EP2379465B1 - Malerleinwand mit einem mittel zum einfangen von formaldehyd und herstellungsverfahren - Google Patents

Malerleinwand mit einem mittel zum einfangen von formaldehyd und herstellungsverfahren Download PDF

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EP2379465B1
EP2379465B1 EP20090805758 EP09805758A EP2379465B1 EP 2379465 B1 EP2379465 B1 EP 2379465B1 EP 20090805758 EP20090805758 EP 20090805758 EP 09805758 A EP09805758 A EP 09805758A EP 2379465 B1 EP2379465 B1 EP 2379465B1
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radical
canvas
acid
acid dihydrazide
formaldehyde
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EP2379465A2 (de
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Benjamin Blanchard
Katarzyna Chuda
Boris Jaffrennou
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Saint Gobain Adfors SAS
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00—Coverings or linings, e.g. for walls or ceilings
    • E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/242—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads inorganic, e.g. basalt
    • D03D15/267—Glass
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/422—Hydrazides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2508—Coating or impregnation absorbs chemical material other than water

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Architecture (AREA)
  • Inorganic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Building Environments (AREA)
  • Finishing Walls (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Claims (19)

  1. Malerleinwand auf Glasfaserbasis mit einer Appretur, die dazu bestimmt ist, eine Verkleidung einer Innenfläche eines Gebäudes zu bilden, dadurch gekennzeichnet, dass sie ein Mittel enthält, das geeignet ist, Formaldehyd einzufangen, das aus den methylenaktiven Verbindungen, den Hydraziden, den Tanninen, den Amiden, den Aminosäuren, den Peptiden und den Proteinen ausgewählt ist.
  2. Leinwand nach Anspruch 1, dadurch gekennzeichnet, dass die methylenaktive Verbindung eine der folgenden Formeln (I) bis (IV) erfüllt:
    Figure imgb0023
     worin:
    - R1 und R2, die identisch oder unterschiedlich sind, ein Wasserstoffatom, ein C1-C20-, vorzugsweise C1-C6-Alkylradikal, ein Aminoradikal oder ein Radikal der folgenden Formel darstellen
    Figure imgb0024
     worin R4 ein Radikal
    Figure imgb0025
     oder
    Figure imgb0026
     darstellt, worin R5 = H oder -CH3 ist,
    und p eine von 1 bis 6 variierende ganze Zahl ist,
    - R3 ein Wasserstoffatom, ein C1-C10-Alkylradikal, ein Phenylradikal oder ein Halogenatom darstellt,
    - a gleich 0 oder 1 ist
    - b gleich 0 oder 1 ist
    - n gleich 1 oder 2 ist

            ► FORMEL (II) R6-CHR7-C≡N     (II)

    worin:
    - R6 ein Cyano-Radikal oder ein Radikal
    Figure imgb0027
     darstellt, worin:
    - R8 ein Wasserstoffatom, ein C1-C20-, vorzugsweise C1-C6-Alkylradikal oder ein Aminoradikal darstellt,
    - c gleich 0 oder 1 ist
    - R7 ein Wasserstoffatom, ein C1-C10-Alkylradikal, ein Phenylradikal oder ein Halogenatom darstellt
    Figure imgb0028
    worin
    - R9 ein Radikal -C≡N oder -CO-CH3 darstellt,
    - q eine von 1 bis 4 variierende ganze Zahl ist
    Figure imgb0029
     worin
    - A ein Radikal -(CH2)3- oder -C(CH3)2- darstellt,
    - r gleich 0 oder 1 ist.
  3. Leinwand nach Anspruch 2, dadurch gekennzeichnet, dass die Verbindung der Formel (I) 2,4-Pentandion, 2,4-Hexandion, 3,5-Heptandion, 2,4-Octandion, Acetoacetamid, Acetoessigsäure, Methylacetoacetat, Ethylacetoacetat, n-Propylacetoacetat, Isopropylacetoacetat, Isobutylacetoacetat, t-Butylacetoacetat, n-Hexylacetoacetat, Malonamid, Malonsäure, Dimethylmalonat, Diethylmalonat, Din-propylmalonat, Diisopropylmalonat, Di-n-butylmalonat, Acetondicarbonsäure und Dimethylacetondicarboxylat ist.
  4. Leinwand nach Anspruch 2, dadurch gekennzeichnet, dass die Verbindung der Formel (II) 2-Methylcyanoacetat, 2-Ethylcyanoacetat, 2-n-Propylcyanoacetat, 2-Isopropylcyanoacetat, 2-n-Butylcyanoacetat, 2-Isobutylcyanoacetat, 2-ter-Butylcyanoacetat, 2-Cyanoacetamid und Propandinitril ist.
  5. Leinwand nach Anspruch 2, dadurch gekennzeichnet, dass die Verbindung der Formel (III) Trimethylolpropan triacetoacetat und Trimethylolpropan tricyanoacetat ist.
  6. Leinwand nach Anspruch 2, dadurch gekennzeichnet, dass die Verbindung der Formel (IV) 1,3-Cyclohexandion und Meldrumsäure ist.
  7. Leinwand nach Anspruch 1, dadurch gekennzeichnet, dass das Hydrazid ausgewählt ist aus:
    a) den Monohydraziden der Formel R1CONHNH2, worin R1 ein Alkylradikal oder ein Arylradikal darstellt, wobei ein Wasserstoffatom der Alkyl- oder Arylradikale durch eine Hydroxygruppe oder ein Halogenatom ersetzt werden kann und wobei das Arylradikal durch ein Alkylradikal ersetzt werden kann,
    b) den Dihydraziden der Formel H2NHN-X-NHNH2, worin X ein Radikal-CO oder -CO-Y-CO darstellt und Y ein Alkylenradikal oder ein Arylenradikal ist, wobei ein Wasserstoffatom der Alkylen- oder Arylenradikale durch eine Hydroxygruppe oder ein Halogenatom ersetzt werden kann und wobei das Arylradikal durch ein Alkylradikal ersetzt werden kann,
    c) den Polyhydraziden, wie den Trihydraziden, den Tetrahydraziden und den Polyhydraziden, die aus einem Hydrazid-Monomer, das eine polymerisierbare Gruppe enthält, gebildet sind.
  8. Leinwand nach Anspruch 7, dadurch gekennzeichnet, dass das Hydrazid Oxalsäuredihydrazid, Malonsäuredihydrazid, Bernsteinsäuredihydrazid, Adipinsäuredihydrazid, Sebacinsäuredihydrazid, Maleinsäuredihydrazid, Fumarsäuredihydrazid, Diglykolsäuredihydrazid, Weinsäuredihydrazid, Apfelsäuredihydrazid, Isophthalsäuredihydrazid, Terephthalsäuredihydrazid, Carbohydrazid, Zitronensäuretrihydrazid, Pyromellitsäuretrihydrazid, 1,2,4-Benzoltrihydrazid, Nitriloessigsäuretrihydrazid, Cyclohexantricarbonsäuretrihydrazid, Ethylendiamintetraessigsäuretetrahydrazid, 1,4,5,8-Naphthoesäuretetrahydrazid, ein Polyacrylsäurehydrazid oder ein Polymethacrylsäurehydrazid ist.
  9. Leinwand nach Anspruch 1, dadurch gekennzeichnet, dass das Tannin ein Tannin der Mimose, des Quebracho, der Kiefer, der Pekan-Nuss, des Holzes von Schierling oder von Sumach ist.
  10. Leinwand nach Anspruch 1, dadurch gekennzeichnet, dass das Amid Harnstoff, 1,3-Dimethylharnstoff, Ethylenharnstoff oder seine Derivate, Biharnstoff, Biuret, Triuret, Acrylamid, Methacrylamid, Polyacrylamide und Polymethacrylamide ist.
  11. Leinwand nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass der Gehalt an Verbindung, die geeignet ist, Formaldehyd einzufangen, von 0,1 bis 500 g/m2, vorzugsweise von 0,5 bis 100 g/m2 und vorteilhafterweise von 1 bis 50 g/m2 variiert.
  12. Leinwand nach einem der Ansprüche 1 bis 10, dadurch gekennzeichnet, dass sie auf der Basis von Glasfasern und eventuell von aus einem thermoplastischen organischen Material gebildeten Fasern ist.
  13. Leinwand nach Anspruch 12, dadurch gekennzeichnet, dass es sich um ein Gewebe handelt, das aus Glasfäden, welche aus einer Vielzahl von Glasfilamenten (oder Grundfaden) bestehen oder aus diesen Fäden abgeleitet sind, oder aus Mischfäden, die wenigstens einen Glasfaden bestehend aus einer Vielzahl von Glasfilamenten sowie wenigstens einen Faden bestehend aus einer Vielzahl von Filamenten aus dem vorgenannten thermoplastischen organischen Material umfassen, oder aus "miteinander vermengten" Fäden, die von Glasfilamenten und von Filamenten aus dem vorgenannten organischen Material, welche innig gemischt werden, gebildet sind, erhalten wird.
  14. Leinwand nach Anspruch 13, dadurch gekennzeichnet, dass sie als Kette einen gezwirnten Glasfaden und als Schuss einen nicht gezwirnten, geöffneten Glasfaden umfasst und dass die Feinheit der Kettfäden und Schussfäden von 34 bis 1500 tex variiert.
  15. Leinwand nach einem der Ansprüche 1 bis 14, dadurch gekennzeichnet, dass sie eine flächenbezogene Masse aufweist, die von 30 bis 1000 g/m2 variiert.
  16. Verfahren zur Herstellung der Malerleinwand nach einem der Ansprüche 1 bis 15, wobei man die Malerleinwand einen Foulard (3) oder die Vorrichtung (30) durchlaufen lässt, die zwei Walzen 31a und 31b umfasst, welche jeweils einen mittleren Stutzen 32 zum Zuführen der Appreturzusammensetzung unter Druck aufweisen, und bei der der Umfangsbereich der Walzen mit Löchern 33 versehen ist, die von der Appreturzusammensetzung, welche auf der Malerleinwand abgeschieden wird, durchlaufen werden, die Leinwand getrocknet und eingesammelt wird, dadurch gekennzeichnet, dass es einen Schritt zur Behandlung mit einem Mittel, das geeignet ist, Formaldehyd einzufangen, umfasst.
  17. Verfahren nach Anspruch 16, dadurch gekennzeichnet, dass die Behandlung darin besteht, das Mittel in die Appreturzusammensetzung einzubringen.
  18. Verfahren nach Anspruch 16, dadurch gekennzeichnet, dass die Behandlung darin besteht, das Mittel nach dem Foulard (3) oder der Vorrichtung (30) und bevor die Malerleinwand über die Trocknungsvorrichtung (5) läuft aufzubringen.
  19. Verfahren nach Anspruch 18, dadurch gekennzeichnet, dass das Aufbringen durch Sprühen einer wässrigen Lösung des Mittels vollzogen wird.
EP20090805758 2008-12-19 2009-12-18 Malerleinwand mit einem mittel zum einfangen von formaldehyd und herstellungsverfahren Active EP2379465B1 (de)

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FR0858856A FR2940273B1 (fr) 2008-12-19 2008-12-19 Toile a peindre renfermant un agent apte a pieger le formalehyde et procede de fabrication
PCT/FR2009/052626 WO2010070248A2 (fr) 2008-12-19 2009-12-18 Toile a peindre renfermant un agent apte a pieger le formaldehyde et procede de fabrication

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US (1) US20110300359A1 (de)
EP (1) EP2379465B1 (de)
JP (2) JP5749654B2 (de)
CN (2) CN106367965A (de)
AU (1) AU2009329357B2 (de)
BR (1) BRPI0923143B8 (de)
CA (1) CA2747694C (de)
DK (1) DK2379465T3 (de)
FR (1) FR2940273B1 (de)
MX (1) MX2011006531A (de)
RU (1) RU2517509C2 (de)
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102022204321A1 (de) 2022-05-02 2023-11-02 Benecke-Kaliko Aktiengesellschaft Polyurethanformulierung mit verminderter Aldehydemission und daraus hergestellte Verbundgebilde
EP4273182A1 (de) 2022-05-02 2023-11-08 Benecke-Kaliko AG Polyurethanformulierung mit verminderter aldehydemission und daraus hergestellte verbundgebilde

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FR2940273B1 (fr) 2010-12-31
BRPI0923143B1 (pt) 2019-10-22
AU2009329357B2 (en) 2015-07-23
CA2747694C (fr) 2017-01-31
JP5749654B2 (ja) 2015-07-15
EP2379465A2 (de) 2011-10-26
US20110300359A1 (en) 2011-12-08
CN102325734A (zh) 2012-01-18
BRPI0923143B8 (pt) 2020-03-10
FR2940273A1 (fr) 2010-06-25
WO2010070248A3 (fr) 2010-08-12
AU2009329357A1 (en) 2011-08-04
CN106367965A (zh) 2017-02-01
CA2747694A1 (fr) 2010-06-24
RU2517509C2 (ru) 2014-05-27
DK2379465T3 (da) 2013-04-08
MX2011006531A (es) 2011-08-04
WO2010070248A2 (fr) 2010-06-24
JP2015110897A (ja) 2015-06-18
JP2012512977A (ja) 2012-06-07

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