EP1230977A3 - Catalyseur et procédé de préparation d'acétate de vinyle en présence du catalyseur à base de palladium, d'or et de certains métaux tiers - Google Patents

Catalyseur et procédé de préparation d'acétate de vinyle en présence du catalyseur à base de palladium, d'or et de certains métaux tiers Download PDF

Info

Publication number
EP1230977A3
EP1230977A3 EP02076572A EP02076572A EP1230977A3 EP 1230977 A3 EP1230977 A3 EP 1230977A3 EP 02076572 A EP02076572 A EP 02076572A EP 02076572 A EP02076572 A EP 02076572A EP 1230977 A3 EP1230977 A3 EP 1230977A3
Authority
EP
European Patent Office
Prior art keywords
catalyst
gold
palladium
metal
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP02076572A
Other languages
German (de)
English (en)
Other versions
EP1230977A2 (fr
Inventor
Ioan Nicolau
Phillip M. Colling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Celanese International Corp
Original Assignee
Celanese International Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese International Corp filed Critical Celanese International Corp
Publication of EP1230977A2 publication Critical patent/EP1230977A2/fr
Publication of EP1230977A3 publication Critical patent/EP1230977A3/fr
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/58—Platinum group metals with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EP02076572A 1997-10-30 1998-10-12 Catalyseur et procédé de préparation d'acétate de vinyle en présence du catalyseur à base de palladium, d'or et de certains métaux tiers Ceased EP1230977A3 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/960,888 US5859287A (en) 1997-10-30 1997-10-30 Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
US960888 1997-10-30
EP98954958A EP1044067B1 (fr) 1997-10-30 1998-10-12 Procede de production d'acetate de vinyle a l'aide d'un catalyseur comprenant du palladium, de l'or et un troisieme metal

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP98954958A Division EP1044067B1 (fr) 1997-10-30 1998-10-12 Procede de production d'acetate de vinyle a l'aide d'un catalyseur comprenant du palladium, de l'or et un troisieme metal

Publications (2)

Publication Number Publication Date
EP1230977A2 EP1230977A2 (fr) 2002-08-14
EP1230977A3 true EP1230977A3 (fr) 2002-08-21

Family

ID=25503765

Family Applications (2)

Application Number Title Priority Date Filing Date
EP02076572A Ceased EP1230977A3 (fr) 1997-10-30 1998-10-12 Catalyseur et procédé de préparation d'acétate de vinyle en présence du catalyseur à base de palladium, d'or et de certains métaux tiers
EP98954958A Expired - Lifetime EP1044067B1 (fr) 1997-10-30 1998-10-12 Procede de production d'acetate de vinyle a l'aide d'un catalyseur comprenant du palladium, de l'or et un troisieme metal

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP98954958A Expired - Lifetime EP1044067B1 (fr) 1997-10-30 1998-10-12 Procede de production d'acetate de vinyle a l'aide d'un catalyseur comprenant du palladium, de l'or et un troisieme metal

Country Status (30)

Country Link
US (1) US5859287A (fr)
EP (2) EP1230977A3 (fr)
JP (2) JP4906187B2 (fr)
KR (2) KR100579351B1 (fr)
CN (1) CN1104952C (fr)
AR (2) AR015979A1 (fr)
AT (1) ATE275000T1 (fr)
AU (1) AU734360B2 (fr)
BR (1) BR9813299B1 (fr)
CA (1) CA2306788C (fr)
CZ (1) CZ300008B6 (fr)
DE (1) DE69826031T2 (fr)
ES (1) ES2227889T3 (fr)
HU (1) HUP0004382A2 (fr)
ID (1) ID24489A (fr)
MY (1) MY127878A (fr)
NO (1) NO321475B1 (fr)
NZ (1) NZ504032A (fr)
PE (1) PE56399A1 (fr)
PL (2) PL209621B1 (fr)
RU (1) RU2216402C2 (fr)
SA (1) SA98190674B1 (fr)
SG (1) SG106071A1 (fr)
SK (1) SK5902000A3 (fr)
TR (2) TR200001181T2 (fr)
TW (1) TWI239949B (fr)
UA (1) UA66814C2 (fr)
WO (1) WO1999022863A2 (fr)
YU (1) YU49186B (fr)
ZA (1) ZA989630B (fr)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5859287A (en) * 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals
GB9817365D0 (en) * 1998-08-11 1998-10-07 Bp Chem Int Ltd Process for the production of vinyl acetate
US6358882B1 (en) 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
US6013834A (en) * 1999-03-04 2000-01-11 Celanese International Corporation Production of vinyl acetate in a catalytic reactor equipped with filter and distribution bed
US20030039659A1 (en) * 1999-09-24 2003-02-27 Mccormick Alison A. Self antigen vaccines for treating B cell lymphomas and other cancers
US6303537B1 (en) * 1999-11-17 2001-10-16 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication
TW201236755A (en) * 2003-12-19 2012-09-16 Celanese Int Corp Halide free precursors for catalysts
RU2422433C2 (ru) * 2004-12-20 2011-06-27 Селаниз Интернэшнл Корпорейшн Модифицированные материалы носителей для катализаторов
US8227369B2 (en) 2005-05-25 2012-07-24 Celanese International Corp. Layered composition and processes for preparing and using the composition
JP4964170B2 (ja) * 2007-04-09 2012-06-27 昭和電工株式会社 酢酸アルケニル製造用触媒の製造方法
DE102007047430A1 (de) * 2007-10-04 2009-04-09 Evonik Degussa Gmbh Katalysator
DE102008059342A1 (de) * 2008-11-30 2010-06-10 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
JP2011121048A (ja) 2009-12-09 2011-06-23 Rohm & Haas Co 固体触媒物質をブレンドし、管状構造物に装填する方法
US8507720B2 (en) * 2010-01-29 2013-08-13 Lyondell Chemical Technology, L.P. Titania-alumina supported palladium catalyst
US8273682B2 (en) * 2009-12-16 2012-09-25 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalyst
US8329611B2 (en) 2009-12-16 2012-12-11 Lyondell Chemical Technology, L,P. Titania-containing extrudate
US11384045B2 (en) * 2018-07-27 2022-07-12 Kuraray Co., Ltd. Method for producing 1,3-bisacyloxy-2-methylene propane
KR20200116730A (ko) 2019-04-02 2020-10-13 최미순 미량의 과산화수소수의 농도를 측정하는 장치 및 방법
JP6935039B1 (ja) * 2019-12-16 2021-09-15 昭和電工株式会社 酢酸アルケニル製造用固定床多管式反応器

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775342A (en) * 1968-02-01 1973-11-27 Bayer Ag Process for the production of catalysts for making vinyl esters
EP0723810A1 (fr) * 1995-01-23 1996-07-31 Degussa Aktiengesellschaft Catalyseur, procédé pour sa préparation et son utilisation pour la production du monomère d'acétate de vinyle
US5567839A (en) * 1993-11-19 1996-10-22 Bp Chemicals Limited Process for the preparation of vinyl acetate
WO1997038790A1 (fr) * 1996-04-16 1997-10-23 Hoechst Celanese Corporation Procede d'adjonction d'or en deux operations pour la confection d'un catalyseur d'acetate vinylique

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW213869B (fr) * 1991-06-21 1993-10-01 Hoechst Ag
DE4120492A1 (de) * 1991-06-21 1992-12-24 Hoechst Ag Verfahren zur herstellung von vinylacetat
US5332710A (en) * 1992-10-14 1994-07-26 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5314858A (en) * 1992-10-14 1994-05-24 Hoechst Celanese Corporation Vinyl acetate catalyst preparation method
US5466652A (en) * 1994-02-22 1995-11-14 The Standard Oil Co. Process for the preparation of vinyl acetate catalyst
IN188013B (fr) * 1995-05-23 2002-08-10 Hoechst Celanese Corp
US5859287A (en) * 1997-10-30 1999-01-12 Celanese International Corporation Process for preparing vinyl acetate utilizing a catalyst comprising palladium, gold, and any of certain third metals

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3775342A (en) * 1968-02-01 1973-11-27 Bayer Ag Process for the production of catalysts for making vinyl esters
US5567839A (en) * 1993-11-19 1996-10-22 Bp Chemicals Limited Process for the preparation of vinyl acetate
EP0723810A1 (fr) * 1995-01-23 1996-07-31 Degussa Aktiengesellschaft Catalyseur, procédé pour sa préparation et son utilisation pour la production du monomère d'acétate de vinyle
WO1997038790A1 (fr) * 1996-04-16 1997-10-23 Hoechst Celanese Corporation Procede d'adjonction d'or en deux operations pour la confection d'un catalyseur d'acetate vinylique

Also Published As

Publication number Publication date
AR015979A1 (es) 2001-05-30
PE56399A1 (es) 1999-06-11
CA2306788C (fr) 2007-05-08
TWI239949B (en) 2005-09-21
PL194845B1 (pl) 2007-07-31
ES2227889T3 (es) 2005-04-01
CN1104952C (zh) 2003-04-09
BR9813299B1 (pt) 2010-06-01
PL209621B1 (pl) 2011-09-30
HUP0004382A2 (en) 2001-03-28
CA2306788A1 (fr) 1999-05-14
CZ300008B6 (cs) 2009-01-14
JP2009108094A (ja) 2009-05-21
EP1044067B1 (fr) 2004-09-01
NO20002233D0 (no) 2000-04-28
NO20002233L (no) 2000-04-28
DE69826031D1 (de) 2004-10-07
AR019907A2 (es) 2002-03-20
JP2001521817A (ja) 2001-11-13
EP1230977A2 (fr) 2002-08-14
ATE275000T1 (de) 2004-09-15
JP4975721B2 (ja) 2012-07-11
PL340627A1 (en) 2001-02-12
DE69826031T2 (de) 2005-09-08
BR9813299A (pt) 2000-08-29
KR100577508B1 (ko) 2006-05-10
SK5902000A3 (en) 2000-10-09
ZA989630B (en) 2000-04-25
SA98190674B1 (ar) 2006-07-30
YU49186B (sh) 2004-07-15
AU734360B2 (en) 2001-06-14
US5859287A (en) 1999-01-12
CZ20001580A3 (cs) 2001-03-14
YU48098A (sh) 2000-03-21
KR20050088166A (ko) 2005-09-01
KR20010031648A (ko) 2001-04-16
TR200103086T2 (tr) 2002-07-22
UA66814C2 (uk) 2004-06-15
WO1999022863A3 (fr) 1999-08-05
TR200001181T2 (tr) 2001-03-21
WO1999022863A2 (fr) 1999-05-14
EP1044067A2 (fr) 2000-10-18
JP4906187B2 (ja) 2012-03-28
ID24489A (id) 2000-07-20
NZ504032A (en) 2002-10-25
CN1278192A (zh) 2000-12-27
MY127878A (en) 2006-12-29
KR100579351B1 (ko) 2006-05-12
NO321475B1 (no) 2006-05-15
SG106071A1 (en) 2004-09-30
RU2216402C2 (ru) 2003-11-20
AU1187499A (en) 1999-05-24

Similar Documents

Publication Publication Date Title
EP1230977A3 (fr) Catalyseur et procédé de préparation d'acétate de vinyle en présence du catalyseur à base de palladium, d'or et de certains métaux tiers
RU2132230C1 (ru) Способ получения катализатора для синтеза винилацетата и способ получения винилацетата
JP2002508240A5 (fr)
KR100575967B1 (ko) 칼륨 오레이트로 제조된, 금속 팔라듐 및 금을 포함하는비닐 아세테이트 제조용 촉매
NZ514433A (en) Catalysts for the gas-phase oxidation of ethylene and acetic acid to vinyl acetate and method for the production and use thereof
DE69729744D1 (de) Verbessertes verfahren für die herstellung von palladium - gold- trägerkatalysatoren
RU2000133240A (ru) Катализатор для винилацетата, содержащий металлические палладий и золото, полученный с ауратом калия
JP2001521817A5 (fr)
NZ505647A (en) Magnesium, calcium, barium or zirconium used as a fourth metal catalyst in the production of vinyl acetate
RU2000113735A (ru) Способ получения винилацетата с применением катализатора, включающего палладий, золото и любой из определенных третьих металлов
HUP0003486A2 (hu) Réztartalmú hordozóra felvitt palládium- és aranytartalmú katalizátor, vinil-acetát előállítására
NZ508273A (en) A method of preparing a catalyst for the production of vinyl acetate comprising metallic palladium, copper and gold deposited on a support
CA2388808A1 (fr) Catalyseur de production d'acetate de vinyle comportant du palladium et de l'or sous forme metallique et prepare par sonification
RU97121498A (ru) Способ получения катализатора для производства винилацетата и катализатор
MX9709066A (es) Catalizador para fabricacion de acetato de vinilo.
JP2003525723A5 (fr)
NO984809D0 (no) FremgangsmÕte for fremstilling av vinylacetat-katalysator
CA2292651A1 (fr) Procede de production d'acetate de vinyle mettant en oeuvre un catalyseur de palladium, d'or et de cuivre
JP2009090283A (ja) 触媒
ATE287398T1 (de) Verfahren zur selektiven herstellung von tetrahydrofuran durch hydrierung von maleinsäureanhydrid
CA2249187A1 (fr) Procede de preparation de catalyseur pour l'acetate de vinyle au moyen de borate de metal alcalin
US4394290A (en) Regeneration of supported catalysts containing palladium and/or platinum and tellurium
PT1112775E (pt) Catalisador para a preparacao de acetato alilico
JPH10330291A (ja) ヘテロ元素含有オキシド化合物の製造方法
TH26235A (th) ตัวเร่งปฏิกิริยาและกระบวนการสำหรับการเตรียมไวนิลแอซีเตต

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AC Divisional application: reference to earlier application

Ref document number: 1044067

Country of ref document: EP

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FR GB IE IT LI NL SE

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FR GB IE IT LI NL SE

RIC1 Information provided on ipc code assigned before grant

Free format text: 7B 01J 23/52 A, 7B 01J 23/66 B, 7C 07C 67/055 B, 7B 01J 23/58 B, 7B 01J 23/63 B

17P Request for examination filed

Effective date: 20030204

AKX Designation fees paid

Designated state(s): AT BE CH DE DK ES FR GB IE IT LI NL SE

17Q First examination report despatched

Effective date: 20030508

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED

18R Application refused

Effective date: 20060304