EP1111124A1 - Matériaux fibreux textiles colorés par filage et leur utilisation pour la production d'articles de camouflage - Google Patents

Matériaux fibreux textiles colorés par filage et leur utilisation pour la production d'articles de camouflage Download PDF

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Publication number
EP1111124A1
EP1111124A1 EP00127409A EP00127409A EP1111124A1 EP 1111124 A1 EP1111124 A1 EP 1111124A1 EP 00127409 A EP00127409 A EP 00127409A EP 00127409 A EP00127409 A EP 00127409A EP 1111124 A1 EP1111124 A1 EP 1111124A1
Authority
EP
European Patent Office
Prior art keywords
vat
black
dyed
green
textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00127409A
Other languages
German (de)
English (en)
Other versions
EP1111124B1 (fr
Inventor
Horst Roland Dipl.-Ing. Mach
Guido Dipl.-Ing. Krabbe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dystar Textilfarben GmbH and Co Deutschland KG
Original Assignee
Dystar Textilfarben GmbH and Co Deutschland KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dystar Textilfarben GmbH and Co Deutschland KG filed Critical Dystar Textilfarben GmbH and Co Deutschland KG
Publication of EP1111124A1 publication Critical patent/EP1111124A1/fr
Application granted granted Critical
Publication of EP1111124B1 publication Critical patent/EP1111124B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/04—Pigments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/06—Dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8247—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and vat, sulfur or indigo dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/34—Material containing ester groups
    • D06P3/52—Polyesters
    • D06P3/54—Polyesters using dispersed dyestuffs

Definitions

  • the present invention relates to textile, spun-dyed fiber material Synthetic fibers or mixtures of cellulose and synthetic fibers, in which the synthetic fiber portion is colored and its use for the production of Camouflage articles.
  • Textile materials for the military sector usually consist of Synthetic fibers, such as polyester or polyamide, or made of Mixtures of cellulose and synthetic fibers.
  • Synthetic fibers such as polyester or polyamide
  • the aim is remission behavior that corresponds to that of natural leafy green, i.e. of Chlorophylls.
  • a high level of authenticity especially with regard to light, chlorine, rubbing, washing and scouring, required.
  • the present invention thus relates to a textile, spun-dyed fiber material from synthetic fibers or mixtures of cellulose and synthetic fibers for Production of military camouflage articles, characterized in that the Synthetic fiber portion is spin-dyed with a dye that is in the IR range chlorophyll-like remission course.
  • the present invention also relates to the use of textile, Spun-dyed fiber material from synthetic fibers for the production of military camouflage articles, characterized in that camouflage patterns in an be printed in a known manner.
  • the present invention further relates to the use of textile, spun-dyed fiber material made from blends of cellulose and synthetic fibers for the production of military camouflage articles, characterized in that the Cellulose content is dyed or printed with camouflage patterns.
  • the textile, spin-dyed fiber materials according to the invention lie especially as a fabric and can consist of pure synthetic fibers, especially made of polyester or polyamide. But they prefer Blended fabrics with cellulose, being cellulose-polyester blended fabrics are particularly preferred.
  • the synthetic fiber portion of the textile, spun-dyed fiber materials according to the invention is generally dyed in a medium gray, green or olive tone by means of spin dyeing.
  • spin dyeing it is possible to use all dyes which are suitable for spin dyeing and which have the required reflectance curve in the IR region, which is similar to chlorophyll.
  • These dyes can be used alone or as a mixture with one another. In order to achieve the desired basic colors, they can also be combined with other colorants that can be used in spin dyeing. However, it must always be ensured that the IR reflectance behavior of the end product does not have a disruptive or negative effect on the chlorophyll-typical curve shape.
  • the proportions of the individual dyes or colorants used are not critical and are only determined by the desired basic color.
  • Preferred dyes that can be used for the spin dyeing of the synthetic fiber portion are, for example, CI Solvent Blue 122, CI Solvent Blue 132, CI Solvent Blue 104, CI Solvent Blue 45, CI Solvent Yellow 83, CI Solvent Yellow 147, CI Solvent Brown 53, CI Disperse Violet 57 and Cl Pigment Blue 29.
  • the method of spin dyeing is known as such. Pigments or soluble dyes are added to the spinning solution or the melt, which remain in the fibers during the precipitation and thus color them.
  • the colorants are preferably used in the form of so-called masterbatches, which may already contain any auxiliaries required. Details on spin dyeing can be found in Römpp Chemielexikon, 9th edition, 1992, Volume 5, page 4247 and in particular the literature cited therein.
  • Textile, spun-dyed fiber material according to the invention which consists exclusively of synthetic fibers, can also be used as such for use as a camouflage article, if only a plain dyeing is desired. In this case, the desired shade is obtained exclusively by spin dyeing using appropriate amounts of dye.
  • the desired camouflage patterns in the corresponding camouflage shades are printed in a second step.
  • the same dyes can be used that were already used in spin dyeing.
  • disperse dyes are used for polyester fibers and acid or metal complex dyes for polyamide fibers.
  • the lightest shade is usually light green.
  • the textile, spun-dyed fiber material according to the invention consists of a mixture of cellulose and synthetic fibers, it can be used for the production of military camouflage articles by dyeing or printing only the cellulose portion in a second operation. If a uni-colored end product is to be obtained, the dye present from the spin dyeing is over-dyed with a dye suitable for cellulose fibers. It is advantageous if the hue produced by the spin dyeing has already been set very close to the final hue.
  • the textile according to the invention are spin-dyed Fiber materials made from a blend of cellulose and synthetic fibers exist, but printed in a second step with camouflage patterns, whereby in turn, dyes suitable for cellulose are used. It is in preferred in this case, the spin dyeing in a medium gray, green or Olivton and the subsequent printing with typical camouflage nuances such as Black, brown and various olive or green tones. The middle tones of the spin dyeing are thereby from the stronger, overprinted Nuances are superimposed and do not disturb the overall picture of the finished product.
  • cellulose suitable dyes in question for dyeing or printing the cellulose part, all come for cellulose suitable dyes in question, although care must be taken that their IR reflectance curve is also similar to that of chlorophyll or at least the reflectance curve used for the spin dyeing Dye not too badly affected.
  • a variant of the present Invention can also be used with an extremely low remitting black Dye can be printed, which completes the chlorophyll-like remission curve eliminated.
  • the IR reflectance values correspond to those of the natural soil, so that it can also be used for camouflage purposes is advantageous.
  • the cellulose content usable dyes can be used alone or in mixtures with one another wide mixing ratios can be used.
  • Preferred dyes suitable for cellulose are in particular vat dyes and sulfur dyes.
  • Particularly suitable dyes are Cl Vat Yellow 4, Cl Vat Yellow 33, Cl Vat Orange 1, Cl Vat Orange 7, Cl Vat Orange 11, Cl Vat Orange 15, Cl Vat Blue 5, CI Vat Blue 19, Cl Vat Blue 66 , Cl Vat Green 1, Cl Vat Green 3, Cl Vat Green 9, Cl Vat Green 13, Cl Vat Brown 1, Cl Vat Brown 3, Cl Vat Brown 57, Cl Vat Black 7, Cl Vat Black 8, Cl Vat Black 9 , Cl Vat Black 19, Cl Vat Black 25, Cl Vat Black 27, Cl Sulfur Black 1, Cl Sulfur Black 6 and Cl Sulfur Black 7.
  • Spun-dyed fiber material can be made according to the methods known per se
  • the different classes of dyes are applied, for example with H. Rath, Textbook of Textile Chemistry, Springer Verlag, Berlin, Heidelberg, New York, 3rd edition 1972, especially pages 557-568, 571-575, 678.683 and 703-704 or with M.Peter and H.K. Rouette, basics of textile finishing, Deutscher fraverlag, 13th revised edition, 1989, especially pages 500-509 and 624-625.
  • Shades of camouflage are printed on the fabric produced according to Example 1a), a printing paste of the following composition being used. 13.0 g / kg Cl Vat Orange 01 16.0 g / kg Cl Vat Blue 66 10.0 g / kg Cl Vat Black 27 700.0 g / kg Thickening for 2-phase fixation 261.0 g / kg Compensation (water or thickening) 1,000.00g After a 2-phase fixation, which is common for vat dyes, a dark green shade with IR reflectance values is obtained which comes very close to that of natural chlorophyll in the dark green area.
  • the textile fabric produced according to Example 1a) is in a continuous dyeing process over-dyed with the vat dyes mentioned in Example 2.
  • the textile fabric produced according to Example 1a) is in a continuous dyeing process over-dyed with the sulfur dyes mentioned in Example 4.
  • a masterbatch for PA spin dyeing consisting of 40% Cl Solvent Blue 132, 40% Cl Solvent Yellow 83 and 20% Carrier for PA is used with a concentration of 2.5% as spin dyeing for PA (PA 6 or PA6.6) - Fiber production used.
  • An olive-green polyamide fiber is obtained, which is spun and woven, knitted or tiled into a textile fabric. The fabric is dyed uniformly and can then be printed in the usual way with dye classes typical of polyamide fibers, such as acid, metal complex or reactive dyes.
  • the polyamide fibers obtained according to Example 6 are with cotton fibers in Ratio 50:50 mixed and as described in a textile fabric transferred. This structure is analogous to Examples 1b, 2 or 4 Printed camouflage shades.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Coloring (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)
EP00127409A 1999-12-23 2000-12-14 Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage Expired - Lifetime EP1111124B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19962916A DE19962916A1 (de) 1999-12-23 1999-12-23 Textiles, spinngefärbtes Fasermaterial und seine Verwendung zur Herstellung von Tarnartikeln
DE19962916 1999-12-23

Publications (2)

Publication Number Publication Date
EP1111124A1 true EP1111124A1 (fr) 2001-06-27
EP1111124B1 EP1111124B1 (fr) 2006-05-17

Family

ID=7934431

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00127409A Expired - Lifetime EP1111124B1 (fr) 1999-12-23 2000-12-14 Utilisation de matériaux fibreux textiles colorés par filage pour la production d'articles de camouflage

Country Status (9)

Country Link
US (1) US6589297B2 (fr)
EP (1) EP1111124B1 (fr)
KR (1) KR100679770B1 (fr)
CN (1) CN1238593C (fr)
DE (2) DE19962916A1 (fr)
ID (1) ID28993A (fr)
TR (1) TR200003786A3 (fr)
TW (1) TW496918B (fr)
ZA (1) ZA200007771B (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002057537A1 (fr) * 2001-01-22 2002-07-25 Clariant International Ltd Utilisation de colorants pigmentaires pour la coloration en dispersion a partir de milieux aqueux
WO2004020731A1 (fr) * 2002-08-24 2004-03-11 Dystar Textilfarben Gmbh & Co. Deutschland Kg Matiere en fibres textiles teintes dans la masse et utilisation de cette matiere dans la production d'articles de camouflage
US6994736B2 (en) 2001-01-22 2006-02-07 Clariant Finance (Bvi) Limited Use of pigment dyes for dispersion dyeing from aqueous media
US7004982B2 (en) 2001-01-15 2006-02-28 Clariant Finance (Bvi) Limited Use of pigments as disperse dyestuffs
WO2006063998A1 (fr) * 2004-12-17 2006-06-22 Dystar Textilfarben Gmbh & Co Deutschland Kg Melanges bleu marine et noir, procede permettant de les produire et leur utilisation pour teinter des materiaux a base de groupes hydroxy
WO2009118419A1 (fr) * 2008-03-28 2009-10-01 Clariant International Ltd Action sur la réflectance des matériaux textiles colorés dans l'infrarouge proche

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003065461A (ja) 2001-08-24 2003-03-05 Toyota Motor Corp 電磁駆動弁の制御装置
GB0212691D0 (en) * 2002-06-05 2002-07-10 Clariant Int Ltd Composition for dyeing polyester textile materials
JP2004104261A (ja) * 2002-09-05 2004-04-02 Sharp Corp 通信端末機
US6833202B2 (en) * 2003-03-13 2004-12-21 City University Of Hong Kong Electroluminescent devices
US20050058816A1 (en) * 2003-09-12 2005-03-17 Gorres Geoffrey H. Camouflage self-adherent wrap
EP2039830A1 (fr) * 2007-09-22 2009-03-25 Bonar Yarns & Fabrics, Ltd. Gazon artificiel frais
US8932965B1 (en) 2008-07-30 2015-01-13 International Textile Group, Inc. Camouflage pattern with extended infrared reflectance separation
US20110005008A1 (en) * 2009-04-16 2011-01-13 Schoots Harrie P Vinyl acetate/ethylene (vae) copolymers for fabric finishing
US10433593B1 (en) 2009-08-21 2019-10-08 Elevate Textiles, Inc. Flame resistant fabric and garment
US8209785B2 (en) 2010-02-09 2012-07-03 International Textile Group, Inc. Flame resistant fabric made from a fiber blend
US8793814B1 (en) 2010-02-09 2014-08-05 International Textile Group, Inc. Flame resistant fabric made from a fiber blend
US8986808B2 (en) * 2011-08-03 2015-03-24 Milo George Chlorophyll cooling agent for synthetic turf components
KR101347192B1 (ko) * 2012-05-12 2014-01-03 (주)원영티앤비 국방 5도 디지털 무늬를 가지는 우수한 방수성의 위장용 날염 원단 및 그 위장용 날염 원단의 제조 방법
CN103215656B (zh) * 2013-04-26 2016-08-31 大连合成纤维研究设计院股份有限公司 聚酯纤维的溶剂载体纺前原液着色工艺
CN109385920B (zh) * 2018-10-25 2021-04-16 绍兴九洲化纤有限公司 一种聚丁二酸丁二醇酯纤维的染色工艺

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2200323C1 (de) * 1972-01-05 1978-06-15 Hoechst Ag Verfahren zur Herstellung von Faerbungen und Drucken,die im sichtbaren wie im Infrarotbereich zwischen 700 und 1100 nm den Anforderungen fuer Tarnartikel entsprechen
EP0091785A2 (fr) * 1982-04-06 1983-10-19 PFE Limited Teinture à l'état fondu de polyoléfines
US4831068A (en) * 1987-02-27 1989-05-16 Ciba-Geigy Corporation Process for improving the photochemical stability of dyeings on polyester fibre materials

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2281748B (en) * 1993-09-01 1997-11-26 Gore & Ass Camouflage fabric
US5863633A (en) * 1994-01-12 1999-01-26 Squires; William J. Flocked fabric with water resistant film
US5607483A (en) * 1994-07-29 1997-03-04 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The U.K. Of Great Britain & Northern Ireland Dyed materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2200323C1 (de) * 1972-01-05 1978-06-15 Hoechst Ag Verfahren zur Herstellung von Faerbungen und Drucken,die im sichtbaren wie im Infrarotbereich zwischen 700 und 1100 nm den Anforderungen fuer Tarnartikel entsprechen
EP0091785A2 (fr) * 1982-04-06 1983-10-19 PFE Limited Teinture à l'état fondu de polyoléfines
US4831068A (en) * 1987-02-27 1989-05-16 Ciba-Geigy Corporation Process for improving the photochemical stability of dyeings on polyester fibre materials

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7004982B2 (en) 2001-01-15 2006-02-28 Clariant Finance (Bvi) Limited Use of pigments as disperse dyestuffs
WO2002057537A1 (fr) * 2001-01-22 2002-07-25 Clariant International Ltd Utilisation de colorants pigmentaires pour la coloration en dispersion a partir de milieux aqueux
US6994736B2 (en) 2001-01-22 2006-02-07 Clariant Finance (Bvi) Limited Use of pigment dyes for dispersion dyeing from aqueous media
US7001437B2 (en) 2001-01-22 2006-02-21 Clariant Finance (Bvi) Limited Use of pigment dyes for dispersion dyeing from aqueous media
WO2004020731A1 (fr) * 2002-08-24 2004-03-11 Dystar Textilfarben Gmbh & Co. Deutschland Kg Matiere en fibres textiles teintes dans la masse et utilisation de cette matiere dans la production d'articles de camouflage
DE10238890A1 (de) * 2002-08-24 2004-03-18 Dystar Textilfarben Gmbh & Co. Deutschland Kg Textiles, spinngefärbtes Fasermaterial und seine Verwendung zur Herstellung von Tarnartikeln
WO2006063998A1 (fr) * 2004-12-17 2006-06-22 Dystar Textilfarben Gmbh & Co Deutschland Kg Melanges bleu marine et noir, procede permettant de les produire et leur utilisation pour teinter des materiaux a base de groupes hydroxy
WO2009118419A1 (fr) * 2008-03-28 2009-10-01 Clariant International Ltd Action sur la réflectance des matériaux textiles colorés dans l'infrarouge proche

Also Published As

Publication number Publication date
US20010004780A1 (en) 2001-06-28
TW496918B (en) 2002-08-01
ZA200007771B (en) 2001-07-16
TR200003786A2 (tr) 2001-07-23
DE19962916A1 (de) 2001-07-05
CN1306121A (zh) 2001-08-01
KR20010057577A (ko) 2001-07-04
ID28993A (id) 2001-07-19
DE50012766D1 (de) 2006-06-22
EP1111124B1 (fr) 2006-05-17
CN1238593C (zh) 2006-01-25
US6589297B2 (en) 2003-07-08
TR200003786A3 (tr) 2001-07-23
KR100679770B1 (ko) 2007-02-07

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