EP1966363B1 - Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite - Google Patents

Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite Download PDF

Info

Publication number
EP1966363B1
EP1966363B1 EP06819024A EP06819024A EP1966363B1 EP 1966363 B1 EP1966363 B1 EP 1966363B1 EP 06819024 A EP06819024 A EP 06819024A EP 06819024 A EP06819024 A EP 06819024A EP 1966363 B1 EP1966363 B1 EP 1966363B1
Authority
EP
European Patent Office
Prior art keywords
alkali metal
cleaning agent
use according
hypochlorite
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP06819024A
Other languages
German (de)
English (en)
Other versions
EP1966363A1 (fr
Inventor
Carlos Malet
Xavier Closa Cruxens
Miguel Osset
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL06819024T priority Critical patent/PL1966363T3/pl
Publication of EP1966363A1 publication Critical patent/EP1966363A1/fr
Application granted granted Critical
Publication of EP1966363B1 publication Critical patent/EP1966363B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0073—Anticorrosion compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0084—Antioxidants; Free-radical scavengers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/16—Metals

Definitions

  • the present invention relates to the reduction of corrosivity of hypochlorite on metal surfaces when using hypochlorite-containing liquid detergents for cleaning metal surfaces.
  • Hard surface cleaners such as kitchen and bathroom cleaners, have historically been highly abrasive powders, optionally containing low levels of surfactants and properly referred to as scouring powders. They were aggressive not only to the user's hand, but also to the surface with which they were brought into contact for cleaning purposes. In some cases, a bleaching agent has been incorporated into such scrubbing powders to oxidatively break up soils and thereby facilitate their removability. Although modern abrasive cleaners are now much more skin-friendly in their composition, these cleaners still rely essentially on the action of Abrasivstoffs to remove stains, which in particular soap deposits, which are usually derived mainly from personal hygiene, from hard Remove surfaces such as bathroom tiles or sinks.
  • hypochlorite is known to be a highly effective bleaching agent and has been used for a long time, optionally with soaps and / or synthetic surfactants, to remove stains and all sorts of soils from laundry to textiles as well as hard surface cleaning. It is normally sold in concentrations of about 2 to 10% by weight in water for household use. While the use of hypochlorite agents an excellent disinfecting performance and very good Cleaning results achieved on hard surfaces, observed in sensitive cleaning in some cases, a change in the surface. This can range from a slight impairment of the visual impression to the appearance of pits in the surface or even pitting, with severe cases usually occurring only with improper use of the agent.
  • the sensitive surfaces mentioned here include, in particular, those made of metal, for example steel surfaces, such as those found in kitchen sinks, as housing surfaces of domestic appliances or linings of kitchen or bathroom cabinets.
  • metal for example steel surfaces, such as those found in kitchen sinks, as housing surfaces of domestic appliances or linings of kitchen or bathroom cabinets.
  • Hypochlorite-containing detergents are biespielweise EP 311 175 . DE 19700799 unnd EP903403 known.
  • hypochlorite detergent positively influences the corrosion behavior.
  • the metal surface is a steel surface, since then the improvement effect of the combination used in the invention is particularly pronounced.
  • the combination used according to the invention is preferably a constituent of the hypochlorite-containing cleaning agent.
  • the cleaning agent contains 0.5 wt .-% to 10 wt .-%, in particular 2 wt .-% to 5.5 wt .-% alkali metal hypochlorite.
  • alkali metal hypochlorites such as potassium hypochlorite
  • sodium hypochlorite it is still preferable to use sodium hypochlorite in the present invention.
  • aqueous sodium hypochlorite solutions often contain considerable amounts of chloride salts. These can readily be used for the production of corrosion-enhanced agents according to the invention, so that it is not necessarily dependent on the use of high-purity NaOCl.
  • hypochlorite-containing agents are alkaline, it being preferred according to the invention, when the cleaning agent contains more than 0 wt .-% up to 5 wt .-%, in particular 0.1 wt .-% to 2 wt .-% alkali metal hydroxide.
  • more than 0 wt .-% up to 5 wt .-%, in particular 0.1 wt .-% to 2.5 wt .-% alkali metal silicate in the agent is preferably, more than 0 wt .-% up to 5 wt .-%, in particular 0.1 wt .-% to 2.5 wt .-% alkali metal silicate in the agent. This not only improves the corrosion behavior but also increases the storage stability of the hypochlorite.
  • alkyl (alkoxy) n- sulfate which may also be referred to as alkyl ether sulfate and by reacting alcohols (preferably having 6 to 22 carbon atoms) with alkylene oxides, in particular ethylene oxide, and subsequent Sulfation and neutralization, especially with alkaline alkali metal salts such as alkali metal hydroxides, is available.
  • alcohols preferably having 6 to 22 carbon atoms
  • alkylene oxides in particular ethylene oxide
  • alkaline alkali metal salts such as alkali metal hydroxides
  • the alkyl (alkoxy) n- sulphate preferably has a C 8-18 , in particular C 12-16 -alkyl group, -OCH 2 CH 2 - and / or -OCHCH 3 CH 2 -alkoxy group (s), where n is preferably is a number from 1 to 6, especially 2 to 5.
  • the preferred alkali hydroxide is sodium hydroxide, and also the alkali salts mentioned in connection with the other ingredients of the compositions are preferably the sodium salts.
  • the alkali metal silicate sodium silicate and / or the alkali metal counterion of the ether sulfate is the sodium ion.
  • the cleaning agent may contain up to 5% by weight of additional bleach-stable surfactant.
  • betaines in particular those of the general formula I, wherein R 1 is an alkyl or alkenyl group having 6 to 22 carbon atoms or a group R 4 is CO-NH- (CH 2 ) n -, R 2 is hydrogen or an alkyl group having 1 to 4 carbon atoms, R 3 is hydrogen or an alkyl group with 1 to 4 carbon atoms, R 4 is an alkyl or alkenyl group having 6 to 22 carbon atoms, m is a number from 1 to 6 and n is a number from 1 to 3.
  • particularly suitable members of this class of surfactants include C 12-18 alkyl dimethyl betaine, commercially available as coconut betaine, and C 10-16 alkyl dimethyl betaine, commercially available as lauryl betaine.
  • the preparations may additionally contain sequestering agents, preferably phosphates, alkyl phosphates, alkylphosphonic acids and among these in particular those having at least one amine oxide substituent on the alkyl group, referred to herein as Aminoxidphosphonklaren, polyacrylic acids and / or phosphono-containing polyacrylic acids, which are also present in the form of their alkali metal salts can.
  • sequestering agents preferably phosphates, alkyl phosphates, alkylphosphonic acids and among these in particular those having at least one amine oxide substituent on the alkyl group
  • Aminoxidphosphonklaren phosphates, alkyl phosphates, alkylphosphonic acids and among these in particular those having at least one amine oxide substituent on the alkyl group
  • Aminoxidphosphonklaren phosphates, alkyl phosphates, alkylphosphonic acids and among these in particular those having at least one amine oxide substituent on the alkyl group
  • Amine oxide phosphonic acids are the amine oxide based on aminotrimethylene phosphonic acid. Preferably, from 0.01% to 2% by weight of such sequestering agents are present.
  • the agents contain 0.1% by weight to 2% by weight of carbonate, in particular alkali carbonate.
  • the corrosion-improved preparations according to the invention may contain small amounts of one or more pale-stable dyes or fragrances.
  • the optional perfume component is preferably of higher relative volatility than the ingredients optionally responsible for a bleaching odor.
  • the stabilized compositions according to the invention can be prepared in a simple manner by mixing the above-mentioned ingredients in the indicated amounts. They are applied after dilution with water or, if desired, also undiluted.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Detergent Compositions (AREA)

Claims (11)

  1. Utilisation d'une combinaison d'un hydroxyde de métal alcalin, d'un silicate de métal alcalin, d'un sulfate d'alkyl-(alcoxy)n où n = 0,5 à 10, et d'un phosphate d'alkyle dans un agent de nettoyage liquide aqueux contenant de l'hypochlorite, afin de diminuer la corrosivité de l'hypochlorite sur des surfaces métalliques.
  2. Utilisation selon la revendication 1, caractérisée en ce que la surface métallique est une surface en acier.
  3. Utilisation selon la revendication 1 ou 2, caractérisée en ce que l'agent de nettoyage contient de 0,5 % en poids à 10 % en poids, en particulier de 2 % en poids à 5,5 % en poids d'un hypochlorite de métal alcalin en particulier l'hypochlorite de sodium.
  4. Utilisation selon l'une quelconque des revendications 1 à 3, caractérisée en ce que l'agent de nettoyage contient de plus de 0 % en poids jusqu'à 5 % en poids, en particulier de 0,1 % en poids à 2 % en poids d'un hydroxyde de métal alcalin.
  5. Utilisation selon l'une quelconque des revendications 1 à 4, caractérisée en ce que l'agent de nettoyage contient de plus de 0 % en poids jusqu'à 5 % en poids, en particulier de 0,1 % en poids à 2,5 % en poids d'un silicate de métal alcalin.
  6. Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que l'agent de nettoyage contient de plus de 0 % en poids jusqu'à 5 % en poids d'un sulfate d'alkyl-(alcoxy)n.
  7. Utilisation selon l'une quelconque des revendications 1 à 6, caractérisée en ce que l'agent de nettoyage contient un sulfate d'alkyl-(alcoxy)n comprenant un groupe alkyle en C8-C18, en particulier un groupe alkyle en C12-C16, un groupe -OCH2CH2- et/ou un groupe -OCHCH3CH2- à titre de groupes alcoxy, où n représente un nombre de 1 à 6, en particulier de 2 à 5, et présente un ion antagoniste de métal alcalin pour le groupe sulfate.
  8. Utilisation selon l'une quelconque des revendications 1 à 7, caractérisée en ce que l'hydroxyde de métal alcalin est l'hydroxyde de sodium, le silicate de métal alcalin est le silicate de sodium et/ou l'ion antagoniste du métal alcalin est un ion de sodium.
  9. Utilisation selon l'une quelconque des revendications 1 à 8, caractérisée en ce que l'agent de nettoyage contient, jusqu'à 5 % en poids, un agent tensioactif stable au blanchiment, en particulier de la bétaïne.
  10. Utilisation selon l'une quelconque des revendications 1 à 9, caractérisée en ce que l'agent de nettoyage contient en outre, de 0,01 % en poids à 2 % en poids, d'un acide alkylphosphonique et/ou d'un phosphonate, en particulier d'un acide aminoxyde-phosphonique, d'un acide polyacrylique présentant des groupes phosphono et/ou d'un sel de métal alcalin d'un de ces acides ou des deux, et/ou de 0,1 % en poids à 2 % en poids d'un carbonate, en particulier d'un carbonate de métal alcalin.
  11. Procédé pour le nettoyage de surfaces métalliques, en particulier de surfaces en acier, caractérisé par la mise en oeuvre d'un agent de nettoyage liquide aqueux contenant de l'hypochlorite, qui contient une combinaison d'un hydroxyde de métal alcalin, d'un silicate de métal alcalin, d'un sulfate d'alkyl-(alcoxy)n où n = 0,5 à 10, et d'un phosphate d'alkyle.
EP06819024A 2005-12-29 2006-12-13 Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite Active EP1966363B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL06819024T PL1966363T3 (pl) 2005-12-29 2006-12-13 Hamowanie korozji ciekłych, zawierających podchloryn środków czyszczących

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005063065A DE102005063065A1 (de) 2005-12-29 2005-12-29 Korrosionsinhibierung flüssiger hypochlorithaltiger Reinigungsmittel
PCT/EP2006/011960 WO2007079881A1 (fr) 2005-12-29 2006-12-13 Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite

Publications (2)

Publication Number Publication Date
EP1966363A1 EP1966363A1 (fr) 2008-09-10
EP1966363B1 true EP1966363B1 (fr) 2012-10-24

Family

ID=37836934

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06819024A Active EP1966363B1 (fr) 2005-12-29 2006-12-13 Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite

Country Status (6)

Country Link
US (1) US20080274934A1 (fr)
EP (1) EP1966363B1 (fr)
DE (1) DE102005063065A1 (fr)
ES (1) ES2394363T3 (fr)
PL (1) PL1966363T3 (fr)
WO (1) WO2007079881A1 (fr)

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393153A (en) * 1965-12-20 1968-07-16 Procter & Gamble Novel liquid bleaching compositions
US3655566A (en) * 1970-03-05 1972-04-11 Purex Corp Ltd Bleach having stable brighteners
US3666680A (en) * 1970-03-05 1972-05-30 Purex Corp Ltd Method of combining optical brighteners with polymers for stability in bleach and encapsulated product
US4193888A (en) * 1971-09-01 1980-03-18 Colgate-Palmolive Company Color-yielding scouring cleanser compositions
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
US4116849A (en) * 1977-03-14 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4117994A (en) * 1977-06-21 1978-10-03 Irvin Industries Canada Ltd. Parachute with canopy opening assist and opening control
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
US4388204A (en) * 1982-03-23 1983-06-14 The Drackett Company Thickened alkali metal hypochlorite compositions
US5180514A (en) * 1985-06-17 1993-01-19 The Clorox Company Stabilizing system for liquid hydrogen peroxide compositions
US4828723A (en) * 1987-07-15 1989-05-09 Colgate-Palmolive Company Stable non-aqueous suspension containing organophilic clay and low density filler
US4830782A (en) * 1987-08-31 1989-05-16 Colgate-Palmolive Company Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use
GB8723675D0 (en) * 1987-10-08 1987-11-11 Unilever Plc Sanitizer
US5139695A (en) * 1988-01-14 1992-08-18 Ciba-Geigy Corporation Stable bleaching compositions containing fluorescent whitening agents
US4986926A (en) * 1989-04-10 1991-01-22 The Drackett Company Thickened alkali metal hypochlorite compositions
US5034150A (en) * 1989-05-03 1991-07-23 The Clorox Company Thickened hypochlorite bleach solution and method of use
US5185096A (en) * 1991-03-20 1993-02-09 Colgate-Palmolive Co. Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and bleach stabilizer
US5229027A (en) * 1991-03-20 1993-07-20 Colgate-Palmolive Company Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and an iodate or iodide hypochlorite bleach stabilizer
JP2721804B2 (ja) * 1993-12-28 1998-03-04 クリーンケミカル株式会社 医療機器用殺菌洗浄剤
DE4413433C2 (de) * 1994-04-18 1999-09-16 Henkel Kgaa Wäßrige Bleichmittel
JPH10505114A (ja) * 1994-08-30 1998-05-19 ザ、プロクター、エンド、ギャンブル、カンパニー キレート化剤によって高められた光漂白
DE19700799C2 (de) * 1997-01-13 1999-02-04 Henkel Kgaa Wäßrige Textilbleichmittel
WO1999000347A1 (fr) * 1997-06-27 1999-01-07 The Procter & Gamble Company Acetals et cetals lineaires precurseurs de parfum
US6083892A (en) * 1997-08-19 2000-07-04 The Procter & Gamble Company Automatic dishwashing detergents comprising β-ketoester pro-fragrances
EP0903403B1 (fr) * 1997-09-19 2003-04-16 The Procter & Gamble Company Compositions de blanchiment stables
ATE360679T1 (de) * 1997-09-19 2007-05-15 Procter & Gamble Selbstverdickende bleichmittelzusammensetzungen
ATE283342T1 (de) * 1998-01-16 2004-12-15 Procter & Gamble Stabile gefärbte verdickte bleichmittelzusammensetzungen
US6448215B1 (en) * 1998-01-16 2002-09-10 The Procter & Gamble Company Stable colored thickened bleaching compositions
DE19803054A1 (de) * 1998-01-28 1999-07-29 Henkel Kgaa Bleich- und Desinfektionsmittel
US6506718B1 (en) * 1998-09-01 2003-01-14 The Procter & Gamble Company Bleaching compositions
US6894015B1 (en) * 1998-11-11 2005-05-17 Procter & Gamble Company Bleaching compositions
DE19855329A1 (de) * 1998-12-01 2000-06-08 Henkel Kgaa Aktivchlorhaltige Zubereitungen mit stabilisierten optischen Aufhellern
KR100490564B1 (ko) * 2002-07-23 2005-05-19 주식회사 메디슨 초음파 영상 신호로부터 장기를 인식하는 장치 및 방법
ITMI20021693A1 (it) * 2002-07-30 2004-01-30 3V Sigma Spa Composizioni liquide stabilizzate contenenti cloro attivo

Also Published As

Publication number Publication date
US20080274934A1 (en) 2008-11-06
PL1966363T3 (pl) 2013-03-29
DE102005063065A1 (de) 2007-07-12
ES2394363T3 (es) 2013-01-31
WO2007079881A1 (fr) 2007-07-19
EP1966363A1 (fr) 2008-09-10

Similar Documents

Publication Publication Date Title
DE69827845T2 (de) Reinigungsmittel für Keramik- und Porzellanoberflächen sowie hierfür geeignete Verfahren
DE2362114C2 (de) Flüssiges schaumreguliertes Wasch- und Reinigungsmittel
DE69325589T2 (de) Reinigen mit kurzkettigen tensiden
DE2701727B2 (de) Waschmittel
DE10206172A1 (de) Flüssige Bleichreinigungszusammensetzung
EP2098587B1 (fr) Mélange de décalquage, de nettoyage et/ou de désinfection
DE2327234A1 (de) Phosphatfreies waschmittel
DE2317076C2 (de) Geschirrspülmittel
DE2244310A1 (de) Detergenszusammensetzung
DE2628976A1 (de) Klares, stabiles, einphasiges und fluessiges wasch- und reinigungsmittel
WO2010084057A1 (fr) Détergent pour vaisselle à la main ayant une action antibactérienne
DE2225250A1 (de) Geschirrspülmittel
EP1966363B1 (fr) Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite
EP1963474B1 (fr) Réduction des odeurs causées par des produits contenant de l'hypochlorite
DE3832885A1 (de) Verfahren zum maschinellen reinigen, desinfizieren und klarspuelen von geschirr und dafuer geeignetes mittel
EP1957620B1 (fr) Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite
WO2007079880A1 (fr) Détergent pour laver la vaisselle à la main
DE102005059048A1 (de) Reinigungsmittel für harte Oberflächen
EP1957621B1 (fr) Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite
DE2445710A1 (de) Waschmittelmischung und verfahren zur herstellung derselben
DE10124288A1 (de) Reinigungsmittel für harte Oberflächen (II)
DE60217358T2 (de) Verdickte flüssige Bleichmittelzusammensetzungen
DE10124304A1 (de) Reinigungsmittel für harte Oberflächen (III)
EP2171029B1 (fr) Agent blanchissant doux
DE2731152C2 (de) Reinigungsmittel für Gegenstände mit harter Oberfläche

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20080510

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20100311

RIC1 Information provided on ipc code assigned before grant

Ipc: C11D 1/37 20060101ALI20120127BHEP

Ipc: C11D 3/395 20060101AFI20120127BHEP

Ipc: C11D 3/08 20060101ALI20120127BHEP

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

DAX Request for extension of the european patent (deleted)
RIN1 Information on inventor provided before grant (corrected)

Inventor name: CLOSA CRUXENS, XAVIER

Inventor name: MALET, CARLOS

Inventor name: OSSET, MIGUEL

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 580988

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121115

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: RO

Ref legal event code: EPE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502006012141

Country of ref document: DE

Effective date: 20121220

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2394363

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20130131

REG Reference to a national code

Ref country code: PL

Ref legal event code: T3

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20121024

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130224

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130225

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130125

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

BERE Be: lapsed

Owner name: HENKEL A.G. & CO. KGAA

Effective date: 20121231

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121231

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20130124

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20130124

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121231

26N No opposition filed

Effective date: 20130725

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121213

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121231

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121231

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502006012141

Country of ref document: DE

Effective date: 20130725

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130124

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 580988

Country of ref document: AT

Kind code of ref document: T

Effective date: 20121213

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121213

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20121213

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20061213

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121024

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: RO

Payment date: 20141112

Year of fee payment: 9

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20151213

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230531

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20231228

Year of fee payment: 18

Ref country code: FR

Payment date: 20231221

Year of fee payment: 18

Ref country code: DE

Payment date: 20231214

Year of fee payment: 18

Ref country code: CZ

Payment date: 20231206

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20231130

Year of fee payment: 18

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20240126

Year of fee payment: 18