EP2010690B1 - Verfahren zum schmelztauchbeschichten eines stahlflachproduktes aus höherfestem stahl - Google Patents
Verfahren zum schmelztauchbeschichten eines stahlflachproduktes aus höherfestem stahl Download PDFInfo
- Publication number
- EP2010690B1 EP2010690B1 EP06754869A EP06754869A EP2010690B1 EP 2010690 B1 EP2010690 B1 EP 2010690B1 EP 06754869 A EP06754869 A EP 06754869A EP 06754869 A EP06754869 A EP 06754869A EP 2010690 B1 EP2010690 B1 EP 2010690B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steel product
- flat steel
- oxide layer
- heat treatment
- iron oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 67
- 239000010959 steel Substances 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000003618 dip coating Methods 0.000 title description 13
- 239000012298 atmosphere Substances 0.000 claims abstract description 45
- 238000010438 heat treatment Methods 0.000 claims abstract description 38
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 36
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000011248 coating agent Substances 0.000 claims abstract description 22
- 238000000576 coating method Methods 0.000 claims abstract description 22
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 18
- 239000011701 zinc Substances 0.000 claims abstract description 18
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
- 229910052742 iron Inorganic materials 0.000 claims abstract description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims abstract 4
- 230000008018 melting Effects 0.000 claims abstract 4
- 230000002045 lasting effect Effects 0.000 claims abstract 2
- 239000000470 constituent Substances 0.000 claims description 15
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 229910045601 alloy Inorganic materials 0.000 claims description 6
- 239000000956 alloy Substances 0.000 claims description 6
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 238000005246 galvanizing Methods 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 abstract description 12
- 238000000137 annealing Methods 0.000 abstract description 11
- 238000005275 alloying Methods 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000011651 chromium Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910000967 As alloy Inorganic materials 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000794 TRIP steel Inorganic materials 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
- C23C2/004—Snouts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0222—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/024—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by cleaning or etching
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
Definitions
- the invention relates to a method for coating a flat steel product made of high-strength, different alloying constituents, in particular Mn, Al, Si and / or Cr, containing steel, such as steel strip or sheet, with a metallic coating, in which the flat steel product is subjected to a heat treatment, to then be provided in the heated state in a total of at least 85% zinc and / or aluminum melt bath by hot dip coating with the metallic coating.
- hot-rolled or cold-rolled sheets made of steel are used, which are surface-finished for reasons of corrosion protection.
- the demands placed on such sheets are many. They should on the one hand be well deformable and on the other hand have a high strength.
- the high strength is achieved by adding certain alloying constituents, such as Mn, Si, Al and Cr, to the iron.
- RTF Radiant Tube Furnace
- a two-stage hot dip coating method of a chromium-containing steel alloy strip is known.
- the strip is annealed in a first stage to be at the Band surface to obtain an iron enrichment.
- the tape is heated in a non-oxidizing atmosphere to the temperature of the coating metal.
- the document JP 02 285057 discloses a method of hot dip coating a steel strip that includes a preheat treatment.
- the heat treatment includes heating the tape in a reducing atmosphere, a second step of heating in an oxidizing atmosphere, and further heating up to 800 ° C in a reducing atmosphere.
- the document US 2004/177903 discloses a process for hot dip coating a high strength steel strip with various oxidizable alloying constituents.
- the method includes heating in a reducing atmosphere, and further, the heat treatment furnace comprises a region consisting of an oxidizing atmosphere.
- the invention had the object of specifying a method for hot dip coating of a high-strength steel produced flat steel product with zinc and / or aluminum, with which a steel strip can be produced with an optimally finished surface in a RTF plant.
- the temperature control according to the invention in step a) prevents that during the heating essential alloying constituents diffuse to the surface of the flat steel product.
- the diffusion of alloy constituents to the surface is particularly effectively suppressed so that an effective iron oxide layer can be formed in the following step , This prevents further alloying constituents from diffusing to the surface during the subsequently increased annealing temperature.
- a pure iron layer can be formed which is suitable for a full-surface and firmly adhering coating of zinc and / or aluminum is very suitable.
- the work result can be optimized by completely reducing the iron oxide layer produced in the oxidizing atmosphere to pure iron. In this state, the coating also has optimum properties with regard to its deformability and strength.
- the thickness of the forming oxide layer is measured and adjusted depending on this thickness and dependent on the flow rate of the flat steel product treatment time of O 2 content such that the Oxide layer can then be completely reduced.
- the change in the flow rate of the flat steel product z. B. as a result of disturbances can be considered in this way without detriment to the surface quality of the hot dip coated flat steel product.
- a diffusion of alloy constituents to the surface of the flat steel product can also be counteracted by the heating in step a) of the process according to the invention taking place as rapidly as possible.
- Good work results are in particular then if the duration of the heating upstream of the oxidation of the flat steel product to more than 750 ° C to 850 ° C to max. 300 s, in particular max. 250 s, is limited.
- the heating rate in the case of the heating of the flat steel product preceding the oxidation according to the invention is at least 2.4 ° C./s, in particular in the range from 2.4 to 4.0 ° C./s.
- the heat treatment followed by oxidation followed by cooling of the flat steel product should take more than 30 seconds, in particular more than 50 seconds, in order to ensure a sufficiently sufficient reduction of the previously formed iron oxide layer to pure iron.
- the high-strength steel may contain at least one of the following constituents: Mn> 0.5%, A1> 0.2%, Si> 0.1%, Cr> 0.3%. Other ingredients such. Mo, Ni, V, Ti, Nb and P can be added.
- the heat treatment of the flat steel product in the reducing atmosphere both during warm-up and later annealing, lasts many times longer than the heat treatment in the oxidizing atmosphere.
- the volume of the oxidizing atmosphere is very small compared to the remaining volume of the reducing atmosphere.
- the inventive heat treatment of the flat steel product in the reducing atmosphere can be carried out in a continuous furnace, which is equipped with a chamber containing the oxidizing atmosphere, wherein the volume of the chamber can be many times smaller than the remaining volume of the continuous furnace.
- the single figure shows schematically a galvanizing plant with a continuous furnace 5 and a melt bath 7.
- the temperature profile over the cycle time is plotted in the figure for the continuous furnace.
- the galvanizing plant is intended for continuous coating of a flat steel product in the form of hot rolled or cold rolled steel strip 1, which is made of higher strength steel containing at least one alloying element of the Mn, Al, Si and Cr group and optionally further alloying elements containing certain alloying elements.
- the steel may in particular be a TRIP steel.
- the steel strip 1 is withdrawn from a coil 2 and passed through a pickling 3 and / or another system 4 for surface cleaning.
- the cleaned belt 1 then passes through a continuous furnace 5 in a continuous operation and is passed from there via a sealed relative to the surrounding atmosphere trunk 6 in a hot dip bath 7.
- the hot-dip bath 7 is presently formed by a molten zinc.
- the emerging from the hot dip 7, provided with the zinc coating steel strip 1 passes through a Cooling section 8 or a device for heat treatment to a winding station 9, in which it is wound into a coil.
- the steel strip 1 is meander-shaped passed through the continuous furnace 5 in order to achieve sufficiently long treatment times with practical length of the continuous furnace 5 can.
- the middle zone 5b forms a reaction chamber and is atmospherically closed with respect to the first and last zones 5a, 5c.
- Their length is only about 1/100 of the total length of the continuous furnace 5. For better illustration, the drawing is not to scale extent.
- a typical composition of this atmosphere consists of 2% to 8% H 2 , typically 5% H 2 , and balance N 2 .
- the strip is heated to more than 750 to 850 ° C, typically 800 ° C.
- the heating takes place at a heating rate of at least 3.5 ° C / s. At this temperature and heating rate diffuse in the steel strip. 1 containing alloying ingredients in only small amounts at the surface.
- the steel strip 1 is kept substantially only at the temperature reached in the first zone 5a.
- the atmosphere of the zone 5b is oxygen-containing, so that oxidation of the surface of the steel strip 1 occurs.
- the O 2 content of the atmosphere prevailing in zone 5b is between 0.01% to 1%, typically 0.5%.
- the oxygen content of the atmosphere prevailing in the zone 5b can be adjusted, for example, as a function of the treatment time and the thickness of the oxide layer to be produced on the steel bath 1. If the treatment time is short, for example, a high O 2 content is set, while with a long treatment time, for example, a lower oxygen content can be selected in order to produce an oxide layer of the same thickness.
- the desired iron oxide layer forms on the surface of the strip.
- the thickness of this iron oxide layer can be detected optically, the result of the measurement being used to set the respective oxygen content of the zone 5b.
- the chamber volume is correspondingly small. Therefore, the reaction time for a change in the composition of the atmosphere is small, so that on a Changing the belt speed or to a different thickness of the target thickness of the oxide layer by a corresponding adjustment of the oxygen content of the prevailing atmosphere in the zone 5b can be reacted quickly.
- the small volume of Zone 5b allows for short control times.
- the steel strip 1 is heated to an annealing temperature of about 900 ° C.
- the annealing carried out in zone 5c takes place in a reducing nitrogen atmosphere which has an H 2 content of 5%.
- the iron oxide layer prevents alloying constituents from diffusing to the strip surface.
- the iron oxide layer is converted into a pure iron layer.
- the steel strip 1 is further cooled on its further way in the direction of the hot dip bath 7, so that it has a temperature when leaving the continuous furnace 5, which is higher by up to 10% than the temperature of the hot dip bath 7 of about 480 ° C. Since the strip 1 is made of pure iron after leaving the continuous furnace 5 on its surface, it provides an optimum basis for a firmly adhering connection of the zinc coating applied in the hot dip bath 7.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Coating With Molten Metal (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL06754869T PL2010690T3 (pl) | 2006-04-26 | 2006-04-26 | Sposób metalizacji zanurzeniowej płaskiego wyrobu stalowego ze stali wysokowytrzymałej |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/EP2006/061858 WO2007124781A1 (de) | 2006-04-26 | 2006-04-26 | Verfahren zum schmelztauchbeschichten eines stahlflachproduktes aus höherfestem stahl |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2010690A1 EP2010690A1 (de) | 2009-01-07 |
EP2010690B1 true EP2010690B1 (de) | 2010-02-24 |
Family
ID=37492622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06754869A Active EP2010690B1 (de) | 2006-04-26 | 2006-04-26 | Verfahren zum schmelztauchbeschichten eines stahlflachproduktes aus höherfestem stahl |
Country Status (12)
Country | Link |
---|---|
US (1) | US8636854B2 (es) |
EP (1) | EP2010690B1 (es) |
JP (1) | JP5189587B2 (es) |
KR (1) | KR101275839B1 (es) |
CN (1) | CN101501235B (es) |
AT (1) | ATE458838T1 (es) |
BR (1) | BRPI0621610A2 (es) |
CA (1) | CA2647687C (es) |
DE (1) | DE502006006289D1 (es) |
ES (1) | ES2339804T3 (es) |
PL (1) | PL2010690T3 (es) |
WO (1) | WO2007124781A1 (es) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010037254A1 (de) | 2010-08-31 | 2012-03-01 | Thyssenkrupp Steel Europe Ag | Verfahren zum Schmelztauchbeschichten eines Stahlflachprodukts |
DE102011051731A1 (de) | 2011-07-11 | 2013-01-17 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts |
WO2013092479A1 (de) | 2011-12-21 | 2013-06-27 | Thyssenkrupp Steel Europe Ag | Düseneinrichtung für einen ofen zum wärmebehandeln eines stahlflachprodukts und mit einer solchen düseneinrichtung ausgestatteter ofen |
EP2824216A1 (de) | 2013-05-24 | 2015-01-14 | ThyssenKrupp Steel Europe AG | Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts und Durchlaufofen für eine Schmelztauchbeschichtungsanlage |
WO2016177590A1 (en) | 2015-05-07 | 2016-11-10 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3135778A1 (en) | 2015-08-31 | 2017-03-01 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3173495A1 (en) | 2015-11-25 | 2017-05-31 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3686534A1 (fr) | 2019-01-23 | 2020-07-29 | Drever International | Procédé et four pour le traitement thermique d'une bande d acier de haute résistance comprenant une chambre d homogénéisation en température |
US10801086B2 (en) | 2015-04-02 | 2020-10-13 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
US10821706B2 (en) * | 2016-05-30 | 2020-11-03 | Jfe Steel Corporation | Ferritic stainless steel sheet |
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JP5555992B2 (ja) * | 2008-09-05 | 2014-07-23 | Jfeスチール株式会社 | 表面外観とめっき密着性に優れる高強度溶融亜鉛めっき鋼板の製造方法 |
JP5556033B2 (ja) * | 2009-03-19 | 2014-07-23 | Jfeスチール株式会社 | 高強度溶融亜鉛めっき鋼板の製造方法 |
EP2415896B1 (en) | 2009-03-31 | 2016-11-16 | JFE Steel Corporation | Method for producing high-strength hot-dip galvanized steel plate |
EP2374910A1 (de) | 2010-04-01 | 2011-10-12 | ThyssenKrupp Steel Europe AG | Stahl, Stahlflachprodukt, Stahlbauteil und Verfahren zur Herstellung eines Stahlbauteils |
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WO2015001367A1 (en) * | 2013-07-04 | 2015-01-08 | Arcelormittal Investigación Y Desarrollo Sl | Cold rolled steel sheet, method of manufacturing and vehicle |
CN107532270B (zh) | 2015-04-22 | 2019-08-20 | 考克利尔维修工程 | 用于反应控制的方法及装置 |
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DE102010037254A1 (de) | 2010-08-31 | 2012-03-01 | Thyssenkrupp Steel Europe Ag | Verfahren zum Schmelztauchbeschichten eines Stahlflachprodukts |
WO2012028465A1 (de) | 2010-08-31 | 2012-03-08 | Thyssenkrupp Steel Europe Ag | Verfahren zum schmelztauchbeschichten eines stahlflachprodukts |
DE102011051731A1 (de) | 2011-07-11 | 2013-01-17 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts |
DE102011051731B4 (de) * | 2011-07-11 | 2013-01-24 | Thyssenkrupp Steel Europe Ag | Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts |
WO2013007578A3 (de) * | 2011-07-11 | 2013-05-02 | Thyssenkrupp Steel Europe Ag | Verfahren zur herstellung eines durch schmelztauchbeschichten mit einer metallischen schutzschicht versehenen stahlflachprodukts |
DE102011056823A1 (de) | 2011-12-21 | 2013-06-27 | Thyssen Krupp Steel Europe AG | Düseneinrichtung für einen Ofen zum Wärmebehandeln eines Stahlflachprodukts und mit einer solchen Düseneinrichtung ausgestatteter Ofen |
WO2013092479A1 (de) | 2011-12-21 | 2013-06-27 | Thyssenkrupp Steel Europe Ag | Düseneinrichtung für einen ofen zum wärmebehandeln eines stahlflachprodukts und mit einer solchen düseneinrichtung ausgestatteter ofen |
EP2824216A1 (de) | 2013-05-24 | 2015-01-14 | ThyssenKrupp Steel Europe AG | Verfahren zur Herstellung eines durch Schmelztauchbeschichten mit einer metallischen Schutzschicht versehenen Stahlflachprodukts und Durchlaufofen für eine Schmelztauchbeschichtungsanlage |
US10801086B2 (en) | 2015-04-02 | 2020-10-13 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
WO2016177590A1 (en) | 2015-05-07 | 2016-11-10 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3135778A1 (en) | 2015-08-31 | 2017-03-01 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
EP3173495A1 (en) | 2015-11-25 | 2017-05-31 | Cockerill Maintenance & Ingenierie S.A. | Method and device for reaction control |
US10821706B2 (en) * | 2016-05-30 | 2020-11-03 | Jfe Steel Corporation | Ferritic stainless steel sheet |
EP3686534A1 (fr) | 2019-01-23 | 2020-07-29 | Drever International | Procédé et four pour le traitement thermique d'une bande d acier de haute résistance comprenant une chambre d homogénéisation en température |
BE1026986A1 (fr) | 2019-01-23 | 2020-08-17 | Drever Int Sa | Procédé et four pour le traitement thermique d’une bande d’acier de haute résistance comprenant une chambre d’homogénéisation en température |
Also Published As
Publication number | Publication date |
---|---|
CA2647687A1 (en) | 2007-11-08 |
CA2647687C (en) | 2012-10-02 |
DE502006006289D1 (de) | 2010-04-08 |
US8636854B2 (en) | 2014-01-28 |
KR101275839B1 (ko) | 2013-06-18 |
JP5189587B2 (ja) | 2013-04-24 |
BRPI0621610A2 (pt) | 2011-12-13 |
US20090199931A1 (en) | 2009-08-13 |
PL2010690T3 (pl) | 2010-07-30 |
CN101501235A (zh) | 2009-08-05 |
JP2009534537A (ja) | 2009-09-24 |
ES2339804T3 (es) | 2010-05-25 |
KR20080111492A (ko) | 2008-12-23 |
CN101501235B (zh) | 2012-07-04 |
EP2010690A1 (de) | 2009-01-07 |
WO2007124781A1 (de) | 2007-11-08 |
ATE458838T1 (de) | 2010-03-15 |
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