EP1730328A2 - Procede pour realiser des revetements en oxyde d'iridium - Google Patents
Procede pour realiser des revetements en oxyde d'iridiumInfo
- Publication number
- EP1730328A2 EP1730328A2 EP05735009A EP05735009A EP1730328A2 EP 1730328 A2 EP1730328 A2 EP 1730328A2 EP 05735009 A EP05735009 A EP 05735009A EP 05735009 A EP05735009 A EP 05735009A EP 1730328 A2 EP1730328 A2 EP 1730328A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- colloidal
- ircl
- iridium oxide
- aqueous
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 229910000457 iridium oxide Inorganic materials 0.000 title claims abstract description 25
- 238000000576 coating method Methods 0.000 title claims abstract description 22
- HTXDPTMKBJXEOW-UHFFFAOYSA-N dioxoiridium Chemical compound O=[Ir]=O HTXDPTMKBJXEOW-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 150000003839 salts Chemical class 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 10
- 239000002184 metal Substances 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 8
- 239000001301 oxygen Substances 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 230000001476 alcoholic effect Effects 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 239000003341 Bronsted base Substances 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 claims description 2
- 125000005595 acetylacetonate group Chemical group 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 239000003651 drinking water Substances 0.000 claims description 2
- 235000020188 drinking water Nutrition 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 150000004677 hydrates Chemical class 0.000 claims description 2
- 150000002503 iridium Chemical class 0.000 claims description 2
- 150000002823 nitrates Chemical class 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000002341 toxic gas Substances 0.000 abstract description 4
- VRIVJOXICYMTAG-IYEMJOQQSA-L iron(ii) gluconate Chemical compound [Fe+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O VRIVJOXICYMTAG-IYEMJOQQSA-L 0.000 abstract 3
- 239000010936 titanium Substances 0.000 description 20
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 15
- 229910052719 titanium Inorganic materials 0.000 description 15
- 239000011248 coating agent Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 238000010304 firing Methods 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 101100425947 Mus musculus Tnfrsf13b gene Proteins 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YJZATOSJMRIRIW-UHFFFAOYSA-N [Ir]=O Chemical class [Ir]=O YJZATOSJMRIRIW-UHFFFAOYSA-N 0.000 description 2
- 238000000502 dialysis Methods 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- DANYXEHCMQHDNX-UHFFFAOYSA-K trichloroiridium Chemical class Cl[Ir](Cl)Cl DANYXEHCMQHDNX-UHFFFAOYSA-K 0.000 description 2
- IYWJIYWFPADQAN-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;ruthenium Chemical compound [Ru].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O IYWJIYWFPADQAN-LNTINUHCSA-N 0.000 description 1
- NGCRLFIYVFOUMZ-UHFFFAOYSA-N 2,3-dichloroquinoxaline-6-carbonyl chloride Chemical compound N1=C(Cl)C(Cl)=NC2=CC(C(=O)Cl)=CC=C21 NGCRLFIYVFOUMZ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001514 alkali metal chloride Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 239000008131 herbal destillate Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- HLYTZTFNIRBLNA-LNTINUHCSA-K iridium(3+);(z)-4-oxopent-2-en-2-olate Chemical compound [Ir+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O HLYTZTFNIRBLNA-LNTINUHCSA-K 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
- C01G55/004—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1225—Deposition of multilayers of inorganic material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1229—Composition of the substrate
- C23C18/1241—Metallic substrates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/125—Process of deposition of the inorganic material
- C23C18/1283—Control of temperature, e.g. gradual temperature increase, modulation of temperature
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
Definitions
- the present invention relates to a process for the production of coatings from iridium oxide, a colloidal iridium oxide and a process for the production of colloidal iridium oxide.
- Metal oxide coated titanium electrodes are used in several electrochemical processes
- Iridium oxide coatings in particular have proven their worth for the electrocatalysis of oxygen evolution. Iridium mixed oxides such as lrO x -SnO 2 , lrRuO x , lrO x -Ta 2 O 5 and lrO x -Sb 2 O 5 -SnO 2 can also be used for the coating.
- Oxide-coated titanium electrodes are mostly produced by thermal decomposition of metal salts. Suitable metal salts are dissolved in water or alcohols and the electrodes are wetted with the solution. Then they are wetted
- Electrodes typically heated at temperatures between 400 and 700 ° C.
- the metal salts decompose under these conditions and form the corresponding metal oxides or mixed oxides. Electrodes manufactured in this way often have good mechanical stability, a satisfactory service life and show a low overvoltage for the development of oxygen.
- the electrodes are expensive due to the high iridium load (at least 7.5 g iridium per square meter of titanium).
- US Pat. No. 3,234,110 discloses that titanium sheets are coated with an ethanolic IrCl 4 solution and heated to 250-300 ° C. The process is repeated 4 times. The Ti / IrO x electrodes obtained can be used for the electrolysis of NaCl solutions become. No information is given about the life of the coating during the chlorine development.
- U.S. Patent 3,926,751 describes a method of preparing Ti / IrTaO x electrodes. Titanium sheets are immersed in a solution of IrCI 3 and TaCI 5 12 to 15 times and each heated at 450 to 550 ° C. The electrodes show a lifespan of about 6000 h during the development of oxygen in 10% sulfuric acid.
- U.S. Patents 5,294,317, 5,098,546, and 5,156,726 describe methods of making electrodes for oxygen evolution. Titanium electrodes, which are coated with mixed oxides, are produced by multiple, usually 10 times, immersion in butanolic solutions of H 2 lrCl 6 and tantalum ethoxide and subsequent firing at 500 ° C. A lifespan of more than 2000 hours is stated for the electrodes.
- the electrode coatings described above due to the thermal decomposition of metal salts have the disadvantage that toxic gases are released when the electrodes are burned, in particular Cl 2 and HCl.
- Titanium sheets are sandblasted, etched with 10% oxalic acid and immersed in an alcoholic ruthenium acetylacetonate / iridium acetylacetonate solution.
- the wetted electrodes are then pyrolyzed at 400-600 ° C.
- the wetting and pyrolysis process is repeated several times until a coating thickness of at least
- the object of the invention was to develop a method which does not have the disadvantages described above and which enables coatings to be made from iridium oxides using low-chloride compounds.
- a further object of the present invention was to coat titanium electrodes with low-chloride iridium oxides.
- the present invention relates to a method for producing coatings of iridium oxide, which comprises the following steps: a) applying colloidal lRO x , where x is a number from 1 to 2, to a surface, b) drying the coated surface and c ) Firing the surface at a temperature of 300 to 1000 ° C, wherein steps a to c can be repeated until the desired layer thickness is obtained.
- the method according to the invention becomes colloidal
- the colloidal iridium oxide used according to the invention can be obtained in any manner known from the prior art.
- a Brönsted base is added to an aqueous, alcoholic and / or aqueous-alcoholic solution of an Ir salt, optionally with stirring.
- Particularly suitable Bronsted bases are alkali metal hydroxides, in particular NaOH or KOH.
- a colloidal iridium oxide solution is formed.
- the aqueous, alcoholic and / or aqueous-alcoholic solution of an Ir salt optionally with stirring.
- Particularly suitable Bronsted bases are alkali metal hydroxides, in particular NaOH or KOH.
- a colloidal iridium oxide solution is formed.
- the a Brönsted base is added to an aqueous, alcoholic and / or aqueous-alcoholic solution of an Ir salt, optionally with stirring.
- Particularly suitable Bronsted bases are alkali metal hydroxides, in particular NaOH or KOH.
- Water-soluble Ir salts are preferably used to produce the colloidal iridium oxide.
- the water-soluble Ir salts can be selected from the halides, nitrates, sulfates, acetates, acetylacetonates, the hydrates of the above and the
- IrCl 3 xH 2 O, IrCl 4 xH 2 O, H 2 IrCl 6 xH 2 O, Na 2 IrCl 6 xH 2 O, K 2 IrCl 6 xH 2 O are particularly preferred.
- the method according to the invention can be used for coating any surface that is stable at the firing temperature. It works particularly well for coating metal and metal oxide surfaces, in particular Ti, TiO 2 , ZnO, SnO 2 , and glass.
- a particularly suitable area of application for the method according to the invention is the coating of Ti electrodes.
- Such electrodes are used for the development of oxygen and chlorine or for the oxidation of organic residues in drinking water.
- Colloidal iridium oxide as used in the process described above is new.
- Another object of the present invention is accordingly a colloidal
- Iridium oxide which has a particle size ⁇ 10 nm, in particular ⁇ 3 nm.
- the colloidal iridium oxide can be obtained by adjusting an aqueous, alcoholic or aqueous-alcoholic solution of an Ir salt with stirring to a pH> 11, preferably> _12 and then adding the resulting mixture over a period of 3 to 72 hours a temperature of 0 to 100 ° C is stirred.
- the iridium oxide obtained can be used for the production of coatings without further processing. If necessary, any undesirable soluble ingredients can be cleaned and removed by dialysis.
- iridium chlorides are converted into iridium oxide colloids by basic hydrolysis.
- the colloids could be produced as concentrated hydrosols without additional stabilizers.
- the chloride concentration of the solution can be greatly reduced by dialysis. Titanium substrates can be wetted with the processed colloidal solution. The burning of the wetted electrodes leads to closed lrO x films. No or only minimal amounts of toxic gases are released during the firing process, since chloride may be bound in the form of the salts when the alkali metal hydroxides are used as Bronsted base as alkali metal chloride. Examples
- Titanium sheets were sandblasted, transferred to deionized water and cleaned with ultrasound for 10 minutes. The sheets were then placed in hot (70-90 ° C.) 10% oxalic acid for 5 minutes and rinsed with deionized water before they were ultrasonically cleaned again.
- the pretreated titanium sheets were immersed in the dialyzed colloidal lrO x solution and dried at 80 ° C for 5 minutes before being baked at 600 ° C for 5 minutes. This coating process was repeated 5 times. The burning process was carried out over 1 hour.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Ceramic Engineering (AREA)
- Electrochemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Chemically Coating (AREA)
- Paints Or Removers (AREA)
Abstract
L'invention concerne un procédé pour réaliser des revêtements en oxyde d'iridium selon les opérations suivantes: a) appliquer sur une surface de l'IrOX colloïdal, x étant un nombre de 1 à 2, b) sécher la surface ainsi recouverte et c) cuire la surface à une température allant de 300 à 1000 °C, les opérations a) à c) pouvant être répétées jusqu'à obtention de l'épaisseur de couche voulue. L'utilisation d'IrOX colloïdal comme composant de départ pour réaliser des revêtements en IrOX permet d'éviter la formation de gaz toxiques pendant la cuisson.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004015633A DE102004015633A1 (de) | 2004-03-31 | 2004-03-31 | Verfahren zur Herstellung von Beschichtungen aus Iridiumoxiden |
PCT/DE2005/000399 WO2005095671A2 (fr) | 2004-03-31 | 2005-03-09 | Procede pour realiser des revetements en oxyde d'iridium |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1730328A2 true EP1730328A2 (fr) | 2006-12-13 |
Family
ID=34965127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05735009A Withdrawn EP1730328A2 (fr) | 2004-03-31 | 2005-03-09 | Procede pour realiser des revetements en oxyde d'iridium |
Country Status (5)
Country | Link |
---|---|
US (1) | US20080248195A1 (fr) |
EP (1) | EP1730328A2 (fr) |
JP (1) | JP5090901B2 (fr) |
DE (1) | DE102004015633A1 (fr) |
WO (1) | WO2005095671A2 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8022004B2 (en) | 2008-05-24 | 2011-09-20 | Freeport-Mcmoran Corporation | Multi-coated electrode and method of making |
US20160056409A1 (en) * | 2013-03-28 | 2016-02-25 | National Institute For Materials Science | Organic el element and method for manufacturing same |
US9790605B2 (en) | 2013-06-27 | 2017-10-17 | Yale University | Iridium complexes for electrocatalysis |
US10081650B2 (en) | 2013-07-03 | 2018-09-25 | Yale University | Metal oxide-organic hybrid materials for heterogeneous catalysis and methods of making and using thereof |
CN105803482A (zh) * | 2016-03-17 | 2016-07-27 | 同济大学 | 一种电解水制氢用电解池的集电极材料的改性方法及用途 |
KR101773564B1 (ko) | 2016-03-31 | 2017-08-31 | 유니테크 주식회사 | 전해반응기용 다공성 이리듐 전극의 제조방법 |
CN106854001B (zh) * | 2016-12-19 | 2018-06-19 | 有研亿金新材料有限公司 | 一种三氯化铱的控制还原制备方法 |
CN115872466B (zh) * | 2022-12-15 | 2023-09-08 | 苏州擎动动力科技有限公司 | 一种铱的氧化物及其制备方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0898318A2 (fr) * | 1997-08-01 | 1999-02-24 | Matsushita Electric Industrial Co., Ltd. | Procédé de préparation de poudre catalytique pour électrode |
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NL235848A (fr) * | 1959-02-06 | |||
US3711385A (en) * | 1970-09-25 | 1973-01-16 | Chemnor Corp | Electrode having platinum metal oxide coating thereon,and method of use thereof |
US3926751A (en) * | 1972-05-18 | 1975-12-16 | Electronor Corp | Method of electrowinning metals |
IT959730B (it) * | 1972-05-18 | 1973-11-10 | Oronzio De Nura Impianti Elett | Anodo per sviluppo di ossigeno |
US4579942A (en) * | 1984-09-26 | 1986-04-01 | Union Carbide Corporation | Polysaccharides, methods for preparing such polysaccharides and fluids utilizing such polysaccharides |
JPS62254817A (ja) * | 1986-04-30 | 1987-11-06 | Fuji Electric Co Ltd | 電気浸透式脱水機の陽極電極 |
US5156726A (en) * | 1987-03-24 | 1992-10-20 | Tdk Corporation | Oxygen-generating electrode and method for the preparation thereof |
JP2713788B2 (ja) * | 1989-12-22 | 1998-02-16 | ティーディーケイ株式会社 | 酸素発生用電極及びその製造方法 |
KR100196094B1 (ko) * | 1992-03-11 | 1999-06-15 | 사토 히로시 | 산소발생전극 |
JPH0688270A (ja) * | 1992-09-03 | 1994-03-29 | Permelec Electrode Ltd | 電解用電極とその製造方法 |
DE4313474C2 (de) * | 1993-04-24 | 1997-02-13 | Dornier Gmbh | Doppelschichtkondensator, der aus Doppelschichtkondensatoreinheiten zusammengesetzt ist und seine Verwendung als elektrochemischer Energiespeicher |
JPH06346267A (ja) * | 1993-06-14 | 1994-12-20 | Daiso Co Ltd | 酸素発生用電極及びその製法 |
US5851506A (en) * | 1994-04-21 | 1998-12-22 | The United States Of America As Represented By The Secretary Of The Army | Electrode materials from hydrous metal and/or hydrous mixed metal oxides and method of preparing the same |
FR2720542B1 (fr) * | 1994-05-30 | 1996-07-05 | Alsthom Cge Alcatel | Procédé de fabrication d'une électrode de supercondensateur. |
FR2782280B1 (fr) * | 1998-08-12 | 2000-09-22 | Inst Francais Du Petrole | Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques |
JP2003253254A (ja) * | 2002-02-28 | 2003-09-10 | Fuji Photo Film Co Ltd | 酸化物半導体超微粒子からなる発光層構造物 |
DE10211701A1 (de) * | 2002-03-16 | 2003-09-25 | Studiengesellschaft Kohle Mbh | Verfahren zur in situ Immobilisierung von wasserlöslichen nanodispergierten Metalloxid-Kolloiden |
-
2004
- 2004-03-31 DE DE102004015633A patent/DE102004015633A1/de not_active Ceased
-
2005
- 2005-03-09 EP EP05735009A patent/EP1730328A2/fr not_active Withdrawn
- 2005-03-09 WO PCT/DE2005/000399 patent/WO2005095671A2/fr active Application Filing
- 2005-03-09 US US10/599,434 patent/US20080248195A1/en not_active Abandoned
- 2005-03-09 JP JP2007505364A patent/JP5090901B2/ja not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0898318A2 (fr) * | 1997-08-01 | 1999-02-24 | Matsushita Electric Industrial Co., Ltd. | Procédé de préparation de poudre catalytique pour électrode |
Also Published As
Publication number | Publication date |
---|---|
JP5090901B2 (ja) | 2012-12-05 |
WO2005095671A2 (fr) | 2005-10-13 |
DE102004015633A1 (de) | 2005-10-20 |
WO2005095671A3 (fr) | 2006-05-11 |
JP2007530793A (ja) | 2007-11-01 |
US20080248195A1 (en) | 2008-10-09 |
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