Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/18—Manufacture of films or sheets
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
  • A61F13/00—Bandages or dressings; Absorbent pads
  • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
  • A61F13/42—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators with wetness indicator or alarm
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
  • A61F13/00—Bandages or dressings; Absorbent pads
  • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
  • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
  • A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
  • A61F13/51456—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by its properties
  • A61F13/51458—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by its properties being air-pervious or breathable
  • A61F13/51462—Backsheet, i.e. the impermeable cover or layer furthest from the skin characterised by its properties being air-pervious or breathable being defined by a value or parameter
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
  • A61F13/00—Bandages or dressings; Absorbent pads
  • A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
  • A61F13/51—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
  • A61F13/514—Backsheet, i.e. the impermeable cover or layer furthest from the skin
  • A61F13/51496—Backsheet, i.e. the impermeable cover or layer furthest from the skin having visual effects
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
  • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
  • C08J2323/04—Homopolymers or copolymers of ethene
  • C08J2323/08—Copolymers of ethene
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/249921—Web or sheet containing structurally defined element or component
  • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
  • Y10T428/249955—Void-containing component partially impregnated with adjacent component
  • Y10T428/249956—Void-containing component is inorganic
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/249921—Web or sheet containing structurally defined element or component
  • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
  • Y10T428/249967—Inorganic matrix in void-containing component
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/249921—Web or sheet containing structurally defined element or component
  • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
  • Y10T428/249978—Voids specified as micro
  • Y10T428/24998—Composite has more than two layers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/249921—Web or sheet containing structurally defined element or component
  • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
  • Y10T428/249987—With nonvoid component of specified composition
  • Y10T428/249991—Synthetic resin or natural rubbers
  • Y10T428/249992—Linear or thermoplastic
  • Y10T428/249993—Hydrocarbon polymer

Definitions

• the present invention relates to a novel porous polyolefin film and to a process for producing same. More particularly, the present invention relates to a porous polyolefin film suitable for use in various medical or sanitary supplies, in particular, such as back-sheets for disposable diapers, which is excellent in vapor-permeability and liquid-imparmeability, good see-through property by virtue of light transmission, and high tear strength, a process for producing the film and an intended use thereof.
• porous polyolefin films having a number of small holes resulting from an inorganic filler are produced by stretching an unstretched film of polyolefin incorporated with the inorganic filler.
• porous polyolefin films are, however, opaque throughout the films and poor in see-through property due to low light transmission so that it is hard to confirm the color and the state of an article existing on the opposite surface of the film.
• porous polyolefin film provided with partial see-through property by subjecting a porous polyolefin film to an embossing treatment and fusing the resin in microporous portions to collapse voids (Japanese Laid-open Patent Appln. No. Hei. 5-168660), etc.
• porous films mechanically formed portions higher in light transmission exist locally, through which portions it is at any rate possible to observe the opposite surface.
• porous polyolefin films of a non-homogeneous series obtained according to the embossing method which contain non-porous portions or low porous portions and porous portions in mixed state, are poor in see-through property in the porous portions so that degradation of the moisture permeability is obliged to take place for sufficiently enhancing the see-through property of the whole film.
• the light transmission of a porous polyolefin film obtained according to embossing was generally at most about 60%.
• a porous polyolefin film possessing coarse embossed portions varies the ratio of the non-(or lower-)porous portions to the porous portions, thus forming difference in the physical properties of the film, such as moisture-permeability.
• porous polyolefin film is used as a back-sheet or the like, on the other hand, a high degree of tear strength is also required lest the sheet should be broken on the use.
• the porous polyolefin film wherein the nonhomogeneous portions having been formed by the aforesaid embossing still leaves room for improvement in this point.
• a porous polyolefin film which comprises a polyolefin containing an inorganic filler and a wax of polyolefin series, the film being provided with micropores originated from the inorganic filler, a water vapor transmission rate of at least 1000 g/m 2 ⁇ 24 hours, a light transmission of at least 65%, and a tear strength of at least 0.6 N, and the film having a uniform moisture-permeability throughout.
• a process for producing a porous polyolefin film which comprises stretching an unstretched polyolefin film having a resin composition of 100 parts by weight of polyolefin, 50-150 parts by weight of an inorganic filler having a 50% median diameter of at least 2 ⁇ m but less than 7 ⁇ m measured according to the light-scattering method, and 2-20 parts by weight of a wax of polyolefin series in at least uniaxial direction at an area magnification of 1.1-1.5 times,
• a composite porous polyolefin film composed of the porous polyolefin film and a non-woven fabric of polyolefin series as well as a back-sheet for disposable diapers which comprises the above porous polyolefin film or the above composite porous polyolefin film.
• the porous polyolefin film of the present invention comprises polyolefin containing an inorganic filler and a wax of polyolefin series.
• any of the known inorganic fillers used heretofore for producing porous polyolefin film may be employed without any limitation.
• calcium carbonate is especially preferred.
• the inorganic filler functions synergestically with the wax to increase light transmission due to micropores based thereon and to improve see-through property so that the filler having a 50% median diameter measured according to the light-scattering method (referred to hereinafter simply as "the median diameter") of at least 2 ⁇ m but less than 7 ⁇ m, especially 2.5-5.5 ⁇ m is preferably used.
• the median diameter measured according to the light-scattering method
• polystyrene resin No limitation exists in the polyolefin in the porous polyolefin film of the present invention.
• illustrative of the representative one are homopolymers of ⁇ -olefins such as polyethylene, polypropylene, polybutene-1, and poly(methylpentene), copolymers of ⁇ -olefins with other copolymerizable monomers, and a mixture of these polymers.
• monomers copolymerizable with the ⁇ -olefin and known monomers can be employed, but ⁇ -olefins having 2-8 carbon atoms are generally preferable.
• polyethylene, polypropylene, propyleneethylene copolymer, and a linear low density polyethylene produced according to the intermediate or low pressure method are preferable.
• a linear low density polyethylene preferable as it affords good flexibility.
• the aforesaid polyolefin constitutes a skeleton of the porous polyolefin film and so preferably has a melt flow rate of 1-30 g/10 minutes, preferably 0.5-10 g/10 minutes for fully exhibiting the strength such as tear strength mentioned hereinafter.
• the wax of polyolefin series is important, as it functions synergestically together with the inorganic filler added to impart a high degree of light transmission to the porous polyolefin film. Further, the wax of polyolefin series is preferable in the point of workability such as extrusion or of non-odor.
• the wax of polyolefin is a general term for low molecular weight polyolefins which are solid at normal temperature.
• low molecular weight polyethylene and low molecular weight polypropylene are representative.
• the number average molecular weight is preferably 900-10000, in particular 1500-6000.
• the low molecular weight polypropylene (polypropylene wax) its number average molecular weight is preferably 1000-15000, in particular 3000-10000.
• polarized waxes such as an oxide type wax or a maleic acid-modified wax can be used without any problem.
• waxes of polyolefin a low molecular weight polyethylene capable of enhancing see-through property is particularly preferred.
• the porous polyolefin film of the present invention is characterized by containing the inorganic filler and the wax of polyolefin series.
• a conventional porous polyolefin film is obtained by stretching an unstretched film of polyolefin containing the above inorganic filler alone.
• the film thus obtained is uniform and possesses a high moisture permeability but is less than 50% in light transmission and is extremely poor in see-through property.
• the film becomes desirably thin for enhancing light transmission.
• the thickness of the film has to be not more than 10 ⁇ m.
• tear strength of the film is considerably reduced to about 0.2 N.
• porous polyolefin film of the present invention employing the wax of polyolefin series together with the inorganic filler can achieve extremely high degree of moisture permeability, light transmission and tear strength and need not be subjected separately to an embossing treatment so that uniform moisture permeability can be imparted to all over the film.
• the porous polyolefin film of the present invention possesses a water vapor transmission rate of at least 1000 g/m 2 ⁇ 24 hrs, in particular 1100-2000 g/m 2 ⁇ 24 hrs.
• the moisture permeability is shown as an average value of the individual measured values obtained by sampling 5 circular portions each having a diameter of 40 mm arbitrarily from the film, measuring for each circular portion a water vapor permeated amount in the period of 24 hours under the condition that a temperature is 40°C and a humidity is 60% and converting the measured amount into a moisture permeability in terms of m 2 .
• porous polyolefin film of the present invention possessing such an excellent moisture permeability exhibits a high function in prevention of a stuffy condition when used as a back-sheet for disposable diapers.
• porous film of the present invention possessing uniform moisture permeability throughout the film stably exhibits the aforesaid function in any of the portions of the film.
• scattering of the aforesaid uniform moisture permeability in the porous polyolefin film of the present invention is within the range of ⁇ 20%, in particular ⁇ 15%.
• the scattering of the moisture permeability is shown in terms of percentage by sampling 5 circular portions of 40 mm in diameter from the film, measuring moisture permeability of the individual portions and dividing the individual measured values by an average value thereof.
• a porous polyolefin film obtained by subjecting the porous film to embossing treatment or subjecting the film to partial stretching to enhance light transmission contains non-(or lower-)porous portions and porous portions in mixed state so that the proportion of both portions is different according to the sampled portions to make it difficult to obtain such uniform moisture permeability.
• the porous film of the present invention possesses an outstanding see-through property shown by light transmission of at least 65%, in particular 70-80%, while maintaining uniform and extremely high moisture permeability.
• the porous polyolefin film of the present invention is significant in strength; its tear strength is at least 0.6 N, in particular at least 1 N, so that stable characteristics can be exhibited in handling of the film alone or use as the back-sheet.
• tear strength is at least 0.6 N, in particular at least 1 N, so that stable characteristics can be exhibited in handling of the film alone or use as the back-sheet.
• difficulty in tear of the film is further enhanced even in case immoderate force is applied at the time of wearing or detaching.
• the porous polyolefin film of the present invention no particular limitation exists in thickness of the film. In relation with the light transmission and tear strength, etc., however, the thickness is preferably 20-50 ⁇ m, more preferably 20-40 ⁇ m. Further, the porous polyolefin film of the present invention usually has a hydraulic pressure resistance of at least 15 KPa, preferably 25-200 KPa.
• an inorganic filler having a median diameter of at least 2 ⁇ m but less than 7 ⁇ m, preferably at least 2.5-5.5 ⁇ m.
• the median diameter is not more than 2 ⁇ m, the light transmission of the resultant porous polyolefin film tends to deteriorate even if the wax is jointly used. In case the median diameter is at least 7 ⁇ m, the light transmission is enhanced but the film tends to be torn and the tear strength tends to deteriorate due to increase in granular diameter of the inorganic filler.
• the inorganic filler preferably has such a granule distribution that at least 95% by weight, preferably at least 99% by weight of the whole filler has preferably a granular diameter of 0.01255-25 ⁇ m, more preferably 0.05-20 ⁇ m.
• the inorganic filler is 50-150 parts by weight, preferably 80-120 parts by weight for 100 parts by weight of the polyolefin. If the proportion of the inorganic filler is less than 50 parts by weight, the formation of continuously communicated holes will become difficult to make moisture permeability poor. If the proportion of the inorganic filler is more than 150 parts by weight, a number of very fine holes will be generated to make it difficult to obtain a porous film having the aforesaid high degree of light transmission.
• the proportion of the wax of polyolefin series is 2-20 parts by weight per 100 parts by weight of the polyolefin resin. Especially, in case the wax is 3-10 parts by weight, the characteristics of the porous polyolefin film can sufficiently be exhibited.
• the film will be stretched evenly, thus resulting in promotion of whitening throughout the film so that the resultant porous polyolefin film tends to become poor in light transmission.
• the amount of the wax added is more than 20 parts by weight, not only unevenness in whitening will tend to become coarse adversely, but also molding stability will tend to become poor.
• the polyolefin may conveniently be incorporated with other thermoplastic resins, pigments, stabilizers, surfactants, plasticizers, oils, and the like additives at need so far as the object of the present invention be not damaged.
• the porous polyolefin film of the present invention can be obtained by stretching an unstretched film having a composition of the polyolefin, the inorganic filler and the wax of polyolefin series in at least uniaxial direction.
• the aforesaid stretching is preferably biaxial stretching.
• Representative is a method wherein the unstretched film is molded, for example, by using a T-die or a circular-die, uniaxially stretched according to a roll-stretching method and then successively biaxially stretched by way of Tenter stretching machine, an air-inflation method, a mandrel stretching method, etc.
• a method wherein the unstretched film is tubularly molded by way of an air-inflation method, the film is stretched in a first uniaxial direction (lengthwise) by way of a roll stretching machine and then the film is stretched in a second uniaxial direction (lateral) by way of a mandrel stretching method is especially preferably adopted in the point that this method is better in balance of film orientation at the time of extrusion of the film and is excellent in tear strength after the biaxial stretching, as compared with the T-die biaxial stretching method.
• a stretching ratio in the aforesaid stretching is desirably as small as possible for obtaining a film higher in light transmission so far as the moisture permeation be not damaged.
• a range of 1.1-1.5 times, preferably 1.2-1.4 times in terms of area magnification is preferable to obtain a porous polyolefin film having a high degree of light transmission.
• the area magnification is smaller than 1.1 times, the formation of continuously communicated holes is not sufficient to make it difficult to obtain a high moisture permeability.
• the area magnification is larger than 1.5 times, a number of voids are formed so that relatively transparent portions in the film is decreased to make it difficult to obtain sufficient light transmission.
• the stretching is preferably carried out a temperature lower than the melting point of the resin component, above all, at a temperature 10°C lower than the melting point. Subsequent to the stretching step, a thermal treatment or a surface treatment such as corona discharge, etc. may be carried out.
• the porous polyolefin film of the present invention is excellent in light transmission and moisture permeability
• the film can be laminated with a non-woven fabric of polyolefin series to form a composite porous polyolefin film excellent in light transmission and moisture permeation.
• this composite porous polyolefin film can also be used for sanitary supplies such as back-sheet for disposable diapers as in the porous polyolefin film of the present invention and for other materials in medical and constructive fields.
• the film exhibits superior properties such that the internal state can visibly be confirmed, both leak-preventing property and moisture permeation are good, and the film shows textile-like structure.
• the film is preferably in the form of a composite porous polyolefin film having a light transmission of at least 65% and a water vapor transmisson rate of at least 1000 g/m 2 ⁇ 24 hours.
• the starting porous polyolefin film of the present invention has a light transmission of at least 70%.
• the starting porous polyolefin film of the present invention has a water vapor transmission rate of at least 1100 g/m 2 ⁇ 24 hours.
• a material or structure for the known non-woven fabric of polyolefin series can be used without any special limitation for the material and structure of non-woven fabric of polyolefin series to be laminated with the porous polyolefin film of the present invention for making a composite porous polyolefin film.
• polyethylene, polypropylene, ethylene-propylene copolymer, etc. are preferable, and these polyolefins may be used singly or as composition.
• the aforesaid non-woven fabric of polyolefin series preferably has a light transmission of at least 85% in order to raise a light transmission of a composite porous polyolefin film, which has been made by laminating the porous polyolefin film with the non-woven fabric of polyolefin series, to at least 65%.
• the basis weight of the non-woven fabric of polyolefin series is defined as not more than 25 g/m 2 , preferably not more than 20 g/m 2 . If the basis weight exceeds 25 g/m 2 , a space clogged by fibers is increased to make it difficult to attain the above light transmission. On the other hand, if the basis weight is at least 10 g/m 2 , preferably at least 12 g/m 2 , it is preferable to impart cotton-like feeling to the composite porous polyolefin film.
• the fiber diameter of the non-woven fabric of polyolefin series is 10-50 ⁇ m, preferably 15-30 ⁇ m. In case the fiber diameter is less than 10 ⁇ m, the light transmission will tend to deteriorate. If the value is larger than 50 ⁇ m, the resultant composite porous polyolefin film will be damaged in flexibility.
• a known lamination method wherein the porous polyolefin film is not damaged in air-permeability is preferably adopted for a method for laminating the porous polyolefin film with the non-woven fabric of polyolefin series for constituting the composite porous polyolefin film.
• lamination for making composite materials can be effected according to the method for dry lamination and hot melt lamination wherein a binder is used or the method for thermal lamination wherein no binder is used.
• a method wherein a binder is sprayed or applied spirally at random and then binding is effected as in hot melt binding can preferably be used in addition to a regular intermittent binding such as a dot-like, lattice-like or linear binding.
• a binder for binding the non-woven fabric of polyolefin series with the porous polyolefin film a binder of an urethane-type, a rubber-type, an epoxy-type or a vinyl acetate-type is used for the dry lamination method, while a binder of an olefin-type, an ethylene-vinyl acetate-type and a synthetic rubber type is used for the hot melt lamination method.
• the melting point of a resin of the non-woven fabric is preferably similar to or lower than the melting point of a resin constituting the porous polyolefin film.
• the sheath fiber constituting the non-woven fabric is a low density polyethylene while the core fiber is polypropylene, or a composite fiber of a low density polyethylene and polypropylene in the side-by-side form is applied to the porous polyolefin film constituting a low density polyethylene.
• the binding area is as small as possible.
• at least a certain constant area is necessary for binding in consideration of the total tensile strength and binding strength, so that it is general that fusing and binding is effected within a area range of about 5-30%.
• the measurement was carried out with a measuring device using the light scattering method manufactured by Shimazu Seisakusho, SALD-2000.
• Transparency was measured by using a Haze computer HGM-2DP manufactured by Suga Shikenki in accordance with JIS K7105 and shown as light transmission.
• the tear strength of the film in MD direction was measured in accordance with JIS K 7128 A.
• this pellet was molded into a tubular film of 400 mm in diameter at a cylinder temperature of 175°C, a die temperature of 170°C and a take-up speed of 10 m/min., stretched in longitudinal direction by the aid of a roll stretcher at normal temperature, and successively stretched in lateral direction by the aid of a mandrel stretcher at a temperature of 80°C whereby each porous film was obtained.
• Example 1 25 70 1200 ⁇ 20% 150 1.2
• Example 2 22 71 1500 ⁇ 15% 180 1.4
• Example 3 21 70 1300 ⁇ 15% 160 1.2
• Example 4 25 70 1500 ⁇ 15% 200 1.1
• Example 5 22 70 1550 ⁇ 15% 170 1.5
• Example 6 24 70 1600 ⁇ 15% 150 1.6
• Example 7 28 69 1650 ⁇ 20% 130 1.3
• Example 8 25 70 1300 ⁇ 15% 180 1.5
• Example 9 25 66 1700 ⁇ 20% 160 1.3
• Example 10 45 68 1000 ⁇ 20% 200 2.0
• Example 11 27 70 1800 ⁇ 15% 140 1.7
• Example 12 27 72 1500 ⁇ 15% 170 1.4
• Example 13 22 67 1200 ⁇ 20% 140 1.3
• Comparative 26 66 600 ⁇ 20% 150 1.4
• Example 1 Comparative 23 63 1000 ⁇ 20% 130 1.4
• Example 2 Referential 20 50 980 ⁇ 20% 130 0.3
• Example 3 25 70 1300 ⁇ 15% 160
• Example 12 In the same proportion and stretching ratio as illustrated in Example 12, a porous polyolefin film was obtained in the same manner as illustrated in the foregoing Examples.
• This porous polyolefin film had a light transmission of 75%, a moisture permeability of 1500 g/m 2 ⁇ 24 hours, a scattering of the water vapor transmission rate of ⁇ 15%, a hydraulic pressure resistance of 120 kPa, and a tear strength of 1.2 N.
• a non-woven fabric of polypropylene having a basis weight of 15 g/m 2 and a of 15 g/m 2 and a light transmission of 90.5% and the porous polyolefin film were sprayed with a hot melt binder of EVA series in an applying amount of 2 g/m 2 and bound to obtain a composite porous polyolefin film having a textile feeling complexed with the non-woven fabric.
• the resultant composite porous polyolefin film had a light transmission of 67%, a moisture permeation of 1400 g/m 2 ⁇ 24 hrs and a hydraulic pressure resistance of 120 kPa.
• the aforesaid composite porous polyolefin film shows a high degree of light transmission even in combination with the non-woven fabric and suitable, for example, as a back-sheet for diapers of textile feeling externally see-through.
• the porous polyolefin film of the present invention having a uniform moisture permeability exhibits extremely high moisture permeability and light transmission in combination without being subjected to an embossing treatment, and is a film having a sufficiently high tear strength.
• the resultant film excels in moisture permeability and light transmission and has a textile touch and feeling.
• the porous polyolefin film shows good wear feeling due to high moisture permeability.
• the film has the most important properties in combination; good in see-through property of the contents and strong against tear at the time of wearing and detaching, thus showing extremely high usefulness.
• the porous polyolefin film of the present invention is not limited to the use for the back-sheet for diapers but is used for a variety of applications utilizing the aforesaid characteristic properties, for example, constructive goods, medical or sanitary goods other than diapers, packaging materials necessitating air permeability, etc.

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• Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Epidemiology (AREA)
• Biomedical Technology (AREA)
• Heart & Thoracic Surgery (AREA)
• Vascular Medicine (AREA)
• Life Sciences & Earth Sciences (AREA)
• Animal Behavior & Ethology (AREA)
• General Health & Medical Sciences (AREA)
• Public Health (AREA)
• Veterinary Medicine (AREA)
• Chemical & Material Sciences (AREA)
• Manufacturing & Machinery (AREA)
• Dermatology (AREA)
• Materials Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
• Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
• Laminated Bodies (AREA)
• Absorbent Articles And Supports Therefor (AREA)
• Orthopedics, Nursing, And Contraception (AREA)

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Citations (6)

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• 2000
  • 2000-07-11 JP JP2000209325A patent/JP2001233982A/ja active Pending
  • 2000-12-13 EP EP00981668A patent/EP1152025A4/fr not_active Withdrawn
  • 2000-12-13 US US09/926,006 patent/US6767622B2/en not_active Expired - Fee Related
  • 2000-12-13 WO PCT/JP2000/008794 patent/WO2001044353A1/fr not_active Application Discontinuation

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