EP2589678B1 - High-strength steel sheet with excellent processability and process for producing same - Google Patents
High-strength steel sheet with excellent processability and process for producing same Download PDFInfo
- Publication number
- EP2589678B1 EP2589678B1 EP11801026.3A EP11801026A EP2589678B1 EP 2589678 B1 EP2589678 B1 EP 2589678B1 EP 11801026 A EP11801026 A EP 11801026A EP 2589678 B1 EP2589678 B1 EP 2589678B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- phase
- steel sheet
- temperature
- pearlite
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
Definitions
- the present invention relates to a high strength steel sheet which is required to have excellent formability (stretch flangeability) and is suitable for use as a strength member or the like of automobile parts, and a method of manufacturing the high strength steel sheet.
- DP steel sheet dual phase steel sheet having a dual phase microstructure composed of a ferrite phase and a martensite phase
- PTL 1 describes a method of manufacturing a high strength cold rolled steel sheet having excellent local ductility.
- a cold rolled steel sheet having a composition including 0.08 to 0.30% of C, 0.1 to 2.5% of Si, 0.5 to 2.5% of Mn, and 0.01 to 0.15% of P is subjected to recrystallization annealing at a temperature equal to or higher than an A c1 point, forcibly air-cooled to a temperature region ranging from an A r1 point to 600°C, rapidly cooled at a cooling rate equal to or higher than 100°C/s to form a multi phase microstructure composed of a ferrite phase and a low-temperature transformed phase, and overaged at a temperature in the range of 350°C to 600°C so that a ratio Hv (L)/Hv ( ⁇ ) of the hardness Hv (L) of the low-temperature transformed phase to ferrite hardness Hv ( ⁇ ), which is obtained by a predetermined relational expression, is in the
- the volume fraction of the low-temperature transformed phase is increased by increasing a quenching start temperature and then the overaging is performed at a temperature of 350°C to 600°C to precipitate C in the ferrite, soften the low-temperature transformed phase, and thereby reduce the ratio Hv (L)/Hv ( ⁇ ) and improve local elongation.
- PTL 2 describes a method of manufacturing a high tensile hot rolled steel sheet with a low yield ratio and excellent corrosion resistance, the method including hot-rolling a steel slab containing 0.02 to 0.25% of C, 2.0% or less of Si, 1.6 to 3.5% of Mn, 0.03 to 0.20% of P, 0.02% or less of S, 0.05 to 2.0% of Cu, 0.005 to 0.100% of sol.Al, and 0.008% or less of N to form a hot rolled coil, pickling the hot rolled coil, and annealing the hot rolled coil at a temperature of 720°C to 950°C by a continuous annealing line.
- it is possible to manufacture a high tensile hot rolled steel sheet which maintains a low yield ratio, high ductility, and excellent hole expandability, exhibits excellent corrosion resistance, and has a multi phase microstructure.
- PTL 3 describes a high strength cold rolled steel sheet with an excellent balance between the strength and the stretch flangeability.
- This high strength cold rolled steel sheet has a composition containing 0.03 to 0.17% of C, 1.0% or less of Si, 0.3 to 2.0% of Mn, 0.010% or less of P, 0.010% or less of S, and 0.005 to 0.06% of Al and satisfying C (%) > (3/40) ⁇ Mn, has a microstructure composed of a ferrite phase and a second phase including mainly bainite or pearlite, and satisfies (Vickers hardness of second phase)/(Vickers hardness of ferrite phase) ⁇ 1.6.
- the high strength cold rolled steel sheet described in PTL 3 is obtained by an annealing treatment followed by an overaging treatment at a temperature of 500 to 250°C.
- steel (slab) having the above-described composition is hot-rolled, coiled at a temperature equal to or lower than 650°C, pickled, cold-rolled, soaked at a temperature equal to or higher than an A 1 point and equal to or lower than (A 3 point +50°C), gradually cooled to a temperature T 1 in the range of 750°C to 650°C at a rate of 20°C/s or lower, and cooled T 1 to 500°C at a rate of 20°C/s or higher.
- the technique described in PTL 1 has problems in that a continuous annealing facility which can perform rapid cooling (quenching) after recrystallization annealing is required, and addition of large amounts of alloy elements is required to suppress a rapid decrease in strength due to the overaging at a high temperature.
- the high strength cold rolled steel sheet described in PTL 3 has excellent stretch flangeability. However, at a strength as high as 540 MPa or higher, the elongation is less than 26% and a problem occurs in that the elongation sufficient for maintaining desired excellent formability cannot be ensured.
- An object of the invention is to address such problems in the related art and to provide a high strength steel sheet having a small sheet thickness of about 1.0 to 1.8 mm and excellent formability and a method for manufacturing the high strength steel sheet.
- the "high strength” means that the steel sheet has a tensile strength TS equal to or higher than 540 MPa and preferably equal to or higher than 590 MPa.
- the "excellent formability” means that the elongation El is equal to or greater than 30% (with a JIS No. 5 test piece) and a hole expanding ratio ⁇ in a hole expanding test based on the Japan Iron and Steel Federation Standard JFST 1001-1996 is equal to or higher than 80%.
- a microstructure composed of a ferrite phase as a main phase and a second phase including mainly fine pearlite can be formed by subjecting a hot rolled sheet in which the amounts of alloy elements are adjusted within an appropriate range to an annealing treatment which includes heating to an appropriate dual phase temperature region and an appropriate cooling treatment without cold rolling, and thus a desired high strength can be ensured, formability is significantly improved, and a high strength steel sheet having excellent formability with desired elongation and a desired hole expanding ratio can be obtained.
- the gist of the invention is as follows.
- a high strength steel sheet with excellent formability having a high strength, i.e., a tensile strength TS of 540 MPa or higher, an elongation El of 30% or greater, and a stretch flangeability ⁇ of 80% or higher can be easily manufactured at a low cost, and thus the invention has particularly significant industrial advantages.
- the invention also has an effect of significantly contributing to reduction of manufacturing cost, improvements of productivity, etc., since cold rolling can be omitted.
- the steel sheet of the invention is applied to parts of automobile bodies, it can significantly contribute to the weight-reduction of automobile bodies. Description of Embodiments
- C is an element that contributes to an increase in the strength of a steel sheet and effectively acts on formation of a multi phase microstructure composed of a ferrite phase and a second phase other than the ferrite phase.
- 0.08% or more of C is required to be contained in order to ensure a desired high strength, i.e., a tensile strength of 540 MPa or higher.
- a desired high strength i.e., a tensile strength of 540 MPa or higher.
- the C content is limited in the range of 0.08 to 0.15% and preferably 0.10 to 0.15%.
- Si is an element that dissolves in steel and effectively acts to strengthen the ferrite, and also contributes to an improvement in ductility. 0.5% or more of Si is required to be contained in order to ensure a desired high strength, i.e., a tensile strength of 540 MPa or higher.
- a desired high strength i.e., a tensile strength of 540 MPa or higher.
- the Si content is limited in the range of 0.5 to 1.5% and preferably 0.7 to 1.2%.
- Mn is an element that contributes to an increase in the strength of a steel sheet and effectively acts on formation of a multi phase microstructure. 0.5% or more of Mn is required to be contained in order to obtain such an effect. When more than 1.5% of Mn is contained, a martensite phase is easily formed in the course of cooling in the annealing, and thus formability, particularly, stretch flangeability, is lowered. Therefore, the Mn content is limited in the range of 0.5 to 1.5% and preferably 0.7 to 1.5%.
- P is an element that dissolves in steel and acts to increase the strength of a steel sheet.
- P shows a marked tendency to segregate to grain boundaries and lowers the bonding power of grain boundaries. This results in a decrease in formability and concentration of P in the surface of the steel sheet, thereby decreasing chemical treatability and corrosion resistance.
- Such an adverse effect of P is notably shown when more than 0.1% of P is contained. Therefore, the P content is limited to 0.1% or less.
- the P content is preferably decreased to 0.1% or less as much as possible.
- the P content is preferably about 0.001% or more.
- S mainly forms sulfides (inclusions) such as MnS in steel and lowers formability of a steel sheet, particularly, local elongation. In addition, presence of sulfides (inclusions) also lowers weldability.
- inclusions such as MnS in steel
- S content is limited to 0.01% or less.
- the S content is preferably decreased to 0.01% or less as much as possible.
- the excessive decrease leads to a rise in manufacturing cost, and thus the S content is preferably about 0.0001% or more.
- Al is an element that acts as a deoxidizing agent and is necessary for improving the cleanliness of a steel sheet. Furthermore, Al effectively acts to improve a yield of carbide-forming elements. 0.01% or more of Al is required to be contained in order to obtain such an effect. When less than 0.01% of Al is contained, Si-based inclusions which serve as starting points for delayed fracture are not sufficiently removed, and thus the risk of occurrence of delayed fracture is increased. However, when more than 0.1% of Al is contained, the above-described effect is saturated and thus the effect matching the content cannot be expected, resulting in economic disadvantages. In addition, formability is lowered and the tendency for generation of surface defects is increased. Therefore, the Al content is limited in the range of 0.01 to 0.1% and preferably 0.01 to 0.05%.
- the N content is preferably decreased as much as possible since N is an intrinsically harmful element, but up to 0.005% of N can be permitted. Therefore, the N content is limited to 0.005% or less. Since excessively decreasing the N content leads to a rise in manufacturing cost, the N content is preferably about 0.0001% or more.
- the above-described components are basic components. However, in addition to the basic components, one or more selected from among 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, and 0.005 to 0.2% of Mo, and/or one or two selected from between 0.01 to 0.1% of Ti and 0.01 to 0.1% of Nb, and/or 0.0003 to 0.0050% of B, and/or one or two selected from between 0.05 to 0.5% of Ni and 0.05 to 0.5% of Cu, and/or one or two selected from between 0.001 to 0.005% of Ca and 0.001 to 0.005% of REM can be contained in accordance with need.
- All of Cr, V, and Mo are elements that increase the strength of a steel sheet and contribute to formation of a multi phase microstructure, and one or more selected in accordance with need can be contained. In order to obtain such an effect, it is desired that 0.05% or more of Cr, 0.005% or more of V, and 0.005% or more of Mo be contained. When more than 0.5%, more than 0.2%, and more than 0.2% of Cr, V, and Mo, respectively, are contained, it is difficult to form a desired amount of pearlite in the cooling treatment after the annealing treatment, and thus a desired multi phase microstructure cannot be ensured, thereby lowering stretch flangeability and formability.
- the Cr content is preferably limited in the range of 0.05 to 0.5%
- the V content is preferably limited in the range of 0.005 to 0.2%
- the Mo content is preferably limited in the range of 0.005 to 0.2%.
- Both of Ti and Nb are elements that increase the strength of a steel sheet by precipitation strengthening, and one or two selected in accordance with need can be contained. In order to obtain such an effect, it is desired that 0.01% or more of Ti and 0.01% or more of Nb be contained, respectively. When more than 0.1% of Ti and more than 0.1% of Nb are contained, formability and shape fixability are lowered. Therefore, when Ti and/or Nb is contained, the Ti content is preferably limited in the range of 0.01 to 0.1% and the Nb content is preferably limited in the range of 0.01 to 0.1%.
- B is an element that segregates to austenite grain boundaries and acts to suppress formation and growth of ferrite from the grain boundaries.
- B can be contained in accordance with need. In order to obtain such an effect, it is desired that 0.0003% or more of B be contained. However, when more than 0.0050% of B is contained, formability is lowered. Therefore, when B is contained, the B content is preferably limited in the range of 0.0003 to 0.0050%. In addition, in order to obtain the above-described effect of B, it is necessary to suppress formation of BN, and Ti is preferably contained together with B.
- Ni and Cu are elements that act to increase the strength of a steel sheet and also act to promote internal oxidation to thereby improve adhesion of the coating.
- Ni and Cu can be selected and contained in accordance with need. In order to obtain such an effect, it is desired that 0.05% or more of Ni and 0.05% or more of Cu be contained, respectively.
- the Ni content is preferably limited in the range of 0.05 to 0.5% and the Cu content is preferably limited in the range of 0.05 to 0.5%.
- Both of Ca and REM are elements that contribute to controlling the form of sulfides. They act to spheroidize the form of sulfides and suppress the adverse effects of sulfides on the formability, particularly, stretch flangeability. In order to obtain such an effect, it is desired that 0.001% or more of Ca and 0.001% or more of REM be contained. However, when more than 0.005% of Ca and more than 0.005% of REM are contained, the amount of inclusions increases and surface defects and internal defects occur frequently. Therefore, when Ca and/or REM is contained, the Ca content is preferably limited in the range of 0.001 to 0.005%, and the REM content is preferably limited in the range of 0.001 to 0.005%.
- the balance other than the above-described components includes Fe and inevitable impurities.
- the steel sheet of the invention has the above-described composition and has a microstructure composed of a ferrite phase as a main phase and a second phase including at least pearlite.
- the area fraction of the ferrite phase i.e., the main phase
- the area fraction of the ferrite phase is 75 to 90%.
- the area fraction of the ferrite phase is lower than 75%, desired elongation and a desired hole expanding ratio cannot be obtained and formability is lowered.
- the area fraction of the ferrite phase exceeds 90%, the area fraction of the second phase is lowered and a desired high strength cannot be obtained. Therefore, the area fraction of the ferrite phase which is the main phase is limited to the range of 75 to 90% and preferably 80 to 90%.
- At least pearlite is included in the second phase.
- the area fraction of the pearlite is 10 to 25% with respect to the entire microstructure.
- the area fraction of the pearlite is lower than 10%, a desired hole expanding ratio cannot be obtained and stretch flangeability and formability are lowered.
- the area fraction of the pearlite exceeds 25%, the number of interfaces between the ferrite phase and the pearlite increases and voids are easily formed during the forming. Accordingly, stretch flangeability is lowered and formability is lowered.
- the pearlite is fine grains having an average grain size of 5 ⁇ m or less.
- the average grain size of the pearlite is large, that is, exceeding 5 ⁇ m, stress concentration occurs at the pearlite grains (interfaces) in forming the steel sheet and microvoids are formed. Accordingly, stretch flangeability is lowered and formability is lowered. Therefore, the average grain size of the pearlite is limited to 5 ⁇ m or less and preferably 4.0 ⁇ m or less.
- the second phase of the microstructure of the steel sheet of the invention is a phase that includes at least pearlite and that is mainly composed of pearlite, area fraction of which is 70% or more of the total area of the second phase.
- area fraction of pearlite is less than 70% with respect to the total area of the second phase, the amount of a hard martensite or bainite phase, or retained ⁇ becomes too large, and thus formability is easily lowered. Therefore, the area fraction of pearlite is limited to 70% or greater and preferably 75 to 100% with respect to the total area of the second phase.
- the second phase may include bainite, martensite, retained austenite (retained ⁇ ) and the like, in addition to pearlite.
- bainite and martensite are hard phases and retained ⁇ is transformed into martensite during the forming, bainite, martensite, and retained austenite lower formability. Therefore, it is desired that the amounts of the bainite, martensite and retained austenite are as small as possible, and the area fraction of these with respect to the entire microstructure is preferably 5% or less in total and more preferably 3% or less in total.
- a steel having the above-described composition is used as a starting material. It is not necessary to particularly limit the method for manufacturing the steel. However, from the point of view of productivity, molten steel having the above-described composition is preferably refined through a general refining method using a steel converter, an electric furnace or the like, and formed into a steel such as a slab through a common casting method such as a continuous casting method. An ingot making-slabbing method, a thin-slab casting method, and the like can also be applied.
- a steel having the above-described composition is hot-rolled into a hot rolled sheet.
- the hot rolling step preferably includes heating the steel at a temperature in the range of 1100°C to 1280°C, hot rolling the heated steel with a finish hot rolling temperature of 870°C to 950°C to form a hot rolled sheet, and, upon completion of the hot rolling, coiling the hot rolled sheet at a coiling temperature of 350°C to 720°C.
- the heating temperature for hot rolling is preferably in the range of 1100°C to 1280°C and more preferably lower than 1280°C.
- the finish hot rolling temperature is lower than 870°C, ferrite ( ⁇ ) and austenite ( ⁇ ) are formed during the rolling, and a banded microstructure is easily formed in the steel sheet. This banded microstructure remains even after annealing, and sometimes causes generation of anisotropy in the obtained steel sheet characteristics and lowers the formability.
- the finish hot rolling temperature is higher than 950°C, the microstructure of the hot rolled sheet becomes coarse, and thus a desired microstructure cannot be obtained even after annealing in some cases. Therefore, the finish hot rolling temperature is preferably in the range of 870°C to 950°C.
- the coiling temperature after the hot rolling is lower than 350°C, bainitic ferrite, bainite, martensite and the like are formed and the hot rolled microstructure tends to become hard and nonuniform in grain size. In the subsequent annealing step, the microstructure tends to be nonuniform in grain size due to this hot rolled microstructure, and desired formability cannot be obtained in some cases.
- the coiling temperature is high, that is, higher than 720°C, it becomes difficult to ensure uniform mechanical characteristics over the entire steel sheet in the longitudinal direction and in the width direction of the steel sheet. Therefore, the coiling temperature is preferably in the range of 350°C to 720°C and more preferably 500°C to 680°C.
- the hot rolled sheet obtained through the hot rolling step is pickled according to a common method to remove scales on surfaces of the steel sheet, and then directly subjected to a continuous annealing step that includes an annealing treatment and a subsequent cooling treatment in a continuous annealing line without cold-rolling the hot rolled sheet.
- the annealing treatment is a process in which the sheet is held in a first temperature region of an A c1 transformation point to an A c3 transformation point for 5 to 400 s.
- the heating temperature of the annealing treatment is high, that is, higher than the A c3 transformation point, coarsening of austenite grains is notably shown, the microstructure formed by the subsequent cooling treatment is coarsened, and the formability is thereby decreased in some cases.
- the holding time (annealing time) in the first temperature region is longer than 400 s, the amount of time for the treatment is increased, the amount of consumed energy is increased, and the manufacturing cost is increased. Therefore, the annealing treatment is limited to a process in which holding is performed for 5 to 400 s in the first temperature region of the A c1 transformation point to the A c3 transformation point.
- a value calculated using Expression (1) below is used as the A c1 transformation point of each steel sheet and a value calculated using Expression (2) below is used as the A c3 transformation point.
- the cooling treatment after the annealing treatment is a process of cooling the sheet at an average cooling rate of 5°C/s or higher from the above-described first temperature region to 700°C and adjusting the residence time in a second temperature region of 700°C to 400°C in the range of 30 to 400 s.
- the average cooling rate from the first temperature region to 700°C is lower than 5°C/s, the amount of formed ferrite becomes too large. As a result, a desired multi phase microstructure is not obtained, the formability is lowered, and a desired tensile strength (540 MPa or higher) cannot be ensured in some cases. Therefore, the average cooling rate from the first temperature region to 700°C is limited to 5°C/s or higher, preferably 20°C/s or lower, and more preferably 5 to 15°C/s.
- the residence time in the second temperature region of 700°C to 400°C is an important factor for the formation of pearlite included in the second phase.
- the "residence time” means the length of time the sheet remains in the above-described second temperature region. This covers the case where the sheet is held at a specific temperature in the second temperature region, a case where the sheet is cooled in the second temperature region at a specific cooling rate, and a case where the sheet is cooled by the combination of the two cases.
- the residence time in the second temperature region is shorter than 30 s, pearlite transformation does not occur or the amount of formed pearlite is insufficient, and thus a desired multi phase microstructure cannot be obtained.
- the residence time in the second temperature region is limited in the range of 30 to 400 s and preferably 150 s or shorter.
- the cooling time in a temperature region of 700°C to 550°C in the second temperature region is preferably 10 s or longer, that is, the average cooling rate in the temperature region of 700°C to 550°C is preferably 15°C/s or lower.
- Molten steels each having a composition shown in Table 1 were refined and formed into steels by a common method.
- the steels were hot-rolled at the heating temperatures and the finish hot rolling temperatures shown in Table 2 to form 1.6 mm-thick hot rolled sheets.
- the hot rolled sheets were coiled at the coiling temperatures shown in Table 2. Thereafter, pickling was performed.
- Some of the hot rolled sheets (sheet thickness: 3.2 mm) were subjected to pickling and then to cold rolling with a rolling reduction of 50% to form 1.6 mm-thick cold rolled sheets, which were used as the comparative examples.
- the obtained hot rolled sheets or cold rolled sheets were further subjected to a continuous annealing step that includes an annealing treatment of heating the sheets to a temperature in the first temperature region and holding the sheets thereat, and a cooling treatment of cooling the sheets at average cooling rates shown in Table 2 from the temperature in the first temperature region to 700°C, cooling the sheets at average cooling rates (cooling time) shown in Table 2 from 700°C to 550°C in a second temperature region, and adjusting the residence time in the second temperature region of 700°C to 400°C to the time shown in Table 2 so as to form annealed sheets.
- the transformation points of the respective steel sheets shown in Table 2 are values calculated using the above-described Expressions (1) and (2).
- Test pieces were taken from the obtained annealed sheets, and observation of microstructure, a tensile test, and a hole expanding test were performed thereon.
- the test methods were as follows.
- a test piece for observation of microstructure was taken from an obtained annealed sheet.
- a cross-section (L cross-section) parallel to the rolling direction was polished and corroded with a nital solution, and the microstructure was observed in three or more fields by using a scanning electron microscope (magnification: 3000) and photographed to determine the type of the microstructure and an area fraction of each phase with respect to the entire microstructure.
- an area fraction of the total area of the second phase with respect to the entire microstructure was calculated.
- the average crystal grain size of the pearlite included in the second phase was also calculated.
- an area of each pearlite grain was measured, an equivalent circle diameter was calculated from the area, the obtained equivalent circle diameters of the grains were arithmetically averaged, and the arithmetically averaged value was used as the average crystal grain size of the pearlite grains.
- the number of the measured pearlite grains was equal to or more than 20.
- An area fraction of the pearlite with respect to the total area of the second phase was also calculated.
- a JIS No. 5 test piece was taken from an obtained annealed sheet so that the tensile direction is coincident with a direction perpendicular to the rolling direction.
- the tensile test was performed on the basis of the provisions of JIS Z 2241 and tensile characteristics (yield point YP, tensile strength TS, and elongation El) were determined.
- a 100 mm-square test piece for a hole expanding test was taken from an obtained annealed sheet.
- the hole expanding test was performed on the basis of the Japan Iron and Steel Federation Standard JFST 1001-1996, and a hole expanding ratio ⁇ (%) was determined.
- high strength steel sheets having excellent formability with a high strength i.e., a tensile strength TS of 540 MPa or higher, high ductility, i.e., elongation El of 30% or greater, and excellent stretch flangeability, i.e., hole expanding ratio ⁇ of 80% or higher are obtained.
- a desired high strength is not obtained, desired elongation is not obtained, or a desired hole expanding ratio ⁇ is not obtained, and thus formability is lowered.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Description
- The present invention relates to a high strength steel sheet which is required to have excellent formability (stretch flangeability) and is suitable for use as a strength member or the like of automobile parts, and a method of manufacturing the high strength steel sheet.
- In recent years, an improvement in fuel economy of vehicles has become an important issue from the point of view of preservation of the global environment. Thus, trends toward increasing the strength of the materials used, decreasing the thickness of the structural members used, and reducing the weight of the automobile bodies have accelerated. As materials to be used, high strength steel sheets having a tensile strength of 540 MPa or higher are particularly required. However, since increasing the strength of steel sheets leads to a decrease in formability, high strength steel sheets having excellent formability are in demand. This demand is particularly high for steel sheets having a small thickness (thin steel sheets).
- To meet such demand, various multi phase steel sheets have been proposed such as a dual phase steel sheet (DP steel sheet) having a dual phase microstructure composed of a ferrite phase and a martensite phase and a steel sheet having a multi phase microstructure including a ferrite phase, a martensite phase, and a bainite phase.
- For example, PTL 1 describes a method of manufacturing a high strength cold rolled steel sheet having excellent local ductility. According to this method, a cold rolled steel sheet having a composition including 0.08 to 0.30% of C, 0.1 to 2.5% of Si, 0.5 to 2.5% of Mn, and 0.01 to 0.15% of P is subjected to recrystallization annealing at a temperature equal to or higher than an Ac1 point, forcibly air-cooled to a temperature region ranging from an Ar1 point to 600°C, rapidly cooled at a cooling rate equal to or higher than 100°C/s to form a multi phase microstructure composed of a ferrite phase and a low-temperature transformed phase, and overaged at a temperature in the range of 350°C to 600°C so that a ratio Hv (L)/Hv (α) of the hardness Hv (L) of the low-temperature transformed phase to ferrite hardness Hv (α), which is obtained by a predetermined relational expression, is in the range of 1.5 to 3.5. According to the technique described in PTL 1, the volume fraction of the low-temperature transformed phase is increased by increasing a quenching start temperature and then the overaging is performed at a temperature of 350°C to 600°C to precipitate C in the ferrite, soften the low-temperature transformed phase, and thereby reduce the ratio Hv (L)/Hv (α) and improve local elongation.
- PTL 2 describes a method of manufacturing a high tensile hot rolled steel sheet with a low yield ratio and excellent corrosion resistance, the method including hot-rolling a steel slab containing 0.02 to 0.25% of C, 2.0% or less of Si, 1.6 to 3.5% of Mn, 0.03 to 0.20% of P, 0.02% or less of S, 0.05 to 2.0% of Cu, 0.005 to 0.100% of sol.Al, and 0.008% or less of N to form a hot rolled coil, pickling the hot rolled coil, and annealing the hot rolled coil at a temperature of 720°C to 950°C by a continuous annealing line. According to the technique described in PTL 2, it is possible to manufacture a high tensile hot rolled steel sheet which maintains a low yield ratio, high ductility, and excellent hole expandability, exhibits excellent corrosion resistance, and has a multi phase microstructure.
- PTL 3 describes a high strength cold rolled steel sheet with an excellent balance between the strength and the stretch flangeability. This high strength cold rolled steel sheet has a composition containing 0.03 to 0.17% of C, 1.0% or less of Si, 0.3 to 2.0% of Mn, 0.010% or less of P, 0.010% or less of S, and 0.005 to 0.06% of Al and satisfying C (%) > (3/40) × Mn, has a microstructure composed of a ferrite phase and a second phase including mainly bainite or pearlite, and satisfies (Vickers hardness of second phase)/(Vickers hardness of ferrite phase) < 1.6. The high strength cold rolled steel sheet described in PTL 3 is obtained by an annealing treatment followed by an overaging treatment at a temperature of 500 to 250°C. In this annealing treatment, steel (slab) having the above-described composition is hot-rolled, coiled at a temperature equal to or lower than 650°C, pickled, cold-rolled, soaked at a temperature equal to or higher than an A1 point and equal to or lower than (A3 point +50°C), gradually cooled to a temperature T1 in the range of 750°C to 650°C at a rate of 20°C/s or lower, and cooled T1 to 500°C at a rate of 20°C/s or higher.
-
- [PTL 1] Japanese Unexamined Patent Application Publication No.
63-293121 - [PTL 2] Japanese Unexamined Patent Application Publication No.
05-112832 - [PTL 3] Japanese Unexamined Patent Application Publication No.
10-60593 JPH09118952 - However, the technique described in PTL 1 has problems in that a continuous annealing facility which can perform rapid cooling (quenching) after recrystallization annealing is required, and addition of large amounts of alloy elements is required to suppress a rapid decrease in strength due to the overaging at a high temperature.
- In the technique described in PTL 2, it is essential to add large amounts of P and Cu in combination. However, when a large amount of Cu is contained, hot formability decreases, and when a large amount of P is contained, steel is embrittled. In addition, P shows a marked tendency to segregate in the steel, and this segregated P causes problems such as a decrease in the stretch flangeability of the steel sheet and embrittlement of a welded portion.
- The high strength cold rolled steel sheet described in PTL 3 has excellent stretch flangeability. However, at a strength as high as 540 MPa or higher, the elongation is less than 26% and a problem occurs in that the elongation sufficient for maintaining desired excellent formability cannot be ensured.
- An object of the invention is to address such problems in the related art and to provide a high strength steel sheet having a small sheet thickness of about 1.0 to 1.8 mm and excellent formability and a method for manufacturing the high strength steel sheet. Here, the "high strength" means that the steel sheet has a tensile strength TS equal to or higher than 540 MPa and preferably equal to or higher than 590 MPa. The "excellent formability" means that the elongation El is equal to or greater than 30% (with a JIS No. 5 test piece) and a hole expanding ratio λ in a hole expanding test based on the Japan Iron and Steel Federation Standard JFST 1001-1996 is equal to or higher than 80%. Solution to Problem
- In order to achieve the above-described object, the inventors of the invention have conducted intensive studies on the effect of the composition and the microstructure on the strength and formability. As a result, they have found that a microstructure composed of a ferrite phase as a main phase and a second phase including mainly fine pearlite can be formed by subjecting a hot rolled sheet in which the amounts of alloy elements are adjusted within an appropriate range to an annealing treatment which includes heating to an appropriate dual phase temperature region and an appropriate cooling treatment without cold rolling, and thus a desired high strength can be ensured, formability is significantly improved, and a high strength steel sheet having excellent formability with desired elongation and a desired hole expanding ratio can be obtained.
- The detailed mechanism with regard to a significant improvement in formability by directly performing an appropriate annealing treatment on a hot rolled sheet without cold rolling has not been clear until now, but following has been presumed by the inventors of the invention.
- When a hot rolled sheet is subjected to an annealing treatment of heating the sheet to a dual phase temperature region without cold rolling, the only transformation that occurs during the annealing heating is from α to γ and new recrystallization does not occur. In this case, transformation from α to γ only occurs preferentially in portions with a high C concentration, and a more uniform microstructure can be obtained. In addition, C that diffuses rapidly is redistributed into α and γ up to an equilibrium composition during the annealing treatment. Therefore, presumably, precipitation of film cementite at grain boundaries has been suppressed, which particularly contributes to improvements in stretch flangeability. In contrast, when the hot rolled sheet is cold-rolled and then subjected to an annealing treatment, recrystallization and α to γ transformation competitively occur during the annealing heating, and thus the microstructure tends to become nonuniform and a significant improvement in formability is not readily expected.
- The invention has been completed on the basis of such findings with further examination. That is, the gist of the invention is as follows.
- (1) A high strength steel sheet having excellent formability which has a composition consisting of, including, by mass%, 0.08 to 0.15% of C, 0.5 to 1.5% of Si, 0.5 to 1.5% of Mn, 0.1% or less of P, 0.01% or less of S, 0.01 to 0.1% of Al, 0.005% or less of N, optionally one or more of 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, 0.005 to 0.2% of Mo, 0.01 to 0.1% of Ti, 0.01 to 0.1% of Nb, 0.0003 to 0.0050% of B, 0.05 to 0.5% of Ni, 0.05 to 0.5% of Cu, 0.001 to 0.005% of Ca, 0.001 to 0.005% of REM, and the balance Fe with inevitable impurities, the steel sheet having a microstructure composed of a ferrite phase which is a main phase and a second phase including at least pearlite, wherein an area fraction of the ferrite phase is in the range of 75 to 90% and an area fraction of the pearlite is in the range of 10 to 25% with respect to the entire microstructure, an average grain size of the pearlite is 5 µm or smaller, and an area fraction of the pearlite is 70% or greater with respect to the total area of the second phase.
- (7) A method for manufacturing a high strength steel sheet having excellent formability, including: a hot rolling step of hot-rolling a steel having a composition which consists of, by mass%, 0.08 to 0.15% of C, 0.5 to 1.5% of Si, 0.5 to 1.5% of Mn, 0.1% or less of P, 0.01% or less of S, 0.01 to 0.1% of Al, 0.005% or less of N, optionally one or more of 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, 0.005 to 0.2% of Mo, 0.01 to 0.1% of Ti, 0.01 to 0.1% of Nb, 0.0003 to 0.0050% of B, 0.05 to 0.5% of Ni, 0.05 to 0.5% of Cu, 0.001 to 0.005% of Ca, 0.001 to 0.005% of REM, and the balance Fe with inevitable impurities to form a hot rolled sheet; and a continuous annealing step including an annealing treatment of pickling the hot rolled sheet, and holding the pickled hot rolled sheet in a first temperature region of an Ac1 transformation point to an Ac3 transformation point for 5 to 400 s, and a cooling treatment of cooling the sheet at an average cooling rate of 5 °C/s or higher from the first temperature region to 700°C after the annealing treatment and adjusting a residence time in a second temperature region of 700°C to 400°C in the range of 30 to 400 s by using a continuous annealing line.
- (8) The method for manufacturing a high strength steel sheet according to (7), in which the hot rolling step includes heating the steel at a temperature in the range of 1100°C to 1280°C, hot-rolling the heated steel with a finish hot rolling temperature of 870°C to 950°C to form a hot rolled sheet, and coiling the hot rolled sheet at a coiling temperature of 350°C to 720°C upon completion of the hot rolling.
- (9) The method for manufacturing a high strength steel sheet according to (7) or (8), in which a cooling time in a temperature region of 700°C to 550°C in the second temperature region is 10 s or longer.
- According to the invention, a high strength steel sheet with excellent formability having a high strength, i.e., a tensile strength TS of 540 MPa or higher, an elongation El of 30% or greater, and a stretch flangeability λ of 80% or higher can be easily manufactured at a low cost, and thus the invention has particularly significant industrial advantages. The invention also has an effect of significantly contributing to reduction of manufacturing cost, improvements of productivity, etc., since cold rolling can be omitted. When the steel sheet of the invention is applied to parts of automobile bodies, it can significantly contribute to the weight-reduction of automobile bodies. Description of Embodiments
- First, reasons for limitations on the composition of a steel sheet of the invention will be described. Hereinafter, mass% will be simply expressed by % unless otherwise noted.
- C is an element that contributes to an increase in the strength of a steel sheet and effectively acts on formation of a multi phase microstructure composed of a ferrite phase and a second phase other than the ferrite phase. In the invention, 0.08% or more of C is required to be contained in order to ensure a desired high strength, i.e., a tensile strength of 540 MPa or higher. When more than 0.15% of C is contained, spot weldability is lowered and formability such as ductility is lowered. Therefore, the C content is limited in the range of 0.08 to 0.15% and preferably 0.10 to 0.15%.
- Si is an element that dissolves in steel and effectively acts to strengthen the ferrite, and also contributes to an improvement in ductility. 0.5% or more of Si is required to be contained in order to ensure a desired high strength, i.e., a tensile strength of 540 MPa or higher. When an excessive amount more than 1.5% of Si is contained, generation of red scale and the like is accelerated, the surface quality of a steel sheet is lowered, and chemical treatability is lowered. When an excessive amount of Si is contained, resistance weldability is deteriorated with an increase in electric resistance in resistance welding. Therefore, the Si content is limited in the range of 0.5 to 1.5% and preferably 0.7 to 1.2%.
- Mn is an element that contributes to an increase in the strength of a steel sheet and effectively acts on formation of a multi phase microstructure. 0.5% or more of Mn is required to be contained in order to obtain such an effect. When more than 1.5% of Mn is contained, a martensite phase is easily formed in the course of cooling in the annealing, and thus formability, particularly, stretch flangeability, is lowered. Therefore, the Mn content is limited in the range of 0.5 to 1.5% and preferably 0.7 to 1.5%.
- P is an element that dissolves in steel and acts to increase the strength of a steel sheet. However, P shows a marked tendency to segregate to grain boundaries and lowers the bonding power of grain boundaries. This results in a decrease in formability and concentration of P in the surface of the steel sheet, thereby decreasing chemical treatability and corrosion resistance. Such an adverse effect of P is notably shown when more than 0.1% of P is contained. Therefore, the P content is limited to 0.1% or less. In order to avoid such an adverse effect of P, the P content is preferably decreased to 0.1% or less as much as possible. However, the excessive decrease leads to a rise in manufacturing cost, and thus the P content is preferably about 0.001% or more.
- S mainly forms sulfides (inclusions) such as MnS in steel and lowers formability of a steel sheet, particularly, local elongation. In addition, presence of sulfides (inclusions) also lowers weldability. Such an adverse effect of S is notably shown when more than 0.01% of S is contained. Therefore, the S content is limited to 0.01% or less. In order to avoid such an adverse effect of S, the S content is preferably decreased to 0.01% or less as much as possible. However, the excessive decrease leads to a rise in manufacturing cost, and thus the S content is preferably about 0.0001% or more.
- Al is an element that acts as a deoxidizing agent and is necessary for improving the cleanliness of a steel sheet. Furthermore, Al effectively acts to improve a yield of carbide-forming elements. 0.01% or more of Al is required to be contained in order to obtain such an effect. When less than 0.01% of Al is contained, Si-based inclusions which serve as starting points for delayed fracture are not sufficiently removed, and thus the risk of occurrence of delayed fracture is increased. However, when more than 0.1% of Al is contained, the above-described effect is saturated and thus the effect matching the content cannot be expected, resulting in economic disadvantages. In addition, formability is lowered and the tendency for generation of surface defects is increased. Therefore, the Al content is limited in the range of 0.01 to 0.1% and preferably 0.01 to 0.05%.
- In the invention, the N content is preferably decreased as much as possible since N is an intrinsically harmful element, but up to 0.005% of N can be permitted. Therefore, the N content is limited to 0.005% or less. Since excessively decreasing the N content leads to a rise in manufacturing cost, the N content is preferably about 0.0001% or more.
- The above-described components are basic components. However, in addition to the basic components, one or more selected from among 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, and 0.005 to 0.2% of Mo, and/or one or two selected from between 0.01 to 0.1% of Ti and 0.01 to 0.1% of Nb, and/or 0.0003 to 0.0050% of B, and/or one or two selected from between 0.05 to 0.5% of Ni and 0.05 to 0.5% of Cu, and/or one or two selected from between 0.001 to 0.005% of Ca and 0.001 to 0.005% of REM can be contained in accordance with need.
- All of Cr, V, and Mo are elements that increase the strength of a steel sheet and contribute to formation of a multi phase microstructure, and one or more selected in accordance with need can be contained. In order to obtain such an effect, it is desired that 0.05% or more of Cr, 0.005% or more of V, and 0.005% or more of Mo be contained. When more than 0.5%, more than 0.2%, and more than 0.2% of Cr, V, and Mo, respectively, are contained, it is difficult to form a desired amount of pearlite in the cooling treatment after the annealing treatment, and thus a desired multi phase microstructure cannot be ensured, thereby lowering stretch flangeability and formability. Therefore, when Cr, V, and/or Mo are contained, the Cr content is preferably limited in the range of 0.05 to 0.5%, the V content is preferably limited in the range of 0.005 to 0.2%, and the Mo content is preferably limited in the range of 0.005 to 0.2%.
- Both of Ti and Nb are elements that increase the strength of a steel sheet by precipitation strengthening, and one or two selected in accordance with need can be contained. In order to obtain such an effect, it is desired that 0.01% or more of Ti and 0.01% or more of Nb be contained, respectively. When more than 0.1% of Ti and more than 0.1% of Nb are contained, formability and shape fixability are lowered. Therefore, when Ti and/or Nb is contained, the Ti content is preferably limited in the range of 0.01 to 0.1% and the Nb content is preferably limited in the range of 0.01 to 0.1%.
- B is an element that segregates to austenite grain boundaries and acts to suppress formation and growth of ferrite from the grain boundaries. B can be contained in accordance with need. In order to obtain such an effect, it is desired that 0.0003% or more of B be contained. However, when more than 0.0050% of B is contained, formability is lowered. Therefore, when B is contained, the B content is preferably limited in the range of 0.0003 to 0.0050%. In addition, in order to obtain the above-described effect of B, it is necessary to suppress formation of BN, and Ti is preferably contained together with B.
- Both of Ni and Cu are elements that act to increase the strength of a steel sheet and also act to promote internal oxidation to thereby improve adhesion of the coating. Ni and Cu can be selected and contained in accordance with need. In order to obtain such an effect, it is desired that 0.05% or more of Ni and 0.05% or more of Cu be contained, respectively. However, when more than 0.5% of Ni and more than 0.5% of Cu are contained, it is difficult to form a desired amount of pearlite in the cooling treatment after the annealing treatment, and thus a desired multi phase microstructure cannot be ensured and stretch flangeability and formability are lowered. Therefore, when Ni and/or Cu is contained, the Ni content is preferably limited in the range of 0.05 to 0.5% and the Cu content is preferably limited in the range of 0.05 to 0.5%.
- Both of Ca and REM are elements that contribute to controlling the form of sulfides. They act to spheroidize the form of sulfides and suppress the adverse effects of sulfides on the formability, particularly, stretch flangeability. In order to obtain such an effect, it is desired that 0.001% or more of Ca and 0.001% or more of REM be contained. However, when more than 0.005% of Ca and more than 0.005% of REM are contained, the amount of inclusions increases and surface defects and internal defects occur frequently. Therefore, when Ca and/or REM is contained, the Ca content is preferably limited in the range of 0.001 to 0.005%, and the REM content is preferably limited in the range of 0.001 to 0.005%.
- The balance other than the above-described components includes Fe and inevitable impurities.
- The steel sheet of the invention has the above-described composition and has a microstructure composed of a ferrite phase as a main phase and a second phase including at least pearlite.
- In the steel sheet of the invention, the area fraction of the ferrite phase, i.e., the main phase, with respect to the entire microstructure is 75 to 90%. When the area fraction of the ferrite phase is lower than 75%, desired elongation and a desired hole expanding ratio cannot be obtained and formability is lowered. On the other hand, when the area fraction of the ferrite phase exceeds 90%, the area fraction of the second phase is lowered and a desired high strength cannot be obtained. Therefore, the area fraction of the ferrite phase which is the main phase is limited to the range of 75 to 90% and preferably 80 to 90%.
- In the steel sheet of the invention, at least pearlite is included in the second phase. The area fraction of the pearlite is 10 to 25% with respect to the entire microstructure. When the area fraction of the pearlite is lower than 10%, a desired hole expanding ratio cannot be obtained and stretch flangeability and formability are lowered. On the other hand, when the area fraction of the pearlite exceeds 25%, the number of interfaces between the ferrite phase and the pearlite increases and voids are easily formed during the forming. Accordingly, stretch flangeability is lowered and formability is lowered.
- The pearlite is fine grains having an average grain size of 5 µm or less. When the average grain size of the pearlite is large, that is, exceeding 5 µm, stress concentration occurs at the pearlite grains (interfaces) in forming the steel sheet and microvoids are formed. Accordingly, stretch flangeability is lowered and formability is lowered. Therefore, the average grain size of the pearlite is limited to 5 µm or less and preferably 4.0 µm or less.
- The second phase of the microstructure of the steel sheet of the invention is a phase that includes at least pearlite and that is mainly composed of pearlite, area fraction of which is 70% or more of the total area of the second phase. When the area fraction of pearlite is less than 70% with respect to the total area of the second phase, the amount of a hard martensite or bainite phase, or retained γ becomes too large, and thus formability is easily lowered. Therefore, the area fraction of pearlite is limited to 70% or greater and preferably 75 to 100% with respect to the total area of the second phase.
- The second phase may include bainite, martensite, retained austenite (retained γ) and the like, in addition to pearlite. However, particularly, since bainite and martensite are hard phases and retained γ is transformed into martensite during the forming, bainite, martensite, and retained austenite lower formability. Therefore, it is desired that the amounts of the bainite, martensite and retained austenite are as small as possible, and the area fraction of these with respect to the entire microstructure is preferably 5% or less in total and more preferably 3% or less in total.
- Next, a preferred method for manufacturing the steel sheet of the invention will be described.
- A steel having the above-described composition is used as a starting material. It is not necessary to particularly limit the method for manufacturing the steel. However, from the point of view of productivity, molten steel having the above-described composition is preferably refined through a general refining method using a steel converter, an electric furnace or the like, and formed into a steel such as a slab through a common casting method such as a continuous casting method. An ingot making-slabbing method, a thin-slab casting method, and the like can also be applied.
- A steel having the above-described composition is hot-rolled into a hot rolled sheet. The hot rolling step preferably includes heating the steel at a temperature in the range of 1100°C to 1280°C, hot rolling the heated steel with a finish hot rolling temperature of 870°C to 950°C to form a hot rolled sheet, and, upon completion of the hot rolling, coiling the hot rolled sheet at a coiling temperature of 350°C to 720°C.
- When the heating temperature of the steel is lower than 1100°C, deformation resistance becomes too high, and thus a rolling load becomes excessive and it becomes difficult to perform the hot rolling in some cases. On the other hand, when the heating temperature is higher than 1280°C, the crystal grains become too coarse, and thus a desired fine steel sheet microstructure cannot be easily obtained even when hot rolling is performed. Therefore, the heating temperature for hot rolling is preferably in the range of 1100°C to 1280°C and more preferably lower than 1280°C.
- When the finish hot rolling temperature is lower than 870°C, ferrite (α) and austenite (γ) are formed during the rolling, and a banded microstructure is easily formed in the steel sheet. This banded microstructure remains even after annealing, and sometimes causes generation of anisotropy in the obtained steel sheet characteristics and lowers the formability. On the other hand, when the finish hot rolling temperature is higher than 950°C, the microstructure of the hot rolled sheet becomes coarse, and thus a desired microstructure cannot be obtained even after annealing in some cases. Therefore, the finish hot rolling temperature is preferably in the range of 870°C to 950°C.
- When the coiling temperature after the hot rolling is lower than 350°C, bainitic ferrite, bainite, martensite and the like are formed and the hot rolled microstructure tends to become hard and nonuniform in grain size. In the subsequent annealing step, the microstructure tends to be nonuniform in grain size due to this hot rolled microstructure, and desired formability cannot be obtained in some cases. On the other hand, when the coiling temperature is high, that is, higher than 720°C, it becomes difficult to ensure uniform mechanical characteristics over the entire steel sheet in the longitudinal direction and in the width direction of the steel sheet. Therefore, the coiling temperature is preferably in the range of 350°C to 720°C and more preferably 500°C to 680°C.
- The hot rolled sheet obtained through the hot rolling step is pickled according to a common method to remove scales on surfaces of the steel sheet, and then directly subjected to a continuous annealing step that includes an annealing treatment and a subsequent cooling treatment in a continuous annealing line without cold-rolling the hot rolled sheet.
- The annealing treatment is a process in which the sheet is held in a first temperature region of an Ac1 transformation point to an Ac3 transformation point for 5 to 400 s.
- When the temperature (heating temperature) in the first temperature region of the annealing treatment is lower than the Ac1 transformation point or when the holding time (annealing time) in the first temperature region is shorter than 5 s, carbides in the hot rolled sheet are not sufficiently dissolved and/or a sufficient α-to-γ transformation may not occur or the α-to-γ transformation does not occur at all. Accordingly, a desired multi phase microstructure cannot be obtained by the subsequent cooling treatment, and thus a steel sheet having ductility and stretch flangeability that satisfy desired elongation and a desired hole expanding ratio cannot be obtained. On the other hand, when the heating temperature of the annealing treatment is high, that is, higher than the Ac3 transformation point, coarsening of austenite grains is notably shown, the microstructure formed by the subsequent cooling treatment is coarsened, and the formability is thereby decreased in some cases. In addition, when the holding time (annealing time) in the first temperature region is longer than 400 s, the amount of time for the treatment is increased, the amount of consumed energy is increased, and the manufacturing cost is increased. Therefore, the annealing treatment is limited to a process in which holding is performed for 5 to 400 s in the first temperature region of the Ac1 transformation point to the Ac3 transformation point.
- A value calculated using Expression (1) below is used as the Ac1 transformation point of each steel sheet and a value calculated using Expression (2) below is used as the Ac3 transformation point. When a steel sheet does not contain all elements set forth in the expressions, the contents of elements that are not contained are assumed to be zero in performing the calculations.
- The cooling treatment after the annealing treatment is a process of cooling the sheet at an average cooling rate of 5°C/s or higher from the above-described first temperature region to 700°C and adjusting the residence time in a second temperature region of 700°C to 400°C in the range of 30 to 400 s.
- When the average cooling rate from the first temperature region to 700°C is lower than 5°C/s, the amount of formed ferrite becomes too large. As a result, a desired multi phase microstructure is not obtained, the formability is lowered, and a desired tensile strength (540 MPa or higher) cannot be ensured in some cases. Therefore, the average cooling rate from the first temperature region to 700°C is limited to 5°C/s or higher, preferably 20°C/s or lower, and more preferably 5 to 15°C/s.
- The residence time in the second temperature region of 700°C to 400°C is an important factor for the formation of pearlite included in the second phase. Here, the "residence time" means the length of time the sheet remains in the above-described second temperature region. This covers the case where the sheet is held at a specific temperature in the second temperature region, a case where the sheet is cooled in the second temperature region at a specific cooling rate, and a case where the sheet is cooled by the combination of the two cases. When the residence time in the second temperature region is shorter than 30 s, pearlite transformation does not occur or the amount of formed pearlite is insufficient, and thus a desired multi phase microstructure cannot be obtained. On the other hand, when the residence time in the second temperature region is long, that is, longer than 400 s, productivity is lowered. Therefore, the residence time in the second temperature region is limited in the range of 30 to 400 s and preferably 150 s or shorter. For securing of a desired amount of pearlite, the cooling time in a temperature region of 700°C to 550°C in the second temperature region is preferably 10 s or longer, that is, the average cooling rate in the temperature region of 700°C to 550°C is preferably 15°C/s or lower. When the cooling time in the temperature region of 700°C to 550°C is shorter than 10 s, pearlite is not sufficiently formed, a desired multi phase microstructure is not obtained, and desired formability cannot be obtained in some cases.
- Hereinafter, the invention will be more specifically described on the basis of the examples. The invention is not limited to these examples.
- Molten steels each having a composition shown in Table 1 were refined and formed into steels by a common method. The steels were hot-rolled at the heating temperatures and the finish hot rolling temperatures shown in Table 2 to form 1.6 mm-thick hot rolled sheets. Upon completion of the hot rolling, the hot rolled sheets were coiled at the coiling temperatures shown in Table 2. Thereafter, pickling was performed. Some of the hot rolled sheets (sheet thickness: 3.2 mm) were subjected to pickling and then to cold rolling with a rolling reduction of 50% to form 1.6 mm-thick cold rolled sheets, which were used as the comparative examples.
- Under the conditions shown in Table 2, the obtained hot rolled sheets or cold rolled sheets were further subjected to a continuous annealing step that includes an annealing treatment of heating the sheets to a temperature in the first temperature region and holding the sheets thereat, and a cooling treatment of cooling the sheets at average cooling rates shown in Table 2 from the temperature in the first temperature region to 700°C, cooling the sheets at average cooling rates (cooling time) shown in Table 2 from 700°C to 550°C in a second temperature region, and adjusting the residence time in the second temperature region of 700°C to 400°C to the time shown in Table 2 so as to form annealed sheets. The transformation points of the respective steel sheets shown in Table 2 are values calculated using the above-described Expressions (1) and (2).
- Test pieces were taken from the obtained annealed sheets, and observation of microstructure, a tensile test, and a hole expanding test were performed thereon. The test methods were as follows.
- A test piece for observation of microstructure was taken from an obtained annealed sheet. A cross-section (L cross-section) parallel to the rolling direction was polished and corroded with a nital solution, and the microstructure was observed in three or more fields by using a scanning electron microscope (magnification: 3000) and photographed to determine the type of the microstructure and an area fraction of each phase with respect to the entire microstructure. Moreover, an area fraction of the total area of the second phase with respect to the entire microstructure was calculated. The average crystal grain size of the pearlite included in the second phase was also calculated. Regarding the average crystal grain size of the pearlite, an area of each pearlite grain was measured, an equivalent circle diameter was calculated from the area, the obtained equivalent circle diameters of the grains were arithmetically averaged, and the arithmetically averaged value was used as the average crystal grain size of the pearlite grains. The number of the measured pearlite grains was equal to or more than 20. An area fraction of the pearlite with respect to the total area of the second phase was also calculated.
- A JIS No. 5 test piece was taken from an obtained annealed sheet so that the tensile direction is coincident with a direction perpendicular to the rolling direction. The tensile test was performed on the basis of the provisions of JIS Z 2241 and tensile characteristics (yield point YP, tensile strength TS, and elongation El) were determined.
- A 100 mm-square test piece for a hole expanding test was taken from an obtained annealed sheet. The hole expanding test was performed on the basis of the Japan Iron and Steel Federation Standard JFST 1001-1996, and a hole expanding ratio λ (%) was determined.
- The obtained results are shown in Table 3.
[Table 1] Steel No. Chemical Composition (mass%) Remarks C Si Mn P S Al N Cr,V,Mo Ti,Nb B Ni,Cu Ca,REM A 0.10 0.72 1.22 0.014 0.002 0.043 0.0038 - - - - - Suitable Example B 0.09 0.72 1.21 0.023 0.002 0.035 0.0028 Cr:0.35 - - - - Suitable Example C 0.09 1.30 0.80 0.013 0.002 0.036 0.0029 - - - - - Suitable Example D 0.14 1.02 1.32 0.015 0.001 0.035 0.0025 - - - - - Suitable Example E 0.09 1.55 1.24 0.013 0.001 0.043 0.0034 - - - - - Comparative Example F 0.15 0.23 1.40 0.015 0.002 0.042 0.0041 - - - - - Comparative Example G 0.14 1.02 1.62 0.012 0.001 0.039 0.0034 - - - - - Comparative Example H 0.14 0.71 2.00 0.012 0.001 0.041 0.0036 - - - - - Comparative Example I 0.15 0.80 0.75 0.010 0.001 0.038 0.0029 Mo:0.1 - - - - Suitable Example J 0.10 1.02 1.23 0.015 0.001 0.037 0.0039 V:0.1 - - - - Suitable Example K 0.13 1.00 0.82 0.015 0.002 0.037 0.0040 - Nb:0.031 - - - Suitable Example L 0.14 1.41 0.88 0.013 0.001 0.040 0.0028 - Ti:0.022 B:0.0012 - - Suitable Example M 0.14 1.02 0.84 0.015 0.001 0.037 0.0039 - - - Ni:0.2 - Suitable Example N 0.14 0.81 0.82 0.015 0.002 0.042 0.0034 - - - - - Suitable Example O 0.12 1.43 0.91 0.011 0.002 0.042 0.0041 - - - - REM:0.002 Suitable Example P 0.07 1.00 1.20 0.014 0.003 0.038 0.0035 - - - - - Comparative Example Q 0.16 1.01 1.24 0.013 0.002 0.043 0.0035 - - - - - Comparative Example R 0.13 0.40 1.32 0.012 0.001 0.036 0.0038 - - - - - Comparative Example [Table 2] Steel sheet no. Steel no. Hot rolling step Cold rolling Sheet thickness (mm) Continuous annealing step Transformation point Remarks Heating temperature (°c) Finish hot rolling temperature (°c) Coiling temperature (°c) Yes/No Annealing treatment Cooling treatment Ac1 (°C) Ac3 (°C) First temperature region Average cooling rate up to 700°c* (°c/s) Second temperature region Temperature (°C) Holding time (s) Cooling time** (s) Cooling rate** (°C/s) Residence time*** (s) 1 A 1200 900 600 No 1.6 800 100 10 15 10 35 731 868 Suitable Example 2 B 1200 900 600 No 1.6 820 100 15 15 10 150 737 873 Suitable Example 3 B 1200 900 600 No 1.6 850 100 15 15 10 300 737 873 Suitable Example 4 B 1200 900 600 Yes 1.6 820 100 15 15 10 150 737 873 Comparative Example 5 C 1200 920 560 No 1.6 820 100 10 15 10 35 752 907 Suitable Example 6 C 1200 920 560 No 1.6 800 100 10 15 10 20 752 907 Comparative Example 7 D 1200 900 560 No 1.6 820 100 10 15 10 150 739 865 Suitable Example 8 D 1200 900 560 Yes 1.6 820 100 10 15 10 150 739 865 Comparative Example 9 E 1200 920 560 No 1.6 850 100 3 15 10 150 755 908 Comparative Example 10 F 1200 900 600 No 1.6 800 100 10 15 10 35 715 827 Comparative Example 11 F 1200 900 600 Yes 1.6 800 100 10 15 10 150 715 827 Comparative Example 12 G 1200 900 600 No 1.6 800 100 10 20 8 70 735 855 Comparative Example 13 H 1200 900 600 No 1.6 800 100 10 20 8 70 722 831 Comparative Example 14 I 1200 900 640 No 1.6 820 100 10 15 10 150 738 871 Suitable Example 15 I 1200 900 640 No 1.6 820 100 10 0.2 750 0.4 738 871 Comparative Example 16 J 1250 900 600 No 1.6 820 100 15 15 10 150 740 890 Suitable Example 17 K 1250 900 560 No 1.6 820 150 10 30 5 35 743 882 Suitable Example 18 K 1250 900 560 No 1.6 820 100 10 5 30 20 743 882 Comparative Example 19 K 1250 900 560 No 1.6 715 100 10 30 5 150 743 882 Comparative Example 20 L 1250 920 600 No 1.6 820 150 10 15 10 35 755 905 Suitable Example 21 L 1250 920 600 No 1.6 820 150 10 15 10 150 755 905 Suitable Example 22 L 1250 920 600 No 1.6 820 150 10 15 10 300 755 905 Suitable Example 23 L 1250 920 600 No 1.6 920 150 10 15 10 150 755 905 Comparative Example 24 M 1200 920 600 No 1.6 840 100 15 20 8 70 740 877 Suitable Example 25 M 1200 900 600 No 1.6 840 100 15 15 10 300 740 877 Suitable Example 26 N 1200 900 640 No 1.6 820 100 15 15 10 150 738 873 Suitable Example 27 O 1200 920 600 No 1.6 820 100 15 15 10 150 755 901 Suitable Example 28 P 1200 920 600 No 1.7 800 100 10 15 10 35 739 890 Comparative Example 29 P 1200 920 600 No 1.6 800 100 10 5 30 10 739 890 Comparative Example 30 Q 1200 900 640 No 1.6 820 100 10 15 10 70 739 863 Comparative Example 31 R 1200 900 640 No 1.6 820 100 10 15 10 70 721 838 Comparative Example *) Cooling rate (average) from temperature in first temperature region to 700°C
**) Cooling time and average cooling rate (°C/s) between 700°C and 550°C
***) Residence time between 700°C and 400°C[Table 3] Steel sheet no. Steel no. Microstructure Tensile characteristics Stretch-flangeability Remarks Type Fraction of Microstructure (area fraction) P average grain size (µm) Yield strength YS (MPa) Tensile strength TS (MPa) Elongation EI (%) λ (%) Main phase Second Phase F* P* M* Ret. γ* Total P fraction ** 1 A F+P+M 87.7 12.1 0.2 - 12.3 98 3.1 436 545 33.4 127 Invention Example 2 B F+P+M 84.5 15.3 0.2 - 15.5 99 3.0 442 552 32.1 116 Invention Example 3 B F+P+M 84.1 15.8 0.1 - 15.9 99 3.2 450 558 31.6 121 Invention Example 4 B F+P+M 87.9 3.2 8.9 - 12.1 26 2.8 458 599 31.8 67 Comparative Example 5 C F+P+M+Ret. γ 83.6 15.2 0.1 1.1 16.4 93 3.2 453 553 34.5 132 Invention Example 6 C F+M 84.8 0.0 15.2 - 15.2 0 - 488 724 28.2 65 Comparative Example 7 D F+P+M 82.6 13.2 4.2 - 17.4 76 3.4 452 624 31.7 108 Invention Example 8 D F+P+M 82.2 10.6 7.2 - 17.8 60 3.2 448 625 32.4 69 Comparative Example 9 E F+P+M 86.7 1.2 12.1 - 13.3 9 2.1 387 624 33.6 58 Comparative Example 10 F F+P+M 88.8 10.6 0.6 - 11.2 95 2.9 425 518 34.2 85 Comparative Example 11 F F+P+M 88.2 10.9 0.9 - 11.8 92 3.2 429 526 33.7 83 Comparative Example 12 G F+M 85.9 0.0 14.1 - 14.1 0 - 425 638 30.2 56 Comparative Example 13 H F+M 83.6 0.0 16.4 - 16.4 0 - 463 672 28.9 51 Comparative Example 14 I F+P+M 85.0 14.8 0.2 - 15.0 99 2.9 449 564 33.1 114 Invention Example 15 I F+M 54.8 0.0 45.2 - 45.2 0 - 653 1082 13.8 32 Comparative Example 16 J F+P+M 83.6 16.2 0.2 - 16.4 99 3.7 462 592 32.4 118 Invention Example 17 K F+P+M 83.4 15.1 1.5 - 16.6 91 3.4 472 611 31.8 111 Invention Example 18 K F+M 84.8 0.0 15.2 - 15.2 0 - 502 752 24.7 54 Comparative Example 19 K F+C 90.4 0.0 - - 0.0 0 - 402 535 31.1 79 Comparative Example 20 L F+P+M+Retained γ 85.9 11.5 1.4 1.2 14.1 82 3.8 453 603 32.5 105 Invention Example 21 L F+P+M+Ret. γ 85.3 12.4 1.2 1.1 12.3 84 3.9 468 601 32.6 111 Invention Example 22 L F+P+M 86.5 12.2 1.3 - 13.5 90 3.9 462 597 32.4 104 Invention Example 23 L F+P+M 83.0 15.8 1.2 - 17.0 93 6.5 488 625 31.1 75 Comparative Example 24 M F+P+M 87.3 12.5 0.2 - 12.7 98 3.2 482 614 31.5 117 Invention Example 25 M F+P 86.1 13.9 - - 13.9 100 3.4 469 586 32.0 120 Invention Example 26 N F+P+M 86.8 13.1 0.1 - 13.2 99 3.0 442 564 32.9 118 Invention Example 27 O F+P+M+Ret. γ 86.0 12.4 0.2 1.4 14.0 89 3.2 467 608 31.8 109 Invention Example 28 P F+P+M 91.7 8.2 0.1 - 8.3 99 3.1 385 482 35.1 105 Comparative Example 29 P F+P+M 87.8 5.8 6.4 - 12.2 48 2.2 425 572 32.4 62 Comparative Example 30 Q F+P+M 90.9 4.9 4.2 - 9.1 54 2.2 524 694 26.8 69 Comparative Example 31 R F+P 89.7 10.3 - - 10.3 100 3.1 409 528 32.9 110 Comparative Example *) F: ferrite, P: pearlite, M: martensite, Ret. γ: retained austenite, C: cementite
**) P fraction: P area/second phase total area ratio - In all of the invention examples, high strength steel sheets having excellent formability with a high strength, i.e., a tensile strength TS of 540 MPa or higher, high ductility, i.e., elongation El of 30% or greater, and excellent stretch flangeability, i.e., hole expanding ratio λ of 80% or higher are obtained. In contrast, in the comparative examples outside the range of the invention, a desired high strength is not obtained, desired elongation is not obtained, or a desired hole expanding ratio λ is not obtained, and thus formability is lowered.
Claims (3)
- A high strength steel sheet having excellent formability which has a composition consisting of, by mass%:0.08 to 0.15% of C, 0.5 to 1.5% of Si, 0.5 to 1.5% of Mn, 0.1% or less of P, 0.01% or less of S, 0.01 to 0.1% of Al, 0.005% or less of N,and optionally one or more of 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, 0.005 to 0.2% of Mo, 0.01 to 0.1% of Ti, 0.01 to 0.1% of Nb, 0.0003 to 0.0050% of B, 0.05 to 0.5% of Ni, 0.05 to 0.5% of Cu, 0.001 to 0.005% of Ca, 0.001 to 0.005% of REM,and the balance Fe with inevitable impurities,the steel sheet having a microstructure composed of a ferrite phase which is a main phase and a second phase including at least pearlite, wherein an area fraction of the ferrite phase is in the range of 75 to 90% and an area fraction of the pearlite is in the range of 10 to 25% with respect to the entire microstructure, an average grain size of the pearlite is 5 µm or smaller, and an area fraction of the pearlite is 70% or greater with respect to the total area of the second phase.
- A method for manufacturing a high strength steel sheet having excellent formability, comprising:a hot rolling step of hot-rolling a steel having a composition consisting of, by mass%,0.08 to 0.15% of C, 0.5 to 1.5% of Si, 0.5 to 1.5% of Mn, 0.1% or less of P, 0.01% or less of S, 0.01 to 0.1% of Al, 0.005% or less of N,and optionally one or more of 0.05 to 0.5% of Cr, 0.005 to 0.2% of V, 0.005 to 0.2% of Mo, 0.01 to 0.1% of Ti, 0.01 to 0.1% of Nb, 0.0003 to 0.0050% of B, 0.05 to 0.5% of Ni, 0.05 to 0.5% of Cu, 0.001 to 0.005% of Ca, 0.001 to 0.005% of REM,and the balance Fe with inevitable impurities to form a hot rolled sheet;and a continuous annealing step including an annealing treatment of pickling the hot rolled sheet, and holding the pickled hot rolled sheet in a first temperature region of an Ac1 transformation point to an Ac3 transformation point for 5 to 400 s,and a cooling treatment of cooling the sheet at an average cooling rate of 5 °C/s or higher from the first temperature region to 700°C after the annealing treatment and adjusting a residence time in a second temperature region of 700°C to 400°C in the range of 30 to 400 s by using a continuous annealing line, wherein a cooling time in a temperature region of 700°C to 550°C in the second temperature region is 10 s or longer.
- The method for manufacturing a high strength steel sheet according to Claim 2, wherein the hot rolling step includes heating the steel at a temperature in the range of 1100°C to 1280°C, hot-rolling the heated steel with a finish hot rolling temperature of 870°C to 950°C to form a hot rolled sheet, and coiling the hot rolled sheet at a coiling temperature of 350°C to 720°C upon completion of the hot rolling.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010147419A JP5018934B2 (en) | 2010-06-29 | 2010-06-29 | High-strength steel sheet with excellent workability and method for producing the same |
PCT/JP2011/065415 WO2012002566A1 (en) | 2010-06-29 | 2011-06-29 | High-strength steel sheet with excellent processability and process for producing same |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2589678A1 EP2589678A1 (en) | 2013-05-08 |
EP2589678A4 EP2589678A4 (en) | 2017-07-19 |
EP2589678B1 true EP2589678B1 (en) | 2018-09-05 |
Family
ID=45402263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP11801026.3A Active EP2589678B1 (en) | 2010-06-29 | 2011-06-29 | High-strength steel sheet with excellent processability and process for producing same |
Country Status (7)
Country | Link |
---|---|
US (1) | US20130233453A1 (en) |
EP (1) | EP2589678B1 (en) |
JP (1) | JP5018934B2 (en) |
KR (1) | KR101485237B1 (en) |
CN (1) | CN102971443B (en) |
TW (1) | TWI431124B (en) |
WO (1) | WO2012002566A1 (en) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5018935B2 (en) * | 2010-06-29 | 2012-09-05 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet excellent in workability and manufacturing method thereof |
JP5316634B2 (en) * | 2011-12-19 | 2013-10-16 | Jfeスチール株式会社 | High-strength steel sheet with excellent workability and method for producing the same |
KR20140104497A (en) * | 2012-01-18 | 2014-08-28 | 제이에프이 스틸 가부시키가이샤 | Steel strip for coiled tubing and method for producing same |
KR101417260B1 (en) * | 2012-04-10 | 2014-07-08 | 주식회사 포스코 | High carbon rolled steel sheet having excellent uniformity and mehtod for production thereof |
CN102719755A (en) * | 2012-05-31 | 2012-10-10 | 攀钢集团攀枝花钢铁研究院有限公司 | High-strength high-processability hot-rolled pickled plate for automobile structures and production method thereof |
CN103741067B (en) * | 2013-12-26 | 2016-08-31 | 马钢(集团)控股有限公司 | A kind of block automobile-used high tenacity wheel hub steel and the preparation method of wheel hub |
CN104060169A (en) * | 2014-06-18 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | Hot-rolled steel sheet and production method thereof |
CN104060167A (en) * | 2014-06-18 | 2014-09-24 | 攀钢集团攀枝花钢铁研究院有限公司 | Hot-rolled steel sheet and production method thereof |
US20170218475A1 (en) * | 2014-08-07 | 2017-08-03 | Jfe Steel Corporation | High-strength steel sheet and method for manufacturing same |
CN104264038A (en) * | 2014-09-23 | 2015-01-07 | 攀钢集团西昌钢钒有限公司 | 440 MPa-grade continuous-annealed and cold-rolled structural steel plate and production process thereof |
CN104694854A (en) * | 2015-03-20 | 2015-06-10 | 苏州科胜仓储物流设备有限公司 | High-strength steel plate for cantilever type goods shelves and heat processing process thereof |
CN104674138A (en) * | 2015-03-20 | 2015-06-03 | 苏州科胜仓储物流设备有限公司 | Friction-resistant steel plate for narrow path type goods shelf and thermal treatment technology of friction-resistant steel plate |
CN105619025A (en) * | 2015-12-30 | 2016-06-01 | 浙江吉利汽车研究院有限公司 | Thermoforming method for high-strength fatigue-resisting torsion beam |
KR101726130B1 (en) * | 2016-03-08 | 2017-04-27 | 주식회사 포스코 | Composition structure steel sheet having excellent formability and method for manufacturing the same |
CN105839001A (en) * | 2016-05-30 | 2016-08-10 | 苏州双金实业有限公司 | Steel with excellent machinability |
CN106435384A (en) * | 2016-09-28 | 2017-02-22 | 河钢股份有限公司承德分公司 | Vanadium-containing automobile structural steel and production method thereof |
CN110405372B (en) * | 2019-07-09 | 2021-02-09 | 中国石油大学(华东) | Duplex stainless steel heat exchange plate composite welding method based on residual stress regulation |
KR102307946B1 (en) * | 2019-12-09 | 2021-09-30 | 주식회사 포스코 | Steel plate for structure with a good seawater corrosion resistive property and method of manufacturing the same |
CN111187985A (en) * | 2020-02-17 | 2020-05-22 | 本钢板材股份有限公司 | Hot-rolled extending flange steel with high hole expansion performance and fatigue life and preparation process thereof |
KR102484995B1 (en) * | 2020-12-10 | 2023-01-04 | 주식회사 포스코 | Hot-rolled steel for hyper tube and manufacturing method for the same |
JP2024530517A (en) * | 2021-08-31 | 2024-08-21 | ポスコ カンパニー リミテッド | Hot-rolled steel sheet for vacuum train tubes and its manufacturing method |
KR20230093722A (en) * | 2021-12-20 | 2023-06-27 | 주식회사 포스코 | Hot-rolled steel for hyper tube and manufacturing method for the same |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0759726B2 (en) * | 1987-05-25 | 1995-06-28 | 株式会社神戸製鋼所 | Method for manufacturing high strength cold rolled steel sheet with excellent local ductility |
JP3144572B2 (en) | 1991-10-18 | 2001-03-12 | 日新製鋼株式会社 | Manufacturing method of low yield ratio high tensile strength hot rolled steel sheet with excellent corrosion resistance |
JP3369658B2 (en) * | 1993-08-26 | 2003-01-20 | 川崎製鉄株式会社 | High-strength and high-workability steel sheet for cans with excellent bake hardenability, aging resistance and non-earring properties, and method for producing the same |
JPH09118952A (en) * | 1995-10-20 | 1997-05-06 | Kobe Steel Ltd | Member made of high-strength hot rolled steel sheet having lower yield ratio |
JPH1060593A (en) | 1996-06-10 | 1998-03-03 | Kobe Steel Ltd | High strength cold rolled steel sheet excellent in balance between strength and elongation-flanging formability, and its production |
JP3916113B2 (en) * | 1999-01-29 | 2007-05-16 | 住友金属工業株式会社 | High strength Ti-added hot-rolled steel sheet for processing and manufacturing method thereof |
JP3680262B2 (en) * | 2000-06-28 | 2005-08-10 | Jfeスチール株式会社 | Hot-dip galvanized steel sheet with excellent stretch flangeability and manufacturing method thereof |
JP2003193188A (en) * | 2001-12-25 | 2003-07-09 | Jfe Steel Kk | High tensile strength galvannealed, cold rolled steel sheet having excellent stretch-flanging property and production method therefor |
JP4023225B2 (en) * | 2002-06-11 | 2007-12-19 | Jfeスチール株式会社 | Hot-rolled steel sheet for rotating ironing process, method for producing the same, and automotive part |
JP4867177B2 (en) * | 2005-02-28 | 2012-02-01 | Jfeスチール株式会社 | High tensile hot rolled steel sheet excellent in bake hardenability and formability and method for producing the same |
JP4967360B2 (en) * | 2006-02-08 | 2012-07-04 | 住友金属工業株式会社 | Plated steel sheet for hot pressing, method for manufacturing the same, and method for manufacturing hot press-formed members |
CN100519808C (en) * | 2007-12-05 | 2009-07-29 | 攀钢集团攀枝花钢铁研究院 | Vanadium-containing hot rolled steel plate and preparation method thereof |
KR100928782B1 (en) * | 2007-12-26 | 2009-11-25 | 주식회사 포스코 | High-strength structural steel with excellent low temperature toughness and tensile strength at welded heat affected zone and its manufacturing method |
-
2010
- 2010-06-29 JP JP2010147419A patent/JP5018934B2/en active Active
-
2011
- 2011-06-29 TW TW100122843A patent/TWI431124B/en not_active IP Right Cessation
- 2011-06-29 CN CN201180032346.4A patent/CN102971443B/en active Active
- 2011-06-29 US US13/704,781 patent/US20130233453A1/en not_active Abandoned
- 2011-06-29 EP EP11801026.3A patent/EP2589678B1/en active Active
- 2011-06-29 WO PCT/JP2011/065415 patent/WO2012002566A1/en active Application Filing
- 2011-06-29 KR KR1020127032907A patent/KR101485237B1/en active IP Right Grant
Non-Patent Citations (1)
Title |
---|
None * |
Also Published As
Publication number | Publication date |
---|---|
TWI431124B (en) | 2014-03-21 |
US20130233453A1 (en) | 2013-09-12 |
EP2589678A4 (en) | 2017-07-19 |
JP5018934B2 (en) | 2012-09-05 |
KR101485237B1 (en) | 2015-01-22 |
CN102971443A (en) | 2013-03-13 |
WO2012002566A1 (en) | 2012-01-05 |
CN102971443B (en) | 2015-03-25 |
TW201207126A (en) | 2012-02-16 |
EP2589678A1 (en) | 2013-05-08 |
KR20130021409A (en) | 2013-03-05 |
JP2012012623A (en) | 2012-01-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2589678B1 (en) | High-strength steel sheet with excellent processability and process for producing same | |
EP2589677B1 (en) | High-strength hot-dip galvanized steel sheet with excellent processability and process for producing same | |
EP3128027B1 (en) | High-strength cold rolled steel sheet having high yield ratio, and production method therefor | |
JP5003785B2 (en) | High tensile steel plate with excellent ductility and method for producing the same | |
JP6179461B2 (en) | Manufacturing method of high-strength steel sheet | |
EP2604715B1 (en) | Method for manufacturing a high-strength cold-rolled steel sheet having excellent formability and crashworthiness | |
JP5971434B2 (en) | High-strength hot-dip galvanized steel sheet excellent in stretch flangeability, in-plane stability and bendability of stretch flangeability, and manufacturing method thereof | |
JP5924332B2 (en) | High-strength hot-dip galvanized steel sheet excellent in workability and manufacturing method thereof | |
EP2792762B1 (en) | High-yield-ratio high-strength cold-rolled steel sheet and method for producing same | |
JP2004068050A (en) | High tensile strength cold rolled steel sheet and its manufacturing method | |
JPWO2013018722A1 (en) | High-strength steel sheet excellent in formability, high-strength galvanized steel sheet, and production method thereof | |
JP2010275627A (en) | High-strength steel sheet and high-strength hot-dip galvanized steel sheet having excellent workability, and method for producing them | |
EP3187613A1 (en) | High-strength cold-rolled steel sheet and method for producing same | |
EP3128026A1 (en) | High-strength cold rolled steel sheet exhibiting excellent material-quality uniformity, and production method therefor | |
JP6079726B2 (en) | Manufacturing method of high-strength steel sheet | |
JP5817671B2 (en) | Hot-rolled steel sheet and manufacturing method thereof | |
WO2013088692A1 (en) | Steel sheet with excellent aging resistance, and method for producing same | |
WO2013094130A1 (en) | High-strength steel sheet and process for producing same | |
EP3705592A1 (en) | High-strength cold-rolled steel sheet, high-strength plated steel sheet, and production methods therefor | |
JP4752522B2 (en) | Manufacturing method of high strength cold-rolled steel sheet for deep drawing | |
EP1394276B1 (en) | High tensile hot-rolled steel sheet excellent in resistance to scuff on mold and in fatigue characteristics | |
WO2016147550A1 (en) | High-strength cold-rolled steel sheet and method for manufacturing same | |
JP2011214070A (en) | Cold-rolled steel sheet, and method for producing same | |
JP2009144251A (en) | High-tensile strength cold-rolled steel sheet | |
WO2023002910A1 (en) | Cold-rolled steel sheet and manufacturing method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20130129 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
DAX | Request for extension of the european patent (deleted) | ||
RA4 | Supplementary search report drawn up and despatched (corrected) |
Effective date: 20170621 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: C22C 38/14 20060101ALI20170615BHEP Ipc: C22C 38/54 20060101ALI20170615BHEP Ipc: C22C 38/06 20060101AFI20170615BHEP Ipc: C22C 38/00 20060101ALI20170615BHEP Ipc: C22C 38/18 20060101ALI20170615BHEP Ipc: C22C 38/08 20060101ALI20170615BHEP Ipc: C21D 9/46 20060101ALI20170615BHEP Ipc: C22C 38/02 20060101ALI20170615BHEP Ipc: C22C 38/04 20060101ALI20170615BHEP Ipc: C22C 38/12 20060101ALI20170615BHEP Ipc: C21D 8/02 20060101ALI20170615BHEP |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: GRANT OF PATENT IS INTENDED |
|
INTG | Intention to grant announced |
Effective date: 20180322 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE PATENT HAS BEEN GRANTED |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 1037888 Country of ref document: AT Kind code of ref document: T Effective date: 20180915 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 602011051828 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MP Effective date: 20180905 |
|
REG | Reference to a national code |
Ref country code: LT Ref legal event code: MG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181205 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181205 Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20181206 Ref country code: RS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MK05 Ref document number: 1037888 Country of ref document: AT Kind code of ref document: T Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: HR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190105 Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20190105 Ref country code: SM Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 602011051828 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
26N | No opposition filed |
Effective date: 20190606 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20190628 Year of fee payment: 9 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20190630 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190629 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190629 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190630 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190630 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20190630 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20200629 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200629 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO Effective date: 20110629 Ref country code: MT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20180905 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20230510 Year of fee payment: 13 Ref country code: DE Payment date: 20230502 Year of fee payment: 13 |