EP1957621A1 - Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite - Google Patents
Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochloriteInfo
- Publication number
- EP1957621A1 EP1957621A1 EP06818842A EP06818842A EP1957621A1 EP 1957621 A1 EP1957621 A1 EP 1957621A1 EP 06818842 A EP06818842 A EP 06818842A EP 06818842 A EP06818842 A EP 06818842A EP 1957621 A1 EP1957621 A1 EP 1957621A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- weight
- use according
- hypochlorite
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 title claims abstract description 15
- 238000005406 washing Methods 0.000 title abstract description 5
- 238000004140 cleaning Methods 0.000 title abstract description 4
- 150000001412 amines Chemical class 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 10
- 239000002184 metal Substances 0.000 claims abstract description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 claims description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 7
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 7
- -1 alkyl ether sulfate Chemical class 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000007844 bleaching agent Substances 0.000 claims description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 6
- 239000001301 oxygen Chemical group 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 125000001424 substituent group Chemical group 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 4
- 229960003237 betaine Drugs 0.000 claims description 4
- 125000003386 piperidinyl group Chemical group 0.000 claims description 4
- 230000006641 stabilisation Effects 0.000 claims description 3
- 238000011105 stabilization Methods 0.000 claims description 3
- 150000001447 alkali salts Chemical class 0.000 claims description 2
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 2
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 claims description 2
- 239000001007 phthalocyanine dye Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 6
- 239000004584 polyacrylic acid Substances 0.000 claims 2
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 claims 1
- 229910001516 alkali metal iodide Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 15
- 238000002360 preparation method Methods 0.000 description 12
- 150000002431 hydrogen Chemical class 0.000 description 7
- 239000012459 cleaning agent Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FAPCFNWEPHTUQK-UHFFFAOYSA-N 2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-ol Chemical compound CC1(C)CC(O)CC(C)(C)[NH+]1[O-] FAPCFNWEPHTUQK-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019093 NaOCl Inorganic materials 0.000 description 1
- 102100038239 Protein Churchill Human genes 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3951—Bleaching agents combined with specific additives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
Definitions
- the present invention relates to the stabilization of hypochlorite-containing liquid detergents and / or cleaning agents for hard surfaces in households, for example for cleaning tiles.
- Sodium hypochlorite is known as a highly effective bleaching agent and has been used for a long time, optionally together with soaps and / or synthetic surfactants, to remove stains and all types of soiling when washing textiles and when cleaning hard surfaces. It is usually sold in concentrations of about 2 to 10% by weight in water for household use. It is not uncommon for such preparations to contain hydrotropes to regulate their viscosity.
- Liquid detergent preparations or corresponding preparations of cleaning agents for hard surfaces which contain hypochlorite as the bleaching component, are susceptible to loss of activity in the case of prolonged storage, in particular because of the degradation of the hypochlorite which then takes place.
- the ingredients that are desirable in washing and cleaning agents from the point of view of use or for aesthetic reasons include, in addition to the active ingredients that decisively influence the performance of such agents, in particular hypochlorite in this case, also coloring agents which are intended to give liquid preparations in particular a pleasant visual appearance. Dyes in particular are usually slightly oxidatively attacked by hypochlorite, so that the color impression of hypochlorite-containing liquid agents changes rapidly during storage.
- the invention therefore relates to the joint use of an alkali iodide and a sterically hindered amine which has the group of the general formula (I)
- a second object of the invention is an aqueous liquid bleaching agent containing alkali hypochlorite and colored metal pigment, which is characterized in that it additionally contains a combination of akali iodide and sterically hindered amine, which has the group of the general formula (I), CR'R 2 -N-CR 3 R 4 -
- radicals R 1 , R 2 , R 3 and R 4 independently of one another represent hydrogen, a methyl group or an ethyl group, with the proviso that no more than 2 of these radicals are simultaneously hydrogen, and X represents hydrogen, oxygen, represents a methyl group, an ethyl group, -OH or -OR 5 , where R 5 is a Ci -4 alkyl group or a cyclohexyl group.
- the piperidine ring preferably has a substituent in position 4 which is -OH, -NHR 6 or oxygen linked via a double bond, where R 6 is a Ci -4 is an alkyl group or a cyclohexyl group.
- the liquid agent stabilized according to the invention contains 0.5% by weight to 5% by weight of alkali hypochlorite, in particular sodium hypochlorite.
- compositions are particularly suitable and very effective as cleaning agents for hard surfaces, for example for use on walls, work surfaces, floors and the like.
- the compositions particularly because of their hypochlorite content, are particularly suitable for removing soiling that occurs in kitchens or bathrooms, including the greasy soiling that can occur after the use of bathtubs, shower cubicles and wash basins.
- a bleaching agent in the form of hypochlorite is an essential component of the agents according to the invention.
- Bleaching agents in themselves are well known components of detergent compositions and are particularly successful in combating mildew and mold, soiling that can often be found in soap deposits or in association with them.
- alkali hypochlorites such as, for example, potassium hypochlorite
- sodium hypochlorite in agents stabilized according to the invention.
- Commercial aqueous sodium hypochlorite solutions often contain considerable amounts of chloride salts. These can easily be used to produce agents according to the invention, so that one does not necessarily have to rely on the use of high-purity NaOCl.
- the compositions contain 0.5% by weight to 4.5% by weight, in particular 1% by weight to 4% by weight, of alkali hypochlorite.
- compositions preferably contain more than 0% by weight to 0.01% by weight, in particular up to 0.005% by weight, of colored, in particular blue and / or green, metal pigment.
- colored, in particular blue and / or green, metal pigment preferably contain more than 0% by weight to 0.01% by weight, in particular up to 0.005% by weight, of colored, in particular blue and / or green, metal pigment.
- complex compounds of nickel, cobalt, cupfer, iron and / or manganese are preferred; copper phthalocyanine dyes are particularly preferred.
- the stability of both the colored metal pigment and the alkali hypochlorite is increased by the presence of alkali iodide.
- alkali iodide There is preferably more than 0% by weight up to about 0.01% by weight, in particular about 0.0005% by weight up to about 0.003% by weight, of alkali iodide, in particular potassium iodide.
- the agents stabilized according to the invention are normally alkaline and for this purpose can contain about 0.1% by weight to 2% by weight, in particular 0.1% by weight to 1.1% by weight, of alkali metal hydroxide.
- the preferred alkali hydroxide is sodium hydroxide, and the alkali salts, which are mentioned in connection with the other ingredients of the compositions, are preferably the sodium salts.
- the preparations can contain surfactants which are stable in the presence of the hypochlorite.
- Betaines in particular of general formula II, are preferred, R 8
- Examples of particularly suitable representatives of this class of surfactants include d 2- i 8 alkyl dimethyl betaine, commercially available as coconut betaine, and Ci O. I 6 alkyl dimethyl betaine, commercially available as lauryl betaine.
- a further class of particularly preferred surfactants are the alkyl ether sulfates which are obtainable by reaction of alcohols (preferably containing 6 to 22 carbon atoms), with alkylene oxides, especially ethylene oxide followed by sulfation and neutralization available, particularly an alkoxylated with 2 equivalents of ethylene oxide Ci2-I4 - fatty alcohol ether sulphate .
- the corresponding cation is preferably sodium.
- surfactants are preferably present in amounts up to 5% by weight, in particular from 0.01% by weight to 3% by weight, in agents stabilized according to the invention.
- the preparations can additionally contain sequestering agents, preferably alkylphosphonic acids and, in particular, those with at least one amine oxide substituent on the alkyl group, here referred to as amine oxidephosphonic acids, polyacrylic acids and / or polyacrylic acids having phosphono groups, which may also be present in the form of their alkali metal salts.
- sequestering agents preferably alkylphosphonic acids and, in particular, those with at least one amine oxide substituent on the alkyl group, here referred to as amine oxidephosphonic acids, polyacrylic acids and / or polyacrylic acids having phosphono groups, which may also be present in the form of their alkali metal salts.
- amine oxidephosphonic acids preferably alkylphosphonic acids and, in particular, those with at least one amine oxide substituent on the alkyl group
- polyacrylic acids and / or polyacrylic acids having phosphono groups which may also be present in the form of their alkali metal salts.
- R 1 ' is hydrogen, a group - (CH 2 ) x (CHCH 3 ) y -NH 2 -> 0 or an alkali metal, x is a number from 1 to 4 and y is 0 or 1.
- Particularly preferred amine oxide phosphonic acids are those based on aminotrimethylene phosphonic acid, preferably 0.01% to 2% by weight of such sequestering agents.
- the preparations stabilized according to the invention can contain small amounts of one or more bleach-stable fragrances.
- the fragrance component optionally contained is preferably of higher relative volatility than the components which are possibly responsible for a bleach odor.
- the agents stabilized according to the invention can be prepared in a simple manner by mixing the above-mentioned ingredients in the stated amounts.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL06818842T PL1957621T3 (pl) | 2005-12-06 | 2006-11-27 | Polepszenie trwałości ciekłych, zawierających podchloryn, środków piorących i czyszczących |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005058339A DE102005058339A1 (de) | 2005-12-06 | 2005-12-06 | Stabilitätsverbesserung flüssiger hypochlorithaltiger Wasch- und Reinigungsmittel |
PCT/EP2006/011348 WO2007065581A1 (fr) | 2005-12-06 | 2006-11-27 | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1957621A1 true EP1957621A1 (fr) | 2008-08-20 |
EP1957621B1 EP1957621B1 (fr) | 2010-10-06 |
Family
ID=37853024
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06818842A Not-in-force EP1957621B1 (fr) | 2005-12-06 | 2006-11-27 | Augmentation de la stabilite de produits de purification et de nettoyage liquides contenant de l'hypochlorite |
Country Status (7)
Country | Link |
---|---|
US (1) | US20080308766A1 (fr) |
EP (1) | EP1957621B1 (fr) |
AT (1) | ATE483786T1 (fr) |
DE (2) | DE102005058339A1 (fr) |
ES (1) | ES2353976T3 (fr) |
PL (1) | PL1957621T3 (fr) |
WO (1) | WO2007065581A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2021185702A1 (fr) * | 2020-03-17 | 2021-09-23 | Basf Se | Procédé de fabrication d'un granulé |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3393153A (en) * | 1965-12-20 | 1968-07-16 | Procter & Gamble | Novel liquid bleaching compositions |
US3666680A (en) * | 1970-03-05 | 1972-05-30 | Purex Corp Ltd | Method of combining optical brighteners with polymers for stability in bleach and encapsulated product |
US3655566A (en) * | 1970-03-05 | 1972-04-11 | Purex Corp Ltd | Bleach having stable brighteners |
US4193888A (en) * | 1971-09-01 | 1980-03-18 | Colgate-Palmolive Company | Color-yielding scouring cleanser compositions |
US3876551A (en) * | 1972-02-14 | 1975-04-08 | Int Flavors & Fragrances Inc | Perfumed aqueous hypochlorite composition and method for preparation of same |
US3834579A (en) * | 1973-03-27 | 1974-09-10 | American Can Co | Container having a metal overcap-thermoplastic lid closure assembly |
US4116849A (en) * | 1977-03-14 | 1978-09-26 | The Procter & Gamble Company | Thickened bleach compositions for treating hard-to-remove soils |
US4113645A (en) * | 1977-07-26 | 1978-09-12 | Polak's Frutal Works, Inc. | Bleach compositions containing perfume oils |
JPS57119981A (en) * | 1981-01-19 | 1982-07-26 | Nitto Chem Ind Co Ltd | Method for stabilizing aqueous solution containing chlorine-containing oxidizing agent |
US4474677A (en) * | 1981-11-06 | 1984-10-02 | Lever Brothers Company | Colored aqueous alkalimetal hypochlorite compositions |
US5180514A (en) * | 1985-06-17 | 1993-01-19 | The Clorox Company | Stabilizing system for liquid hydrogen peroxide compositions |
US4828723A (en) * | 1987-07-15 | 1989-05-09 | Colgate-Palmolive Company | Stable non-aqueous suspension containing organophilic clay and low density filler |
US4830782A (en) * | 1987-08-31 | 1989-05-16 | Colgate-Palmolive Company | Hot water wash cycle built nonaqueous liquid nonionic laundry detergent composition containing amphoteric surfactant and method of use |
US5139695A (en) * | 1988-01-14 | 1992-08-18 | Ciba-Geigy Corporation | Stable bleaching compositions containing fluorescent whitening agents |
US5185096A (en) * | 1991-03-20 | 1993-02-09 | Colgate-Palmolive Co. | Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and bleach stabilizer |
US5229027A (en) * | 1991-03-20 | 1993-07-20 | Colgate-Palmolive Company | Aqueous liquid automatic dishwashing detergent composition comprising hypochlorite bleach and an iodate or iodide hypochlorite bleach stabilizer |
EP0565788A1 (fr) * | 1992-04-15 | 1993-10-20 | Colgate-Palmolive Company | Composition détergente aqueuse liquide pour le lavage automatique de la vaisselle contenant un agent de blanchiment à base d'hypochlorite et un stabilisateur de blanchiment |
US5380458A (en) * | 1992-10-02 | 1995-01-10 | Colgate-Palmolive Co. | Stabilized hypohalite compositions |
DE69515318D1 (de) * | 1994-08-30 | 2000-04-06 | Procter & Gamble | Mittels chelatbildnern verbessertes photobleichen |
US5705044A (en) * | 1995-08-07 | 1998-01-06 | Akashic Memories Corporation | Modular sputtering machine having batch processing and serial thin film sputtering |
NL1003225C2 (nl) * | 1996-05-29 | 1997-12-03 | Heineken Tech Services | Werkwijze voor het reinigen van apparatuur die toegepast is bij het brouwen van bier. |
DE19700799C2 (de) * | 1997-01-13 | 1999-02-04 | Henkel Kgaa | Wäßrige Textilbleichmittel |
ES2182333T3 (es) * | 1997-06-27 | 2003-03-01 | Procter & Gamble | Acetales y cetales lineales como pro-fragancias. |
US6083892A (en) * | 1997-08-19 | 2000-07-04 | The Procter & Gamble Company | Automatic dishwashing detergents comprising β-ketoester pro-fragrances |
US6448215B1 (en) * | 1998-01-16 | 2002-09-10 | The Procter & Gamble Company | Stable colored thickened bleaching compositions |
US6506718B1 (en) * | 1998-09-01 | 2003-01-14 | The Procter & Gamble Company | Bleaching compositions |
US6894015B1 (en) * | 1998-11-11 | 2005-05-17 | Procter & Gamble Company | Bleaching compositions |
DE19855329A1 (de) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Aktivchlorhaltige Zubereitungen mit stabilisierten optischen Aufhellern |
KR100490564B1 (ko) * | 2002-07-23 | 2005-05-19 | 주식회사 메디슨 | 초음파 영상 신호로부터 장기를 인식하는 장치 및 방법 |
ITMI20021693A1 (it) * | 2002-07-30 | 2004-01-30 | 3V Sigma Spa | Composizioni liquide stabilizzate contenenti cloro attivo |
EP1614742B1 (fr) * | 2004-07-08 | 2007-12-05 | The Procter & Gamble Company | Composition de blanchissement comprenant une amine cyclique à empèchement stérique |
US7998886B2 (en) * | 2005-10-24 | 2011-08-16 | Milliken & Company | Hindered amine treated textiles |
-
2005
- 2005-12-06 DE DE102005058339A patent/DE102005058339A1/de not_active Ceased
-
2006
- 2006-11-27 EP EP06818842A patent/EP1957621B1/fr not_active Not-in-force
- 2006-11-27 PL PL06818842T patent/PL1957621T3/pl unknown
- 2006-11-27 ES ES06818842T patent/ES2353976T3/es active Active
- 2006-11-27 DE DE502006008043T patent/DE502006008043D1/de active Active
- 2006-11-27 WO PCT/EP2006/011348 patent/WO2007065581A1/fr active Application Filing
- 2006-11-27 AT AT06818842T patent/ATE483786T1/de active
-
2008
- 2008-05-29 US US12/129,232 patent/US20080308766A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of WO2007065581A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE102005058339A1 (de) | 2007-06-28 |
US20080308766A1 (en) | 2008-12-18 |
WO2007065581A1 (fr) | 2007-06-14 |
ATE483786T1 (de) | 2010-10-15 |
DE502006008043D1 (de) | 2010-11-18 |
PL1957621T3 (pl) | 2011-04-29 |
ES2353976T3 (es) | 2011-03-08 |
EP1957621B1 (fr) | 2010-10-06 |
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