EP1957620B1 - Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite - Google Patents

Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite Download PDF

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Publication number
EP1957620B1
EP1957620B1 EP06828979A EP06828979A EP1957620B1 EP 1957620 B1 EP1957620 B1 EP 1957620B1 EP 06828979 A EP06828979 A EP 06828979A EP 06828979 A EP06828979 A EP 06828979A EP 1957620 B1 EP1957620 B1 EP 1957620B1
Authority
EP
European Patent Office
Prior art keywords
hypochlorite
alkali
use according
composition contains
metal pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06828979A
Other languages
German (de)
English (en)
Other versions
EP1957620A1 (fr
Inventor
Carlos Malet
Carlos Perez
Miguel Osset
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
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Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1957620A1 publication Critical patent/EP1957620A1/fr
Application granted granted Critical
Publication of EP1957620B1 publication Critical patent/EP1957620B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments

Definitions

  • the present invention relates to the stabilization of hypochlorite-containing liquid detergents and / or cleaners for hard surfaces in households, for example for cleaning tiles.
  • Sodium hypochlorite is known to be a highly effective bleaching agent and has been used for a long time, optionally with soaps and / or synthetic surfactants, to remove stains and all sorts of soils from laundry to textiles as well as hard surface cleaning. It is normally sold in concentrations of about 2% to 10% by weight in water for household use.
  • Liquid detergent formulations or corresponding preparations of hard surface cleaners containing hypochlorite as a bleach component are susceptible to loss of activity upon prolonged storage, especially because of the then-degradation of the hypochlorite.
  • ingredients that are desirable from an application point of view or for aesthetic reasons in detergents and cleaners include, in addition to the performance of such agents crucial influencing agents, in particular hypochlorite, and colorants, which should give a pleasant visual appearance in particular liquid preparations.
  • dyes are attacked by hypochlorite usually slightly oxidative, so that in addition to the loss of the bleaching agent and the color impression of hypochlorite-containing liquid agent changes rapidly on storage.
  • fragrances which are attacked by the strong oxdating agent hypochlorite in a large number of cases, so that the fragrance impression of perfumed agents changes on storage in often unacceptable ways.
  • Thickened bleach compositions containing stabilizers such as anisic acid are known US 6,448,215 and EP 1 348 755 ,
  • the invention therefore relates to the use of p-methoxybenzyl alcohol for the stabilization of hypochlorite-containing aqueous liquid compositions containing colored metal pigment.
  • a second aspect of the invention is therefore the co-use of p-methoxybenzyl alcohol and an alkali iodide for stabilizing hypochlorite-containing aqueous liquid compositions containing colored metallic pigment.
  • Another object of the invention is an aqueous liquid bleach containing alkali hypochlorite and colored metal pigment, which is characterized in that it additionally contains p-methoxybenzyl alcohol, optionally in combination with Akalijodid.
  • p-methoxybenzyl alcohol is also referred to as anisalcohol. It is commercially available and has hitherto been used, for example, as a component of perfume mixtures.
  • the liquid agent stabilized according to the invention contains from 0.5% to 5% by weight alkali hypochlorite, especially sodium hypochlorite.
  • Such formulations are particularly suitable and very effective as hard surface cleaners, for example for use on walls, work surfaces, floors and the like.
  • the agents especially because of their hypochlorite content, are particularly suitable for removing stains such as occur in kitchens or bathrooms, including greasy stains that may occur after using bathtubs, shower cubicles and sinks.
  • a bleaching agent in the form of hypochlorite is an essential component of the compositions according to the invention.
  • Bleaches per se are well-known components of detergent compositions and are particularly successful in controlling mildew and mildew, soils that are commonly found in soap deposits or in association with them.
  • alkali metal hypochlorites such as potassium hypochlorite
  • sodium hypochlorite in stabilized compositions of this invention.
  • chloride salts In commercial aqueous sodium hypochlorite solutions are often considerable amounts of chloride salts contain. These can readily be used for the production of agents according to the invention, so that it is not necessarily dependent on the use of high-purity NaOCl.
  • the compositions contain 0.5% by weight to 4.5% by weight, in particular 1% by weight to 4% by weight, of alkali metal hypochlorite.
  • the compositions contain from more than 0 wt% to about 0.01 wt%, more preferably from about 0.001 wt% to about 0.008 wt% of colored, especially blue and / or green, metal pigment.
  • colored, especially blue and / or green, metal pigment especially blue and / or green, metal pigment.
  • complex compounds of nickel, cobalt, cuprous, iron and / or manganese are preferred; particularly preferred are copper phthalocyanine dyes.
  • alkali iodide Preferably, more than 0 wt% to about 0.01 wt%, more preferably from about 0.001 wt% to about 0.006 wt% alkali iodide, especially potassium iodide, is present.
  • the stabilized agents according to the invention are normally alkaline and may contain for this purpose about 0.1 wt .-% to 2 wt .-%, in particular 0.1 wt .-% to 1.1 wt .-% alkali metal hydroxide.
  • the preferred alkali hydroxide is sodium hydroxide, and also the alkali salts mentioned in connection with the other ingredients of the compositions are preferably the sodium salts.
  • the formulations may contain surfactants that are stable in the presence of the hypochlorite.
  • betaines in particular of the general formula I, in which R 1 is an alkyl or alkenyl group having 6 to 22 carbon atoms or a group R 4 CO-NH- (CH 2 ) n -, R 2 is hydrogen or an alkyl group having 1 to 4 Carbon atoms, R 3 is hydrogen or an alkyl group having 1 to 4 carbon atoms, R 4 is an alkyl or alkenyl group having 6 to 22 carbon atoms, m is a number from 1 to 6 and n is a number from 1 to 3.
  • surfactants examples include C 12-18 alkyl dimethyl betaine, commercially available as coconut betaine, and C 10-16 alkyl dimethyl betaine, commercially available as lauryl betaine.
  • Another class of particularly preferred surfactants are the alkyl ether sulfates obtainable by reacting alcohols (preferably having 6 to 22 carbon atoms) with alkylene oxides, especially ethylene oxide, followed by sulfation and neutralization, especially a C 12-14 fatty alcohol ether sulfate alkoxylated with 2 equivalents of ethylene oxide , In the ether sulfates, the corresponding cation is preferably sodium.
  • Surfactants are, if present, preferably in amounts up to 5 wt.%, In particular from 0.01 wt .-% to 3 wt .-% in accordance with the invention stabilized agents.
  • the preparations may additionally comprise sequestering agents, preferably alkylphosphonic acids, and among these in particular those having at least one amine oxide substituent on the alkyl group, referred to herein as amine oxide phosphonic acids, polyacrylic acids and / or polyoxyacids containing phosphono groups, which may also be in the form of their alkali metal salts.
  • sequestering agents preferably alkylphosphonic acids, and among these in particular those having at least one amine oxide substituent on the alkyl group, referred to herein as amine oxide phosphonic acids, polyacrylic acids and / or polyoxyacids containing phosphono groups, which may also be in the form of their alkali metal salts.
  • amine oxide phosphonic acids are the amine oxide based on aminotrimethylene phosphonic acid. Preferably, from 0.01% to 2% by weight of such sequestering agents are present.
  • the preparations stabilized according to the invention may contain small amounts of one or more bleach-stable fragrances.
  • the fragrance component optionally present in addition to the anise alcohol is preferably of higher relative volatility than the ingredients which are optionally responsible for a bleaching odor.
  • the stabilized compositions according to the invention can be prepared in a simple manner by mixing the above-mentioned ingredients in the indicated amounts.
  • compositions according to the invention I1, I2 with different pigment contents and preparations for otherwise identical composition without anisalcohol and potassium iodide ( C1, C2 ) were prepared by mixing the ingredients with water.
  • the compositions were composed as follows [wt%]: Table 1: Compositions I1 I2 C1 C2 sodium hypochlorite 3.4 3.4 3.4 C 12/14 fatty alcohol 2 EO sulfate, sodium salt 1.25 1.25 1.25 1.25 1.25 anisalcohol 0.08 0.08 - - potassium iodide 0,004 0,004 - - Cu phthalocyanine, blue 0,002 0.005 0,002 0.005 sodium hydroxide 1 1 1 1 1 Aminotrimethylenephosphonic acid-N-oxide 0.1 0.1 0.1 0.1 water on 100 on 100 on 100 on 100 on 100 on 100 on 100 on 100 on 100 on 100

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Claims (11)

  1. Utilisation d'alcool p-méthoxybenzylique pour la stabilisation de compositions liquides aqueuses contenant de l'hypochlorite, qui contiennent un pigment métallique coloré.
  2. Utilisation d'alcool p-méthoxybenzylique avec un iodure de métal alcalin pour la stabilisation de compositions liquides aqueuses contenant de l'hypochlorite, qui contiennent un pigment métallique coloré.
  3. Utilisation selon la revendication 1 ou 2, caractérisée en ce que la composition contient plus de 0% en poids jusqu'à 0,5% en poids, en particulier 0,01% en poids à 0,1% en poids d'alcool p-méthoxybenzylique.
  4. Utilisation selon l'une quelconque des revendications 1 à 3, caractérisée en ce que la composition contient plus de 0% en poids à 0,01% en poids, en particulier 0,001% en poids à 0,006% en poids d'iodure de métal alcalin, en particulier d'iodure de potassium.
  5. Utilisation selon l'une quelconque des revendications 1 à 4, caractérisée en ce que la composition contient plus de 0% en poids à 0,01% en poids, en particulier 0,001% en poids à 0,008% en poids de pigment métallique coloré.
  6. Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que le pigment métallique est un colorant de type cuivre-phtalocyanine.
  7. Utilisation selon l'une quelconque des revendications 1 à 6, caractérisée en ce que la composition contient 0,5% en poids à 5% en poids d'hypochlorite de métal alcalin, en particulier l'hypochlorite de sodium.
  8. Utilisation selon l'une quelconque des revendications 1 à 7, caractérisée en ce que la composition contient jusqu'à 5% en poids d'agent tensioactif stable au blanchiment, en particulier la bétaïne et/ou un alkyléthersulfate.
  9. Utilisation selon l'une quelconque des revendications 1 à 8, caractérisée en ce que la composition contient 0,01% en poids à 2% en poids d'acide alkylphosphonique et/ou de phosphonate d'alkyle, en particulier l'oxyde d'amine de l'acide phosphonique, le poly(acide acrylique), le poly(acide acrylique) présentant des groupes phosphono et/ou un sel alcalin d'un, de deux ou de trois de ces acides.
  10. Agent de blanchiment liquide aqueux contenant de l'hypochlorite de métal alcalin et un pigment métallique coloré, caractérisé en ce qu'il contient en outre de l'alcool p-méthoxybenzylique.
  11. Agent selon la revendication 10, caractérisé en ce qu'il contient en outre de l'iodure de métal alcalin.
EP06828979A 2005-12-07 2006-11-09 Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite Not-in-force EP1957620B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005058642A DE102005058642B3 (de) 2005-12-07 2005-12-07 Erhöhung der Stabilität flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel
PCT/EP2006/010743 WO2007065525A1 (fr) 2005-12-07 2006-11-09 Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite

Publications (2)

Publication Number Publication Date
EP1957620A1 EP1957620A1 (fr) 2008-08-20
EP1957620B1 true EP1957620B1 (fr) 2010-05-12

Family

ID=37671949

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06828979A Not-in-force EP1957620B1 (fr) 2005-12-07 2006-11-09 Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite

Country Status (6)

Country Link
US (1) US20080308767A1 (fr)
EP (1) EP1957620B1 (fr)
AT (1) ATE467675T1 (fr)
DE (2) DE102005058642B3 (fr)
ES (1) ES2344225T3 (fr)
WO (1) WO2007065525A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013199390A (ja) * 2012-03-23 2013-10-03 Kurita Water Ind Ltd 次亜塩素酸ナトリウムの保存方法
CN103146370A (zh) * 2013-02-26 2013-06-12 中国石油大学(华东) 一种油层预置用防垢剂

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3393153A (en) * 1965-12-20 1968-07-16 Procter & Gamble Novel liquid bleaching compositions
US3666680A (en) * 1970-03-05 1972-05-30 Purex Corp Ltd Method of combining optical brighteners with polymers for stability in bleach and encapsulated product
US3655566A (en) * 1970-03-05 1972-04-11 Purex Corp Ltd Bleach having stable brighteners
US4193888A (en) * 1971-09-01 1980-03-18 Colgate-Palmolive Company Color-yielding scouring cleanser compositions
US3876551A (en) * 1972-02-14 1975-04-08 Int Flavors & Fragrances Inc Perfumed aqueous hypochlorite composition and method for preparation of same
US4116849A (en) * 1977-03-14 1978-09-26 The Procter & Gamble Company Thickened bleach compositions for treating hard-to-remove soils
US4113645A (en) * 1977-07-26 1978-09-12 Polak's Frutal Works, Inc. Bleach compositions containing perfume oils
JPS57119981A (en) * 1981-01-19 1982-07-26 Nitto Chem Ind Co Ltd Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent
US4509949A (en) * 1983-06-13 1985-04-09 The B. F. Goodrich Company Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters
US4828723A (en) * 1987-07-15 1989-05-09 Colgate-Palmolive Company Stable non-aqueous suspension containing organophilic clay and low density filler
US4830782A (en) * 1987-08-31 1989-05-16 Colgate-Palmolive Company Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use
US5185096A (en) * 1991-03-20 1993-02-09 Colgate-Palmolive Co. Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and bleach stabilizer
US5229027A (en) * 1991-03-20 1993-07-20 Colgate-Palmolive Company Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and an iodate or iodide hypochlorite bleach stabilizer
JP2588345B2 (ja) * 1992-09-16 1997-03-05 花王株式会社 着色液体洗浄漂白剤組成物
CN1100861C (zh) * 1994-08-30 2003-02-05 普罗格特-甘布尔公司 增强光漂白作用的螯合剂
CA2228674C (fr) * 1995-08-10 2000-10-10 David A. Chang Compositions detergentes rheopexiques pigmentees dotees de proprietes thixotropes
DE19700799C2 (de) * 1997-01-13 1999-02-04 Henkel Kgaa Wäßrige Textilbleichmittel
CA2295114A1 (fr) * 1997-06-27 1999-01-07 The Procter & Gamble Company Acetals et cetals lineaires precurseurs de parfum
US6083892A (en) * 1997-08-19 2000-07-04 The Procter & Gamble Company Automatic dishwashing detergents comprising β-ketoester pro-fragrances
US5997764A (en) * 1997-12-04 1999-12-07 The B.F. Goodrich Company Thickened bleach compositions
US6448215B1 (en) * 1998-01-16 2002-09-10 The Procter & Gamble Company Stable colored thickened bleaching compositions
US6506718B1 (en) * 1998-09-01 2003-01-14 The Procter & Gamble Company Bleaching compositions
US6894015B1 (en) * 1998-11-11 2005-05-17 Procter & Gamble Company Bleaching compositions
DE19855329A1 (de) * 1998-12-01 2000-06-08 Henkel Kgaa Aktivchlorhaltige Zubereitungen mit stabilisierten optischen Aufhellern
US6180514B1 (en) * 1999-11-12 2001-01-30 Wen-Kuan Yeh Method for forming interconnect using dual damascene

Also Published As

Publication number Publication date
EP1957620A1 (fr) 2008-08-20
US20080308767A1 (en) 2008-12-18
ATE467675T1 (de) 2010-05-15
DE102005058642B3 (de) 2007-07-26
DE502006006949D1 (de) 2010-06-24
ES2344225T3 (es) 2010-08-20
WO2007065525A1 (fr) 2007-06-14

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