Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/17—Component parts, details or accessories; Auxiliary operations
  • B29C45/26—Moulds
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
  • B29C45/14336—Coating a portion of the article, e.g. the edge of the article
  • B29C45/14418—Sealing means between mould and article
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C33/00—Moulds or cores; Details thereof or accessories therefor
  • B29C33/0038—Moulds or cores; Details thereof or accessories therefor with sealing means or the like
  • B29C33/0044—Moulds or cores; Details thereof or accessories therefor with sealing means or the like for sealing off parts of inserts projecting into the mould cavity
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C33/00—Moulds or cores; Details thereof or accessories therefor
  • B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
  • B29C33/3807—Resin-bonded materials, e.g. inorganic particles
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
  • B29C45/14065—Positioning or centering articles in the mould
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
  • B29C45/14549—Coating rod-like, wire-like or belt-like articles
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/17—Component parts, details or accessories; Auxiliary operations
  • B29C45/26—Moulds
  • B29C45/2616—Moulds having annular mould cavities
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/0025—Preventing defects on the moulded article, e.g. weld lines, shrinkage marks
  • B29C2045/0034—Mould parting lines
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
  • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
  • B29C45/14598—Coating tubular articles
  • B29C2045/14606—Mould cavity sealing means
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension

Definitions

• the invention generally relates to insert molding and, in particular, to a system, method and apparatus for forming seals with a positive flash shut-off for the insert molding of liquid silicone rubber are disclosed.
• Curable silicone compositions are used in a variety of applications that range from the automotive industry to medical devices.
• the silicone composition is coupled to a variety of substrates such as polymeric, metallic, or glass substrates.
• substrates such as polymeric, metallic, or glass substrates.
• silicone compositions may be used as a coating or a laminate over a variety of components.
• a mold for injection molding on the component has a base with a cavity and a port that delivers a liquid to the cavity during the injection molding process.
• the base has a component support structure for supporting the component and pockets formed on opposite sides of the cavity. The pockets are slightly spaced apart from the cavity by thin partitions.
• Embodiments further comprise inserts located in the pockets.
• the inserts are formed from a polymer, such as a fluoroelastomer or a perfluoroelastomer. Both the partitions and inserts comprise the component support structure.
• the inserts have a dimension that is smaller than that of the base and partitions so as to form a compression fit around the component during the molding process. This design reduces or eliminates flash of the mold fluid down the component during the molding process.
• FIG. 1 is a side view of a component having seals formed thereon;
• FIG. 2 is an enlarged side view of a portion of the component of FIG. 1 ;
• FIG. 3 is a sectional end view of the portion of FIG. 2, taken along the line 3— 3 of FIG. 2;
• FIG. 4 is an enlarged side view of a second portion of the component of FIG. 1 ;
• FIG. 5 is a sectional end view of the second portion of FIG. 4, taken along the line 5— 5 of FIG. 4;
• FIG. 6 is an isometric view of an embodiment of a mold for molding the seals
• FIG. 7 is a top view of an embodiment of a subassembly for the mold of FIG. 6;
• FIGS. 8 and 9 are top and end views, respectively, of an embodiment of an insert for the subassembly of FIG. 7;
• FIGS. 10 and 11 are top and end views, respectively, of another embodiment of an insert;
• FIGS. 12 and 13 are top and side views, respectively, of another embodiment of a subassembly.
• FIG. 14 is an enlarged top view of a LSR mold cavity for the subassembly of FIGS. 12 and 13.
• Embodiments of a system, method and apparatus for forming an object with a positive flash shut-off for the insert molding of the object on a component are disclosed.
• some embodiments form seals with a positive flash shut-off for the insert molding of liquid silicone rubber (LSR) onto the object.
• LSR liquid silicone rubber
• embodiments of a mold 20 for injection molding comprise at least one base 21 having a cavity 23 (e.g., cavity 23a or 23b) and at least one port 25 (FIGS. 2, 7 and 8) that delivers a liquid to the cavity 23 during the injection molding process.
• a cavity 23 e.g., cavity 23a or 23b
• FIGS. 2, 7 and 8 At least one port 25 that delivers a liquid to the cavity 23 during the injection molding process.
• the base 21 may comprise a subcomponent that is mounted in and supported by a larger base foundation (not shown) for compression against another similar base foundation during the molding process. More than one base 21 may be used in such a base foundation.
• the base is formed from a base material, such as steel.
• the base 21 also has a component support structure 27 having an axis 29.
• the component support structure 27 coaxially supports a component 101 on which one or more objects 103, 105 (FIGS. 10 - 14), such as seals, are molded in cavities 23.
• Embodiments of the base 21 also have a pair of pockets 31 (FIG. 8) formed in the base on opposite axial sides of the cavity 23. The pockets 31 extend in a transverse direction with respect to the axis 29.
• the pockets 31 are axially adjacent to the cavity 23 but axially spaced apart from the cavity 23 by respective partitions 33 extending from the base 21.
• Each partition 33 may comprise an axial thickness 35 (FIG. 2) in a range of 0.002 to 0.050 inches, or approximately 0.010 inches in other embodiments.
• the partitions 33 may be formed from the base material.
• Embodiments further comprise a pair of inserts 41 located in respective ones of the pockets 31.
• each of the inserts 41 may be formed from a polymer that is softer than the base material.
• the polymer may be provided with a Shore A durometer hardness in a range of 75 to 100, or about 90 in some
• the polymer also may have an operating temperature range of 135°C to 205 °C.
• the polymer may comprise a fluoropolymer having a low surface energy and maintain elasticity at a temperature of up to about 300°C. At elevated temperatures, the low surface energy of the fluoropolymer provides excellent release properties relative to the other material substrate.
• the polymer comprises a fluoroelastomer or a perfluoroelastomer, and may comprise at least 60% fluorine, and have a mold release property similar to polytetrafluoroethylene (PTFE).
• PTFE polytetrafluoroethylene
• Both the partitions 33 and the inserts 31 comprise the component support structure 27 as shown.
• the component support structure 27 has a cylindrical shape as shown.
• the base 21 and the partitions 33 have a base diameter 51 (FIG. 2) for the cylindrical shape, and the inserts 41 have an insert diameter 53 for the cylindrical shape.
• the insert diameter 53 is smaller than the base diameter 51.
• some embodiments of the base 21, partitions 33 and the inserts 41 have alignment features such as apertures 26, 28 (e.g., two horizontal apertures 26, and one vertical aperture 28 shown) that are provided for mechanical locating devices, such as pins to ensure alignment between the various parts.
• vertical aperture 28 is used to align an alignment pin with the hole 128 (FIG. 11) in the component 101.
• Clearances are provided between the alignment pins and apertures to allow movement of the inserts under compression, and the apertures may be provided as through holes. For example, clearances on the order of or less than 0.020 inches may be provided. Slots may be formed as well in order to avoid material from breaking away under compression. Without sufficient clearances, some inserts may swell due to the heat from the mold, and the insert material may be pinched during compression and shear edges where it makes contact with the surrounding steel.
• the inserts 41 have a width W (FIG. 5) that is less than a width of the base 21.
• W width
• the component support structure 27 of at least one of the inserts 41 has a neck 55 that tapers radially along an axial direction of the neck 55 and component 101.
• the neck 55 that provides a mechanical stop and positioning feature for the component 101.
• the component has a neck 155 that is complementary in shape to neck 55 in the insert 41.
• each of the inserts 41 has a top 43, two sides 45 and a chamfer 47 extending between the top 43 and two sides 45 on opposite sides of the component support structure 27.
• Embodiments of a method of overmolding a component 101 comprise providing a pair of bases 21, each having a cavity 23 and a port 25. Pockets 31 are formed in the bases 21 on opposite sides of respective one of the cavities 23. The pockets 31 are adjacent to the cavities 23 but spaced apart from the cavities 23 by respective partitions 33 extending from the bases 21.
• the method also comprises installing inserts 41 in respective ones of the pockets 33, with each of the inserts 41 being formed from a polymer that is softer than a base material used to form the bases 21; defining a component support structure 27 in each of the bases 21, partitions 33 and inserts 41 to support the component 101; placing the component 101 on one of the bases 21 such that the component 101 is supported by the component support structure 27 of said one of the bases 21; pressing the other base 21 onto said one of the bases 21 such that the component 101 seats in the component support structure 27 of said other base 21, and the inserts 41 in both bases 21 are compressed, such as in a radial direction with respect to an axis of the component 101.
• a liquid is delivered to the cavity 23 through the port 25 to form at least one object 103, 105 on the component 101.
• the method comprises forming each partition with a thickness in a range of 0.002 to 0.050 inches, approximately 0.010 inches, and/or forming the partitions from the base material.
• Other embodiments comprise forming the polymer with a Shore A durometer hardness in a range of 75 to 100, or about 90, and/or an operating temperature in a range of 135°C to 205°C.
• the polymer may be formed from a fluoropolymer, a fluoroelastomer or a perfluoroelastomer, or at least 60% fluorine.
• the method may comprise defining the component support structure as a cylindrical shape, the bases and the partitions have a base diameter for the cylindrical shape, the inserts have an insert diameter for the cylindrical shape, and the insert diameter is smaller than the base diameter; defining the component support structure of at least one of the inserts with a neck that tapers radially along an axial direction of the neck, and the neck provides a mechanical stop and positioning feature for the component; forming each of the inserts with a top, two sides and chamfers extending between the top and two sides on opposite sides of the component support structure; and/or forming the bases, partitions and inserts with alignment features that respectively align with other.
• Some embodiments of the inserts may comprise fluoroelastomers from the FKM family of rubbers designed for high temperature operation. Examples include Dai-El, Fluorel, Technoflon and Viton®. They can operate continuously in excess of 200°C depending on the grade, and intermittently to temperatures on the order of 300°C.
• inserts may comprise perfluoro elastomers in the FFKM family of rubbers. Examples include Chemraz, Kalrez®, Perfluor, Simriz and Zalak. These materials have even greater heat and chemical resistance than the
• fluoroelastomers They can be used in extreme conditions up to temperatures around 300°C or more with special compounding. Their disadvantages are difficult processing, cost, poorer physical properties at high temperature, and their high glass transition temperatures which limit their use at low temperatures. Some materials cannot be used below 0°C, and even at normal ambient temperatures their creep properties may be limited.
• exemplary fluoropolymers that may be used to form the inserts include a homopolymer, copolymer, terpolymer, or polymer blend formed from a monomer, such as tetrafluoroethylene, hexafluoropropylene, chlorotrifluoroethylene, trifluoroethylene, vinylidene fluoride, vinyl fluoride, perfluoropropyl vinyl ether, perfluoromethyl vinyl ether, or any combination thereof.
• Exemplary fluoropolymers layers may be cast, skived, or extruded. In an embodiment, cast and extruded fluoropolymer layers may include multilayered structures such that the composition of the surfaces of the film may or may not match.
• fluoropolymers include a poly tetrafluoroethylene (PTFE), fluorinated ethylene propylene copolymer (FEP), a copolymer of tetrafluoroethylene and perfluoropropyl vinyl ether (PFA), a copolymer of tetrafluoroethylene and perfluoromethyl vinyl ether (MFA), a copolymer of ethylene tetrafluoroethylene (ETFE), a copolymer of ethylene and chlorotrifluoroethylene (ECTFE),
• PTFE poly tetrafluoroethylene
• FEP fluorinated ethylene propylene copolymer
• PFA perfluoropropyl vinyl ether
• MFA perfluoromethyl vinyl ether
• ETFE ethylene tetrafluoroethylene
• ECTFE chlorotrifluoroethylene
• the fluoropolymer layer may include a poly tetrafluoroethylene (PTFE), fluorinated ethylene propylene copolymer (FEP), or blends, mixtures, or alloys thereof.
• the fluoropolymer may be a polymer crosslinkable through radiation, such as e-beam.
• An exemplary crosslinkable fluoropolymer may include ETFE, THV, PVDF, or any combination thereof.
• a THV resin is available from Dyneon 3M Corporation Minneapolis, Minn.
• An ECTFE polymer is available from Ausimont Corporation (Italy) under the trade name Halar.
• Other fluoropolymers may be obtained from Daikin (Japan) and DuPont (USA).
• FEP fluoropolymers are
• the silicone base polymer may include a non-polar silicone polymer.
• the silicone base polymer may, for example, include
• polyalkylsiloxanes such as silicone polymers formed of a precursor, such as dimethylsiloxane, diethylsiloxane, dipropylsiloxane, methylethylsiloxane, methylpropylsiloxane, or combinations thereof.
• the polyalkylsiloxane includes a polydialkylsiloxane, such as polydimethylsiloxane (PDMS).
• PDMS polydimethylsiloxane
• the polyalkylsiloxane is a silicone hydride- containing polydimethylsiloxane.
• the polyalkylsiloxane is a vinyl-containing polydimethylsiloxane.
• the silicone base polymer is a combination of a hydride-containing polydimethylsiloxane and a vinyl- containing polydimethylsiloxane.
• the silicone base polymer is non- polar and is free of halide functional groups, such as chlorine and fluorine, and of phenyl functional groups.
• the silicone base polymer may include halide functional groups or phenyl functional groups.
• the silicone base polymer may include fluorosilicone or phenylsilicone.
• the silicone base polymer is elastomeric.
• the durometer (Shore A) of the silicone base polymer may be less than about 75, such as about 1 to 70, about 20 to about 50, about 30 to about 50, about 40 to about 50, or about 1 to about 5.
• the silicone base polymer may further include a catalyst and other optional additives. Exemplary additives may include, individually or in combination, fillers, inhibitors, colorants, and pigments.
• the silicone base polymer is platinum catalyzed. Alternatively, the silicone base polymer may be peroxide catalyzed. In another example, the silicone base polymer may be a combination of platinum catalyzed and peroxide catalyzed.
• the silicone base polymer may be a room temperature vulcanizable (RTV) formulation or a gel.
• the silicone base polymer may be a high consistency gum rubber (HCR) or a liquid silicone rubber (LSR).
• the silicone base polymer is an HCR, such as SE6035, SE6075 available from Momentive, MF135 available from Bluestar silicone, and Silastic® Q7-4535, Silastic® Q7-4550 available from Dow Corning.
• the silicone base polymer is a platinum catalyzed LSR.
• the silicone base polymer is an LSR formed from a two-part reactive system.
• the silicone base polymer may be a conventional, commercially prepared silicone base polymer.
• the commercially prepared silicone base polymer typically includes the non-polar silicone polymer, a catalyst, a filler, and optional additives.
• Particular embodiments of conventional, commercially prepared LSR include Wacker Elastosil® LR 3003/50 by Wacker Silicone of Adrian, MI and Silbione® LSR 4340 by Bluestar Silicones of Ventura, CA.
• a commercially prepared silicone base polymer is available as a one-part or two-part reactive system.
• part 1 typically includes a vinyl-containing polydialkylsiloxane, a filler, and catalyst.
• Part 2 typically includes a hydride-containing polydialkylsiloxane and optionally, a vinyl-containing polydialkylsiloxane and other additives.
• a reaction inhibitor may be included in Part 1 or Part 2.
• Mixing Part 1 and Part 2 by any suitable mixing method produces the silicone base polymer.
• the excess hydride-containing siloxane is typically added to the commercially prepared silicone base polymer prior to vulcanization.
• the excess hydride- containing siloxane is added to the mixed two-part system or during the process of mixing the two-part system prior to vulcanization.
• the silicone base polymer and the excess hydride-containing siloxane are mixed in a mixing device.
• the mixing device is a mixer in an injection molder.
• the mixing device is a mixer, such as a dough mixer, Ross mixer, two-roll mill, or Brabender mixer.
• the embodiments described herein have numerous advantages over prior solutions.
• the compression of the inserts forms a pre-load and tight seal around the component to form a positive shut-off and prevent excess flash from forming axially down the component during the molding process.
• the inserts may be installed at the parting lines of the mold to create the positive shut-off and eliminate flash on the component, "as molded” or "as formed”. No subsequent flash removal operation is required for the insert molded components.
• This system is compatible with both hot runner and cold runner mold operations.
• the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion.
• a process, method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such process, method, article, or apparatus.
• “or” refers to an inclusive-or and not to an exclusive-or. For example, a condition A or B is satisfied by any one of the following: A is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present).

Landscapes

• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Manufacturing & Machinery (AREA)
• Chemical & Material Sciences (AREA)
• Inorganic Chemistry (AREA)
• Moulds For Moulding Plastics Or The Like (AREA)
• Injection Moulding Of Plastics Or The Like (AREA)
• Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Applications Claiming Priority (2)

Publications (3)

Family

ID=45004779

Family Applications (1)

Country Status (10)

Families Citing this family (6)

Citations (6)

Family Cites Families (37)

• 2011
  • 2011-05-25 WO PCT/US2011/037950 patent/WO2011150092A2/en active Application Filing
  • 2011-05-25 US US13/115,722 patent/US9085102B2/en active Active
  • 2011-05-25 RU RU2012155057/05A patent/RU2526388C2/ru not_active IP Right Cessation
  • 2011-05-25 KR KR1020127032687A patent/KR101436416B1/ko not_active IP Right Cessation
  • 2011-05-25 CN CN201180025108.0A patent/CN102905869B/zh not_active Expired - Fee Related
  • 2011-05-25 EP EP11787351.3A patent/EP2576178B1/de not_active Not-in-force
  • 2011-05-25 JP JP2013511418A patent/JP2013526440A/ja active Pending
  • 2011-05-25 MX MX2012013435A patent/MX341719B/es active IP Right Grant
  • 2011-05-25 CA CA2799924A patent/CA2799924C/en not_active Expired - Fee Related
  • 2011-05-25 BR BR112012029356-7A patent/BR112012029356B1/pt not_active IP Right Cessation
• 2015
  • 2015-06-09 JP JP2015116334A patent/JP6014209B2/ja not_active Expired - Fee Related

Patent Citations (6)

Also Published As

Similar Documents

Legal Events