EP2796584B1 - High-strength steel sheet and process for producing same - Google Patents
High-strength steel sheet and process for producing same Download PDFInfo
- Publication number
- EP2796584B1 EP2796584B1 EP12860717.3A EP12860717A EP2796584B1 EP 2796584 B1 EP2796584 B1 EP 2796584B1 EP 12860717 A EP12860717 A EP 12860717A EP 2796584 B1 EP2796584 B1 EP 2796584B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- less
- ferrite
- steel sheet
- strength steel
- volume fraction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 229910000831 Steel Inorganic materials 0.000 title claims description 68
- 239000010959 steel Substances 0.000 title claims description 68
- 238000000034 method Methods 0.000 title description 5
- 229910000859 α-Fe Inorganic materials 0.000 claims description 57
- 229910001562 pearlite Inorganic materials 0.000 claims description 27
- 229910001567 cementite Inorganic materials 0.000 claims description 24
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 17
- 230000009466 transformation Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 238000000137 annealing Methods 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 238000005098 hot rolling Methods 0.000 claims description 7
- 229910052720 vanadium Inorganic materials 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 3
- 230000000052 comparative effect Effects 0.000 description 19
- 229910000734 martensite Inorganic materials 0.000 description 11
- 229910001566 austenite Inorganic materials 0.000 description 9
- 230000000717 retained effect Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000005096 rolling process Methods 0.000 description 6
- 230000001965 increasing effect Effects 0.000 description 5
- 239000006104 solid solution Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005204 segregation Methods 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- 229910001563 bainite Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- -1 microstructure Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
- C21D8/0426—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0447—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment
- C21D8/0463—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/26—Methods of annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
Definitions
- the present invention relates to high-strength steel sheets, having excellent formability, applicable to automotive parts and particularly relates to a high-strength steel sheet having a tensile strength TS of 600 MPa to 700 MPa, an elongation El of 25% or more (in the case of a JIS #5 test specimen with a thickness of 1.6 mm), and a hole expansion ratio ⁇ of 80% or more, the hole expansion ratio ⁇ being an indicator for stretch flangeability, and a method for producing the same.
- gauge reduction and weight reduction have been investigated by increasing the strength of steel sheets which are materials of automotive parts.
- the increase in strength of steel sheets generally causes the reduction in ductility thereof; hence, high-strength steel sheets having both high strength and good formability are strongly needed.
- EP 1 001 041 A and JP 2001 089811 A1 both disclose steel sheets having a ferrite main phase and comprising at least 0.03 % Ti.
- Patent Literature 1 discloses a high-strength steel sheet, having an excellent strength-hole expansion ratio balance and excellent shape fixability, for forming.
- the steel sheet contains 0.02% to 0.16% C, 0.010% or less P, 0.003% or more S, 0.2% to 4% one or both of Si and Al in total, and 0.5% to 4% one or more of Mn, Ni, Cr, Mo, and Cu in total as chemical components on a mass basis, the remainder being Fe and inevitable impurities, C / (Si + Al + P) being 0.1 or less.
- the cross-sectional microstructure of the steel sheet contains one or both of martensite and retained austenite, the sum of the area fraction of martensite and the area fraction of retained austenite being less than 3%, and one or both of ferrite and bainite, the sum of the area fraction of ferrite and the area fraction of bainite being 80% or more, the remainder being pearlite.
- the maximum length of pearlite, martensite, and retained austenite is 10 microns or less.
- the number of inclusions, having a size of 20 microns or more, present in a cross section of the steel sheet is 0.3 or less per square millimeter.
- Patent Literature 2 discloses a hot-rolled steel containing 0.05% to less than 0.15% C, 0.8% to 1.2% Mn, 0.02% to 2.0% Si, 0.002% to less than 0.05% sol. Al, and 0.001%% to less than 0.005% N on a mass basis, the remainder being Fe and impurities. Each of Ti, Nb, and V in the impurities is less than 0.005%.
- the hot-rolled steel has a microstructure containing ferrite with an average grain size of 1.1 ⁇ m to 5.0 ⁇ m as a primary phase and one or both of pearlite and cementite as a secondary phase and satisfies the inequality Mn ⁇ / Mn ⁇ ⁇ 1, where Mn ⁇ is the content of Mn in cementite in pearlite containing cementite and Mn ⁇ is the content of Mn in ferrite.
- Patent Literature 3 discloses a method for producing a hot-rolled steel sheet in which the structural fraction of cementite with an equivalent circle radius of 0.1 ⁇ m or more is 0.1% or less and/or the structural fraction of martensite is 5% or less and which has a tensile strength of 50 kgf/mm 2 or more, stretch flangeability corresponding to a hole expansion ratio of 1.8 or more, and excellent ductility.
- the inventors have investigated a high-strength steel sheet targeted as described above and have found that it is effective to form a microstructure which contains ferrite and pearlite and in which the volume fraction of ferrite is 70% to 97%, the volume fraction of pearlite is 3% or more, the volume fraction of cementite present at ferrite grain boundaries is 2% or less, the sum of the volume fractions of the other phases is less than 3% or less, and the average grain size of ferrite is 7 ⁇ m or less.
- the present invention has been made on the basis of this finding and provides a high-strength steel sheet according to claim 1.
- Preferred embodiments of the steel sheet are given in claims 2 to 6.
- a method for producing a high-strength steel sheet according to the present invention is specified in claim 7.
- a preferred embodiment is given in claim 8.
- a high-strength steel sheet excellent in formability, having a TS of 600 MPa to 700 MPa, an El of 25% or more, and a ⁇ of 80% or more can be produced.
- the unit "%" for the content of an element component hereinafter refers to mass percent.
- C forms a secondary phase such as pearlite, microstructure, or cementite to contribute to increasing the strength of the steel sheet.
- the content of C needs to be 0.10% or more.
- the C content is more than 0.18%, the amount of the secondary phase is too large; hence, TS exceeds 700 MPa or El or ⁇ is reduced. Therefore, the C content is 0.10% to 0.18%.
- the C content is preferably 0.12% to 0.16%.
- Si is an element contributing to solid solution hardening. In order to achieve a TS of 600 MPa or more, the content of Si needs to be more than 0.5%. However, when the Si content is more than 1.5%, surface properties of the steel sheet are impaired by scaling. Therefore, the Si content is more than 0.5% to 1.5%.
- the Si content is preferably 0.7% to 1.2%.
- Mn is an element contributing to solid solution hardening. In order to achieve a TS of 600 MPa or more, the content of Mn needs to be 0.5% or more. However, when the Mn content is more than 1.5%, TS exceeds 700 MPa or a reduction in ⁇ is caused by segregation. Therefore, the Mn content is 0.5% to 1.5%. The Mn content is preferably 1.1% to 1.5%.
- P is an element contributing to solid solution hardening.
- the content of P is more than 0.05%, a reduction in El is caused by segregation. Therefore, the P content is 0.05% or less.
- the P content is preferably 0.03% or less.
- the S content of S is more than 0.005%, S segregates at prior-austenite grain boundaries or Mn precipitates in the steel sheet to cause a reduction in ⁇ . Therefore, the S content is 0.005% or less and is preferably low.
- Al is added to steel as a deoxidizer and is an element effective in enhancing the cleanliness of steel.
- the content of Al is more than 0.05%, a large number of inclusions are caused, thereby causing surface defects of the steel sheet. Therefore, the Al content is 0.05% or less.
- the Al content is preferably 0.03% or less.
- the remainder is Fe and inevitable impurities.
- At least one selected from the group consisting of 0.01% to 1.0% Cr and 0.01% to 0.1% V may be contained. This is because Cr and V have a function of suppressing the recrystallization and recovery of austenite in a hot-rolling temperature range, promoting the grain refining of ferrite, forming a carbide, or strengthening ferrite in a solid solution state.
- Nb is an element for achieving a similar effect. The addition of these elements does not significantly reduce the elongation (El) as compared to the addition of the same amount of Nb. It is preferred that Cr is 0.02% to 0.5% and V is 0.02% to 0.05%.
- the inevitable impurities are, for example, O, which is 0.003% or less, Cu, Ni, Sn, and Sb, which are 0.05% or less.
- a microstructure containing ferrite and pearlite is formed.
- the volume fraction of ferrite in the microstructure is less than 70%, TS exceeds 700 MPa or a ⁇ of 80% or more is not achieved. In contrast, when the volume fraction thereof is more than 97%, a TS of 600 MPa is not achieved because the amount of pearlite is reduced. Therefore, the volume fraction of ferrite is 70% to 97%.
- the volume fraction of ferrite is preferably 95% or less and more preferably 80% to 90%.
- volume fraction of pearlite 3% or more
- the volume fraction of pearlite is preferably 5% or more. This is probably because pearlite is soft as compared to cementite, martensite, and retained austenite and therefore the number of voids caused at the interface between ferrite and pearlite is small as compared to the number of voids caused at the interface between ferrite and martensite and the interface between ferrite and retained austenite after forming.
- volume fraction of cementite present at ferrite grain boundaries 2% or less
- the steel sheet according to the present invention may possibly contain cementite, martensite, and the like in addition to ferrite and pearlite.
- the volume fraction of cementite, particularly cementite present at ferrite grain boundaries, in the microstructure is more than 2%, the number of voids caused at the interface between ferrite and cementite during hole expansion is increased and therefore a reduction in ⁇ is caused.
- the volume fraction of the cementite present at the ferrite grain boundaries is 2% or less.
- the volume fraction thereof may be 0%.
- volume fractions of phases other than ferrite, pearlite, and the cementite present at ferrite grain boundaries less than 3% in total. Phases other than ferrite, pearlite, and the cementite present at the ferrite grain boundaries are martensite, retained austenite, and the like. When the sum of the volume fractions of these phases in the microstructure is less than 3%, required properties of the steel sheet are not significantly affected. Therefore, the sum of the volume fractions of the phases other than ferrite, pearlite, and the cementite present at the ferrite grain boundaries is less than 3%. The sum thereof is preferably 2.5% or less and may be 0%.
- Average grain size of ferrite 7 ⁇ m or less
- the average grain size of ferrite is 7 ⁇ m or less.
- the average grain size of ferrite is preferably 5 ⁇ m or less.
- the volume fraction of each of ferrite, pearlite, cementite, martensite, and retained austenite in the microstructure is determined in such a way that a thickness-wise cross-section of the steel sheet that is parallel to the rolling direction of the steel sheet is polished and is subsequently corroded with nital, three fields of view are photographed at 1,000 times magnification using an optical microscope, and the types of structures are identified by image processing. Furthermore, the average grain size of ferrite is also calculated by an intercept method.
- orthogonal line segments are drawn so as to longitudinally divide an image (corresponding to 84 ⁇ m in the rolling direction and 65 ⁇ m in the thickness direction) photographed at 1,000 times magnification using the optical microscope into 20 parts and so as to laterally divide the image into 20 parts, a value obtained by dividing the sum of the lengths of ferrite grains cut by one of the line segments by the number of the ferrite grains is defined as the cut length, and the average intercept length L is calculated for each line segment.
- the volume fraction of the cementite present at the ferrite grain boundaries in the microstructure is determined in such a way that three fields of view are photographed at 3,000 times magnification using a scanning electron microscope and the cementite present at the ferrite grain boundaries is extracted by image processing.
- a steel slab used is preferably produced by a continuous casting process for the purpose of preventing the macro-segregation of components of molten steel, produced by a known process using a converter or the like, having the above composition and may be produced by a ingot-casting process.
- Hot rolling The steel slab produced as described above is reheated in a furnace after being cooled to room temperature or without being cooled to room temperature or is held at high temperature without being fed through a furnace and is then hot-rolled.
- Hot-rolling conditions are not particularly limited. It is preferred that after the steel slab is heated to a temperature of 1,100°C to 1,300°C, hot rolling (finish rolling) is completed at 850°C to 950°C and the steel slab is coiled at 720°C or lower. This is due to reasons below. That is, when the heating temperature is lower than 1,100°C, the deformation resistance of steel is high and therefore hot rolling may possibly be difficult. When the heating temperature is higher than 1,300°C, crystal grains become coarse and therefore TS may possibly be reduced.
- finishing delivery temperature When the finishing delivery temperature is lower than 850°C, ferrite is produced during rolling; hence, extended ferrite is formed and a reduction in ⁇ may possibly be caused.
- finishing delivery temperature is higher than 950°C, crystal grains become coarse and therefore TS may possibly be reduced.
- the coiling temperature is higher than 720°C, the formation of an internal oxidation layer is significant and therefore chemical treatability and post-painting corrosion resistance may possibly be deteriorated.
- a hot-rolled sheet is pickled for the purpose of removing scale formed on the surface of the steel sheet.
- Annealing The pickled hot-rolled sheet is annealed in such a way that the hot-rolled sheet is heated to a two-phase temperature range between the Ac 1 transformation temperature and the Ac 3 transformation temperature, is cooled to a temperature range of 450°C to 600°C at an average cooling rate of 5 °C/s to 30 °C/s, and is then held at this temperature range for 100 s or more.
- the reason for heating the hot-rolled sheet to the two-phase temperature range between the Ac 1 transformation temperature and the Ac 3 transformation temperature is to form the microstructure containing ferrite and pearlite is formed.
- the reason for cooling the hot-rolled sheet to a temperature range of 450°C to 600°C at an average cooling rate of 5 °C/s to 30 °C/s is as follows: when the cooling temperature is higher than 600°C, the volume fraction of the cementite present at the ferrite grain boundaries exceeds 2% and therefore target ⁇ is not achieved; when the cooling temperature is lower than 450°C, the amount of martensite is increased and therefore TS exceeds 700 MPa or ⁇ is reduced; when the average cooling rate is less than 5 °C/s, the ferrite grains become coarse and therefore a TS of 600 MPa is not achieved; and when the average cooling rate is more than 30 °C/s, the volume fraction of the cementite present at the ferrite grain boundaries exceeds 2% and therefore a ⁇ of 80% or more is not achieved.
- the average cooling rate is preferably 10 °C/s to 20 °C/s.
- the reason for holding the hot-rolled sheet at a temperature of 450°C to 600°C for 100 s or more is that when the residence time is less than 100 s, the amount of pearlite is reduced and therefore ⁇ is reduced.
- the residence time is more preferably 150 s or more.
- the residence time is preferably 300 s or less from the viewpoint of production efficiency because an effect due to residence for an excessively long time is saturated. Annealing can be performed using a continuous annealing line.
- the steel sheet obtained as described above was investigated for microstructure by the above-mentioned method and was subjected to a tensile test using a JIS #5 test specimen in accordance with JIS Z 2241, whereby TS and El were determined. Furthermore, a hole expansion test was performed using a 100 mm square test specimen in accordance with The Japan Iron and Steel Federation standard JFST 1001-1996, whereby ⁇ was determined.
- steel sheets of examples of the present invention all have a TS of 600 MPa to 700 MPa, an El of 25% or more, a ⁇ of 80% or more and are high-strength steel sheets with excellent formability.
- steel sheets of comparative examples do not have a target TS or ⁇ .
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Heat Treatment Of Steel (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2011276997A JP5316634B2 (ja) | 2011-12-19 | 2011-12-19 | 加工性に優れた高強度鋼板およびその製造方法 |
PCT/JP2012/007663 WO2013094130A1 (ja) | 2011-12-19 | 2012-11-29 | 高強度鋼板およびその製造方法 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2796584A1 EP2796584A1 (en) | 2014-10-29 |
EP2796584A4 EP2796584A4 (en) | 2015-10-14 |
EP2796584B1 true EP2796584B1 (en) | 2018-03-07 |
Family
ID=48668049
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP12860717.3A Not-in-force EP2796584B1 (en) | 2011-12-19 | 2012-11-29 | High-strength steel sheet and process for producing same |
Country Status (7)
Country | Link |
---|---|
US (1) | US20140332123A1 (ru) |
EP (1) | EP2796584B1 (ru) |
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KR (1) | KR101624439B1 (ru) |
CN (1) | CN104011240B (ru) |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5874376B2 (ja) * | 2011-12-19 | 2016-03-02 | Jfeスチール株式会社 | 加工性に優れた高強度鋼板およびその製造方法 |
CN104674138A (zh) * | 2015-03-20 | 2015-06-03 | 苏州科胜仓储物流设备有限公司 | 一种用于窄道式货架的耐摩擦钢板及其热处理工艺 |
CN104694854A (zh) * | 2015-03-20 | 2015-06-10 | 苏州科胜仓储物流设备有限公司 | 一种用于悬臂式货架的高强度钢板及其热处理工艺 |
US10858717B2 (en) | 2015-08-11 | 2020-12-08 | Jfe Steel Corporation | Material for high strength steel sheets, hot rolled material for high strength steel sheets, hot-rolled and annealed material for high strength steel sheets, high strength steel sheet, high strength hot-dip-coated steel sheet, high strength electroplated steel sheet, and method of manufacturing same |
JP6179584B2 (ja) * | 2015-12-22 | 2017-08-16 | Jfeスチール株式会社 | 曲げ性に優れた高強度鋼板およびその製造方法 |
JP6260676B2 (ja) * | 2016-03-29 | 2018-01-17 | Jfeスチール株式会社 | ホットプレス用鋼板およびその製造方法、ならびにホットプレス部材およびその製造方法 |
EP3438316B1 (en) | 2016-03-29 | 2022-03-09 | JFE Steel Corporation | Steel sheet for hot pressing and production method therefor, and hot press member and production method therefor |
CN109423577B (zh) * | 2017-08-30 | 2021-01-12 | 宝山钢铁股份有限公司 | 一种高强多相钢镀锡原板及其制造方法 |
US12110568B2 (en) * | 2019-02-28 | 2024-10-08 | Jfe Steel Corporation | Steel sheet and member, and methods for manufacturing same |
JP7235621B2 (ja) * | 2019-08-27 | 2023-03-08 | 株式会社神戸製鋼所 | 低強度ホットスタンプ用鋼板、ホットスタンプ部品およびホットスタンプ部品の製造方法 |
DE102020203564A1 (de) * | 2020-03-19 | 2021-09-23 | Sms Group Gmbh | Verfahren zum Herstellen eines gewalzten Mehrphasenstahlbandes mit Sondereigenschaften |
CN116752036A (zh) * | 2023-05-25 | 2023-09-15 | 鞍钢股份有限公司 | 高延伸高凸缘超薄610MPa级汽车大梁用钢板及生产方法 |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0762178B2 (ja) | 1990-07-30 | 1995-07-05 | 新日本製鐵株式会社 | 伸びフランジ性と延性の優れた高強度熱延鋼板の製造方法 |
JPH0826433B2 (ja) * | 1992-12-28 | 1996-03-13 | 株式会社神戸製鋼所 | 伸びフランジ性に優れた高強度熱延鋼板 |
JPH09143611A (ja) * | 1995-11-21 | 1997-06-03 | Nippon Steel Corp | 成形性及び疲労特性に優れた耐熱軟化性を有する熱延 高強度鋼板 |
JPH1192855A (ja) * | 1997-09-22 | 1999-04-06 | Natl Res Inst For Metals | 超微細複相組織鋼 |
JP3039862B1 (ja) * | 1998-11-10 | 2000-05-08 | 川崎製鉄株式会社 | 超微細粒を有する加工用熱延鋼板 |
JP3539548B2 (ja) * | 1999-09-20 | 2004-07-07 | Jfeスチール株式会社 | 加工用高張力熱延鋼板の製造方法 |
CA2353492C (en) * | 1999-10-22 | 2004-10-26 | Kawasaki Steel Corporation | Hot-dip galvanized high-strength steel sheet having superior workability and galvanizability and method for producing the same |
JP4306078B2 (ja) * | 2000-02-15 | 2009-07-29 | Jfeスチール株式会社 | 焼付け硬化性および耐衝撃性に優れた高張力熱延鋼板およびその製造方法 |
CN1145709C (zh) * | 2000-02-29 | 2004-04-14 | 川崎制铁株式会社 | 应变时效硬化特性优良的高强度冷轧钢板及其制造方法 |
JP2001342520A (ja) * | 2000-06-02 | 2001-12-14 | Nippon Steel Corp | 材質変動の少ない靱性に優れた低降伏比高張力鋼の製造方法 |
JP3680262B2 (ja) * | 2000-06-28 | 2005-08-10 | Jfeスチール株式会社 | 伸びフランジ性に優れた溶融亜鉛めっき鋼板およびその製造方法 |
JP3917361B2 (ja) * | 2000-11-16 | 2007-05-23 | 株式会社神戸製鋼所 | コイル内材質の均一性および加工性に優れた高強度熱延鋼板の製造方法 |
JP3793490B2 (ja) | 2002-08-07 | 2006-07-05 | 新日本製鐵株式会社 | 強度−穴広げ率バランスと形状凍結性に優れた加工用高強度熱延鋼板及びその製造方法 |
JP3858803B2 (ja) | 2002-10-18 | 2006-12-20 | 住友金属工業株式会社 | 熱延鋼材及びその製造方法 |
JP4507494B2 (ja) * | 2003-01-17 | 2010-07-21 | Jfeスチール株式会社 | 疲労強度に優れた高強度鋼材の製造方法 |
JP4466619B2 (ja) * | 2006-07-05 | 2010-05-26 | Jfeスチール株式会社 | 自動車構造部材用高張力溶接鋼管およびその製造方法 |
JP4923982B2 (ja) * | 2006-11-29 | 2012-04-25 | Jfeスチール株式会社 | 加工後の伸びフランジ特性および伸び特性に優れた高強度熱延鋼板 |
JP4998756B2 (ja) * | 2009-02-25 | 2012-08-15 | Jfeスチール株式会社 | 加工性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
JP5372696B2 (ja) * | 2009-10-20 | 2013-12-18 | 杏林製薬株式会社 | ジメチルアミノエチルメタクリレート含有共重合体の定量法 |
KR101382664B1 (ko) * | 2009-11-17 | 2014-04-07 | 신닛테츠스미킨 카부시키카이샤 | 저온 어닐링용 강선 및 그 제조 방법 |
JP5786318B2 (ja) * | 2010-01-22 | 2015-09-30 | Jfeスチール株式会社 | 疲労特性と穴拡げ性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
JP5018934B2 (ja) * | 2010-06-29 | 2012-09-05 | Jfeスチール株式会社 | 加工性に優れた高強度鋼板およびその製造方法 |
CN102212747A (zh) * | 2011-06-03 | 2011-10-12 | 首钢总公司 | 一种低成本汽车大梁用钢及其制造方法 |
-
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- 2012-11-29 WO PCT/JP2012/007663 patent/WO2013094130A1/ja active Application Filing
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KR20140100994A (ko) | 2014-08-18 |
EP2796584A4 (en) | 2015-10-14 |
US20140332123A1 (en) | 2014-11-13 |
CN104011240B (zh) | 2016-11-23 |
JP2013127099A (ja) | 2013-06-27 |
KR101624439B1 (ko) | 2016-05-25 |
EP2796584A1 (en) | 2014-10-29 |
JP5316634B2 (ja) | 2013-10-16 |
CN104011240A (zh) | 2014-08-27 |
IN2014KN01170A (ru) | 2015-10-16 |
WO2013094130A1 (ja) | 2013-06-27 |
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