EP2098587B1 - Mélange de décalquage, de nettoyage et/ou de désinfection - Google Patents

Mélange de décalquage, de nettoyage et/ou de désinfection Download PDF

Info

Publication number
EP2098587B1
EP2098587B1 EP09005788A EP09005788A EP2098587B1 EP 2098587 B1 EP2098587 B1 EP 2098587B1 EP 09005788 A EP09005788 A EP 09005788A EP 09005788 A EP09005788 A EP 09005788A EP 2098587 B1 EP2098587 B1 EP 2098587B1
Authority
EP
European Patent Office
Prior art keywords
mixture
weight
acid
mixture according
descaling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP09005788A
Other languages
German (de)
English (en)
Other versions
EP2098587A1 (fr
Inventor
Uwe Dr. Gibbels
Katja Füser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Brauns Heitmann GmbH and Co KG
Original Assignee
Brauns Heitmann GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brauns Heitmann GmbH and Co KG filed Critical Brauns Heitmann GmbH and Co KG
Publication of EP2098587A1 publication Critical patent/EP2098587A1/fr
Application granted granted Critical
Publication of EP2098587B1 publication Critical patent/EP2098587B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/26—Organic compounds containing oxygen
    • C11D7/265—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Definitions

  • the present invention relates to a mixture for descaling, cleaning and / or disinfecting and their use.
  • the cleaning and descaling agent disclosed therein comprises at least one mineral acid and from 0.5 to 50% by weight of an alkoxylated amine in aqueous solution, wherein additionally an organic acid, an organic acid anhydride or a salt of an organic acid may be added to give a thickening effect of an ethoxylated or propoxylated tertiary amine.
  • an organic acid for example, citric acid or tartaric acid can be used.
  • the additional mixture of the mixture according to the invention comprises both malic acid and tartaric acid, preference being given to the weight ratio of malic acid to tartaric acid in a range from about 1: 6 to 6: 1, more preferably in a range from about 0.8: 1 to 4: 1, even more preferably ranges from about 1: 1 to about 3.8: 1.
  • the additional mixture may in principle comprise malic acid, tartaric acid, but also other carboxylic acids such as lactic acid or maleic acid.
  • the inventors have found that when using malic acid and tartaric acid not expected improvements in the descaling performance of the mixture according to the invention can be determined are.
  • Particularly preferred are additional mixtures which contain malic acid in excess, based on the amount by weight, in comparison with tartaric acid.
  • Salts of organic acids having 1 to 6 carbon atoms, in particular trisodium citrate, are particularly preferred as buffering agents.
  • the buffering agent may preferably be present in the blend according to the invention in an amount of about 0.5-10% by weight, more preferably about 1.0 to about 5% by weight, even more preferably about 1.5 to about 4% by weight. % be used.
  • the additional mixture is chosen such that the additional mixture has a weight ratio of malic acid to tartaric acid of about 3: 1, then at a concentration of 50 g of the mixture per liter of water a particularly high level of lime-dissolving capacity in ranges of about 4% by weight to about 10 wt .-% or about 20 wt .-% to about 35 wt .-% of the additional mixture obtained, with a further increase in the concentration of the mixture according to the invention to 100 g per liter of water, the range of very good Kalklös ashameds with the addition of about 4 Wt .-% to about 20 wt .-% and about 45 wt .-% to about 75 wt .-% additional mixture is detectable.
  • the powdered mixture according to the invention will be used, which is simply entered into the kettle or the filling shaft of the washing machine and subsequently filled the container with water or the washing machine in a conventional washing program, preferably in a program with temperatures of more than 30 ° C, filled or operated to achieve a decalcification.
  • the decalcification processes are repeatable even with very stubborn and fixed lime.
  • Fig. 2 Finally, there is an overview of the dependence of the lime dissolving power of citric acid-containing mixtures, to which an additional mixture of malic acid and tartaric acid in different proportions by weight has been added.
  • a concentration of 50 g of the respective mixture or pure citric acid based on 500 ml of tap water, is how Fig. 2 it can be seen, a higher lime dissolving power, determined on marble slabs according to the method described above, compared to solutions of 25 g in 500 ml of tap water or to determine only 10 g in 500 ml of tap water.
  • concentrations of the aqueous solutions of 50 g in 500 ml of water pronounced maxima appear.
  • a weight proportion of malic acid to tartaric acid of 3: 1 is selected under otherwise constant conditions, then a first small maximum in a range from about 6 to about 10% by weight of the additional mixture, which also in the proportions by weight of malic acid to tartaric acid from 1: 3 and 1: 1 was in evidence, and incidentally, a very wide maximum in a range of about 45 wt .-% to about 75 wt .-% of the additional mixture determine.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Claims (13)

  1. Mélange pour éliminer le calcaire, nettoyer et/ou désinfecter, comprenant au moins 25 % en poids d'acide citrique, rapportés à la quantité totale du mélange, et au moins 0,1 à 75 % en poids, rapportés à la quantité totale du mélange, d'un mélange additionnel comportant de l'acide malique et/ou de l'acide tartrique.
  2. Mélange selon la revendication 1, caractérisé en ce que le rapport pondéral de l'acide malique à l'acide tartrique est compris dans un intervalle d'environ 1 : 6 à env. 6:1.
  3. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que ce dernier comprend en outre au moins un tampon.
  4. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que le mélange comprend au moins 75 % en poids d'acide citrique et au moins 3 % en poids du mélange additionnel.
  5. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que le mélange additionnel comprend de 1 à 30 % en poids d'acide malique et de 0,5 à 10 % en poids d'acide tartrique.
  6. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que ce dernier est soluble dans l'eau.
  7. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que la concentration de cette solution est comprise dans un intervalle d'environ 10 g/l à environ 150 g/l.
  8. Mélange selon l'une quelconque des revendications précédentes, comprenant 89 à 96 % en poids d'acide citrique et 4 à 11 % en poids du mélange additionnel, consistant en 3 à 9 % en poids d'acide malique et 1 à 7 % en poids d'acide tartrique.
  9. Mélange selon l'une quelconque des revendications 1 à 7, comprenant 12 à 27 % en poids du mélange additionnel, comprenant 10 à 20 % en poids d'acide malique et 2 à 7 % en poids d'acide tartrique
  10. Mélange selon l'une quelconque des revendications précédentes, caractérisé en ce que celui-ci comporte 0,5 à 5 % en poids de tampon.
  11. Composition liquide comprenant un mélange selon l'une quelconque des revendications 1 à 10, ainsi qu'au moins un solvant.
  12. Composition liquide selon la revendication 11, caractérisée en ce que l'eau est choisie comme solvant.
  13. Utilisation d'un mélange selon l'une quelconque des revendications 1 à 10, respectivement d'une composition liquide selon l'une quelconque des revendications 11 ou 12 à l'élimination du calcaire, au nettoyage et/ou à la désinfection de surfaces de toute sorte.
EP09005788A 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection Active EP2098587B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007045210A DE102007045210A1 (de) 2007-09-21 2007-09-21 Mischung zum Entkalken, Reinigen und/oder Desinfizieren
EP08016320A EP2039750B1 (fr) 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP08016320A Division EP2039750B1 (fr) 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection
EP08016320.7 Division 2008-09-16

Publications (2)

Publication Number Publication Date
EP2098587A1 EP2098587A1 (fr) 2009-09-09
EP2098587B1 true EP2098587B1 (fr) 2011-07-20

Family

ID=40227614

Family Applications (2)

Application Number Title Priority Date Filing Date
EP08016320A Active EP2039750B1 (fr) 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection
EP09005788A Active EP2098587B1 (fr) 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP08016320A Active EP2039750B1 (fr) 2007-09-21 2008-09-16 Mélange de décalquage, de nettoyage et/ou de désinfection

Country Status (3)

Country Link
EP (2) EP2039750B1 (fr)
AT (2) ATE517169T1 (fr)
DE (2) DE102007045210A1 (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012014268B4 (de) * 2012-07-19 2014-02-20 Brauns-Heitmann Gmbh & Co. Kg Vorrichtung zur Reinigung und/oder Entkalkung zur Verwendung in Geschirrspül- oder Waschmaschinen
DE102013201883A1 (de) * 2013-02-05 2014-08-07 Urs Brodbeck Behandlungsflüssigkeit zur Reinigung eines Implantat-Teils
CN104902843B (zh) 2012-11-14 2020-01-14 赛福马有限责任公司 用于种植牙组件的处理构件以及处理系统
ITMI20130697A1 (it) * 2013-04-29 2014-10-30 Fem2 Ambiente S R L Prodotto detergente ecosostenibile a base di acido citrico
DE102014000212B4 (de) 2014-01-14 2018-03-22 Brauns-Heitmann Gmbh & Co. Kg Pulverförmige Zusammensetzung zur Reinigung von Geräten und Maschinen
DE102016108268A1 (de) * 2016-05-04 2017-11-09 Miele & Cie. Kg Verfahren und Vorrichtung zum Entkalken eines betriebsbereiten Kühlkreislaufs für eine betriebsbereite Vakuumpumpe für einen betriebsbereiten Sterilisator und Sterilisator
JP2024519516A (ja) 2021-04-23 2024-05-15 トーマス メネギニ 消毒剤及びその使用
DE102021002147A1 (de) 2021-04-23 2022-10-27 Thomas Meneghini Desinfektionsmittel und dessen Verwendung

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2207984B1 (fr) 1972-11-27 1975-11-21 Reckitt & Colmann Sa
WO1993009213A1 (fr) * 1991-11-07 1993-05-13 Gycor International Ltd. Agent de nettoyage et d'assainissement non toxique
DE4311713C1 (de) 1993-04-08 1994-05-05 Dorothee Roesling Verfahren zur Herstellung eines Reinigers für verkalkte senkrechte Flächen aus Glas, Plexiglas oder Fliesen
DE4430766A1 (de) * 1994-08-30 1996-03-07 Sbf Wasser Und Umwelt Zweignie Reiniger für wassertechnische Anlagen
FR2735788B1 (fr) * 1995-06-23 1997-08-22 Francais Prod Ind Cfpi Composition aqueuse detergente acide a taux reduit ou nul d'acide phosphorique et son utilisation dans l'industrie agro-alimentaire
DE19525604C2 (de) * 1995-07-16 1998-09-03 Yankee Polish Lueth Gmbh & Co Flüssiger Reiniger und dessen Verwendung
WO1998016192A1 (fr) * 1996-10-17 1998-04-23 Alterna, Inc. Composition germicide
EP1061123B2 (fr) * 1999-05-28 2007-02-14 Unilever Plc Procédé et compositions pour le nettoyage de lave-vaisselles
AU2001241632A1 (en) * 2000-02-28 2001-09-12 The Procter And Gamble Company Acidic antimicrobial compositions for treating food and food contact surfaces and methods of use thereof
KR100717699B1 (ko) 2001-11-09 2007-05-11 지로 사쿠라이 금속 제품용 세정제
GB2391810A (en) * 2002-08-14 2004-02-18 Reckitt Benckiser Inc Disinfectant with residual antimicrobial activity
US20060166846A1 (en) * 2002-08-19 2006-07-27 Ying-Hao Li Remover solution
DE10333905A1 (de) 2003-07-24 2005-02-24 Buck-Chemie Gmbh Festes Entkalkungsmittel
US20060118141A1 (en) * 2004-12-08 2006-06-08 The Procter & Gamble Company Method of cleaning a washing machine or a dishwasher

Also Published As

Publication number Publication date
DE502008001810D1 (de) 2010-12-30
ATE488566T1 (de) 2010-12-15
EP2098587A1 (fr) 2009-09-09
EP2039750A1 (fr) 2009-03-25
EP2039750B1 (fr) 2010-11-17
ATE517169T1 (de) 2011-08-15
DE102007045210A1 (de) 2009-04-02

Similar Documents

Publication Publication Date Title
EP2098587B1 (fr) Mélange de décalquage, de nettoyage et/ou de désinfection
DE2610338C2 (de) Reinigungsmittelmischung
DE69026967T2 (de) Saure, desinfizierende flüssige Allzweckreinigungsmittel
DE2362114C2 (de) Flüssiges schaumreguliertes Wasch- und Reinigungsmittel
DE2336449C3 (fr)
DE2321001A1 (de) Zusammensetzung mit kristallisationsimpfwirkung
DE2342461A1 (de) Reinigungsmittelzusammensetzungen
DE2358116A1 (de) Geschirrspuelmittelzusammensetzungen
DE2056556B2 (de) Reinigungsschaumzusammensetzung für Teppiche
DE2029598A1 (fr)
DE1080250B (de) Waschmittel
DE2336291A1 (de) Fluessiges wasch- und reinigungsmittel
DE3048641A1 (de) "tensidhaltiges gemisch zur reinigung harter oberflaechen"
DE69528642T2 (de) Saure Reinigungszusammensetzungen
WO1994007982A1 (fr) Agent liquide de nettoyage et d'entretien pour lave-vaisselle a usage menager
DE1617172B2 (de) Seif enzusam mensetzungen
DE2244310A1 (de) Detergenszusammensetzung
DE1519054B2 (de) Fluessiges scheuermittel
DE2638901A1 (de) Reinigungsmittelmischung
DE19854267A1 (de) Verkapseltes Reinigungsmittel
DE2060849A1 (de) Waschmittel zum gleichzeitigen Reinigen und Weichmachen
DE2225250A1 (de) Geschirrspülmittel
DE1628651C3 (de) Verfahren zum maschinellen Spülen von Geschirr
DE2201022A1 (de) Detergens
EP0523681A2 (fr) Composition détergente pour le lavage automatique de la vaisselle et méthode pour sa production

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20090427

AC Divisional application: reference to earlier application

Ref document number: 2039750

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AC Divisional application: reference to earlier application

Ref document number: 2039750

Country of ref document: EP

Kind code of ref document: P

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MT NL NO PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502008004297

Country of ref document: DE

Effective date: 20110915

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: ZIMMERLI, WAGNER & PARTNER AG

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20110720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111121

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111020

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111120

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

REG Reference to a national code

Ref country code: IE

Ref legal event code: FD4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111021

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

BERE Be: lapsed

Owner name: BRAUNS-HEITMANN G.M.B.H. & CO. KG

Effective date: 20110930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110930

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

26N No opposition filed

Effective date: 20120423

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110930

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502008004297

Country of ref document: DE

Effective date: 20120423

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111031

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110916

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20111020

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 502008004297

Country of ref document: DE

Representative=s name: GESKES PATENT- UND RECHTSANWAELTE, DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20110720

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: WAGNER PATENT AG, CH

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 9

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 10

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20210923

Year of fee payment: 14

Ref country code: FR

Payment date: 20210927

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20210923

Year of fee payment: 14

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20220916

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230528

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220930

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220930

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220916

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 20230915

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240911

Year of fee payment: 17