EP2068081B1 - PROCÉDÉ DE FONCTIONNEMENT ET APPAREIL DE COMMANDE DE FONCTIONNEMENT POUR UN FOUR à FUSION DE GAZÉIFICATION - Google Patents
PROCÉDÉ DE FONCTIONNEMENT ET APPAREIL DE COMMANDE DE FONCTIONNEMENT POUR UN FOUR à FUSION DE GAZÉIFICATION Download PDFInfo
- Publication number
- EP2068081B1 EP2068081B1 EP07806476.3A EP07806476A EP2068081B1 EP 2068081 B1 EP2068081 B1 EP 2068081B1 EP 07806476 A EP07806476 A EP 07806476A EP 2068081 B1 EP2068081 B1 EP 2068081B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- burner
- melting furnace
- gasification
- furnace
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 238000002844 melting Methods 0.000 title claims description 155
- 230000008018 melting Effects 0.000 title claims description 82
- 238000002309 gasification Methods 0.000 title claims description 63
- 238000011017 operating method Methods 0.000 title claims description 14
- 239000002699 waste material Substances 0.000 claims description 97
- 239000007789 gas Substances 0.000 claims description 91
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 37
- 239000001301 oxygen Substances 0.000 claims description 37
- 229910052760 oxygen Inorganic materials 0.000 claims description 37
- 238000000197 pyrolysis Methods 0.000 claims description 36
- 238000002485 combustion reaction Methods 0.000 claims description 34
- 239000000470 constituent Substances 0.000 claims description 6
- 238000001514 detection method Methods 0.000 claims description 4
- 239000002893 slag Substances 0.000 description 116
- 238000000034 method Methods 0.000 description 32
- 238000007599 discharging Methods 0.000 description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- 230000008569 process Effects 0.000 description 13
- 239000002918 waste heat Substances 0.000 description 11
- 238000011144 upstream manufacturing Methods 0.000 description 10
- 230000002269 spontaneous effect Effects 0.000 description 9
- 238000001816 cooling Methods 0.000 description 8
- 238000004458 analytical method Methods 0.000 description 7
- 230000001105 regulatory effect Effects 0.000 description 7
- 230000001186 cumulative effect Effects 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000004364 calculation method Methods 0.000 description 5
- 239000000498 cooling water Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 239000004576 sand Substances 0.000 description 5
- 230000002159 abnormal effect Effects 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000006004 Quartz sand Substances 0.000 description 3
- 238000013459 approach Methods 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 230000001276 controlling effect Effects 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 239000010813 municipal solid waste Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 101150054854 POU1F1 gene Proteins 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000010815 organic waste Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004876 x-ray fluorescence Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/006—General arrangement of incineration plant, e.g. flow sheets
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
- F23G5/0276—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/50—Control or safety arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/20—Combustion to temperatures melting waste
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/30—Cyclonic combustion furnace
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/40—Stationary bed furnace
- F23G2203/403—Stationary bed furnace with substantial cylindrical combustion chamber
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2204/00—Supplementary heating arrangements
- F23G2204/10—Supplementary heating arrangements using auxiliary fuel
- F23G2204/103—Supplementary heating arrangements using auxiliary fuel gaseous or liquid fuel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2207/00—Control
- F23G2207/60—Additives supply
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/55—Controlling; Monitoring or measuring
- F23G2900/55011—Detecting the properties of waste to be incinerated, e.g. heating value, density
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J2700/00—Ash removal, handling and treatment means; Ash and slag handling in pulverulent fuel furnaces; Ash removal means for incinerators
- F23J2700/001—Ash removal, handling and treatment means
Claims (6)
- Procédé de commande d'un four de gazéification et fusion (3, 4), destiné à commander ledit four de gazéification et fusion (3, 4), comportant un four de gazéification (3) destiné à gazéifier un matériau résiduaire à l'entrée, un four de fusion (4) configuré de manière à brûler les constituants combustibles contenus dans le gaz de pyrolyse produit dans ledit four de gazéification (3) et introduit dans le four de fusion (4) et à fondre les cendres dans le gaz de pyrolyse, et un brûleur (40) destiné à assurer une combustion secondaire, agencé dans ledit four de fusion (4), ledit procédé de commande comprenant :la commande d'arrêt de fonctionnement dudit brûleur (40) lorsque l'état opérationnel dudit four de gazéification et fusion (3, 4) remplit une condition spécifique d'arrêt de brûleur ;la commande d'arrêt de chargement du matériau résiduaire dans ledit four de gazéification (3) à un instant pour lequel la température à l'intérieur dudit four de fusion (4) à proximité dudit brûleur (40) chute à une température d'arrêt de chargement de déchets après l'arrêt du fonctionnement dudit brûleur (40) ; etle ré-allumage dudit brûleur (40) à un instant pour lequel la concentration en oxygène dans le gaz délivré à partir dudit four de gazéification (3) audit four de fusion (4) augmente jusqu'à une concentration de ré-allumage de brûleur prédéfinie après que le chargement du matériau résiduaire a été arrêté.
- Procédé de commande du four de gazéification et fusion selon la revendication 1, dans lequel ledit brûleur (40) est ré-allumé indépendamment de la concentration en oxygène à un instant pour lequel la température à l'intérieur dudit four de fusion (4) à proximité dudit brûleur (40) augmente jusqu'à une température prédéfinie, supérieure à la température d'arrêt de chargement de déchets, après l'arrêt du fonctionnement dudit brûleur (40).
- Procédé de commande de four de gazéification et fusion (3, 4) selon la revendication 1 ou 2, dans lequel la condition d'arrêt de brûleur comporte le fait qu'un état dans lequel la température à l'intérieur dudit four de fusion (4), à proximité dudit brûleur (40), ou une valeur moyenne glissante de celle-ci, est supérieure ou égale à une température d'arrêt de brûleur prédéterminée, est maintenu pendant une durée spécifique.
- Dispositif de commande de fonctionnement d'un four de gazéification et fusion (3, 4) destiné à commander le fonctionnement dudit four de gazéification et fusion (3, 4) comportant un four de gazéification (3) destiné à gazéifier un matériau résiduaire à l'entrée, un four de fusion (4) configuré de manière à brûler les constituants combustibles contenus dans le gaz de pyrolyse produit dans ledit four de gazéification (3) et introduit dans le four de fusion (4) et à fondre les cendres dans le gaz de pyrolyse, et un brûleur (40) destiné à assurer une combustion secondaire agencé dans ledit four de fusion (4), ledit dispositif de commande de fonctionnement comprenant : un dispositif d'alimentation de déchets (2) destiné à charger le matériau résiduaire dans ledit four de gazéification (3) et un thermomètre (46) destiné à détecter la température à l'intérieur dudit four de fusion (4) à proximité dudit brûleur (40) ; le dispositif de commande de fonctionnement étant caractérisé en ce que :le dispositif de commande comprend en outre : un analyseur d'oxygène (45) destiné à détecter la concentration en oxygène dans le gaz délivré à partir dudit four de gazéification (3) audit four de fusion (4) ; et un dispositif de commande (50) destiné à commander le fonctionnement dudit four de gazéification (3) sur la base de résultats de détection dudit thermomètre (46) et dudit analyseur d'oxygène (45), ledit dispositif de commande (50) comportant : une unité de commande de brûleur (52) qui délivre un signal de commande d'arrêt de brûleur afin d'arrêter le fonctionnement dudit brûleur (40) lorsqu'un état opérationnel dudit four de gazéification et fusion (3, 4) remplit une condition spécifique d'arrêt de brûleur ;une unité de commande de chargement de déchets (54) qui délivre un signal d'instruction d'arrêt de chargement de déchets afin d'arrêter ledit dispositif d'alimentation de déchets, empêchant de charger le matériau résiduaire dans ledit four de gazéification (3) à un instant pour lequel la température détectée par ledit, thermomètre chute à une température d'arrêt de chargement de déchets prédéfinie après l'arrêt du fonctionnement dudit brûleur (40) ; etl'unité de commande de brûleur (52) délivre un signal de commande de ré-allumage de brûleur afin de ré-allumer ledit brûleur (40) à un instant pour lequel la concentration en oxygène détectée par ledit analyseur d'oxygène (45) augmente jusqu'à une concentration de ré-allumage de brûleur prédéfinie après que ledit dispositif d'alimentation de déchets (2) a arrêté le chargement du matériau résiduaire.
- Dispositif de commande de fonctionnement du four de gazéification et fusion (3, 4) selon la revendication 4, dans lequel l'unité de commande de brûleur (52) délivre le signal de ré-allumage de brûleur indépendamment de la concentration en oxygène à un instant pour lequel la température détectée par ledit thermomètre (46) augmente jusqu'à une température prédéfinie supérieure à la température d'arrêt de chargement de déchets après l'arrêt de fonctionnement dudit brûleur (40).
- Dispositif de commande de fonctionnement du four de gazéification et fusion (3, 4) selon la revendication 4 ou 5, dans lequel la condition d'arrêt de brûleur comporte le fait que la température détectée par ledit thermomètre (46) ou une valeur moyenne glissante de celle-ci s'est maintenue à une valeur supérieure ou égale à une température d'arrêt de brûleur prédéfinie pendant une durée spécifique.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL07806476T PL2068081T3 (pl) | 2006-09-26 | 2007-08-31 | Sposób działania i urządzenie do kontroli pracy pieca do zgazowania |
| EP11001719.1A EP2322855B1 (fr) | 2006-09-26 | 2007-08-31 | Procédé de fonctionnement et appareil de commande pour un four de gazéification à fusion |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006260083 | 2006-09-26 | ||
| JP2007050892A JP2008215665A (ja) | 2007-03-01 | 2007-03-01 | ガス化溶融炉におけるスラグの塩基度の調整方法及び装置 |
| JP2007141664A JP4966743B2 (ja) | 2006-09-26 | 2007-05-29 | ガス化溶融炉の運転方法及び運転制御装置 |
| PCT/JP2007/067003 WO2008038492A1 (fr) | 2006-09-26 | 2007-08-31 | PROCÉDÉ DE FONCTIONNEMENT ET APPAREIL DE COMMANDE DE FONCTIONNEMENT POUR UN FOUR à FUSION DE GAZÉIFICATION |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11001719.1A Division EP2322855B1 (fr) | 2006-09-26 | 2007-08-31 | Procédé de fonctionnement et appareil de commande pour un four de gazéification à fusion |
| EP11001719.1A Division-Into EP2322855B1 (fr) | 2006-09-26 | 2007-08-31 | Procédé de fonctionnement et appareil de commande pour un four de gazéification à fusion |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP2068081A1 EP2068081A1 (fr) | 2009-06-10 |
| EP2068081A4 EP2068081A4 (fr) | 2011-05-11 |
| EP2068081B1 true EP2068081B1 (fr) | 2014-04-16 |
Family
ID=39229931
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP07806476.3A Active EP2068081B1 (fr) | 2006-09-26 | 2007-08-31 | PROCÉDÉ DE FONCTIONNEMENT ET APPAREIL DE COMMANDE DE FONCTIONNEMENT POUR UN FOUR à FUSION DE GAZÉIFICATION |
| EP11001719.1A Active EP2322855B1 (fr) | 2006-09-26 | 2007-08-31 | Procédé de fonctionnement et appareil de commande pour un four de gazéification à fusion |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11001719.1A Active EP2322855B1 (fr) | 2006-09-26 | 2007-08-31 | Procédé de fonctionnement et appareil de commande pour un four de gazéification à fusion |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP2068081B1 (fr) |
| KR (1) | KR101107787B1 (fr) |
| ES (1) | ES2461769T3 (fr) |
| PL (2) | PL2068081T3 (fr) |
| WO (1) | WO2008038492A1 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8940062B2 (en) * | 2009-10-28 | 2015-01-27 | Ihi Corporation | Method and apparatus for controlling temperature in combustion furnace in gasification equipment |
| JP5425983B2 (ja) * | 2012-08-02 | 2014-02-26 | 株式会社神鋼環境ソリューション | ガス化溶融炉のガス温度制御方法、及びガス温度制御装置 |
| FR3009977B1 (fr) * | 2013-09-02 | 2018-07-06 | Savoie Dechets | Procede de vitrification par gazeification d'une matiere carbonee |
| JP5826954B1 (ja) * | 2015-01-19 | 2015-12-02 | 株式会社神鋼環境ソリューション | 廃棄物処理システム及びそのシステムにおけるＮＯｘ処理方法 |
| CN108954364A (zh) * | 2018-05-19 | 2018-12-07 | 潘礼斌 | 一种粪便气化清洁供热系统 |
| CN110094725B (zh) * | 2019-05-10 | 2020-04-28 | 东北电力大学 | 一种燃煤发电机组超低氮燃烧方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4013023A (en) * | 1975-12-29 | 1977-03-22 | Envirotech Corporation | Incineration method and system |
| JPH06159640A (ja) * | 1992-11-26 | 1994-06-07 | Ebara Infilco Co Ltd | 塩基度調整装置及びその調整方法 |
| JP2001182924A (ja) | 1999-12-28 | 2001-07-06 | Nkk Corp | 溶融炉の運転方法 |
| KR100763531B1 (ko) * | 2000-08-11 | 2007-10-05 | 가부시키가이샤 긴세이 산교 | 폐기물의 소각처리방법 |
| JP2003302023A (ja) * | 2002-04-10 | 2003-10-24 | Ebara Corp | 溶融炉の運転方法、運転制御装置及びガス化溶融システム |
| JP4009151B2 (ja) | 2002-07-08 | 2007-11-14 | 株式会社神鋼環境ソリューション | ガス化溶融炉の燃焼制御方法及びその装置 |
| US20040137390A1 (en) * | 2003-01-09 | 2004-07-15 | Arnold Kenny M. | Methods and systems for measuring and controlling the percent stoichiometric oxidant in an incinerator |
| JP2004353944A (ja) * | 2003-05-29 | 2004-12-16 | Hitachi Zosen Corp | ごみ処理設備等における燃焼制御方法およびごみ処理設備 |
| JP4154371B2 (ja) | 2004-07-15 | 2008-09-24 | 株式会社神鋼環境ソリューション | 流動床式ガス化溶融炉の廃棄物供給停止時における保温方法 |
| JP4361890B2 (ja) * | 2005-06-14 | 2009-11-11 | 株式会社神鋼環境ソリューション | ガス化溶融炉のスラグ塩基度調整方法及びその装置 |
-
2007
- 2007-08-31 PL PL07806476T patent/PL2068081T3/pl unknown
- 2007-08-31 PL PL11001719.1T patent/PL2322855T3/pl unknown
- 2007-08-31 ES ES07806476.3T patent/ES2461769T3/es active Active
- 2007-08-31 EP EP07806476.3A patent/EP2068081B1/fr active Active
- 2007-08-31 EP EP11001719.1A patent/EP2322855B1/fr active Active
- 2007-08-31 WO PCT/JP2007/067003 patent/WO2008038492A1/fr active Application Filing
- 2007-08-31 KR KR1020097007726A patent/KR101107787B1/ko active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008038492A1 (fr) | 2008-04-03 |
| EP2068081A4 (fr) | 2011-05-11 |
| EP2322855B1 (fr) | 2016-04-13 |
| PL2322855T3 (pl) | 2016-09-30 |
| EP2068081A1 (fr) | 2009-06-10 |
| ES2461769T3 (es) | 2014-05-21 |
| PL2068081T3 (pl) | 2014-09-30 |
| KR20090057441A (ko) | 2009-06-05 |
| EP2322855A3 (fr) | 2011-08-31 |
| KR101107787B1 (ko) | 2012-01-20 |
| EP2322855A2 (fr) | 2011-05-18 |
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