EP1957621B1 - Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite - Google Patents
Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite Download PDFInfo
- Publication number
- EP1957621B1 EP1957621B1 EP06818842A EP06818842A EP1957621B1 EP 1957621 B1 EP1957621 B1 EP 1957621B1 EP 06818842 A EP06818842 A EP 06818842A EP 06818842 A EP06818842 A EP 06818842A EP 1957621 B1 EP1957621 B1 EP 1957621B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- use according
- hypochlorite
- alkali
- composition contains
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 title claims description 20
- 238000005406 washing Methods 0.000 title abstract 2
- 238000004140 cleaning Methods 0.000 title description 3
- 150000001412 amines Chemical class 0.000 claims abstract description 21
- 239000003513 alkali Substances 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 13
- -1 alkyl ether sulfate Chemical class 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 7
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 6
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000007844 bleaching agent Substances 0.000 claims description 5
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 229960003237 betaine Drugs 0.000 claims description 4
- 125000003386 piperidinyl group Chemical group 0.000 claims description 4
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 claims description 2
- 239000001007 phthalocyanine dye Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 239000004584 polyacrylic acid Substances 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 8
- 150000002431 hydrogen Chemical class 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003599 detergent Substances 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 150000003009 phosphonic acids Chemical class 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- FAPCFNWEPHTUQK-UHFFFAOYSA-N 2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)[NH+]1[O-] FAPCFNWEPHTUQK-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 1
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019093 NaOCl Inorganic materials 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical class [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920003240 metallophthalocyanine polymer Polymers 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Definitions
- the agents contain more than 0 wt .-% to 0.01 wt .-%, in particular up to 0.005 wt .-% of colored, especially blue and / or green, metal pigment.
- colored, especially blue and / or green, metal pigment especially blue and / or green, metal pigment.
- complex compounds of nickel, cobalt, cuprous, iron and / or manganese are preferred; particularly preferred are copper phthalocyanine dyes.
- the preparations stabilized according to the invention may contain small amounts of one or more bleach-stable fragrances.
- the optional perfume component is preferably of higher relative volatility than the ingredients optionally responsible for a bleaching odor.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (11)
- Utilisation conjointe d'un iodure de métal alcalin et d'une amine stériquement encombrée, qui présente le groupe de formule générale (I),
- Utilisation selon la revendication 1, caractérisée en ce que dans l'amine stériquement encombrée, le groupe de formule générale (I) fait partie d'un cycle pipéridine.
- Utilisation selon la revendication 2, caractérisée en ce que dans l'amine stériquement encombrée, le cycle pipéridine présente, en plus des substituants R1, R2, R3, R4 et X, un substituant en position 4, qui est -OH, -NHR6 ou oxygène lié via une double liaison, R6 représentant un groupe C1-4-alkyle ou un groupe cyclohexyle.
- Utilisation selon l'une quelconque des revendications 1 à 3, caractérisée en ce que la composition contient de plus de 0% en poids à 0,01 % en poids, en particulier 0,0005% en poids à 0,003% en poids d'iodure de métal alcalin, en particulier d'iodure de potassium.
- Utilisation selon l'une quelconque des revendications 1 à 4, caractérisée en ce que la composition contient de plus de 0% en poids à 0,1% en poids, en particulier 0,0005% en poids à 0,03% en poids de l'amine stériquement encombrée.
- Utilisation selon l'une quelconque des revendications 1 à 5, caractérisée en ce que la composition contient de plus de 0% en poids à 0,01 % en poids, en particulier jusqu'à 0,005% en poids, de pigment métallique coloré.
- Utilisation selon l'une quelconque des revendications 1 à 6, caractérisée en ce que le pigment métallique est un colorant de type cuivre-phtalocyanine.
- Utilisation selon l'une quelconque des revendications 1 à 7, caractérisée en ce que la composition contient 0,5% en poids à 5% en poids d'hypochlorite de métal alcalin, en particulier l'hypochlorite de sodium.
- Utilisation selon l'une quelconque des revendications 1 à 8, caractérisée en ce que la composition contient jusqu'à 5% en poids d'agent tensioactif stable au blanchiment, en particulier une bétaïne et/ou un alkyléthersulfate.
- Utilisation selon l'une quelconque des revendications 1 à 9, caractérisée en ce que la composition contient 0,01% en poids à 2% en poids d'acide alkylphosphonique et/ou de phosphonate d'alkyle, en particulier l'oxyde d'amine de l'acide phosphonique, le poly(acide acrylique), le poly(acide acrylique) présentant des groupes phosphono et/ou un sel alcalin d'un, de deux ou de tous les trois de ces acides.
- Agent de blanchiment liquide aqueux contenant de l'hypochlorite de métal alcalin et un pigment métallique coloré, caractérisé en ce qu'il contient en outre une combinaison d'iodure de métal alcalin et d'une amine stériquement encombrée, qui présente le groupe de formule générale (I),
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL06818842T PL1957621T3 (pl) | 2005-12-06 | 2006-11-27 | Polepszenie trwałości ciekłych, zawierających podchloryn, środków piorących i czyszczących |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005058339A DE102005058339A1 (de) | 2005-12-06 | 2005-12-06 | Stabilitätsverbesserung flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
| PCT/EP2006/011348 WO2007065581A1 (fr) | 2005-12-06 | 2006-11-27 | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1957621A1 EP1957621A1 (fr) | 2008-08-20 |
| EP1957621B1 true EP1957621B1 (fr) | 2010-10-06 |
Family
ID=37853024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP06818842A Not-in-force EP1957621B1 (fr) | 2005-12-06 | 2006-11-27 | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20080308766A1 (fr) |
| EP (1) | EP1957621B1 (fr) |
| AT (1) | ATE483786T1 (fr) |
| DE (2) | DE102005058339A1 (fr) |
| ES (1) | ES2353976T3 (fr) |
| PL (1) | PL1957621T3 (fr) |
| WO (1) | WO2007065581A1 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021185702A1 (fr) * | 2020-03-17 | 2021-09-23 | Basf Se | Procédé de fabrication d'un granulé |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3393153A (en) * | 1965-12-20 | 1968-07-16 | Procter & Gamble | Novel liquid bleaching compositions |
| US3666680A (en) * | 1970-03-05 | 1972-05-30 | Purex Corp Ltd | Method of combining optical brighteners with polymers for stability in bleach and encapsulated product |
| US3655566A (en) * | 1970-03-05 | 1972-04-11 | Purex Corp Ltd | Bleach having stable brighteners |
| US4193888A (en) * | 1971-09-01 | 1980-03-18 | Colgate-Palmolive Company | Color-yielding scouring cleanser compositions |
| US3876551A (en) * | 1972-02-14 | 1975-04-08 | Int Flavors & Fragrances Inc | Perfumed aqueous hypochlorite composition and method for preparation of same |
| US3834579A (en) * | 1973-03-27 | 1974-09-10 | American Can Co | Container having a metal overcap-thermoplastic lid closure assembly |
| US4116849A (en) * | 1977-03-14 | 1978-09-26 | The Procter & Gamble Company | Thickened bleach compositions for treating hard-to-remove soils |
| US4113645A (en) * | 1977-07-26 | 1978-09-12 | Polak's Frutal Works, Inc. | Bleach compositions containing perfume oils |
| JPS57119981A (en) * | 1981-01-19 | 1982-07-26 | Nitto Chem Ind Co Ltd | Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent |
| US4474677A (en) * | 1981-11-06 | 1984-10-02 | Lever Brothers Company | Colored aqueous alkalimetal hypochlorite compositions |
| US5180514A (en) * | 1985-06-17 | 1993-01-19 | The Clorox Company | Stabilizing system for liquid hydrogen peroxide compositions |
| US4828723A (en) * | 1987-07-15 | 1989-05-09 | Colgate-Palmolive Company | Stable non-aqueous suspension containing organophilic clay and low density filler |
| US4830782A (en) * | 1987-08-31 | 1989-05-16 | Colgate-Palmolive Company | Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use |
| US5139695A (en) * | 1988-01-14 | 1992-08-18 | Ciba-Geigy Corporation | Stable bleaching compositions containing fluorescent whitening agents |
| US5185096A (en) * | 1991-03-20 | 1993-02-09 | Colgate-Palmolive Co. | Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and bleach stabilizer |
| US5229027A (en) * | 1991-03-20 | 1993-07-20 | Colgate-Palmolive Company | Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and an iodate or iodide hypochlorite bleach stabilizer |
| EP0565788A1 (fr) * | 1992-04-15 | 1993-10-20 | Colgate-Palmolive Company | Composition détergente aqueuse liquide pour le lavage automatique de la vaisselle contenant un agent de blanchiment à base d'hypochlorite et un stabilisateur de blanchiment |
| US5380458A (en) * | 1992-10-02 | 1995-01-10 | Colgate-Palmolive Co. | Stabilized hypohalite compositions |
| DE69515318D1 (de) * | 1994-08-30 | 2000-04-06 | Procter & Gamble | Mittels chelatbildnern verbessertes photobleichen |
| US5705044A (en) * | 1995-08-07 | 1998-01-06 | Akashic Memories Corporation | Modular sputtering machine having batch processing and serial thin film sputtering |
| NL1003225C2 (nl) * | 1996-05-29 | 1997-12-03 | Heineken Tech Services | Werkwijze voor het reinigen van apparatuur die toegepast is bij het brouwen van bier. |
| DE19700799C2 (de) * | 1997-01-13 | 1999-02-04 | Henkel Kgaa | Wäßrige Textilbleichmittel |
| ES2182333T3 (es) * | 1997-06-27 | 2003-03-01 | Procter & Gamble | Acetales y cetales lineales como pro-fragancias. |
| US6083892A (en) * | 1997-08-19 | 2000-07-04 | The Procter & Gamble Company | Automatic dishwashing detergents comprising β-ketoester pro-fragrances |
| US6448215B1 (en) * | 1998-01-16 | 2002-09-10 | The Procter & Gamble Company | Stable colored thickened bleaching compositions |
| US6506718B1 (en) * | 1998-09-01 | 2003-01-14 | The Procter & Gamble Company | Bleaching compositions |
| US6894015B1 (en) * | 1998-11-11 | 2005-05-17 | Procter & Gamble Company | Bleaching compositions |
| DE19855329A1 (de) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Aktivchlorhaltige Zubereitungen mit stabilisierten optischen Aufhellern |
| KR100490564B1 (ko) * | 2002-07-23 | 2005-05-19 | 주식회사 메디슨 | 초음파 영상 신호로부터 장기를 인식하는 장치 및 방법 |
| ITMI20021693A1 (it) * | 2002-07-30 | 2004-01-30 | 3V Sigma Spa | Composizioni liquide stabilizzate contenenti cloro attivo |
| EP1614742B1 (fr) * | 2004-07-08 | 2007-12-05 | The Procter & Gamble Company | Composition de blanchissement comprenant une amine cyclique à empèchement stérique |
| US7998886B2 (en) * | 2005-10-24 | 2011-08-16 | Milliken & Company | Hindered amine treated textiles |
-
2005
- 2005-12-06 DE DE102005058339A patent/DE102005058339A1/de not_active Ceased
-
2006
- 2006-11-27 EP EP06818842A patent/EP1957621B1/fr not_active Not-in-force
- 2006-11-27 PL PL06818842T patent/PL1957621T3/pl unknown
- 2006-11-27 ES ES06818842T patent/ES2353976T3/es active Active
- 2006-11-27 DE DE502006008043T patent/DE502006008043D1/de active Active
- 2006-11-27 WO PCT/EP2006/011348 patent/WO2007065581A1/fr active Application Filing
- 2006-11-27 AT AT06818842T patent/ATE483786T1/de active
-
2008
- 2008-05-29 US US12/129,232 patent/US20080308766A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| DE102005058339A1 (de) | 2007-06-28 |
| US20080308766A1 (en) | 2008-12-18 |
| EP1957621A1 (fr) | 2008-08-20 |
| WO2007065581A1 (fr) | 2007-06-14 |
| ATE483786T1 (de) | 2010-10-15 |
| DE502006008043D1 (de) | 2010-11-18 |
| PL1957621T3 (pl) | 2011-04-29 |
| ES2353976T3 (es) | 2011-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE2336291A1 (de) | Fluessiges wasch- und reinigungsmittel | |
| WO1995009227A1 (fr) | Decolorants et desinfectants | |
| EP1957620B1 (fr) | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite | |
| EP1957621B1 (fr) | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite | |
| EP1966364B1 (fr) | Amélioration de la stabilité de détergents contenant de l'hypochlorite | |
| DE102012206707A1 (de) | Wasch-, Reinigungs- oder Spülmittel mit verbessertem Schaumverhalten | |
| DE19803054A1 (de) | Bleich- und Desinfektionsmittel | |
| EP1075506B1 (fr) | Agents de blanchiment et de desinfection | |
| EP1966362B1 (fr) | Amélioration de la stabilité de détergents contenant de l'hypochlorite | |
| WO2007025642A1 (fr) | Agent de blanchiment liquide contenant de l'hypohalogenite | |
| DE102005059048A1 (de) | Reinigungsmittel für harte Oberflächen | |
| DE60014941T2 (de) | Geschirrspülmittel enthaltend farbstabilisierende phosphonate | |
| DE19621048C2 (de) | Wäßrige Bleich- und Desinfektionsmittel | |
| DE60217358T2 (de) | Verdickte flüssige Bleichmittelzusammensetzungen | |
| EP2171029B1 (fr) | Agent blanchissant doux | |
| DE10124288A1 (de) | Reinigungsmittel für harte Oberflächen (II) | |
| DE10136207A1 (de) | Verbesserung der Lichtstabilität flüssiger Wasch- und Reinigungsmittel (II) | |
| DE10124304A1 (de) | Reinigungsmittel für harte Oberflächen (III) | |
| DE10124289A1 (de) | Reinigungsmittel für harte Oberflächen (I) | |
| DE10136209A1 (de) | Verbesserung der Lichtstabilität flüssiger Wasch-und Reinigungsmittel (I) | |
| EP1966363B1 (fr) | Inhibition des proprietes corrosives d'agents de nettoyage liquides contenant de l'hypochlorite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20080318 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| DAX | Request for extension of the european patent (deleted) | ||
| GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
| GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
| AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE SI SK TR |
|
| REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: GERMAN |
|
| REF | Corresponds to: |
Ref document number: 502006008043 Country of ref document: DE Date of ref document: 20101118 Kind code of ref document: P |
|
| REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
| REG | Reference to a national code |
Ref country code: NL Ref legal event code: VDEP Effective date: 20101006 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Effective date: 20110224 |
|
| LTIE | Lt: invalidation of european patent or patent extension |
Effective date: 20101006 |
|
| REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E009400 Country of ref document: HU |
|
| REG | Reference to a national code |
Ref country code: IE Ref legal event code: FD4D |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
| REG | Reference to a national code |
Ref country code: PL Ref legal event code: T3 |
|
| BERE | Be: lapsed |
Owner name: HENKEL A.G. & CO. KGAA Effective date: 20101130 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110207 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110106 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: LV Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110206 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20110107 Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101130 |
|
| REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101130 Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: IE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101130 |
|
| PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101130 |
|
| 26N | No opposition filed |
Effective date: 20110707 |
|
| GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20110106 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 502006008043 Country of ref document: DE Effective date: 20110707 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110106 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20101006 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101127 |
|
| REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 483786 Country of ref document: AT Kind code of ref document: T Effective date: 20111127 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20111127 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 10 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20151027 Year of fee payment: 10 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: PL Payment date: 20151023 Year of fee payment: 10 Ref country code: CZ Payment date: 20151126 Year of fee payment: 10 Ref country code: HU Payment date: 20151118 Year of fee payment: 10 Ref country code: RO Payment date: 20151026 Year of fee payment: 10 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 11 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161127 Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161127 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161128 |
|
| REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 12 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161127 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20181120 Year of fee payment: 13 |
|
| PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20181123 Year of fee payment: 13 Ref country code: ES Payment date: 20181218 Year of fee payment: 13 Ref country code: IT Payment date: 20181126 Year of fee payment: 13 |
|
| REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 502006008043 Country of ref document: DE |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191127 Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191130 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20200603 |
|
| REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20210531 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20191128 |
|
| PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20161127 |