
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Priority claimed from KR1020130153074A external-priority patent/KR101697814B1/ko
Priority claimed from KR1020140154108A external-priority patent/KR101703392B1/ko
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Priority to PL14854897T priority Critical patent/PL2915845T3/pl
Publication of EP2915845A1 publication Critical patent/EP2915845A1/en
Publication of EP2915845A4 publication Critical patent/EP2915845A4/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/02—Ingredients treated with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/02—Inorganic materials
    • C09K21/04—Inorganic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/165—Hypophosphorous acid; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/327—Aluminium phosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/003—Additives being defined by their diameter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Definitions

  • the present invention relates to a polyolefin-based flame retardant resin composition and a molded product. More particularly, the present invention relates to a polyolefin-based flame retardant resin composition satisfying flame retardancy standards (in particular, UL94V V-0, V-1, and V-2, an auto ignition property of 15 seconds or less and eco-friendly flame retardancy), improved extrusion properties, a melt index, tensile elongation, or appearance required in use of extruded tube molds and the like for insulation and wiring in electrical and electronic products, and vehicles using a particular phosphate-based flame retardant, and a molded product manufactured from the composition.
  • flame retardancy standards in particular, UL94V V-0, V-1, and V-2, an auto ignition property of 15 seconds or less and eco-friendly flame retardancy
  • improved extrusion properties a melt index, tensile elongation, or appearance required in use of extruded tube molds and the like for insulation and wiring in electrical and electronic products, and vehicles using
  • polyamide As materials applied to a tube system in a vehicle engine room, there are for example polyamide, polyester, and polyethylene resins, and polyolefin resins such as such as polypropylene resins and the like.
  • phosphate based retardants are added in an amount of 20% or more, properties thereof may be realized without use of halogens, heavy metals, and the like.
  • a flame retardant in the phosphate based retardants when compared with conventional halogen-based materials, it is difficult to effectively disperse the flame retardant and, thus, there are limitations in flame retardancy and extrusion properties. Therefore, there is an urgent need for development of a polyolefin-based flame retardant resin composition which may resolve these problems.
  • US 2013/059956 A1 discloses a composition comprising 90 wt% of polypropylene and 10 wt% of the aluminum salt of methylmethylphosphonic acid.
  • the methylmethylphosphonic acid has an average particle size of less than 5 ⁇ m, the respective composition is useful for making molded automotive parts.
  • US 2012/205136 A1 discloses a molded article made from a flame-retardant resin composition. Further, a flame retardant resin composition is disclosed comprising 58 wt% of a polyolefin resin, 30 wt% of a metal phosphinate and 6 wt% of a liquid phosphate ester-based compound.
  • US 6,124,394 A discloses a fire-retardant tablet which is produced by tableting a fire-retardant mixture containing heat-expandable graphite, and a water-soluble fire-retardant synergist or one containing additionally water-insoluble fire-retardant synergist.
  • US 2013/274390 A1 discloses an integrated molded product comprising a thermoplastic resin molded product, additional reaction type silicone-based composition, and a member, the thermoplastic resin molded product comprising a pentavalent phosphorous compound, and the thermoplastic molded product being in contact with the additional reaction type silicone-based composition.
  • US 2005/250908 A1 discloses a polymer melt additive composition in the form of a powder for use as an additive in the melt processing of a host polymer, the polymer melt additive composition comprising particles of fibrillating polytetrafluoroethylene and an effective amount of a fluorothermoplast to prevent agglomeration of said particles of polytetrafluoroethylene.
  • the present invention has been made in view of the above problems, and it is one object of the present invention to provide a molded product having improved flame retardancy, extrusion properties, and superior appearance by expressing Char foaming as a flame retardant mechanism of conventional phosphate-based flame retardants and runaway effects of dripping behavior at a gas phase together while applying a smaller amount of a particular phosphate-based flame retardant than conventional phosphate-based flame retardants, with regard to a polyolefin-based flame retardant resin composition used in extruded tubes and the like for insulation and wiring of electrical and electronic products and vehicles.
  • a polyolefin-based flame retardant resin composition comprising 50 to 80 wt% of a polyolefin resin, a phosphate-based flame retardant, and 0.1 to 5 wt% of a surface-modified fluorine resin powder based on 100 wt% in total of ingredients constituting the composition
  • the phosphate-based flame retardant comprises 15 to 40 wt% of a solid phase phosphate flame retardant and 0.1 to 15 wt% of a liquid-type phosphate ester flame retardant based on 100 wt% in total of ingredients constituting the composition
  • the surface-modified fluorine resin powder has a weight-average molecular weight of 100,000 g/mol or more and is prepared by extruding 0.1 to 90 wt% of surface-modified polytetrafluoroethylene having an average particle diameter of 10 ⁇ m or less and 10 to 99.9 wt% of a high molecular weight
  • a product molded from the composition is provided.
  • eco-friendly flame retardancy of a polyolefin resin according to the present invention is realized using a phosphate-based flame retardant.
  • a phosphate-based flame retardant a particular solid phase flame retardant having satisfactory dispersibility, thermal stability at high temperature as a result of thermal gravity analysis (TGA), and superior long-term thermal resistance is added in a relatively small amount.
  • TGA thermal gravity analysis
  • a molded product having improved flame retardancy, extrusion properties, and appearance may be provided.
  • eco-friendly flame retardancy of the polyolefin resin is realized using a phosphate flame retardant.
  • a loading amount due to application of the phosphate flame retardant becomes excessive and, thus, effective flame retardant dispersion becomes difficult, thereby deteriorating flame retardancy and extrusion properties.
  • liquid-type phosphate ester is applied, thereby improving flame retardancy and appearance quality.
  • a polypropylene flame retardant resin composition having optimized polymer fluidity and melt strength through application of a surface-modified fluorine resin powder suitable for tube extrusion molding, a extrusion tubing molded product having improved flame retardancy and extrusion properties may be provided while realizing eco-friendliness.
  • FIG. 1 is a graph comparing a smooth dynamic TGA peak of a solid phase phosphate-based flame retardant of Example 1 according to the present invention and a rapid dynamic TGA peak of a conventional solid phase phosphate-based flame retardant used in Comparative Example 2.
  • a polyolefin-based flame retardant resin composition comprising 50 to 80 wt% of a polyolefin resin, a phosphate-based flame retardant, and 0.1 to 5 wt% of a surface-modified fluorine resin powder based on 100 wt% in total of ingredients constituting the composition
  • the phosphate-based flame retardant comprises 15 to 40 wt% of a solid phase phosphate flame retardant and 0.1 to 15 wt% of a liquid-type phosphate ester flame retardant based on 100 wt% in total of ingredients constituting the composition
  • the surface-modified fluorine resin powder has a weight-average molecular weight of 100,000 g/mol or more and is prepared by extruding 0.1 to 90 wt% of surface-modified polytetrafluoroethylene having an average particle diameter of 10 ⁇ m or less and 10 to 99.9 wt% of a high molecular weight polypropylene resin
  • solid phase phosphate flame retardant used in the present invention, so long as not specified otherwise, means a phosphate flame retardant that is a solid at room temperature.
  • the solid phase phosphate flame retardant may be at least one selected from triphenyl phosphate, diphenyl cresyl phosphate, ammonium polyphosphate, melamine polyphosphate, melamine pyrophosphate, melamine ammonium phosphate, piperazine pyrophosphate, piperazine phosphate, piperazine polyphosphate, piperazine pyrophosphate-phosphate-zinc oxide, 2-carboxyethyl phenyl phosphinic acid, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, and 10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide.
  • the solid phase phosphate flame retardant may be at least one selected from ammonium polyphosphate, melamine polyphosphate, melamine pyrophosphate, piperazine polyphosphate, and triphenyl phosphate.
  • the solid phase phosphate flame retardant may comprise an effective N-P-based ingredient as a white powder, other synergists, flame retardant aids, and the like.
  • the solid phase phosphate flame retardant may be water treated, and pre-treated through coating or the like to increase reaction efficiency.
  • liquid-type phosphate ester used in the present invention, so long as not specified otherwise, means phosphate ester in a liquid state at room-temperature (20 °C) under atmospheric pressure.
  • the liquid-type phosphate ester may smooth a surface by improving dispersibility of the solid phase phosphate flame retardant and decrease a use amount of the solid phase phosphate flame retardant by increasing dispersion force.
  • the liquid-type phosphate ester may be at least one selected from trimethyl phosphate, triethyl phosphate, triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, resorcinol bis(diphenyl phosphate), phenyl diresorcinol phosphate, bisphenol diphenyl phosphate, cresyl diphenyl phosphate, xylenyl diphenyl phosphate, phenyl di(isopropylphenyl)phosphate, triisophenyl phosphate, resorcinol diphosphate, and aromatic polyphosphate.
  • the liquid-type phosphate ester may be at least one selected from resorcinol bis(diphenyl phosphate), phenyl diresorcinol phosphate, bisphenol diphenyl phosphate, cresyl diphenyl phosphate, xylenyl diphenyl phosphate, and phenyl di(isopropylphenyl) phosphate.
  • the resin composition comprises 50 to 80 wt% of a polyolefin resin and 0.1 to 5 wt% of a surface-modified fluorine resin powder based on 100 wt% in total of ingredients constituting the composition.
  • the polyolefin resin may be a polypropylene resin.
  • Examples of the polypropylene resin being one example of the polyolefin resin include those described above.
  • the surface-modified fluorine resin powder may optimize fluidity and melt strength of a polymer suitable for extrusion molding of a tube.
  • the surface-modified fluorine resin powder is prepared by extruding 0.1 to 90 wt% of a surface-modified polytetrafluoroethylene having a weight-average molecular weight of 100,000 g/mol or more and an average particle diameter of 10 ⁇ m or less; and 10 to 99.9 wt% of a high molecular weight polypropylene resin having viscosity of 500 to 1400 ml/g.
  • the surface modification is an acrylic modification in which the polytetrafluoroethylene is modified with alkyl (meth) acrylate.
  • the alkyl (meth)acrylate used in the surface modification may comprise 10 to 90 wt% or 50 to 90 wt% of alkyl methacrylate having a C1 to C30 alkyl group and 90 to 10 wt% or 50 to 10 wt% of alkyl acrylate having a C1 to C30 alkyl group.
  • the surface-modified fluorine resin powder may have a weight-average molecular weight of 1,000,000 g/mol or more, 5,000,000 g/mol or more, or 1,000,000 g/mol to 10,000,000 g/mol and may be prepared by extruding 40 to 70 wt% surface-modified polytetrafluoroethylene having an average particle diameter of 0.05 to 1 ⁇ m and 30 to 60 wt% of a high molecular weight polypropylene resin having a viscosity of 500 to 1400 ml/g.
  • the polyolefin-based flame retardant resin composition may comprise 50 to 80 wt% or 51 to 77.9 wt% of a polypropylene resin as one example of the polyolefin resin, 15 to 40 wt% or 20 to 30 wt% of a solid phase phosphate flame retardant, 0.1 to 15 wt% or 2 to 15 wt% of a liquid-type phosphate ester, and 0.1 to 5 wt%, or 0.1 to 4 wt% of a surface-modified fluorine resin powder.
  • the polyolefin-based flame retardant resin composition may further comprise at least one additive selected from a lubricant, an antioxidant, a photostabilizer, a chain extrender, a catalyst, a release agent, a pigment, a dye, an antistatic agent, an antimicrobial agent, a processing aid, a metal deactivator, a smoke suppressant, an inorganic filler, glass fiber, an antifriction agent, an antiwear agent, and a coupling agent.
  • the additive may be used in an amount which does not negatively affect properties of the present invention.
  • the polyolefin-based flame retardant resin composition of the present invention is melt kneaded at 200 to 300 °C using one of a variety of mixing and processing devices such as a twin-screw extruder, a single-screw extruder, a roll mill, a kneader, a banbury mixer, and the like after primarily mixed in a mixer or a super mixer selectively using the additive. Subsequently, a pellet is obtained through extrusion. An extrusion tubing product from the pellet may be obtained or an injection molded product may be manufactured by injection processing after sufficiently drying the pellet using a dehumidifying dryer or a hot-air dryer.
  • an extrusion tubing molded product satisfying flame retardancy such as UL94V V-2 and an auto ignition property of 15 seconds or less required to use in an extrusion tubing molded product for insulation and wiring of electrical and electronic products and vehicles, and improved extrusion properties and appearance may be provided.
  • an injection molded product may be provided.
  • non-anti dripping agent means those except an anti dripping agent, so long as not specified otherwise.
  • an extrusion tubing molded product molded with the polypropylene flame retardant resin composition and satisfying flame retardancy such as UL94V V-0 or V-1 and an auto ignition property of 15 seconds or less required in use of an extrusion tubing molded product for insulation and wiring of electrical and electronic products and vehicles, and improved extrusion properties, melt index, and tensile elongation may be provided.
  • an injection molded product may be manufactured.
  • the molded product may be a blow or vacuum molded product.
  • the molded product may be used in fluid transfer tubes for industry, medicine transfer tubes, tubes for fuel gas supply, tubes for vehicle fuel, protectors for a vehicle cable, electric cables, cable sheaths, cable ties, and the like.
  • the resultant pellet was used as a specimen for a property evaluation.
  • a tube extrusion process using a pelletizer
  • blow or vacuum molding was performed such that a size of a real tube becomes 5 to 40 ⁇ , resulting in a pellet.
  • the resultant pellet was used as a specimen for property evaluation.
  • a specimen was prepared in the same manner as in Example 1 except that ingredients summarized Table 1 below were used in the amounts disclosed in the table.
  • Example 1 polytetrafluoroethylene (not pre-treated) (C) as an anti dripping agent was added as summarized in a table below and the experiments the same as in Example 1 were repeated.
  • Table 3 Classification (wt%) Reference Examples 1 2 A-1 64.5 58.8 A-2 20 20 B-1 0 20 B-2 15 0 C 0.5 0.2
  • the eco-friendly polyolefin-based flame retardant resin composition according to the present invention satisfies flame retardancy such as a UL94V V-2 grade and an auto ignition property of 15 seconds or less, improved extrusion properties, and appearance quality required in an extrusion tubing molded product and the like for insulation and wiring of electrical and electronic products and vehicles. It was confirmed that the polyolefin-based flame retardant resin composition comprising the polyolefin resin and the phosphate-based flame retardant accomplished the proposed flame retardancy, extrusion properties, and appearance quality, even while using a relatively small amount of particular phosphate-based flame retardant as a phosphate-based flame retardant, and a molded product manufactured from the composition may be provided.
  • flame retardancy such as a UL94V V-2 grade and an auto ignition property of 15 seconds or less
  • a specimen was prepared in the same manner as in Example 1 except that ingredients disclosed in Table 5 were used in amounts disclosed in Table 5.
  • an eco-friendly polypropylene flame retardant resin composition used in extruded tube products for insulation and wiring of electrical and electronic products and vehicles eco-friendliness, flame retardancy, extrusion properties, and the like of an extruded tube product molded using the polypropylene flame retardant resin compositions according to the additional experiments of the present invention may be improved by improving flame retardancy and appearance quality through application of liquid-type phosphate ester while avoiding use of a large amount of conventionally added phosphate flame retardant, and optimizing fluidity and melt strength of the polymer suitable for tube extrusion molding due to addition of the surface-modified fluorine resin powder.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
EP14854897.7A 2013-12-10 2014-12-01 Polyolefin flame-retardant resin composition and molded article Active EP2915845B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL14854897T PL2915845T3 (pl) 2013-12-10 2014-12-01 Opóźniająca palenie kompozycja żywicy poliolefinowej i wyrób formowany

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020130153074A KR101697814B1 (ko) 2013-12-10 2013-12-10 폴리프로필렌 난연수지 조성물 및 압출 튜빙 성형품
KR1020140154108A KR101703392B1 (ko) 2014-11-07 2014-11-07 폴리올레핀 난연수지 조성물 및 성형품
PCT/KR2014/011632 WO2015088170A1 (ko) 2013-12-10 2014-12-01 폴리올레핀 난연수지 조성물 및 성형품

Publications (3)

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EP2915845A1 EP2915845A1 (en) 2015-09-09
EP2915845A4 EP2915845A4 (en) 2017-04-19
EP2915845B1 true EP2915845B1 (en) 2019-02-13

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US (1) US9856420B2 (pl)
EP (1) EP2915845B1 (pl)
CN (1) CN104854184B (pl)
PL (1) PL2915845T3 (pl)
WO (1) WO2015088170A1 (pl)

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KR102087375B1 (ko) * 2015-10-30 2020-03-10 주식회사 엘지화학 폴리프로필렌 수지 조성물 및 이를 포함하는 성형품
CN105255012B (zh) * 2015-11-25 2017-11-07 上海雅凯建筑集团有限公司 装修用无甲醛轻质复合板
CN108886121B (zh) * 2016-04-01 2021-11-30 株式会社Lg化学 电池模块
CN107663332A (zh) 2016-07-28 2018-02-06 Sabic环球技术有限责任公司 阻燃剂丙烯组合物
CN106584927A (zh) * 2016-12-15 2017-04-26 常熟市科恒电工塑胶厂 一种阻燃性好的复合塑料制品
JP6279789B1 (ja) * 2017-03-31 2018-02-14 株式会社Adeka 難燃剤組成物及びそれを含有する難燃性合成樹脂組成物
CN109735031A (zh) * 2019-01-11 2019-05-10 浦江金鑫塑业股份有限公司 一种多组分协同无卤阻燃体系及其应用
KR102473869B1 (ko) * 2019-10-31 2022-12-02 롯데케미칼 주식회사 열가소성 수지 조성물 및 이로부터 제조된 성형품
CN112172077B (zh) * 2020-07-31 2022-08-02 任丘市华凯通信设备有限公司 一种梅花管材及其制备方法
CN112409693B (zh) * 2020-11-26 2023-05-09 浙江旭森阻燃剂股份有限公司 具有良好阻燃和加工性能的无卤阻燃剂及阻燃树脂组合物
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EP2915845A4 (en) 2017-04-19
CN104854184A (zh) 2015-08-19
WO2015088170A1 (ko) 2015-06-18
US9856420B2 (en) 2018-01-02
EP2915845A1 (en) 2015-09-09
US20160304785A1 (en) 2016-10-20
PL2915845T3 (pl) 2019-07-31

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