EP2703312B1 - Verbesserter Rohrkopf mit schrankenbildendem Einsatz - Google Patents

Verbesserter Rohrkopf mit schrankenbildendem Einsatz Download PDF

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Publication number
EP2703312B1
EP2703312B1 EP13178391.2A EP13178391A EP2703312B1 EP 2703312 B1 EP2703312 B1 EP 2703312B1 EP 13178391 A EP13178391 A EP 13178391A EP 2703312 B1 EP2703312 B1 EP 2703312B1
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EP
European Patent Office
Prior art keywords
insert
tube head
tube
neck
internal volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP13178391.2A
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English (en)
French (fr)
Other versions
EP2703312A1 (de
Inventor
Eric Kerman
Thierry Maurice
Jean-Claude Jammet
Etienne Hermant
Jérôme Liard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Albea Services SAS
Original Assignee
Albea Services SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
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Application filed by Albea Services SAS filed Critical Albea Services SAS
Priority to PL13178391T priority Critical patent/PL2703312T3/pl
Publication of EP2703312A1 publication Critical patent/EP2703312A1/de
Application granted granted Critical
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00—Details of bottles or jars not otherwise provided for
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/02—Body construction
    • B65D35/10—Body construction made by uniting or interconnecting two or more components

Definitions

  • the present invention relates to the field of flexible tubes, and more specifically the heads of such tubes.
  • Flexible tubes commonly consist of a tube head associated with a skirt, the tube head comprising a neck for extracting a product contained in the tube, while the skirt forms the internal volume of the tube adapted to receive a product.
  • the skirt is conventionally formed of a multilayer sheet, adapted to exhibit satisfactory mechanical strength and sealing properties.
  • the tube head is however commonly made by injection of plastic material, which may be unsatisfactory for some applications because of the very aggressive nature of some products.
  • the present invention aims at providing a structure that does not have such disadvantages.
  • the present invention proposes a tube head (1) adapted to be associated with a skirt (4) so as to form an internal volume of the tube, said tube head (1) having a shape of revolution and comprising a body (11) made of plastic material comprising a neck (3) having at one end an opening (5) through which a product is extracted from the internal volume of the tube and a shoulder (2) connected to a second end of the neck (3 ) opposite to the first end, said tube head (1) further comprising an insert (6) disposed in contact with said shoulder (2), so as to form a barrier between the body (11) and the product contained in the internal volume, said insert (6) ) comprising a central portion (63) and a peripheral region (64), said central portion forming a non-open disc adapted to close the neck (3), and said peripheral region being mounted in contact with a complementary surface of the body (11) , the head being characterized by the fact that the insert is of substantially flat shape, forming part of a cylindrical volume of diameter D and height h, the ratio h / D being less than
  • the invention thus makes it possible to have a tube head having an insert forming a barrier thus protecting the body of the tube head. of the product it contains, and moreover forming an insulating operculum the internal volume of the tube prior to its first use.
  • Said insert is formed, for example, of a multilayer material comprising a metal barrier layer.
  • said insert is disposed substantially perpendicular to a longitudinal axis of the neck.
  • said insert is substantially flat.
  • Such a feature has the advantage of limiting the stresses that brings to the insert conical shapes too marked, that is to say, with a vertex angle too low. Indeed, such forms cause work of the insert during its formation, such work may weaken said insert, in particular its metal barrier layer.
  • substantially flat means that said insert has a shape that can be strictly flat or at least the tube head having a shape of revolution, not extending beyond a cylindrical volume of diameter D and height h, a ratio of the value h / D being less than 0.1, preferably 0.08, even more preferably 0.065, the diameter D corresponding to the diameter of the insert.
  • said insert comprises an aluminum disc or ethylene-vinyl alcohol disc
  • the body further comprises an internal shoulder enclosing the periphery of said insert against the complementary flat surface of the body.
  • said tube head further comprises a plug adapted to be screwed onto said neck, said stopper comprising a punch adapted to allow the perforation of said insert to make an opening in the insert, the opening having a section less than or equal to the internal section of the neck.
  • the invention also relates to an assembly comprising a tube head as defined above and a flexible skirt associated with said tube head so as to form an internal volume of the tube, said internal volume being isolated from the neck by the insert.
  • the figure 1 has a sectional view of a tube head 1 according to one aspect of the invention
  • the tube head 1 comprises a body 11 comprising a shoulder 2 and a neck 3 linked to the shoulder 2.
  • the shoulder 2 is linked to a skirt 4 forming the body of the associated tube and thus defining an internal volume of the tube.
  • the neck 3 defines an internal conduit 5 for dispensing a product contained in the internal volume of the tube.
  • the neck 3 comprises an external thread 31 adapted to allow screwing a cap on said neck 3, and a bearing surface 32 which can perform a stop function for such a cap.
  • the tube head 1 is connected to the skirt 4, typically by overmolding the tube head 1 on the skirt 1, or for example by welding or gluing by assembling the skirt 4 on the previously formed tube head 1, in particular by injection or by injection compression, or by any other technique.
  • the skirt 4 is typically formed of plastic and / or laminated metal; for example a multilayer assembly comprising one or more layers of metallic material such as aluminum, and one or more layers of plastic.
  • the tube head 1 further comprises an insert 6 disposed in contact with, in particular bearing on, the shoulder 2, typically in contact with, in particular against, a face 21 of the shoulder 2 facing the internal volume of the defined by the skirt 4.
  • the insert 6 is thus disposed in direct contact against the face 21 of the shoulder 2, this contact being achieved by overmolding the body 11 of the tube head 1 on the insert 6 which makes it possible in particular to fix the insert 6 to the body 11 of the tube head 1.
  • Said face 21 of the shoulder 2 thus defines a flat bearing surface so as to receive the insert 6.
  • the insert 6 comprises a central portion 63 and a peripheral region 64, the central portion 63 forming a non-open disc adapted to close the neck 3 of the tube head 1, and the peripheral region 64 being typically frustoconical, planar, or a combination of one or more frustoconical and / or planar portions extending from said central portion 63.
  • the insert is substantially flat.
  • the tube head having a form of revolution, it is comprised in a cylindrical volume of diameter D and height h, a ratio of the value h / D being less than 0.1, preferably 0.08, even more preferably 0.065, the diameter D corresponding to the diameter of the insert, as illustrated figure 3 where the height of h to be taken into account has also been indicated.
  • the insert has one or more frustoconical portions, it has a sufficiently large apex angle, especially greater than 80 °, or even 85 °.
  • the tube head as shown is typically associated with a perforating plug, for example of the type shown on the figure 2 .
  • the perforator plug 7 as presented is reversible; it has a first end provided with an internal thread 71 adapted to cooperate with the external thread 31 of the neck 3 and thus screw the perforator plug 7 on the tube head 1, and a second end provided with a punch 76 adapted to be inserted in the neck 3 and perforate all or part of the insert 6, and more precisely all or part of its central portion 63 closing the neck 3.
  • the punch 76 is dimensioned so that when the perforating plug 7 bears against the neck 3, the piercing end of the punch 76 comes to exceed the position of the insert 6 in the tube head 1 and can perforate it, allowing the user to make an opening communicating the internal volume of the tube and the inner pipe 5 of the neck so as to use the product contained in the internal volume.
  • the insert 6, and more particularly its central portion 63 thus forms a seal, sealing the internal volume of the tube defined by the skirt 4 and protecting the product contained therein.
  • the insert has a flat disk shape and therefore does not require plastic deformation steps that would reduce its mechanical properties and in particular the mechanical properties of metal layers of the insert, and in particular its properties allowing it to act as a barrier.
  • the figure 3 shows another embodiment of a tube head according to one aspect of the invention, wherein the geometry of the peripheral section 64 is composed of the combination of a plane section 65 and two successive frustoconical sections 66 and 67 Alternatively, the outer section 67 may be formed of a folded edge terminating substantially axially, over a short length, typically less than 1 mm, or even 0.5 mm.
  • the peripheral section 64 is mounted in contact, in particular in abutment, against a complementary surface of the body 11, while the central portion 63 forms a lid adapted to close the neck 3 of the tube head 1 prior to its first use when which said central portion is perforated at least partially by a punch 76 as presented above.
  • the angle between the flat central portion 63 and the most inclined section of the peripheral section 64, in this case the section 67 is typically between 0 and 30 °, for example between 10 and 30 ° or equal to 30 °, to simplify the injection for the formation of the tube head.
  • the angle between the plane section 65 and the adjacent frustoconical section 66 is, for example, between 0 and 15 °, in particular between 5 and 10 °.
  • the mechanical properties of the insert and in particular the mechanical properties of metal layers of the insert, and in particular its properties enabling it to act as a barrier are not affected. Indeed, the insert undergoes only a small plastic deformation and the rupture of the metal layer is not reached.
  • the product contained in the tube is thus durably and effectively protected during its period of storage prior to its use, which typically represents most of the life of the tube.
  • the insert 6 is full, and does not have a machined central orifice makes it possible to overcome the problems of centering which necessarily arises during the realization of two successive concentric holes. It is indeed complex and expensive to perfectly center the cutting of the outer periphery of the insert 6 relative to a central bore of the disk thus formed.
  • an insert structure 6 is a multilayer insert of Polyethylene-Aluminum-Polyethylene type.
  • the inserts 6 commonly used to perform a barrier function in flexible tube heads are typically composed of two layers of plastic material surrounding a metal interlayer. The two layers of plastic material serve to isolate the metal layer of the product contained in the tube, which is likely to oxidize. Therefore, it is clear that only the edges of the insert 6 expose its metal intermediate layer.
  • the insert 6 is a solid disc, only its outer peripheral edge 61 exposes its metallic intermediate layer.
  • the shoulder 2 of the tube head 1 is advantageously overmolded on the insert 6 so as to cover the outer peripheral edge 61 of the insert 6, for example by forming an internal shoulder 26 enclosing the periphery of said insert 6 against the complementary flat surface of the body 11 and thus protecting the metal intermediate layer of the insert 6 prior to its perforation.
  • the perforation of the insert 6 by the punch 76 forms an inner peripheral edge of the insert through which the metal intermediate layer is exposed.
  • the risk of degradation of the insert 6 after its perforation is negligible.
  • the shelf life of a tube in its state with the non-perforated insert corresponding for example to its storage, handling, transport, is conventionally much higher than its shelf life after its first use.
  • the protection of the insert 6 prior to the first use of the associated tube, and therefore to the perforation of the insert 6, is therefore an important factor in the good preservation of the product contained by the tube, which makes it possible to realize the present invention. .

Claims (8)

  1. Rohrkopf (1), der dazu vorgesehen ist, mit einer Schürze (4) verbunden zu werden, um ein Innenvolumen des Rohrs zu bilden wobei der Rohrkopf (1)eine Umdrehungsform aufweist und einen Körper (11) umfasst, der aus einem Kunststoff hergestellt ist, umfassend einen Hals (3), der an einem ersten Ende eine Öffnung (5) aufweist, durch die ein Produkt aus dem Innenvolumen des Rohrs entnommen wird, und einen Absatz (2), der mit einem zweiten Ende des Halses (3) gegenüber dem ersten Ende verbunden ist,
    wobei der Rohrkopf (1) ferner einen Einsatz (6) umfasst, der in Kontakt mit dem Absatz (2) angeordnet ist, um eine Schranke zwischen dem Körper (11) und dem Produkt, das in dem Innenvolumen enthalten ist, zu bilden, wobei der Einsatz (6) einen zentralen Abschnitt (63) und einen peripheren Abschnitt (64) umfasst, wobei der zentrale Abschnitt eine nicht gelochte Scheibe bildet, die dazu vorgesehen ist, den Hals (3) zu verschließen, und wobei der periphere Abschnitt in Kontakt mit einer komplementären Fläche des Körpers (11) montiert ist,
    wobei der Kopf dadurch gekennzeichnet ist, dass der Einsatz im Wesentlichen flache Form hat, die in ein zylindrisches Volumen mit einem Durchmesser D und einer Höhe h eingeschrieben ist, wobei das Verhältnis h/D kleiner als 0,1 ist, wobei der Durchmesser D dem Durchmesser des Einsatzes entspricht.
  2. Rohrkopf (1) nach Anspruch 1, bei dem der Einsatz (6) im Wesentlichen senkrecht auf eine Längsachse des Halses (3) angeordnet ist.
  3. Rohrkopf (1) nach einem der Ansprüche 1 oder 2, bei dem der Einsatz (6) eine Scheibe aus Aluminium oder aus Vinylalkoholäthylen umfasst.
  4. Rohrkopf (1) nach einem der Ansprüche 1 bis 3, bei dem der Körper (11) ferner einen inneren Absatz (26) umfasst, der die Peripherie des Einsatzes (6) gegen die komplementäre ebene Fläche des Körpers (11) drückt.
  5. Rohrkopf (1) nach einem der Ansprüche 1 bis 4, ferner umfassend einen Stöpsel (7), der dazu geeignet ist, auf den Hals (3) geschraubt zu werden, wobei der Stöpsel einen Stempel (76) umfasst, der dazu geeignet ist, die Perforation des Einsatzes (6) zu ermöglichen, um eine Öffnung in dem Einsatz (6) herzustellen, wobei die Öffnung einen Querschnitt kleiner oder gleich dem Innenquerschnitt des Halses (3) aufweist.
  6. Rohrkopf (1) nach einem der vorhergehenden Ansprüche, bei dem das Verhältnis h/D kleiner als 0,08 ist.
  7. Rohrkopf (1) nach einem der vorhergehenden Ansprüche, bei dem das Verhältnis h/D kleiner als 0,065 ist.
  8. Einheit, umfassend einen Rohrkopf (1) nach einem der vorhergehenden Ansprüche und eine flexible Schürze (4), die mit dem Rohrkopf (1) verbunden ist, um das Innenvolumen des Rohrs zu bilden, wobei das Innenvolumen vom Hals (3) durch den Einsatz (6) isoliert ist.
EP13178391.2A 2012-08-28 2013-07-29 Verbesserter Rohrkopf mit schrankenbildendem Einsatz Active EP2703312B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL13178391T PL2703312T3 (pl) 2012-08-28 2013-07-29 Ulepszona główka tuby zawierająca wkładkę tworzącą barierę

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1258047A FR2994947B1 (fr) 2012-08-28 2012-08-28 Tete de tube amelioree comprenant un insert formant barriere.

Publications (2)

Publication Number Publication Date
EP2703312A1 EP2703312A1 (de) 2014-03-05
EP2703312B1 true EP2703312B1 (de) 2015-03-11

Family

ID=47624203

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13178391.2A Active EP2703312B1 (de) 2012-08-28 2013-07-29 Verbesserter Rohrkopf mit schrankenbildendem Einsatz

Country Status (9)

Country Link
US (1) US9957086B2 (de)
EP (1) EP2703312B1 (de)
CN (1) CN103662335B (de)
BR (1) BR102013020647B1 (de)
ES (1) ES2537422T3 (de)
FR (1) FR2994947B1 (de)
MX (1) MX2013009973A (de)
PL (1) PL2703312T3 (de)
RU (1) RU2654456C2 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020025154A1 (de) 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung
DE102018118888A1 (de) * 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202013012702U1 (de) * 2013-05-24 2018-09-10 Georg Menshen Gmbh & Co. Kg Einschweißteil mit Sperrschicht
FR3012349B1 (fr) 2013-10-29 2020-07-31 Albea Services Tete de tube comprenant un insert formant barriere
EP3235753B1 (de) 2016-04-19 2021-05-12 Albéa Services System für das schliessen einer tube, tube damit und entsprechende perforierende kappe
CN109677769A (zh) * 2018-11-07 2019-04-26 广州市瑞高包装工业有限公司 一种复合软管
KR102076661B1 (ko) * 2019-05-31 2020-02-13 임종수 숄더 및 네크에 차단 기능을 갖는 튜브용기 및 그의 제조방법

Citations (18)

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FR445014A (fr) 1911-06-16 1912-10-31 Charles Joseph Camus Système de fermeture pour bouteilles
GB757562A (en) 1954-05-17 1956-09-19 Gestetner Ltd Improvements in or relating to collapsible containers
GB772964A (en) 1955-07-08 1957-04-17 Hedley Thomas & Co Ltd Collapsible tube
US3260411A (en) 1964-07-13 1966-07-12 American Can Co Collapsible container structure
LU81001A1 (fr) 1978-06-09 1979-06-18 Minmetal Srl Dispositif de fermeture de l'orifice de sortie d'un tube souple destine a contenir un produit alimentaire pateux
GB2098917A (en) 1981-05-07 1982-12-01 Maegerle Karl Tubular container and process for producing same
JPS60172659A (ja) 1984-02-08 1985-09-06 関西チユ−ブ株式会社 積層チユ−ブ
US4792061A (en) 1984-11-09 1988-12-20 Taisei Kako Co., Ltd. Collapsible tube with membrane cap
JPH08169453A (ja) 1994-12-21 1996-07-02 Kose Corp チューブ容器
JP2001158448A (ja) 1999-11-30 2001-06-12 Yoshino Kogyosho Co Ltd 合成樹脂製チューブ容器
JP2002193283A (ja) 2000-12-26 2002-07-10 Yoshino Kogyosho Co Ltd チューブ容器
WO2003013965A1 (de) 2001-08-07 2003-02-20 Kmk Lizence Ltd. Verpackungsbehälter
JP2004284678A (ja) 2003-03-03 2004-10-14 Takeuchi Press Ind Co Ltd チューブ容器
US20070210027A1 (en) 2003-10-10 2007-09-13 Abbott Douglas A Child-Resistant Package
JP2011148512A (ja) 2010-01-19 2011-08-04 Kyodo Printing Co Ltd 閉鎖型チューブ容器
JP2011195144A (ja) 2010-03-17 2011-10-06 Shiseido Co Ltd チューブ容器
WO2012140038A1 (en) 2011-04-15 2012-10-18 L'oreal Multi-compartment device for storing and dispensing products
DE112006002709B4 (de) 2005-10-12 2013-03-21 Kansai Tube Co. Ltd. Verfahren zum Bilden eines Kopfabschnitts einer Tube des geschlossenen Typs, Verfahren zum Herstellen eines röhrenförmigen Behälters des geschlossenen Typs und röhrenförmiger Behälter des geschlossenen Typs

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JP4406344B2 (ja) * 2004-09-27 2010-01-27 富士フイルム株式会社 多孔質膜カートリッジ及びその製造方法
DE102005005166A1 (de) * 2005-02-04 2006-08-10 Georg Menshen Gmbh & Co. Kg Verschluss für einen Beutel
CN201033660Y (zh) * 2007-02-16 2008-03-12 美晨集团股份有限公司 一种旅游牙膏
CN201272536Y (zh) * 2008-09-01 2009-07-15 美晨集团股份有限公司 一种复合牙膏管
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Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR445014A (fr) 1911-06-16 1912-10-31 Charles Joseph Camus Système de fermeture pour bouteilles
GB757562A (en) 1954-05-17 1956-09-19 Gestetner Ltd Improvements in or relating to collapsible containers
GB772964A (en) 1955-07-08 1957-04-17 Hedley Thomas & Co Ltd Collapsible tube
US3260411A (en) 1964-07-13 1966-07-12 American Can Co Collapsible container structure
LU81001A1 (fr) 1978-06-09 1979-06-18 Minmetal Srl Dispositif de fermeture de l'orifice de sortie d'un tube souple destine a contenir un produit alimentaire pateux
GB2022547A (en) 1978-06-09 1979-12-19 Minmetal Srl Flexible tube
GB2098917A (en) 1981-05-07 1982-12-01 Maegerle Karl Tubular container and process for producing same
JPS60172659A (ja) 1984-02-08 1985-09-06 関西チユ−ブ株式会社 積層チユ−ブ
US4792061A (en) 1984-11-09 1988-12-20 Taisei Kako Co., Ltd. Collapsible tube with membrane cap
JPH08169453A (ja) 1994-12-21 1996-07-02 Kose Corp チューブ容器
JP2001158448A (ja) 1999-11-30 2001-06-12 Yoshino Kogyosho Co Ltd 合成樹脂製チューブ容器
JP2002193283A (ja) 2000-12-26 2002-07-10 Yoshino Kogyosho Co Ltd チューブ容器
WO2003013965A1 (de) 2001-08-07 2003-02-20 Kmk Lizence Ltd. Verpackungsbehälter
DE10137937A1 (de) 2001-08-07 2003-03-06 Maegerle Karl Lizenz Verpackungsbehälter
JP2004284678A (ja) 2003-03-03 2004-10-14 Takeuchi Press Ind Co Ltd チューブ容器
US20070210027A1 (en) 2003-10-10 2007-09-13 Abbott Douglas A Child-Resistant Package
DE112006002709B4 (de) 2005-10-12 2013-03-21 Kansai Tube Co. Ltd. Verfahren zum Bilden eines Kopfabschnitts einer Tube des geschlossenen Typs, Verfahren zum Herstellen eines röhrenförmigen Behälters des geschlossenen Typs und röhrenförmiger Behälter des geschlossenen Typs
JP2011148512A (ja) 2010-01-19 2011-08-04 Kyodo Printing Co Ltd 閉鎖型チューブ容器
JP2011195144A (ja) 2010-03-17 2011-10-06 Shiseido Co Ltd チューブ容器
WO2012140038A1 (en) 2011-04-15 2012-10-18 L'oreal Multi-compartment device for storing and dispensing products

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020025154A1 (de) 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung
DE102018118887A1 (de) * 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung
DE102018118888A1 (de) * 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung
WO2020025155A1 (de) 2018-08-03 2020-02-06 Linhardt Gmbh & Co. Kg Tubenverpackung und verfahren zur deren herstellung

Also Published As

Publication number Publication date
US9957086B2 (en) 2018-05-01
RU2013139728A (ru) 2015-03-10
BR102013020647B1 (pt) 2020-05-19
BR102013020647A2 (pt) 2016-05-24
CN103662335A (zh) 2014-03-26
FR2994947B1 (fr) 2015-08-07
PL2703312T3 (pl) 2015-08-31
EP2703312A1 (de) 2014-03-05
US20140061146A1 (en) 2014-03-06
CN103662335B (zh) 2018-01-09
RU2654456C2 (ru) 2018-05-17
MX2013009973A (es) 2016-03-10
ES2537422T3 (es) 2015-06-08
FR2994947A1 (fr) 2014-03-07

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