EP2447395A2 - Electrode pour la production électrolytique de chlore - Google Patents

Electrode pour la production électrolytique de chlore Download PDF

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Publication number
EP2447395A2
EP2447395A2 EP11186428A EP11186428A EP2447395A2 EP 2447395 A2 EP2447395 A2 EP 2447395A2 EP 11186428 A EP11186428 A EP 11186428A EP 11186428 A EP11186428 A EP 11186428A EP 2447395 A2 EP2447395 A2 EP 2447395A2
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EP
European Patent Office
Prior art keywords
ruthenium
titanium
iridium
layer
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP11186428A
Other languages
German (de)
English (en)
Other versions
EP2447395A3 (fr
Inventor
Andreas Bulan
Jürgen KINTRUP
Rainer Weber
Ruiyong Chen
Vinh Trieu
Harald Natter
Rolf Hempelmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Intellectual Property GmbH
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Publication of EP2447395A2 publication Critical patent/EP2447395A2/fr
Publication of EP2447395A3 publication Critical patent/EP2447395A3/fr
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/24Halogens or compounds thereof
    • C25B1/26Chlorine; Compounds thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/093Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Chemically Coating (AREA)
EP11186428A 2010-10-28 2011-10-25 Electrode pour la production électrolytique de chlore Withdrawn EP2447395A3 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102010043085A DE102010043085A1 (de) 2010-10-28 2010-10-28 Elektrode für die elektrolytische Chlorherstellung

Publications (2)

Publication Number Publication Date
EP2447395A2 true EP2447395A2 (fr) 2012-05-02
EP2447395A3 EP2447395A3 (fr) 2013-01-30

Family

ID=45023580

Family Applications (1)

Application Number Title Priority Date Filing Date
EP11186428A Withdrawn EP2447395A3 (fr) 2010-10-28 2011-10-25 Electrode pour la production électrolytique de chlore

Country Status (5)

Country Link
US (1) US20120103828A1 (fr)
EP (1) EP2447395A3 (fr)
JP (1) JP2012092449A (fr)
CN (1) CN102465312A (fr)
DE (1) DE102010043085A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017214810A1 (de) 2017-08-24 2019-02-28 Gabriele Keddo Vorrichtung und Verfahren zur Wasserdesinfektion und Herstellung eines Desinfektionsmittels
EP3416222A4 (fr) * 2016-02-10 2019-10-23 Sumitomo Electric Industries, Ltd. Électrode pour batteries à flux redox, et batterie à flux redox
CN111994967A (zh) * 2020-08-26 2020-11-27 海南尚合超电新能源科技有限公司 一种钛掺杂的高镍三元锂离子正极材料制备方法

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FI2823079T3 (fi) 2012-02-23 2023-05-04 Treadstone Tech Inc Korrosiota kestävä ja sähköä johtava metallin pinta
RU2507640C1 (ru) * 2012-07-02 2014-02-20 Федеральное государственное бюджетное учреждение науки Институт проблем химической физики РАН (ИПХФ РАН) Каталитический электрод для спиртовых топливных элементов
KR101406721B1 (ko) * 2013-04-03 2014-06-16 한국에너지기술연구원 성능이 향상된 전극 소재용 분말 제조 방법과 이를 이용한 전극과 그 활용.
CN103774175B (zh) * 2014-01-26 2015-12-02 福州大学 一种嵌入钌锆锡钛氧化物的活性涂层及其制备方法
CN103774177B (zh) * 2014-01-26 2015-12-02 福州大学 一种嵌入钌锆锡氧化物的活性涂层及其制备方法
DK3224392T3 (en) * 2014-11-24 2018-12-03 Industrie De Nora Spa ANODE FOR ELECTROLYTIC DEVELOPMENT OF CHLOR
US10435782B2 (en) * 2015-04-15 2019-10-08 Treadstone Technologies, Inc. Method of metallic component surface modification for electrochemical applications
JP2016204732A (ja) * 2015-04-28 2016-12-08 旭化成株式会社 電解用電極
US20190338429A1 (en) * 2016-11-22 2019-11-07 Asahi Kasei Kabushiki Kaisha Electrode for electrolysis
CN107142491A (zh) * 2017-04-10 2017-09-08 广东卓信环境科技股份有限公司 一种透气电极及其制备方法
KR102393900B1 (ko) * 2017-09-29 2022-05-03 주식회사 엘지화학 전기분해 음극용 코팅액 조성물
IT201800003533A1 (it) 2018-03-14 2019-09-14 Industrie De Nora Spa Elettrodo per processi di elettroclorazione
IT201800006544A1 (it) * 2018-06-21 2019-12-21 Anodo per evoluzione elettrolitica di cloro
CN109518168B (zh) * 2018-12-14 2020-11-03 广西大学 一种高稳涂层的活性钛基电极板的制备方法
CN111517419A (zh) * 2020-03-20 2020-08-11 昆明学院 一种具有磷选择性的催化电极及其制备方法
CN111704211A (zh) * 2020-06-26 2020-09-25 陕西科技大学 一种铂钌钛钇dsa电极的制备方法
CN114472121B (zh) * 2021-12-21 2023-03-24 西安泰金新能科技股份有限公司 一种高活性涂层钛阳极的制备方法
CN114457368B (zh) * 2022-03-08 2023-11-21 昆明冶金研究院有限公司 一种锌电积用涂层钛阳极及其制备方法
CN114560536B (zh) * 2022-03-09 2023-07-28 四川塔菲尔环境科技有限公司 一种铽铼改性Ti/RuO2形稳阳极、制备方法及应用

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3562008A (en) 1968-10-14 1971-02-09 Ppg Industries Inc Method for producing a ruthenium coated titanium electrode
US3632498A (en) 1967-02-10 1972-01-04 Chemnor Ag Electrode and coating therefor
US3776834A (en) 1972-05-30 1973-12-04 Leary K O Partial replacement of ruthenium with tin in electrode coatings
US3882002A (en) 1974-08-02 1975-05-06 Hooker Chemicals Plastics Corp Anode for electrolytic processes
US3948751A (en) 1967-12-14 1976-04-06 Oronzio De Nora Impianti Elettrochimici S.P.A. Valve metal electrode with valve metal oxide semi-conductive face
US3950240A (en) 1975-05-05 1976-04-13 Hooker Chemicals & Plastics Corporation Anode for electrolytic processes
US4039409A (en) 1975-12-04 1977-08-02 General Electric Company Method for gas generation utilizing platinum metal electrocatalyst containing 5 to 60% ruthenium
EP0046449A1 (fr) 1980-08-18 1982-02-24 Eltech Systems Corporation Electrode dimensionellement stable, pourvue d'un revêtement, destinée à des processus électrochimiques, comportant une couche intermédiaire protectrice d'oxyde à base d'un métal de soupape ainsi que son procédé de fabrication
US4517068A (en) 1981-12-28 1985-05-14 Eltech Systems Corporation Electrocatalytic electrode
US4668531A (en) 1984-01-31 1987-05-26 Permelec Electrode Ltd. Method for manufacture of electrode
DE4032417A1 (de) 1990-10-12 1992-04-16 Univ Halle Wittenberg Dimensionsstabile anode (dsa)
EP0867527A1 (fr) 1997-02-27 1998-09-30 Aragonesas Industrias Y Energia, S.A. Electrode à recouvrement catalytique pour des procesus électrochimiques et procédé de fabrication de celle-ci
WO2006028443A1 (fr) 2004-09-01 2006-03-16 Eltech Systems Corporation Revetement contenant du palladium pour surtension a faible concentration de chlore
CN1900368A (zh) 2006-06-30 2007-01-24 福州大学 高铈含量的含钌涂层钛阳极及其制备方法
US7211177B2 (en) 2002-01-03 2007-05-01 Bayer Aktiengesellschaft Electrode for electrolysis in acidic media
WO2008046784A1 (fr) 2006-10-16 2008-04-24 Industrie De Nora S.P.A. Anode pour électrolyse

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BR8006373A (pt) * 1979-10-08 1981-04-14 Diamond Shamrock Corp Eletrodo para uso em processos eletroliticos, processo para sua fabricacao, e uso do eletrodo
GB2084189B (en) * 1980-08-18 1983-11-02 Diamond Shamrock Corp Coated catalytic electrode for electrochemical processes
CA1190185A (fr) * 1980-08-18 1985-07-09 Michael Katz Electrode enrobee avec couche protectrice intermediaire en polymere conducteur sur assise conductrice
US4331528A (en) * 1980-10-06 1982-05-25 Diamond Shamrock Corporation Coated metal electrode with improved barrier layer
CA1190184A (fr) * 1980-10-07 1985-07-09 Henri B. Beer Electrode metallique enduite, generatrice de pellicule, avec couche antioxydation a base de rhodium ou d'iridium
JP3319887B2 (ja) * 1994-10-05 2002-09-03 クロリンエンジニアズ株式会社 次亜塩素酸塩の製造方法
IT1291604B1 (it) * 1997-04-18 1999-01-11 De Nora Spa Anodo per l'evoluzione di ossigeno in elettroliti contenenti fluoruri o loro derivati
DE10347703A1 (de) * 2003-10-14 2005-05-12 Bayer Materialscience Ag Konstruktionseinheit für bipolare Elektrolyseure
IT1391767B1 (it) * 2008-11-12 2012-01-27 Industrie De Nora Spa Elettrodo per cella elettrolitica

Patent Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3632498A (en) 1967-02-10 1972-01-04 Chemnor Ag Electrode and coating therefor
US3948751A (en) 1967-12-14 1976-04-06 Oronzio De Nora Impianti Elettrochimici S.P.A. Valve metal electrode with valve metal oxide semi-conductive face
US3562008A (en) 1968-10-14 1971-02-09 Ppg Industries Inc Method for producing a ruthenium coated titanium electrode
US3776834A (en) 1972-05-30 1973-12-04 Leary K O Partial replacement of ruthenium with tin in electrode coatings
US3882002A (en) 1974-08-02 1975-05-06 Hooker Chemicals Plastics Corp Anode for electrolytic processes
US3950240A (en) 1975-05-05 1976-04-13 Hooker Chemicals & Plastics Corporation Anode for electrolytic processes
US4039409A (en) 1975-12-04 1977-08-02 General Electric Company Method for gas generation utilizing platinum metal electrocatalyst containing 5 to 60% ruthenium
EP0046449A1 (fr) 1980-08-18 1982-02-24 Eltech Systems Corporation Electrode dimensionellement stable, pourvue d'un revêtement, destinée à des processus électrochimiques, comportant une couche intermédiaire protectrice d'oxyde à base d'un métal de soupape ainsi que son procédé de fabrication
US4517068A (en) 1981-12-28 1985-05-14 Eltech Systems Corporation Electrocatalytic electrode
US4668531A (en) 1984-01-31 1987-05-26 Permelec Electrode Ltd. Method for manufacture of electrode
DE4032417A1 (de) 1990-10-12 1992-04-16 Univ Halle Wittenberg Dimensionsstabile anode (dsa)
EP0867527A1 (fr) 1997-02-27 1998-09-30 Aragonesas Industrias Y Energia, S.A. Electrode à recouvrement catalytique pour des procesus électrochimiques et procédé de fabrication de celle-ci
US7211177B2 (en) 2002-01-03 2007-05-01 Bayer Aktiengesellschaft Electrode for electrolysis in acidic media
WO2006028443A1 (fr) 2004-09-01 2006-03-16 Eltech Systems Corporation Revetement contenant du palladium pour surtension a faible concentration de chlore
CN1900368A (zh) 2006-06-30 2007-01-24 福州大学 高铈含量的含钌涂层钛阳极及其制备方法
WO2008046784A1 (fr) 2006-10-16 2008-04-24 Industrie De Nora S.P.A. Anode pour électrolyse

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ELECTROCHIMICA ACTA, vol. 42, 1997, pages 3525
G.R.P. MALPASS ET AL., ELECTROCHIM. ACTA, vol. 52, 2006, pages 936
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L.M. DA SILVA ET AL., J. ELECTROANAL. CHEM., vol. 532, 2002, pages 141
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T.A.F. LASSALI ET AL., ELECTROCHIMICA ACTA, vol. 39, 1994, pages 1545
TITAN, HAYFIELD, PRECIOUS METAL REVIEW, vol. 27, no. 1, 1983, pages 2 - 8
V. V. PANIC ET AL., COLLOIDS AND SURFACES A, vol. 157, 1999, pages 269
Y. E. ROGINSKAYA ET AL., ELECTROCHIMICA ACTA, vol. 40, 1995, pages 817
Y. TAKASU, ELECTROCHEMICA ACTA, vol. 45, 2000, pages 4135
Y. ZENG ET AL., CERAMICS INTERNATIONAL, vol. 33, 2007, pages 1087

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3416222A4 (fr) * 2016-02-10 2019-10-23 Sumitomo Electric Industries, Ltd. Électrode pour batteries à flux redox, et batterie à flux redox
US11069901B2 (en) 2016-02-10 2021-07-20 Sumitomo Electric Industries, Ltd. Electrode for redox flow battery, and redox flow batteries
DE102017214810A1 (de) 2017-08-24 2019-02-28 Gabriele Keddo Vorrichtung und Verfahren zur Wasserdesinfektion und Herstellung eines Desinfektionsmittels
CN111994967A (zh) * 2020-08-26 2020-11-27 海南尚合超电新能源科技有限公司 一种钛掺杂的高镍三元锂离子正极材料制备方法

Also Published As

Publication number Publication date
DE102010043085A1 (de) 2012-05-03
CN102465312A (zh) 2012-05-23
JP2012092449A (ja) 2012-05-17
EP2447395A3 (fr) 2013-01-30
US20120103828A1 (en) 2012-05-03

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