EP1706354B1 - Procede de production de guanylureadinitramide - Google Patents

Procede de production de guanylureadinitramide Download PDF

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Publication number
EP1706354B1
EP1706354B1 EP05704733.4A EP05704733A EP1706354B1 EP 1706354 B1 EP1706354 B1 EP 1706354B1 EP 05704733 A EP05704733 A EP 05704733A EP 1706354 B1 EP1706354 B1 EP 1706354B1
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EP
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Prior art keywords
acid
guanylurea
reaction mixture
dinitramide
salt
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Application number
EP05704733.4A
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German (de)
English (en)
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EP1706354A1 (fr
Inventor
Carin VÖRDE
Henrik Skifs
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Forsvarets Materielverk
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Forsvarets Materielverk
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00—Nitrogen; Compounds thereof
    • C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B25/00—Compositions containing a nitrated organic compound
    • C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S149/00—Explosive and thermic compositions or charges
    • Y10S149/12—High energy fuel compounds
    • Y10S149/122—Containing N, without B, P or S

Definitions

  • the invention relates to production of salt of dinitramidic acid comprising nitration of an initial compound with a nitrating acid mixture to form dinitramidic acid in a reaction mixture.
  • EP 843 647 discloses a method in which an initial substance is nitrated with a nitrating acid mixture at a temperature of -25°C or below to form dinitramidic acid in the reaction mixture.
  • the initial substance is selected from a group consisting of NH 2 NO 2 , NH 4 NH 2 CO 2 .
  • NH 2 SO 3 H, NH(SO 3 H) 2 , N(SO 3 H) 3 reaction products of ammonia and sulphur trioxide, and salts thereof with metal cations, ammonium and organic cations.
  • the nitrating acid is selected from a group consisting of nitric acid/ sulphuric acid (HNO 3 /H 2 SO 4 ), nitric acid/oleum (HNO 3 /H 2 SO 4 /SO 3 ), nitric acid/sulphuric trioxide (HNO 3 /SO 3 ), nitric acid/perchloric acid (HNO 3 /HClO 4 ), nitric acid/phosphoric acid (HNO 3 /H 3 PO 4 ), nitric acid/diphosphorus pentoxide (HNO 3 /P 2 4 5 ), nitric acid/acetic acid, nitric acid/acetic anhydride, nitric acid/trifluoroacetic acid and nitric acid/trifluoroacetic anhydride.
  • the dinitramidic acid is not stable in the reaction mixture and, during reaction, the dinitramidic acid concentration rises to a maximum and then falls.
  • the reaction mixture is therefore neutralised with a base after a certain reaction time, and the dinitramide ion stabilised as a salt in solution.
  • the dinitramidic acid content is monitored in the course of reaction using UV spectroscopy so that the reaction can be interrupted when an optimal content has been achieved. Then the dinitramide salt can be recovered from the solution using an adsorption agent that adsorbs the dinitramide salt.
  • WO 99 46202, A1 discloses a method of producing organic dinitramide salts, for instance guanylurea dinitramide starting from ammonium dinitramide (ADN).
  • a concentrated aqueous solution of ADN is reacted with a concentrated aqueous solution of an organic salt, whose anion is OH - or CO 3 2- which is capable of taking up a proton from the ammonium ion of ADN and transferring said ion to ammonia.
  • the formed by-products, i.e. ammonia and possibly carbonic acid are driven off from the solution, as well as a certain amount of water to maintain a concentrated solution.
  • the organic dinitramide salt is then precipitated, for instance by cooling the solution.
  • Adding of guanylurea carbonate yields guanylurea dinitramide that is solved in a water solution.
  • WO9855428 ,A1 discloses methods for producing GUDN.
  • One method starts with a first mixture made of guanylurea sulfate that is dissolved in water.
  • the water is acidified with sulfuric acid to a pH of 5-7.
  • the acidification is done to make the guanylurea sulfate dissolve easier.
  • a second mixture is also prepared. This second mixture is made from water and a water-soluble dinitramide salt, for example AND or KDN.
  • the both mixtures are then mixed with each other and GUDN precipitates from the mixture.
  • GUDN Another method for producing of GUDN is also disclosed in WO9855428, A1 , This method starts with a nitrating acid containing sulfuric acid and nitric acid. Ammonium sulfamate is then added to the nitrating acid and dinitramidic acid is formed in the reaction mixture. The dinitramidic acid content is checked as it is not stable in the acid environment. When the dinitramide acid content is at maximum the process is interrupted by adding of a strong base that neutralises the reaction mixture. By the neutralisation nitrates are precipitated from the neutral reaction solution. After neutralisation a dinitramide salt is added. The dinitramide salt reacts with the guanylurea salt and forms GUDN. GUDN then precipitates from the neutral reaction mixture.
  • An object of the present invention is to provide an alternative method that allows the amount of waste to be reduced significantly and acid to be recovered for preparing new nitrating acid.
  • nitration can be performed in the same way, using the same substances and nitrating agent as disclosed in EP 843 647 .
  • the method is generally applicable to nitrations that are made using a nitrating acid mixture and results in dinitramidic acid in a reaction mixture containing spent acid.
  • a preferred nitrating agent according to the invention is a mixture of HNO 3 and H 2 SO 4 , and the potassium or ammonium salt of the sulfamic acid is preferred as the initial substance.
  • a characteristic feature of the invention is that the reaction mixture is not neutralised after a certain reaction time but instead a positive ion is added, which with the dinitramide ion forms an ion pair complex which precipitates in the acid reaction mixture.
  • the precipitate is separated from the mixture and the remaining spent acid can be reprocessed for recovery of acid.
  • the recovered dinitramide salt can be used as energetic material and/or be used as initial material for preparation of other dinitramide salts.
  • guanylurea ion is added to the reaction mixture.
  • the precipitate which is then obtained, guanylurea dinitramide [1] is an energetic material which is highly insensitive to impact and friction, has high thermal stability and storage stability. Isolating the dinitramide ion in the form of guanylurea dinitramide is therefore very advantageous from the viewpoint of handling, and the compound is well suited as initial material for preparation of other dinitramide salts.
  • Guanylurea dinitramide has previously been prepared from ammonium dinitramide and its properties are described in U.
  • the guanylurea ion can be added to the process in various ways.
  • a guanylurea salt can be added to the reaction mixture, for instance by the reaction mixture being mixed with an aqueous solution of the guanylurea salt.
  • Use is suitably made of a salt that corresponds to the used nitrating acid so as not to add new anions to the mixture, for instance a sulphate or nitrogen salt when the nitrating acid is HNO 3 /H 2 SO 4 .
  • Another method is to react the reaction mixture with guanylurea which is then protonated to the guanylurea ion by spent acid in the reaction mixture.
  • the reaction mixture can then be mixed, for example, with an aqueous solution of guanylurea.
  • a further method is to react cyanoguanidine with the reaction mixture, in which the guanylurea ion is formed in situ by the nitrile function being hydrolysed to amide function in the acidic environment.
  • the reaction mixture is suitably mixed with an aqueous slurry of cyanoguanidine. The temperature is raised when the acid is diluted by the aqueous slurry, which starts the hydrolysis.
  • the recovered precipitate can be used as starting material for preparation of other dinitramide salts.
  • the precipitate can be dissolved in a basic solution, preferably an alcohol solution, during heating.
  • a dinitramide salt with a cation from the used base can then be precipitated, for example, by cooling the solution.
  • KOH is used as the base.
  • Potassium dinitramide which is then obtained, can be used as oxidiser in various propellant and pyrotechnic charges and can in turn easily be converted to other dinitramide salts, for instance ammonium dinitramide ADN, by simple ion exchange processes. Such ion exchange processes are disclosed in EP 843 647 for example.
  • guanylurea is set free again and can be recirculated to the process for precipitation of the dinitramide ion from the reaction mixture as described above.
  • the spent acid that remains after separation of the precipitate from the reaction mixture can be reprocessed in prior-art manner by denitration and concentration for recovery of HNO 3 and H 2 SO 4 respectively or another used nitration-promoting strong acid.
  • the recovered acids can be used for preparation of a new nitrating acid mixture.
  • a batch of 12 kg ammonium sulfamate was nitrated in a batch reactor with nitrating acid consisting of fuming HNO 3 and 100% H 2 SO 4 .
  • the weight ratio of HNO 3 /H 2 SO 4 was 7:3 and the weight ratio of substrate/nitrating acid was about 1:5.
  • the temperature was kept between -40°C and -25°C during nitration that lasted for about 30 min.
  • the reaction mixture was poured into a mixture of 6 kg cyanoguanidine in about 60 l of water.
  • the aqueous mixture had a temperature of 15°C and at this temperature was a slurry of partially dissolved and partially suspended cyanoguanidine.
  • KDN potassium dinitramide
  • a solution containing about 30% by weight of water, 60% by weight of ethanol and 10% by weight of KOH was heated to about 50°C, and guanylurea dinitramide was dissolved in this solution during continued heating. After about 15 min, the solution contained 30% by weight of dissolved guanylurea dinitramide, and cooling of the solution was started. KDN began to crystallise and the mixture was further cooled to 15-20°C, after which crystallised KDN was filtered off and washed with ethanol. The mother liquor from crystallisation contained guanylurea and was kept for recovery and use in the process for precipitation of the dinitramide ion in nitration.
  • Example 1 was repeated, with the difference that the reaction mixture from nitration was poured into an aqueous solution of guanylurea nitrate.
  • the solution contained 15% by weight of guanylurea nitrate and had been cooled to about 12°C. The temperature rose when the reaction mixture was poured into the solution and the mixture was cooled to 25°C. Precipitation of guanylurea dinitramide started practically immediately, and the precipitate was filtered off and washed with water. The spent acid was passed to spent acid recovery.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (6)

  1. Procédé d'obtention d'un sel d'acide dinitramidique comprenant (1) une étape de nitration d'un composé initial avec un mélange sulfonitrique, ce mélange sulfonitrique renfermant de l'acide sulfurique et de l'acide nitrique pour former l'acide dinitramidique dans un mélange réactionnel acide, caractérisé en ce que (2) un ion guanylurée est ajouté au mélange de réaction acide pour former un sel d'acide dinitramidique, et (3) le sel de l'acide dinitamidique, guanylurée dinitramide est précipité du mélange réactionnel qui est acide lors de la précipitation.
  2. Procédé conforme à la revendication 1, caractérisé en ce que l'ion guanylurée est ajouté sous la forme de cyanoguanidine qui réagit par hydrolyse avec le mélange réactionnel acide pour former in situ de la guanylurée protonée.
  3. Procédé conforme à la revendication 2, caractérisé en ce que l'ion guanylurée est ajouté au mélange réactionnel acide sous la forme d'une boue aqueuse de cyanoguanidine.
  4. Procédé conforme à la revendication 1, caractérisé en ce que l'ion guanylurée est ajouté sous la forme de nitrate de guanylurée qui réagit par hydrolyse avec le mélange réactionnel acide pour former l'ion guanylurée suite à la formation de guanylurée protonée in situ.
  5. Procédé conforme à l'une quelconque des revendications 1 à 4, caractérisé en ce que le sel d'acide di_nitramidique précipité, guanyluréedinitramide est séparé du mélange réactionnel acide.
  6. Procédé conforme à l'une quelconque des revendications 3 et 4, caractérisé en ce que le composé initial qui est nitré est du sulfamate d'ammonium.
EP05704733.4A 2004-01-21 2005-01-21 Procede de production de guanylureadinitramide Active EP1706354B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0400117A SE526402C2 (sv) 2004-01-21 2004-01-21 Sätt att framställa salt av dinitramidsyra
PCT/SE2005/000060 WO2005070823A1 (fr) 2004-01-21 2005-01-21 Procede de production de sels d'acide dinitramidique

Publications (2)

Publication Number Publication Date
EP1706354A1 EP1706354A1 (fr) 2006-10-04
EP1706354B1 true EP1706354B1 (fr) 2016-07-27

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EP05704733.4A Active EP1706354B1 (fr) 2004-01-21 2005-01-21 Procede de production de guanylureadinitramide

Country Status (10)

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US (1) US7981393B2 (fr)
EP (1) EP1706354B1 (fr)
JP (1) JP4847875B2 (fr)
AU (1) AU2005206466B2 (fr)
BR (1) BRPI0506957A (fr)
CA (1) CA2552765C (fr)
IL (1) IL176722A (fr)
NO (1) NO341907B1 (fr)
SE (1) SE526402C2 (fr)
WO (1) WO2005070823A1 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8425703B1 (en) 2010-03-24 2013-04-23 The United States of Amierica as Represented by the Secretary of the Navy Insensitive munitions primers
CN102731345A (zh) * 2011-12-29 2012-10-17 湖北航天化学技术研究所 一种合成n-脒基脲二硝酰胺盐的方法
SE537747C2 (sv) 2014-01-30 2015-10-13 Totalförsvarets Forskningsinstitut Syntes av ammoniumdinitramid, ADN
SE541421C2 (en) * 2017-06-01 2019-09-24 Foi Grindsjoens Forskningscentrum Synthesis of Ammonium Dinitramide (ADN)
WO2020060451A1 (fr) 2018-09-17 2020-03-26 Totalförsvarets Forskningsinstitut Synthèse de dinitramide d'ammonium (adn)
CN109824549A (zh) * 2019-04-02 2019-05-31 西安近代化学研究所 一种n-脒基脲二硝酰胺盐的制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998055428A1 (fr) * 1997-05-21 1998-12-10 Försvarets Forskningsanstalt Nouveau compose chimique, explosif contenant ce compose et utilisation de ce compose dans des generateurs de gaz

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US2884437A (en) * 1951-09-04 1959-04-28 Roberts Elwyn Process for the production of guanidine and derivatives thereof
DE3243980A1 (de) * 1982-11-27 1984-05-30 Skw Trostberg Ag, 8223 Trostberg Verfahren zur herstellung von guanylharnstoffsulfamat
US5198204A (en) * 1990-06-18 1993-03-30 Sri International Method of forming dinitramide salts
US5254324A (en) * 1990-06-18 1993-10-19 Sri International Dinitramide salts and method of making same
US5316749A (en) * 1991-07-30 1994-05-31 Sri International Process for forming ammonium dinitramide salt by reaction between ammonia and a nitronium-containing compound
US5415852A (en) * 1992-01-29 1995-05-16 Sri International Process for forming a dinitramide salt or acid by reaction of a salt or free acid of an N(alkoxycarbonyl)N-nitroamide with a nitronium-containing compound followed by reaction of the intermediate product respectively with a base or alcohol
JP3719614B2 (ja) * 1995-05-26 2005-11-24 株式会社アイ・エイチ・アイ・エアロスペース Ａｄｎの合成法
SE516719C2 (sv) * 1995-08-08 2002-02-19 Totalfoersvarets Forskningsins Sätt att framställa dinitramidsyra och salter därav
SE511675C2 (sv) * 1998-03-10 1999-11-08 Foersvarets Forskningsanstalt Sätt att framställa dinitramidsalter
US6117255A (en) * 1998-07-28 2000-09-12 Trw Inc. Gas generating composition comprising guanylurea dinitramide
US6787119B2 (en) * 2002-03-13 2004-09-07 Council Of Scientific And Industrial Research Process for the preparation of dinitramidic acid and salts thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998055428A1 (fr) * 1997-05-21 1998-12-10 Försvarets Forskningsanstalt Nouveau compose chimique, explosif contenant ce compose et utilisation de ce compose dans des generateurs de gaz

Also Published As

Publication number Publication date
IL176722A (en) 2010-11-30
NO341907B1 (no) 2018-02-19
US20080226533A1 (en) 2008-09-18
AU2005206466A1 (en) 2005-08-04
JP2007519600A (ja) 2007-07-19
SE0400117L (sv) 2005-07-22
AU2005206466B2 (en) 2010-08-26
WO2005070823A1 (fr) 2005-08-04
SE0400117D0 (sv) 2004-01-21
CA2552765C (fr) 2012-11-27
US7981393B2 (en) 2011-07-19
IL176722A0 (en) 2008-03-20
EP1706354A1 (fr) 2006-10-04
JP4847875B2 (ja) 2011-12-28
BRPI0506957A (pt) 2007-06-26
NO20063241L (no) 2006-10-10
CA2552765A1 (fr) 2005-08-04
SE526402C2 (sv) 2005-09-06

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