EP2270119B1 - Kraftstoffzusammensetzung - Google Patents
Kraftstoffzusammensetzung Download PDFInfo
- Publication number
- EP2270119B1 EP2270119B1 EP10180913.5A EP10180913A EP2270119B1 EP 2270119 B1 EP2270119 B1 EP 2270119B1 EP 10180913 A EP10180913 A EP 10180913A EP 2270119 B1 EP2270119 B1 EP 2270119B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- gasoline fuel
- mono
- use according
- volume
- groups
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Revoked
Links
- 239000000446 fuel Substances 0.000 title claims description 50
- 239000000203 mixture Substances 0.000 title claims description 39
- 239000000654 additive Substances 0.000 claims description 45
- 239000002816 fuel additive Substances 0.000 claims description 26
- 229920002367 Polyisobutene Polymers 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 19
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 18
- -1 alkaline earth metal salts Chemical class 0.000 claims description 15
- 239000003599 detergent Substances 0.000 claims description 14
- 229920000768 polyamine Polymers 0.000 claims description 14
- 150000002009 diols Chemical class 0.000 claims description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 13
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- 239000011593 sulfur Substances 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 11
- 229920006395 saturated elastomer Polymers 0.000 claims description 11
- 229910052783 alkali metal Inorganic materials 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 10
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 10
- 150000001336 alkenes Chemical class 0.000 claims description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 9
- 150000001412 amines Chemical class 0.000 claims description 8
- 238000002485 combustion reaction Methods 0.000 claims description 8
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 8
- 150000002989 phenols Chemical class 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 239000003254 gasoline additive Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229920001083 polybutene Polymers 0.000 claims description 5
- 229920005862 polyol Polymers 0.000 claims description 5
- 150000003077 polyols Chemical class 0.000 claims description 5
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical class O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 238000006268 reductive amination reaction Methods 0.000 claims description 4
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 claims description 4
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 claims description 3
- 238000006683 Mannich reaction Methods 0.000 claims description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 3
- 150000002924 oxiranes Chemical class 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 3
- 229940014800 succinic anhydride Drugs 0.000 claims description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 3
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 3
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- 125000003277 amino group Chemical group 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical group 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000002199 base oil Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 6
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 5
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 5
- 230000002401 inhibitory effect Effects 0.000 description 5
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 238000005576 amination reaction Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229960001124 trientine Drugs 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- IUNMPGNGSSIWFP-UHFFFAOYSA-N dimethylaminopropylamine Chemical compound CN(C)CCCN IUNMPGNGSSIWFP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 1
- UZVAZDQMPUOHKP-UHFFFAOYSA-N 2-(7-methyloctyl)phenol Chemical compound CC(C)CCCCCCC1=CC=CC=C1O UZVAZDQMPUOHKP-UHFFFAOYSA-N 0.000 description 1
- ANHQLUBMNSSPBV-UHFFFAOYSA-N 4h-pyrido[3,2-b][1,4]oxazin-3-one Chemical group C1=CN=C2NC(=O)COC2=C1 ANHQLUBMNSSPBV-UHFFFAOYSA-N 0.000 description 1
- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 1
- RREANTFLPGEWEN-MBLPBCRHSA-N 7-[4-[[(3z)-3-[4-amino-5-[(3,4,5-trimethoxyphenyl)methyl]pyrimidin-2-yl]imino-5-fluoro-2-oxoindol-1-yl]methyl]piperazin-1-yl]-1-cyclopropyl-6-fluoro-4-oxoquinoline-3-carboxylic acid Chemical compound COC1=C(OC)C(OC)=CC(CC=2C(=NC(\N=C/3C4=CC(F)=CC=C4N(CN4CCN(CC4)C=4C(=CC=5C(=O)C(C(O)=O)=CN(C=5C=4)C4CC4)F)C\3=O)=NC=2)N)=C1 RREANTFLPGEWEN-MBLPBCRHSA-N 0.000 description 1
- QDTDKYHPHANITQ-UHFFFAOYSA-N 7-methyloctan-1-ol Chemical compound CC(C)CCCCCCO QDTDKYHPHANITQ-UHFFFAOYSA-N 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical class OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000001414 amino alcohols Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 159000000032 aromatic acids Chemical class 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000001236 detergent effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical class OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/143—Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
Definitions
- the present invention relates to a fuel composition containing a special low-alkanol-containing gasoline fuel in a larger amount and selected gasoline fuel additives in a smaller amount.
- Carburetors and intake systems of gasoline engines are increasingly contaminated by contaminants caused by dust particles from the air, unburned hydrocarbon residues from the combustion chamber and the crankcase ventilation gases passed into the carburetor.
- valve seat wear-resistant additives based on alkali or alkaline earth metal compounds have been developed.
- Modern gasoline engines require fuels with a complex property profile for trouble-free use, which can only be guaranteed in combination with appropriate gasoline additives.
- Such gasoline fuels generally consist of a complex mixture of chemical compounds and are characterized by physical quantities.
- the interaction between gasoline fuels and the corresponding additives is, however, in need of improvement in the known fuel compositions with regard to the cleaning or keeping-clean effect and the valve seat wear-inhibiting effect.
- the WO 01/85874 discloses a fuel composition containing a petrol with a sulfur content of max. 150 ppm, an olefin content of max. 21 vol .-%, a benzene content of max. 1.0 vol .-%, an aromatic content of max. 42 vol .-%, a carrier oil mixture and a detergent additive.
- the fuel composition can include alcohols such as methanol (maximum 3% by volume), ethanol (maximum 5% by volume), isopropanol (maximum 10% by volume), t-butanol (maximum 7% by volume) or isobutanol (maximum 10 vol .-%) included.
- Comparable fuel compositions are also from the EP-A-1277828 known.
- Comparable maximum alcohol levels are in the older one WO 03/074637 disclosed for gasoline fuel compositions which are additive with special mixtures of detergent additive and carrier oil.
- the older one WO 03/076554 describes the use of special hydrocarbylamines to reduce injector deposits in gasoline engines, where the lead-free gasoline used can contain 0.1-15% by volume of additives such as methanol, ethanol and MTBE.
- the object of the present invention was therefore to find a more effective gasoline-gasoline fuel additive composition. In particular, more effective additive formulations should be found.
- the use of a combination of a straight-chain or branched, saturated C 1 -C 6 mono- or diol or mixtures thereof, and at least one gasoline fuel additive with detergent action, for reducing deposits in the intake system of a gasoline engine can be determined according to CEC F-05 -A-93, where the petrol additive in an amount of 1 to 5000 ppm by weight and the alkanol in a content of 5 to 75 vol .-%, based on the total volume of the petrol, a petrol with a sulfur content of maximum 150 ppm by weight is metered in, this gasoline fuel additive having at least one hydrophobic hydrocarbon radical with a number average molecular weight (MN) of 85 to 20,000 and at least one polar grouping.
- MN number average molecular weight
- the lower alkanol used according to the invention is a straight-chain or branched, saturated C 1 -C 6 mono- or diol, in particular a C 1 -C 3 mono-alkanol, such as methanol, ethanol, n- or i-propanol, or a mixture of several of these alkanols.
- the alkanol content based on the total volume of the fuel composition, is 5 to 75% by volume, preferably 10 to 65% by volume, in particular 20 to 55% by volume, such as. B. 30 - 40 vol .-% or 40 - 50 vol .-%.
- the content of other alcohols and ethers in petrol is usually relatively low. Typical maximum contents are 7% by volume for tert-butanol, 10% by volume for isobutanol and 15% by volume for ethers with 5 or more carbon atoms in the molecule.
- the aromatic content of the petrol is preferably at most 40% by volume, in particular at most 38% by volume. Preferred ranges for the aromatic content are 20 to 42% by volume, in particular 25 to 40% by volume.
- the sulfur content of the petrol is preferably at most 100 ppm by weight, in particular at most 50 ppm by weight. Preferred ranges for the sulfur content are 0.5 to 150 ppm by weight, in particular 1 to 100 ppm by weight.
- the petrol has an olefin content of at most 21% by volume, preferably at most 18% by volume, in particular at most 10% by volume. Preferred ranges for the olefin content are 6 to 21% by volume, in particular 7 to 18% by volume.
- the petrol has a benzene content of at most 1.0% by volume, in particular at most 0.9% by volume.
- Preferred ranges for the benzene content are 0.5 to 1.0% by volume, in particular 0.6 to 0.9% by volume.
- the petrol has an oxygen content of at most 2.7% by weight, preferably from 0.1 to 2.7% by weight, especially from 1.0 to 2.7% by weight, in particular from 1.2 to 2.0% by weight.
- Particularly preferred is a petrol which simultaneously has an aromatic content of at most 38 vol.%, An olefin content of at most 21 vol.%, A sulfur content of at most 50 ppm by weight, a benzene content of at most 1.0 vol.% And one Has oxygen content of 1.0 to 2.7 wt .-%.
- the summer vapor pressure of petrol is usually a maximum of 70 kPa, especially 60 kPa (each at 370C).
- the research octane number ("RON") of the petrol is usually 90 to 100.
- a common range for the corresponding engine octane number (“MOZ”) is 80 to 90.
- the hydrophobic hydrocarbon residue in the petrol additives which ensures sufficient solubility in the fuel, has a number average molecular weight (Mn) of 85 to 20,000, in particular 113 to 10,000, especially 300 to 5,000.
- Mn number average molecular weight
- Such additives based on highly reactive polyisobutene, which from the polyisobutene, which can contain up to 20% by weight of n-butene units, by hydroformylation and reductive amination with ammonia, monoamines or polyamines such as dimethylaminopropylamine , Ethylenediamine, diethylenetriamine, triethylenetetramine or tetraethylenepentamine can be produced in particular from the EP-A 244 616 known.
- additives containing monoamino groups (a) are the compounds obtainable from polyisobutene epoxides by reaction with amines and subsequent dehydration and reduction of the amino alcohols, as described in particular in DE-A 196 20 262 are described.
- nitropolyisobutanes e.g. alpha, beta-dinitropolyisobutane
- mixed hydroxynitropolyisobutanes e.g. alpha-nitro-beta-hydroxypolyisobutane
- Additives containing carboxyl groups or their alkali metal or alkaline earth metal salts (d) are preferably copolymers of C 2 -C 40 olefins with maleic anhydride with a total molecular weight of 500 to 20,000, the carboxyl groups of which are wholly or partly to the alkali metal or alkaline earth metal salts and a remaining one The rest of the carboxyl groups are reacted with alcohols or amines.
- Such additives are particularly from EP-A 307 815 known. Such additives serve mainly to prevent valve seat wear and can, as in the WO-A 87/01126 described, are advantageously used in combination with conventional fuel detergents such as poly (iso) butenamines or polyetheramines.
- Additives containing sulfonic acid groups or their alkali metal or alkaline earth metal salts are preferably alkali metal or alkaline earth metal salts of a sulfosuccinic acid alkyl ester, as described in particular in EP-A 639 632 is described.
- Such additives mainly serve to prevent valve seat wear and can advantageously be used in combination with conventional fuel detergents such as poly (iso) butenamines or polyether amines.
- Polyoxy-C 2 - to C 4 -alkylene (f) additives are preferably polyethers or polyetheramines which are obtainable by reaction of C 2 - to C 60 alkanols, C 6 - to C 30 alkanediols, mono- or di-C 2 -C 30 alkylamines, C 1 -C 30 alkylcyclohexanols or C 1 -C 30 alkylphenols with 1 to 30 mol ethylene oxide and / or propylene oxide and / or butylene oxide per hydroxyl group or amino group and, in the case of the polyetheramines, by subsequent reductive amination with ammonia, monoamines or polyamines.
- Such products are used in particular in EP-A 310 875 , EP-A 356 725 , EP-A 700 985 and US-A 4 877 416 described.
- polyethers such products also have carrier oil properties. Typical examples of this are tridecanol or isotridecanol butoxylates, isononylphenol butoxylates and polyisobutenol butoxylates and propoxylates as well as the corresponding reaction products with ammonia.
- Additives containing carboxylic acid ester groups (g) are preferably esters of mono-, di- or tricarboxylic acids with long-chain alkanols or polyols, in particular those with a minimum viscosity of 2 mm 2 / s at 100 ° C., as described in particular in DE-A 38 38 918 are described.
- Aliphatic or aromatic acids can be used as mono-, di- or tricarboxylic acids, and long-chain representatives with, for example, 6 to 24 carbon atoms are particularly suitable as ester alcohols or polyols.
- esters are adipates, phthalates, isophthalates, terephthalates and trimellitates of iso-octanol, iso-nonanol, iso-decanol and iso-tridecanol. Products of this type also fulfill carrier oil properties.
- Derivatives with aliphatic polyamines such as ethylene diamine, diethylene triamine, triethylene tetramine or tetraethylene pentamine are of particular interest.
- Such gasoline fuel additives are particularly in US-A 4,849,572 described.
- Groupings (i) containing additives produced by Mannich reaction of substituted phenols with aldehydes and mono- or polyamines are preferably reaction products of polyisobutene-substituted phenols with formaldehyde and mono- or polyamines such as ethylene diamine, diethylene triamine, triethylene tetramine, tetraethylene pentamine or dimethylaminopropylamine.
- Such "polyisobutene Mannich bases" are particularly in the EP-A 831 141 described.
- the fuel composition which has been additized according to the invention may also contain other customary components and additives.
- solvents or diluents there are aliphatic and aromatic hydrocarbons, e.g. Solvent Naphtha.
- corrosion inhibitors for example based on ammonium salts of organic carboxylic acids which tend to form films, or of heterocyclic aromatics in the case of non-ferrous metal corrosion protection, antioxidants or stabilizers, for example based on amines such as p-phenylenediamine, dicyclohexylamine or derivatives thereof or of phenols such as 2,4-di -tert.-butylphenol or 3,5-di-tert.-butyl-4-hydroxyphenylpropionic acid, demulsifiers, antistatic agents, metallocenes such as ferrocene or methylcyclopentadienylmanganese tricarbonyl, lubricity improvers (lubricity additives) such as certain fatty acids, alkenylsuccinic acid esters, bis (hydroxyalkyl) fatty amides or castor oil and dyes (markers). Sometimes amines are also added to lower the pH of the fuel.
- antioxidants or stabilizers for example
- Combinations of the described gasoline with a mixture of gasoline additives with the polar grouping (f) and corrosion inhibitors and / or lubricity improvers based on carboxylic acids or fatty acids, which may be present as monomeric and / or dimeric species, are also particularly suitable for the fuel composition according to the invention .
- Typical mixtures of this type contain polyisobutenamines in combination with alkanol-started polyethers such as tridecanol or isotridecanol butoxylates or - propoxylates, polyisobutenamines in combination with alkanol-started polyether amines such as tridecanol or isotridecanol butoxylate-ammonia reaction products and alkanol-initiated polyol amine-combiners with alkanol-started polyol amine-combination or ether-alkoxylate-combination products such as tri-alkanolate or trolecidylolamine-amine-like combination products alkanol-started polyethers such as tridecanol or isotridecanol butoxylates or propoxylates, in each case together with the corrosion inhibitors or lubricity improvers mentioned.
- alkanol-started polyethers such as tridecanol or isotridecanol
- gasoline fuel additives with the polar groupings (a) to (i) and the other components mentioned are metered into the gasoline fuel and develop their effect there.
- the components or additives can be added to the petrol individually or as a previously prepared concentrate (“additive package”).
- the petrol additives mentioned with the polar groups (a) to (i) are usually added to the petrol in an amount of 1 to 5000 ppm by weight, in particular 5 to 3000 ppm by weight, especially 10 to 1000 ppm by weight .
- the other components and additives mentioned are added, if desired, in amounts customary for this.
- the same cleaning or cleaning or valve seat wear-inhibiting effect can be achieved as in comparable fuel compositions without the addition of low alkanol.
- the same amounts of detergent or valve seat wear-inhibiting agent in the fuel composition according to the invention compared to conventional fuel compositions, there is a significantly better cleaning or purifying or valve seat wear-inhibiting effect.
- the fuel composition according to the invention additionally shows advantages in that fewer deposits are formed in the combustion chamber of the gasoline engine and that less additive is introduced into the engine oil via the fuel dilution.
- Mn 1000 g / mol
- carrier oil tridecanol etherified with 22 units of butylene oxide
- Example 1 was repeated using OK 2 instead of OK 1.
- Example 1 was repeated using OK 3 instead of OK 1.
- TCD combustion chamber deposits
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Detergent Compositions (AREA)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL10180913T PL2270119T3 (pl) | 2003-04-11 | 2004-04-08 | Kompozycja paliwowa |
EP20174630.2A EP3736317A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10316871A DE10316871A1 (de) | 2003-04-11 | 2003-04-11 | Kraftstoffzusammensetzung |
PCT/EP2004/003811 WO2004090079A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP04726498.1A EP1615985B1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04726498.1A Division EP1615985B1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP04726498.1 Division | 2004-04-08 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20174630.2A Division EP3736317A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP20174630.2A Division-Into EP3736317A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
Publications (2)
Publication Number | Publication Date |
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EP2270119A1 EP2270119A1 (de) | 2011-01-05 |
EP2270119B1 true EP2270119B1 (de) | 2020-07-15 |
Family
ID=33016286
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP10180913.5A Revoked EP2270119B1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP04726498.1A Revoked EP1615985B1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP20174630.2A Withdrawn EP3736317A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04726498.1A Revoked EP1615985B1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
EP20174630.2A Withdrawn EP3736317A1 (de) | 2003-04-11 | 2004-04-08 | Kraftstoffzusammensetzung |
Country Status (22)
Country | Link |
---|---|
US (1) | US20060196110A1 (ko) |
EP (3) | EP2270119B1 (ko) |
JP (3) | JP4452712B2 (ko) |
KR (2) | KR101186408B1 (ko) |
CN (1) | CN100545244C (ko) |
AR (1) | AR044001A1 (ko) |
AU (1) | AU2004227095B2 (ko) |
BR (1) | BRPI0409171A (ko) |
CA (2) | CA2520578C (ko) |
CL (1) | CL2004000766A1 (ko) |
DE (1) | DE10316871A1 (ko) |
DK (1) | DK1615985T3 (ko) |
ES (1) | ES2443993T3 (ko) |
MX (1) | MXPA05010183A (ko) |
MY (1) | MY162483A (ko) |
NO (1) | NO20054374L (ko) |
PL (2) | PL2270119T3 (ko) |
PT (1) | PT1615985E (ko) |
RU (1) | RU2005134823A (ko) |
SI (1) | SI1615985T1 (ko) |
WO (1) | WO2004090079A1 (ko) |
ZA (1) | ZA200509086B (ko) |
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US20080168708A1 (en) * | 2007-01-11 | 2008-07-17 | Cunningham Lawrence J | Method and compositions for reducing deposits in engines combusting ethanol-containing fuels and a corrosion inhibitor |
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GB0903165D0 (en) * | 2009-02-25 | 2009-04-08 | Innospec Ltd | Methods and uses relating to fuel compositions |
CA2801018A1 (en) * | 2010-06-01 | 2011-12-08 | Arno Lange | Low-molecular weight polyisobutyl-substituted amines as detergent boosters |
MY166033A (en) | 2010-12-02 | 2018-05-21 | Basf Se | Use of the reaction product of a hydrocarbyl-substituted dicarboxylic acid and a nitrogen compound for reducing fuel consumption |
EP2554636A1 (en) * | 2011-08-03 | 2013-02-06 | Innospec Limited | Fuel compositions |
US20150113864A1 (en) | 2013-10-24 | 2015-04-30 | Basf Se | Use of a complex ester to reduce fuel consumption |
US20150113867A1 (en) | 2013-10-24 | 2015-04-30 | Basf Se | Use of an alkoxylated polytetrahydrofuran to reduce fuel consumption |
US20150113859A1 (en) | 2013-10-24 | 2015-04-30 | Basf Se | Use of polyalkylene glycol to reduce fuel consumption |
US10457884B2 (en) | 2013-11-18 | 2019-10-29 | Afton Chemical Corporation | Mixed detergent composition for intake valve deposit control |
ES2689347T3 (es) * | 2014-01-29 | 2018-11-13 | Basf Se | Uso de aditivos a base de ácido policarboxílico para carburantes |
EP3099769A1 (de) * | 2014-01-29 | 2016-12-07 | Basf Se | Polymere als additive für kraft und schmierstoffe |
US9249769B1 (en) * | 2015-03-24 | 2016-02-02 | Afton Chemical Corporation | Fuel additives for treating internal deposits of fuel injectors |
WO2018007191A1 (de) | 2016-07-05 | 2018-01-11 | Basf Se | Verwendung von korrosionsinhibitoren für kraft- und schmierstoffe |
RU2019122807A (ru) | 2016-12-20 | 2021-01-22 | Басф Се | Применение смеси комплексного сложного эфира с монокарбоновой кислотой для уменьшения трения |
US10273425B2 (en) | 2017-03-13 | 2019-04-30 | Afton Chemical Corporation | Polyol carrier fluids and fuel compositions including polyol carrier fluids |
RU2019135830A (ru) | 2017-04-11 | 2021-05-11 | Басф Се | Алкоксилированные амины в качестве присадок к топливу |
KR20210127323A (ko) | 2020-04-14 | 2021-10-22 | 정재훈 | 애완견 배변기 |
GB202111108D0 (en) * | 2021-08-02 | 2021-09-15 | Innospec Ltd | Compositions, and methods and uses relating thereto |
US11873461B1 (en) | 2022-09-22 | 2024-01-16 | Afton Chemical Corporation | Extreme pressure additives with improved copper corrosion |
US12024686B2 (en) | 2022-09-30 | 2024-07-02 | Afton Chemical Corporation | Gasoline additive composition for improved engine performance |
US11884890B1 (en) | 2023-02-07 | 2024-01-30 | Afton Chemical Corporation | Gasoline additive composition for improved engine performance |
US11795412B1 (en) | 2023-03-03 | 2023-10-24 | Afton Chemical Corporation | Lubricating composition for industrial gear fluids |
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