JP6069342B2 - フルオロシリコーンゴム層をシリコーンゴム層へ接着する方法 - Google Patents
フルオロシリコーンゴム層をシリコーンゴム層へ接着する方法 Download PDFInfo
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- JP6069342B2 JP6069342B2 JP2014545070A JP2014545070A JP6069342B2 JP 6069342 B2 JP6069342 B2 JP 6069342B2 JP 2014545070 A JP2014545070 A JP 2014545070A JP 2014545070 A JP2014545070 A JP 2014545070A JP 6069342 B2 JP6069342 B2 JP 6069342B2
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- fluorosilicone
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- 229920005560 fluorosilicone rubber Polymers 0.000 title claims description 51
- 229920002379 silicone rubber Polymers 0.000 title claims description 36
- 239000004945 silicone rubber Substances 0.000 title claims description 34
- 238000000034 method Methods 0.000 title claims description 33
- -1 siloxane units Chemical group 0.000 claims description 123
- 239000000203 mixture Substances 0.000 claims description 81
- 229920000642 polymer Polymers 0.000 claims description 41
- 239000003054 catalyst Substances 0.000 claims description 33
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 26
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 25
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 22
- 239000000945 filler Substances 0.000 claims description 21
- 150000002430 hydrocarbons Chemical class 0.000 claims description 21
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000004215 Carbon black (E152) Substances 0.000 claims description 16
- 229930195733 hydrocarbon Natural products 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- 239000010948 rhodium Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 12
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 125000001153 fluoro group Chemical group F* 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000000654 additive Substances 0.000 claims description 7
- 229910052697 platinum Inorganic materials 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001451 organic peroxides Chemical class 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 4
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002318 adhesion promoter Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000004088 foaming agent Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 3
- 230000000181 anti-adherent effect Effects 0.000 claims description 2
- 239000006254 rheological additive Substances 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 2
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 238000002156 mixing Methods 0.000 description 13
- 229920001577 copolymer Polymers 0.000 description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 12
- 229920001971 elastomer Polymers 0.000 description 11
- 239000005060 rubber Substances 0.000 description 11
- 125000003342 alkenyl group Chemical group 0.000 description 10
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- 239000012763 reinforcing filler Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 229920002554 vinyl polymer Polymers 0.000 description 6
- 239000004793 Polystyrene Substances 0.000 description 5
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 229920002223 polystyrene Polymers 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 229910021485 fumed silica Inorganic materials 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- DMWVYCCGCQPJEA-UHFFFAOYSA-N 2,5-bis(tert-butylperoxy)-2,5-dimethylhexane Chemical compound CC(C)(C)OOC(C)(C)CCC(C)(C)OOC(C)(C)C DMWVYCCGCQPJEA-UHFFFAOYSA-N 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 125000003709 fluoroalkyl group Chemical group 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 230000003014 reinforcing effect Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229920002545 silicone oil Polymers 0.000 description 3
- 125000004434 sulfur atom Chemical group 0.000 description 3
- 125000003944 tolyl group Chemical group 0.000 description 3
- WRXCBRHBHGNNQA-UHFFFAOYSA-N (2,4-dichlorobenzoyl) 2,4-dichlorobenzenecarboperoxoate Chemical compound ClC1=CC(Cl)=CC=C1C(=O)OOC(=O)C1=CC=C(Cl)C=C1Cl WRXCBRHBHGNNQA-UHFFFAOYSA-N 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 229940045985 antineoplastic platinum compound Drugs 0.000 description 2
- 125000003710 aryl alkyl group Chemical group 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000005816 fluoropropyl group Chemical group [H]C([H])(F)C([H])([H])C([H])([H])* 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 description 2
- 150000003058 platinum compounds Chemical class 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 125000005504 styryl group Chemical group 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
- 229910052882 wollastonite Inorganic materials 0.000 description 2
- 239000010456 wollastonite Substances 0.000 description 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 description 1
- MYOQALXKVOJACM-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy pentaneperoxoate Chemical compound CCCCC(=O)OOOC(C)(C)C MYOQALXKVOJACM-UHFFFAOYSA-N 0.000 description 1
- KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- NALFRYPTRXKZPN-UHFFFAOYSA-N 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane Chemical compound CC1CC(C)(C)CC(OOC(C)(C)C)(OOC(C)(C)C)C1 NALFRYPTRXKZPN-UHFFFAOYSA-N 0.000 description 1
- GTZYBRAEJNYYGI-UHFFFAOYSA-N 1-[(2,4-dimethylphenyl)methylperoxymethyl]-2,4-dimethylbenzene Chemical compound CC1=CC(C)=CC=C1COOCC1=CC=C(C)C=C1C GTZYBRAEJNYYGI-UHFFFAOYSA-N 0.000 description 1
- PQXKLSYJDSMALY-UHFFFAOYSA-N 1-chloro-4-[(4-chlorophenyl)methylperoxymethyl]benzene Chemical compound C1=CC(Cl)=CC=C1COOCC1=CC=C(Cl)C=C1 PQXKLSYJDSMALY-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- KXCPKXUNEQYGLM-UHFFFAOYSA-N 2,5-dichloro-5-[(1,4-dichlorocyclohexa-2,4-dien-1-yl)methylperoxymethyl]cyclohexa-1,3-diene Chemical compound C1=CC(Cl)=CCC1(Cl)COOCC1(Cl)C=CC(Cl)=CC1 KXCPKXUNEQYGLM-UHFFFAOYSA-N 0.000 description 1
- ULJIVYHHXJIBFP-UHFFFAOYSA-N 5-[(1,4-dimethylcyclohexa-2,4-dien-1-yl)methylperoxymethyl]-2,5-dimethylcyclohexa-1,3-diene Chemical compound CC1(COOCC2(CC=C(C=C2)C)C)CC=C(C=C1)C ULJIVYHHXJIBFP-UHFFFAOYSA-N 0.000 description 1
- 125000004648 C2-C8 alkenyl group Chemical group 0.000 description 1
- 239000004970 Chain extender Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- XUGISPSHIFXEHZ-GPJXBBLFSA-N [(3r,8s,9s,10r,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1h-cyclopenta[a]phenanthren-3-yl] acetate Chemical class C1C=C2C[C@H](OC(C)=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 XUGISPSHIFXEHZ-GPJXBBLFSA-N 0.000 description 1
- WYUIWUCVZCRTRH-UHFFFAOYSA-N [[[ethenyl(dimethyl)silyl]amino]-dimethylsilyl]ethene Chemical compound C=C[Si](C)(C)N[Si](C)(C)C=C WYUIWUCVZCRTRH-UHFFFAOYSA-N 0.000 description 1
- 239000000370 acceptor Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 229910001586 aluminite Inorganic materials 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical class O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 229920005549 butyl rubber Polymers 0.000 description 1
- 238000011088 calibration curve Methods 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 239000011231 conductive filler Substances 0.000 description 1
- 229940116318 copper carbonate Drugs 0.000 description 1
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- UOCIZHQMWNPGEN-UHFFFAOYSA-N dialuminum;oxygen(2-);trihydrate Chemical compound O.O.O.[O-2].[O-2].[O-2].[Al+3].[Al+3] UOCIZHQMWNPGEN-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000005388 dimethylhydrogensiloxy group Chemical group 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- BITPLIXHRASDQB-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane Chemical group C=C[Si](C)(C)O[Si](C)(C)C=C BITPLIXHRASDQB-UHFFFAOYSA-N 0.000 description 1
- RCNRJBWHLARWRP-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane;platinum Chemical compound [Pt].C=C[Si](C)(C)O[Si](C)(C)C=C RCNRJBWHLARWRP-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 101150062840 hcr1 gene Proteins 0.000 description 1
- 150000004687 hexahydrates Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
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- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
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- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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- 229910000077 silane Inorganic materials 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
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- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- 125000004205 trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- MEBONNVPKOBPEA-UHFFFAOYSA-N trimethyl cyclohexane Natural products CC1CCCCC1(C)C MEBONNVPKOBPEA-UHFFFAOYSA-N 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Description
i)硬化前に、ヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンのいずれかを、フルオロシリコーンゴム組成物に加える工程と、
ii)硬化前に、他のヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンを、別のシリコーンゴム組成物に加える工程と、
iii)工程(i)及び工程(ii)の生成物を所望の形状に成形する工程と、
iv)工程(iii)の成形物を互いに接触させる工程と、
v)これらの成形物の間でヒドロシリル化反応を生じさせることによって、互いに接触している成形物を接着させる工程と、を含む。
i)硬化前に、ヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンのいずれかを、フルオロシリコーンゴム組成物に加える工程と、
ii)硬化前に、他のヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンを、別のシリコーンゴム組成物に加える工程と、
iii)工程(i)及び工程(ii)の生成物を含み、かつ40:60〜60:40の範囲内で、工程(ii)の生成物に対する工程(i)の生成物の重量比を有する混合化合物を調製する工程と、
iv)工程(i)、工程(ii)及び工程(iii)の生成物を所望の形状に成形する工程と、
v)工程(iv)の成形物を工程(i)の生成物と工程(ii)の生成物との間の工程(iii)の生成物に接触させる工程と、
vi)工程(v)の生成物を硬化させることによって、互いに接触している成形物を接着させる工程と、を含む。
Me3SiO(Me2SiO)r[R’’CH2CH2Si(Me)O]t(MeHSiO)zSiMe3
(式中、各R’’は、同一であっても異なっていてもよく、1〜8個の炭素原子を有する分枝鎖又は直鎖ペルフルオロアルキルラジカルを示し、rの値はゼロ以上、t及びzの値はそれぞれゼロより大きく、フルオロシリコーンポリマーが1〜10モル%の水素結合シロキサン単位と、少なくとも5モル%のフッ素化シロキサン単位と、残部のジメチルシロキサン単位及び上述した式により表されるような鎖硬化ラジカルとを含有するような値であり、rの値がゼロの場合、t及びzの値はそれぞれゼロより大きく、フルオロシリコーンポリマーが20〜50モル%のフッ素化シロキサン単位を含有し、かつ25℃で10〜10000mPa・sの粘度を有するような値である。)
HMe2SiO(MeHSiO)m[R’’QSi(Me)O]fSiMe2H、
HMe2SiO(MeHSiO)m(R’’QHSiO)fSiMe2H、
R’’QMeHSio(MeHSiO)m(R’’QHSiO)fSiMeHRQ、
Me3SiO(Me2SiO)0.95m(MeHSiO)0.05m(R’’QMeSiO)fSiMe3、
HMe2SiO(Me2SiO)m(R’’QMeSiO)fSiMe2H、
HMeR’’QSiO(R’’QMeSiO)fSiMeR’’QH、
Me2R’’QSiO(R’’QMeSiO)0.95f(R’’QHiSiO)0.05f及び
Me3SiO(Me2SiO)m(R’’QMeSiO)0.90f(R’’QHSiO)0.10fSiMe3
を含む(式中、ポリマーの粘度は自由に流動する液体から緩やかに流動するガムまでの範囲にわたり、m及びfは0〜10,000以上の値を有する)。
(A)100,000を超える重量平均分子量を有し、かつ式(R’’Q)a(R’)b SiO(4−a−b)/2を有するフッ素化シロキサン単位、及び式(R’)cSiO(4−c)/2を有する非フッ素化シロキサン単位(式中、前記フッ素化及び非フッ素化シロキサン単位において、R’’は、1〜8個の炭素原子を有する分枝鎖又は直鎖ペルフルオロアルキルラジカルを示し、Qは、少なくとも2個の炭素原子を介してR’’ラジカルをケイ素原子に連結させる二価炭化水素、炭化水素エーテル又は炭化水素チオエーテルラジカルを示し、R’は、飽和又は不飽和のケイ素結合一価炭化水素基を示し、a=1〜2,b=0〜2,c=0〜3である。)をポリマー中に含むポリオルガノシロキサン100重量部と、
(B)好適な充填剤5〜200重量部と、
(E)1分子あたり平均少なくとも2個のケイ素結合水素ラジカルを含有するフルオロシリコーンポリマーと、
(C)有機過酸化物0.1〜10重量部と、
(D)100,000を超える重量平均分子量及び平均単位式R1 ySiO(4−y)/2(式中、R1は、不飽和であってよいが、フルオロ置換基を含有しない置換又は非置換一価炭化水素基であり、yは、1.96〜2.03の数である)を有する第2のポリオルガノシロキサン0〜20重量部と、を含む。
(i)成分(E)に記載の任意の種類のオルガノポリシロキサンと、
(ii)成分(B)に記載の任意の種類の充填剤又は充填剤群と、
(iii)成分(C)として定義される任意の種類の硬化剤と、
(iv)成分(F)に記載の任意の種類のヒドロシリル化触媒と、
1つ以上のレオロジー改質剤、顔料、着色剤、抗接着剤、可塑剤、接着促進剤、発泡剤、防火剤及び防湿剤などの群から選択される任意の添加剤と、を含む。
A)フッ素化ポリジオルガノシロキサンポリマー
B)1つ以上の補強充填剤及び/又は非補強充填剤
C)好適な非ヒドロシリル化硬化触媒
(R’’Q)a(R’)bSiO(4−a−b)/2
各R’’は、同一であっても異なっていてもよく、1〜8個の炭素原子を有する分枝鎖又は直鎖フルオロアルキルラジカルを示し、
各Qは、同一であっても異なっていてもよく、少なくとも2個の炭素原子を含有する二価炭化水素、炭化水素エーテル又は炭化水素チオエーテルを示す。各R’’ラジカルは、Q基を介してケイ素原子に連結されている。
式中、a=0〜2,b=0〜2であり、aが0である場合、単位あたりの少なくとも1つのR’基は1つ以上の炭素−フッ素結合を含有する。
HMe2SiO(MeHSiO)m[R’’QSi(Me)O]fSiMe2H
HMe2SiO(MeHSiO)m(R’’QHSiO)fSiMe2H
R’’QMeHSiO(MeHSiO)m(R’’QHSiO)fSiMeHRQ
Me3SiO(Me2SiO)0.95m(MeHSiO)0.05m(R’’QMeSiO)fSiMe3
HMe2SiO(Me2SiO)m(R’’QMeSiO)fSiMe2H
HMeR’’QSiO(R’’QMeSiO)fSiMeR’’QH
Me2R’’QSiO(R’’QMeSiO)0.95f(R’’QHiSiO)0.05f及び
Me3SiO(Me2SiO)m(R’’QMeSiO)0.90f(R’’QHSiO)0.10fSiMe3
(式中、ポリマーの粘度は自由に流動する液体から緩やかに流動するガムまでの範囲にわたり、m及びfは0〜10,000以上の値を有する。)を含む。
Me3SiO(Me2SiO)r[R’’CH2CH2Si(Me)O]t(MeHSiO)zSiMe3
式中、rの値はゼロ以上であり、t及びzの値はそれぞれゼロより大きく、かつ、フルオロシリコーンポリマーが1〜95モル%の水素結合シロキサン単位と、少なくとも5モル%のフッ素化シロキサン単位及び残部のジメチルシロキサン単位を含有し、かつ、25℃で10〜10000mPa・sの粘度を有するような値である。
(A)100,000を超える重量平均分子量を有し、かつ式(R’’Q)a(R’)b SiO(4−a−b)/2を有するフッ素化シロキサン単位、及び式(R’)cSiO(4−c)/2を有する非フッ素化シロキサン単位(式中、前記フッ素化及び非フッ素化シロキサン単位において、R’’は、1〜8個の炭素原子を有する分枝鎖又は直鎖ペルフルオロアルキルラジカルを示し、Qは、少なくとも2個の炭素原子を介してR’’ラジカルをケイ素原子に連結させる二価炭化水素、炭化水素エーテル又は炭化水素チオエーテルラジカルを示し、R’は、飽和又は不飽和のケイ素結合一価炭化水素基を示し、a=1〜2,b=0〜2,c=0〜3である。)をポリマー中に含むポリオルガノシロキサン100重量部と、
(B)好適な充填剤5〜200重量部と、
(E)1分子あたり平均少なくとも2個のケイ素結合水素ラジカル含有するフルオロシリコーンポリマーと、
(C)有機過酸化物0.1〜10重量部と、
(D)100,000を超える重量平均分子量及び平均単位式R1 ySiO(4−y)/2(式中、R1は、不飽和であってよいが、フルオロ置換基を含有しない置換又は非置換一価炭化水素基であり、yは、1.96〜2.03の数である)を有する第2のポリオルガノシロキサン0〜20重量部と、を含む。
67重量部の、GPC(1重量%のトルエン溶液、rI検出器、ポリスチレン標準)によって測定される重量平均分子量が610,000である、ヒドロキシ末端トリフルオロプロピルメチルシロキサンビニルメチルシロキサン共重合体(ビニル基含有量:0.13重量%)。
23重量部のヒュームドシリカ。
8重量部のヒドロキシ末端トリフルオロプロピルメチルシロキサン。
0.3重量部のジメチルビニルシロキシ末端ジメチル、メチルビニルシロキサン。
1.8重量部の、25℃で35mm2/sの粘度を有する、トリメチルシリル基末端メチル(ペルフルオロブチルエチル)シロキサンメチルハイドロジェンシロキサン共重合体(SiH含有量:0.5重量%)。
1重量%の、シリコーンオイル中の2,5−ジメチル−2,5−ジ(t−ブチルペルオキシ)ヘキサン触媒45%のペーストの組成物。
[HCR1]
62重量部の、GPC(0.1重量%のテトラヒドロフラン溶液、基準指標検出器、及びポリスチレン標準がGPC分析のための較正曲線を構成するために利用された)によって測定された重量平均分子量が680,000であるジメチルビニルシロキシ末端ジメチルシロキサンメチルビニルシロキサン共重合体(ビニル基含有量:0.02重量%)。
1重量部の、25℃で17000mPa・sの粘度を有するジメチルビニルシロキシ末端ジメチルシロキサンメチルビニルシロキサン共重合体(ビニル基含有量:7.8重量%)。
31.4重量部のヒュームドシリカ。
5重量部の、21mPa・sまでの粘度を有するヒドロキシ−末端ジメチルシロキサン。
0.4重量部の、25℃で20mPa・sの粘度を有するヒドロキシ−末端ジメチルシロキサンメチルビニルシロキサン共重合体(ビニル基含有量:10重量%)。
0.2重量部の、1,3−ジビニル−1,1,3,3−テトラメチルジシロキサン白金錯体とジメチルビニルシロキシ基末端ジメチルシロキサンメチルビニルシロキサン共重合体との混合物(白金金属含有量:0.5重量%)。
1重量%の、シリコーンオイル中の2,5−ジメチル−2,5−ジ(t−ブチルペルオキシ)ヘキサン触媒45%のペーストの組成物。
反対の記載がない限り、以下の実施例に記述される接着性試験に使用された全ての試料は、以下の方法で作製された。
実施例1〜4において調製された試料に対して、50mm・min−1のクロスヘッド速度でインストロン張力計を使用して180°剥離試験が行われた。
この実施例において、未硬化及び予備成形フルオロシリコーンゴム(FSR)及び高稠度のゴム(HCR)試料を、各化合物の試料が、本発明の一実施形態に従って、互いに硬化及び接着されるように、上述の試料調製方法を使用する硬化の前にHCR及びFSRの混合物と結合させた。HCR及びFSRの混合物は、表1に記載の比率で、2本ロールミルで均一に調製された。
2 内部フルオロシリコーンライナー
3 混合層
4 シリコーンゴム内層
5 補強層
6 シリコーンゴム外層
Claims (11)
- 非ヒドロシリル化硬化プロセスを用いて硬化可能なフルオロシリコーンゴム層を、ペルフルオロアルキル基を全く含まず、かつ非ヒドロシリル化硬化プロセスを用いて硬化可能なシリコーンゴム層へ接着する方法であって、
i)硬化前に、ヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンのいずれかを、フルオロシリコーンゴム組成物に加える工程と、
ii)硬化前に、ヒドロシリル化触媒、又はケイ素結合水素基を少なくとも2つ含有するシロキサンの他方を、別のシリコーンゴム組成物に加える工程と、
iii)工程(i)及び工程(ii)の生成物を含み、かつ40:60〜60:40の範囲内で、工程(ii)の生成物に対する工程(i)の生成物の重量比を有する混合化合物を調製する工程と、
iv)工程(i)、工程(ii)及び工程(iii)の生成物を所望の形状に成形する工程と、
v)工程(i)の成形物と工程(ii)の成形物との間に工程(iii)の成形物を配置する工程であって、前記工程(iii)の成形物は前記工程(i)の成形物及び前記工程(ii)の成形物と接触する、工程と、
vi)工程(v)の生成物を硬化させることによって、互いに接触している成形物を接着させる工程と、を含む方法。 - 工程(vi)の前に、工程(iii)の生成物は未硬化のままであることを特徴とする、請求項1に記載の方法。
- 工程(vi)の前に、工程(i)の生成物、工程(ii)の生成物及び工程(iii)の生成物は全て未硬化のままであることを特徴とする、請求項1に記載の方法。
- 工程(vi)の前に、及び/又は工程(vi)の間に、工程(i)、工程(ii)、及び工程(iii)の生成物の間の接触面に圧力が加えられる、請求項1に記載の方法。
- 工程(vi)は室温〜200℃の温度で行われることを特徴とする、請求項1に記載の方法。
- 前記ヒドロシリル化触媒は、白金、ロジウム、イリジウム、パラジウム又はルテニウム系触媒を含む群から選択される白金族金属系触媒であることを特徴とする、請求項1に記載の方法。
- 前記ケイ素結合水素含有シロキサンは、式
Me3SiO(Me2SiO)r[R’’CH2CH2Si(Me)O]t(MeHSiO)zSiMe3
で表される、ケイ素結合水素ラジカルを有する直鎖構造であることを特徴とし、
式中、各R’’は、同一であっても異なっていてもよく、1〜8個の炭素原子を有する分枝鎖又は直鎖ペルフルオロアルキルラジカルを示し、rの値はゼロ以上、t及びzの値はそれぞれゼロより大きく、フルオロシリコーンポリマーが1〜10モル%の水素結合シロキサン単位と、少なくとも5モル%のフッ素化シロキサン単位と、残部のジメチルシロキサン単位及び上述した式により表されるような鎖硬化ラジカルとを含有するような値であり、rの値がゼロの場合、t及びzの値はそれぞれゼロより大きく、フルオロシリコーンポリマーが20〜50モル%のフッ素化シロキサン単位を含有し、かつ25℃で10〜10000mPa・sの粘度を有するような値である、請求項1に記載の方法。 - 前記ケイ素結合水素含有シロキサンは、
HMe2SiO(MeHSiO)m[R’’QSi(Me)O]fSiMe2H、
HMe2SiO(MeHSiO)m(R’’QHSiO)fSiMe2H、
R’’QMeHSiO(MeHSiO)m(R’’QHSiO)fSiMeHRQ、
Me3SiO(Me2SiO)0.95m(MeHSiO)0.05m(R’’QMeSiO)fSiMe3、
HMe2SiO(Me2SiO)m(R’’QMeSiO)fSiMe2H、
HMeR’’QSiO(R’’QMeSiO)fSiMeR’’QH、
Me2R’’QSiO(R’’QMeSiO)0.95f(R’’QHiSiO)0.05f及び
Me3SiO(Me2SiO)m(R’’QMeSiO)0.90f(R’’QHSiO)0.10fSiMe3
を含み、
式中、ポリマーの粘度は自由に流動する液体から緩やかに流動するガムまでの範囲にわたり、m及びfは0〜10,000以上の値を有する、請求項7に記載の方法。 - 前記フルオロシリコーンゴム組成物は、
(A)100,000を超える重量平均分子量を有し、かつ式(R’’Q)a(R’)b SiO(4−a−b)/2を有するフッ素化シロキサン単位、及び式(R’)cSiO(4−c)/2を有する非フッ素化シロキサン単位(式中、前記フッ素化及び非フッ素化シロキサン単位において、R’’は、1〜8個の炭素原子を有する分枝鎖又は直鎖ペルフルオロアルキルラジカルを示し、Qは、少なくとも2個の炭素原子を介してR’’ラジカルをケイ素原子に連結させる二価炭化水素、炭化水素エーテル又は炭化水素チオエーテルラジカルを示し、R’は、飽和又は不飽和のケイ素結合一価炭化水素基を示し、a=1〜2,b=0〜2,c=0〜3である)をポリマー中に含むポリオルガノシロキサン100重量部と、
(B)好適な充填剤5〜200重量部と、
(E)1分子あたり平均少なくとも2個のケイ素結合水素ラジカル含有するフルオロシリコーンポリマーと、
(C)有機過酸化物0.1〜10重量部と、
(D)100,000を超える重量平均分子量及び平均単位式R1 ySiO(4−y)/2(式中、R1は、不飽和であってよいが、フルオロ置換基を含有しない置換又は非置換一価炭化水素基であり、yは、1.96〜2.03の数である)を有する第2のポリオルガノシロキサン0〜20重量部と、を含む、請求項1に記載の方法。 - 使用可能なシリコーンゴム組成物は、
(i)請求項9の成分(E)に記載の任意の種類のオルガノポリシロキサンと、(ii)請求項9の成分(B)に記載の任意の種類の充填剤又は充填剤群と、(iii)請求項9の成分(C)として定義される任意の種類の硬化剤と、
1つ以上のレオロジー改質剤、顔料、着色剤、抗接着剤、可塑剤、接着促進剤、発泡剤、防火剤及び防湿剤の群から選択される任意の添加剤と、を含むことを特徴とする、請求項1〜9のいずれか一項に記載の方法。 - 請求項1〜10のいずれか一項に記載の方法によってシリコーンゴムに接着されたフルオロシリコーンゴムを含むホースを調整する方法。
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CN101835825B (zh) * | 2007-10-26 | 2014-04-23 | 道康宁东丽株式会社 | 粘结硅橡胶部件的方法 |
JP2010215763A (ja) * | 2009-03-16 | 2010-09-30 | Shin-Etsu Chemical Co Ltd | 定着ロール用付加硬化型シリコーン接着剤及び定着ロール |
JP5024570B2 (ja) * | 2009-10-29 | 2012-09-12 | 信越化学工業株式会社 | フルオロシリコーンゴムとジメチルシリコーンゴムの接着方法及び積層体 |
CN102168500A (zh) | 2010-11-26 | 2011-08-31 | 重庆大众防腐有限公司 | 砖内衬烟囱的压顶部位的防腐处理方法 |
CN102241936A (zh) | 2011-05-26 | 2011-11-16 | 开平市日固力涂料有限公司 | 一种耐高温隔热保温涂料 |
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CN103159968B (zh) | 2017-04-05 |
EP2788410B1 (en) | 2016-08-17 |
WO2013082989A1 (en) | 2013-06-13 |
US9908308B2 (en) | 2018-03-06 |
US20140335296A1 (en) | 2014-11-13 |
EP2788410A1 (en) | 2014-10-15 |
EP2788410A4 (en) | 2015-08-05 |
KR20140105511A (ko) | 2014-09-01 |
JP2015502431A (ja) | 2015-01-22 |
CN103159968A (zh) | 2013-06-19 |
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