EP1111124B1 - Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage - Google Patents

Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage Download PDF

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Publication number
EP1111124B1
EP1111124B1 EP00127409A EP00127409A EP1111124B1 EP 1111124 B1 EP1111124 B1 EP 1111124B1 EP 00127409 A EP00127409 A EP 00127409A EP 00127409 A EP00127409 A EP 00127409A EP 1111124 B1 EP1111124 B1 EP 1111124B1
Authority
EP
European Patent Office
Prior art keywords
vat
black
dyed
green
spun
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00127409A
Other languages
German (de)
English (en)
Other versions
EP1111124A1 (fr
Inventor
Horst Roland Dipl.-Ing. Mach
Guido Dipl.-Ing. Krabbe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dystar Textilfarben GmbH and Co Deutschland KG
Original Assignee
Dystar Textilfarben GmbH and Co Deutschland KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dystar Textilfarben GmbH and Co Deutschland KG filed Critical Dystar Textilfarben GmbH and Co Deutschland KG
Publication of EP1111124A1 publication Critical patent/EP1111124A1/fr
Application granted granted Critical
Publication of EP1111124B1 publication Critical patent/EP1111124B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/06—Dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8247—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and vat, sulfur or indigo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs

Definitions

  • the present invention relates to the use of textile spun-dyed fiber material of synthetic fibers or mixtures of cellulose and synthetic fibers, in which the synthetic fiber portion is colored for the production of camouflage articles.
  • Textile materials for the military sector are usually made of synthetic fibers, such as polyester or polyamide, or of mixtures of cellulose and synthetic fibers.
  • synthetic fibers such as polyester or polyamide
  • a remission behavior is sought mainly in the shades of light green, gray-green, olive and dark green in the short-wave infrared range, which corresponds to that of the natural leaf green, i. of chlorophyll.
  • a high level of authenticity in particular as regards light, chlorine, friction, washing and Scheuerechtheit required.
  • the present invention thus relates to the use of textile, spun-dyed fiber material of synthetic fibers for the production of military camouflage articles, wherein camouflage patterns are printed in a conventional manner.
  • the present invention further relates to the use of textile, spun-dyed fiber material from mixtures of cellulose and synthetic fibers for the production of military Tarn
  • the cellulose content is dyed or printed with camouflage patterns.
  • the textile, spun-dyed fiber materials used according to the invention are in particular as a woven fabric and may consist of pure synthetic fibers, in particular of polyester or polyamide. Preferably, however, they are mixed fabrics with cellulose, wherein cellulose-polyester blended fabrics are particularly preferred.
  • the synthetic fiber content of the textile, spun-dyed fiber materials used according to the invention is usually colored in a medium gray, green or olive shade by spin dyeing.
  • all dyes which are suitable for spin dyeing and which have the required remission course in the IR range which is similar to chlorophyll can be used. These dyes can be used alone or mixed with each other. In order to achieve the desired base shades, they can further be combined with other colorants which can be used in spin dyeing. However, it is always important to ensure that the IR remission behavior of the final product does not interfere or adversely affect the typical chlorophyll curve. If this condition is met, the proportions of the individual dyes or colorants used are not critical and are determined only by the desired basic color.
  • Preferred dyes which can be used for the spin-dyeing of the synthetic fiber fraction are, for example, CI Solvent Blue 122, CI Solvent Blue 132, CI Solvent Blue 104, CI Solvent Blue 45, CI Solvent Yellow 83, CI Solvent Yellow 147, CI Solvent Brown 53, CI Disperse Violet 57 and CI Pigment Blue 29.
  • the process of spin dyeing is known as such.
  • the spinning solution or the spin melt pigment or soluble dyes are added, which remain in the precipitate in the fiber and thus dye them.
  • the colorants are preferably used in the form of so-called masterbatches, which may already contain any required auxiliary agents. Details on spin dyeing are Römpp Chemielexikon, 9.Avemlage, 1992, Volume 5, page 4247 and in particular the cited therein See literature.
  • Textile, spun-dyed fiber material used according to the invention which consists exclusively of synthetic fibers, is used for the production of military camouflage articles. For this, the desired camouflage patterns are printed in the corresponding camouflage shades in a second work step.
  • the same dyes can be used, which have also been used in spin dyeing.
  • disperse dyes are used for polyester fibers and acid or metal complex dyes for polyamide fibers. It is advantageous in this case to produce the spin dyeing in the shade corresponding to the brightest shade of the camouflage print pattern and to print the darker patterns.
  • the brightest shade is usually light green.
  • the textile, spun-dyed fibrous material used according to the invention consists of a mixture of cellulose fibers and synthetic fibers, it can be used for the production of military camouflage articles, in which only the cellulose content is dyed or printed in a second operation. If a plain-colored end product is to be obtained, the dyeing present in the spin dyeing is over-dyed with a dye suitable for cellulose fibers. It is advantageous if the hue produced by spin dyeing has already been set very close to the final hue.
  • the textile, spun-dyed fiber materials used according to the invention which consist of a mixture of cellulose fibers and synthetic fibers, but are printed in a second operation with camouflage patterns, again suitable for cellulose dyes are used.
  • the spin dyeing in a medium gray, green or olive tone and the subsequent printing with typical camouflage nuances such Black, brown and various olive or green tones.
  • the middle notes of spin dyeing are superimposed by the stronger, overprinted nuances and do not disturb the overall picture of the finished product.
  • Preferred dyes suitable for cellulose are in particular vat dyes and sulfur dyes.
  • Particularly suitable dyes are CI Vat Yellow 4, CI Vat Yellow 33, CI Vat Orange 1, CI Vat Orange 7, CI Vat Orange 11, CI Vat Orange 15, CI Vat Blue 5, CI Vat Blue 19, CI Vat Blue 66 CI Vat Green 1, CI Vat Green 3, CI Vat Green 9, CI Vat Green 13, CI Vat Brown 1, CI Vat Brown 3, CI Vat Brown 57, CI Vat Black 7, CI Vat Black 8, CI Vat Black 9 CI Vat Black 19, CI Vat Black 25, CI Vat Black 27, CI Sulfur Black 1, CI Sulfur Black 6 and CI Sulfur Black 7.
  • the dyeing and printing of the cellulose content of the textile, spun-dyed fiber material used according to the invention can be carried out by the methods known per se for applying the various classes of dyes, as described, for example, by H. Rath, Lehrbuch der Textilchemie, Springer Verlag, Berlin, Heidelberg, New York, 3rd Edition 1972, in particular pages 557-568, 571-575, 678.683 and 703-704 or M.Peter and HKRouette, Kunststoffn der Textilveredlung, Deutscher fraverlag, 13th Revised Edition, 1989, in particular pages 500-509 and 624-625.
  • a master batch for PES spin dyeing consisting of 25% CI Solvent Blue 122, 50% CI Solvent Yellow 147 and 25% PBT carrier is used with a concentration of 2.5% as spin dyeing in the PES fiber production.
  • the fineness of the fiber is 1.6 dtex.
  • An olive-green PES fiber is obtained, which is mixed with cotton fibers in the ratio 50:50, spun and woven into a textile fabric or else forfeited or tiled.
  • Tarnnuancen are printed on the textile material produced according to a), wherein a printing paste of the following composition is used.
  • camouflage are printed using a printing paste of the following composition is used. 13.0 g / kg CI Vat Orange 01 16.0 g / kg CI Vat Blue 66 10.0 g / kg CI Vat Black 27 700.0 g / kg Thickening for 2-phase fixation 261.0 g / kg Compensation (water or thickening) 1.000,00g After a usual for vat dyes 2-phase fixation to obtain a dark green shade with IR remission values, which are very close to those of natural chlorophyll in the dark green.
  • Example 2 The textile material produced according to Example 1a) is over-dyed in a continuous dyeing process with the vat dyes mentioned in Example 2.
  • camouflage are printed using a printing paste of the following composition is used. 100.0 g / kg CI Sulfur Black 06 700.0 g / kg Thickening for 2-phase fixation 200.0 g / kg Compensation (water or thickening) 1.000,00g After a typical for vat dyes 2-phase fixation to obtain a black shade with IR remission values, which are between 3.0% (600nm) and 10.0% (1300nm) and correspond to those of the natural soil. The original, chlorophyll-like remission curve of the spun-dyed polyester fiber fraction is completely eliminated by the extremely low-repellency black dye.
  • Example 1a The textile material produced according to Example 1a) is over-dyed in a continuous dyeing process with the sulfur dyes mentioned in Example 4.
  • a master batch for PA spin dyeing consisting of 40% CI Solvent Blue 132, 40% CI Solvent Yellow 83 and 20% Carrier for PA is provided with a Concentration of 2.5% used as spin dyeing in PA (PA 6 or PA6.6) fiber production.
  • An olive-green polyamide fiber is obtained, which is spun and woven into a textile fabric, forfeited or tiled.
  • the fabric is uniformly colored and can then be printed in the usual way with dye classes typical for polyamide fibers, such as acid, metal complex or reactive dyes.
  • the polyamide fibers obtained according to Example 6 are mixed with cotton fibers in a ratio of 50:50 and converted as described into a textile fabric. On this structure are printed analogously to Examples 1b, 2 or 4 camouflage shades.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)

Claims (6)

  1. Utilisation de matériaux fibreux textiles colorés par filage, constitués de fibres de synthèse qui sont colorées par filage avec un colorant qui présente, dans le domaine IR, une variation de réflexion spectrale semblable à celle de la chlorophylle, pour la production d'articles imprimés de camouflage militaires, sur lesquels sont imprimés des dessins de camouflage.
  2. Utilisation de matériaux fibreux textiles, colorés par filage, constitués de mélanges de fibres de cellulose et de synthèse, seule la partie fibres de synthèse étant colorée par filage avec un colorant qui présente dans le domaine IR une variation de réflexion spectrale semblable à celle de la chlorophylle, pour la production d'articles de camouflage militaires, la partie cellulose étant colorée ou imprimée avec des dessins de camouflage.
  3. Utilisation selon la revendication 2, caractérisée en ce qu'on sur-imprime des matériaux fibreux textiles colorés par filage en des tons gris, vert ou olive moyens avec des dessins de camouflage en tons noir, marron, olive ou vert.
  4. Utilisation selon la revendication 2 et/ou 3, caractérisée en ce que la partie cellulose est colorée ou imprimée avec des colorants de cuve ou des colorants au soufre.
  5. Utilisation selon la revendication 4, caractérisée en ce qu'on utilise, comme colorants de cuve, C.I. Vat Yellow 4, C.I. Vat Yellow 33, C.I. Vat Orange 1, C.I. Vat Orange 7, C.I. Vat Orange 11, C.I. Vat Orange 15, C.I. Vat Blue 5, C.I. Vat Blue 19, C.I. Vat Blue 66, C.I. Vat Green 1, C.I. Vat Green 3, C.I. Vat Green 9, C.I. Vat Green 13, C.I. Vat Brown 1, C.I. Vat Brown 3, C.I. Vat Brown 57, C.I. Vat Black 7, C.I. Vat Black 8, C.I. Vat Black 9, C.I. Vat Black 19, C.I. Vat Black 25 ou C.I. Vat Black 27.
  6. Utilisation selon la revendication 4, caractérisée en ce qu'on utilise, comme colorants au soufre, C.I. Sulfur Black 1, C.I. Sulfur Black 6 ou C.I. Sulfur Black 7.
EP00127409A 1999-12-23 2000-12-14 Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage Expired - Lifetime EP1111124B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19962916A DE19962916A1 (de) 1999-12-23 1999-12-23 Textiles, spinngefärbtes Fasermaterial und seine Verwendung zur Herstellung von Tarnartikeln
DE19962916 1999-12-23

Publications (2)

Publication Number Publication Date
EP1111124A1 EP1111124A1 (fr) 2001-06-27
EP1111124B1 true EP1111124B1 (fr) 2006-05-17

Family

ID=7934431

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00127409A Expired - Lifetime EP1111124B1 (fr) 1999-12-23 2000-12-14 Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage

Country Status (9)

Country Link
US (1) US6589297B2 (fr)
EP (1) EP1111124B1 (fr)
KR (1) KR100679770B1 (fr)
CN (1) CN1238593C (fr)
DE (2) DE19962916A1 (fr)
ID (1) ID28993A (fr)
TR (1) TR200003786A3 (fr)
TW (1) TW496918B (fr)
ZA (1) ZA200007771B (fr)

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GB0101546D0 (en) 2001-01-22 2001-03-07 Clariant Int Ltd Use of pigment dyes for dispersion dyeing from aqueous media
GB0101544D0 (en) 2001-01-22 2001-03-07 Clariant Int Ltd Use of pigment dyes for dispersion dyeing from aqueous media
JP2003065461A (ja) 2001-08-24 2003-03-05 Toyota Motor Corp 電磁駆動弁の制御装置
GB0212691D0 (en) * 2002-06-05 2002-07-10 Clariant Int Ltd Composition for dyeing polyester textile materials
DE10238890A1 (de) * 2002-08-24 2004-03-18 Dystar Textilfarben Gmbh & Co. Deutschland Kg Textiles, spinngefärbtes Fasermaterial und seine Verwendung zur Herstellung von Tarnartikeln
JP2004104261A (ja) * 2002-09-05 2004-04-02 Sharp Corp 通信端末機
US6833202B2 (en) * 2003-03-13 2004-12-21 City University Of Hong Kong Electroluminescent devices
US20050058816A1 (en) * 2003-09-12 2005-03-17 Gorres Geoffrey H. Camouflage self-adherent wrap
DE102004060968B4 (de) * 2004-12-17 2008-12-04 Dystar Textilfarben Gmbh & Co. Deutschland Kg Marineblau- und Schwarzmischungen, Verfahren zu ihrer Herstellung und ihre Verwendung zum Färben von Hydroxygruppen-haltigen Material
EP2039830A1 (fr) * 2007-09-22 2009-03-25 Bonar Yarns & Fabrics, Ltd. Gazon artificiel frais
BRPI0909385B1 (pt) * 2008-03-28 2020-10-20 Schoeller Technologies Ag uso de tinturas para fibras para reduzir, reter ou aumentar a refletância de infravermelho próximo
US8932965B1 (en) 2008-07-30 2015-01-13 International Textile Group, Inc. Camouflage pattern with extended infrared reflectance separation
US20110005008A1 (en) * 2009-04-16 2011-01-13 Schoots Harrie P Vinyl acetate/ethylene (vae) copolymers for fabric finishing
US10433593B1 (en) 2009-08-21 2019-10-08 Elevate Textiles, Inc. Flame resistant fabric and garment
US8209785B2 (en) 2010-02-09 2012-07-03 International Textile Group, Inc. Flame resistant fabric made from a fiber blend
US8793814B1 (en) 2010-02-09 2014-08-05 International Textile Group, Inc. Flame resistant fabric made from a fiber blend
US8986808B2 (en) * 2011-08-03 2015-03-24 Milo George Chlorophyll cooling agent for synthetic turf components
KR101347192B1 (ko) * 2012-05-12 2014-01-03 (주)원영티앤비 국방 5도 디지털 무늬를 가지는 우수한 방수성의 위장용 날염 원단 및 그 위장용 날염 원단의 제조 방법
CN103215656B (zh) * 2013-04-26 2016-08-31 大连合成纤维研究设计院股份有限公司 聚酯纤维的溶剂载体纺前原液着色工艺
CN109385920B (zh) * 2018-10-25 2021-04-16 绍兴九洲化纤有限公司 一种聚丁二酸丁二醇酯纤维的染色工艺

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GB2281748B (en) * 1993-09-01 1997-11-26 Gore & Ass Camouflage fabric
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US5607483A (en) * 1994-07-29 1997-03-04 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The U.K. Of Great Britain & Northern Ireland Dyed materials

Also Published As

Publication number Publication date
US20010004780A1 (en) 2001-06-28
TW496918B (en) 2002-08-01
ZA200007771B (en) 2001-07-16
TR200003786A2 (tr) 2001-07-23
DE19962916A1 (de) 2001-07-05
CN1306121A (zh) 2001-08-01
KR20010057577A (ko) 2001-07-04
ID28993A (id) 2001-07-19
DE50012766D1 (de) 2006-06-22
CN1238593C (zh) 2006-01-25
US6589297B2 (en) 2003-07-08
TR200003786A3 (tr) 2001-07-23
EP1111124A1 (fr) 2001-06-27
KR100679770B1 (ko) 2007-02-07

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