EP1093510B1 - Composition et procede pour l'enrobage de metaux avec un plastique lubrifie - Google Patents

Composition et procede pour l'enrobage de metaux avec un plastique lubrifie Download PDF

Info

Publication number
EP1093510B1
EP1093510B1 EP99927194A EP99927194A EP1093510B1 EP 1093510 B1 EP1093510 B1 EP 1093510B1 EP 99927194 A EP99927194 A EP 99927194A EP 99927194 A EP99927194 A EP 99927194A EP 1093510 B1 EP1093510 B1 EP 1093510B1
Authority
EP
European Patent Office
Prior art keywords
liquid composition
weight
water
composition
percent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99927194A
Other languages
German (de)
English (en)
Other versions
EP1093510A1 (fr
EP1093510A4 (fr
Inventor
Yasuo Imai
Shuji Nagata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP1093510A1 publication Critical patent/EP1093510A1/fr
Publication of EP1093510A4 publication Critical patent/EP1093510A4/fr
Application granted granted Critical
Publication of EP1093510B1 publication Critical patent/EP1093510B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/065—Sulfides; Selenides; Tellurides
    • C10M2201/066—Molybdenum sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/081—Inorganic acids or salts thereof containing halogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/082—Inorganic acids or salts thereof containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08—Inorganic acids or salts thereof
    • C10M2201/084—Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087—Boron oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/18—Ammonia
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/024—Propene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14—Synthetic waxes, e.g. polythene waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/101—Condensation polymers of aldehydes or ketones and phenols, e.g. Also polyoxyalkylene ether derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/11—Complex polyesters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/11—Complex polyesters
    • C10M2209/111—Complex polyesters having dicarboxylic acid centres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/11—Complex polyesters
    • C10M2209/112—Complex polyesters having dihydric acid centres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
    • C10M2211/044—Acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/06—Perfluorinated compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
    • C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/042—Metal salts thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/02—Groups 1 or 11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/06—Groups 3 or 13
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Definitions

  • This invention relates to a highly effective composition for use in the plastic working of metals, for example, iron, steel, titanium, and aluminum. More particularly, this invention relates to a composition of the aforementioned type that forms a strongly-lubricating coating by a simple process in which, before a workpiece is to be subjected to plastic working, the composition is coated on the workpiece by spray or immersion and then dried. The invention also relates to processes for lubricated plastic working of metal, utilizing a lubricant composition according to the invention.
  • a solid or fluid lubricant is generally used during the plastic working of metals in order to reduce the friction generated by metal to metal contact between the tool and workpiece and thereby prevent seizure and scarring.
  • Lubricated processes for plastic working of metals can be broadly classified into two categories based on the method of use of the lubricant. Into one category fall processes in which lubricants are directly applied to the metal surface, while in the other category a carrier film is first formed on the metal surface by chemical reaction and then the lubricating agent is applied to the carrier film.
  • the former category often utilizes lubricants prepared by the addition of an extreme-pressure additive to a base oil such as a mineral oil, vegetable oil, or synthetic oil.
  • the former category also can utilize lubricants in which a solid lubricating agent such as a metal soap, graphite, or molybdenum disulfide is dispersed in water along with a binder component. In this case the lubricant is applied to the metal surface and plastic working is carried out after a drying step.
  • a solid lubricating agent such as a metal soap, graphite, or molybdenum disulfide
  • the other category of lubricated process for plastic working of metals requires a chemical conversion coating.
  • a carrier coating most often a phosphate type coating
  • a lubricating agent such as a nonreactive soap or a reactive soap such as sodium stearate or calcium stearate.
  • the lubricating coatings formed by this process have a double-layer structure composed of the conversion carrier coating and the metal soap lubricating agent and as a result exhibit a very high resistance to seizure. This feature has resulted in the use of lubricating coatings of this type in a very broad range of plastic working operations, e.g., wire drawing, pipe drawing, and forging.
  • Phosphate treatments are known to have a number of problems.
  • phosphate treatments because they are based on chemical reactions, have required a complex bath management. They have also required a large number of treatment processes ⁇ including water and acid rinses ⁇ since the lubricating agent is applied after formation of a conversion coating.
  • Phosphate treatments have also been associated with high plant and equipment costs and high operating costs due to the discharge of large amounts of effluent from the conversion coating and the water rinses used during the treatment and due to the necessity for heating in order to optimize the chemical reactions.
  • Japanese Published (Examined or Kokoku) Patent Application Number Hei 4-1798 discloses a "lubricant for cold working in which a metal soap or solid lubricant is blended into a lubricating oil comprising a mixture of extreme-pressure additive (e.g., chlorinated paraffin, phosphate esters), isobutylene/n-butene copolymer, and animal oil or vegetable oil".
  • extreme-pressure additive e.g., chlorinated paraffin, phosphate esters
  • isobutylene/n-butene copolymer e.g., isobutylene/n-butene copolymer
  • animal oil or vegetable oil e.g., animal oil or vegetable oil.
  • Another drawback of this high-performance lubricant is the unpleasant odor produced during plastic working operations that use it.
  • Water-based lubricants are either used wet without drying (wet method) or are used in the form of a dried coating (dry method).
  • the wet-method water-based lubricants are used by direct application to the tool or workpiece, as in the case of the above-described oil-based lubricants, while the dry-method water-based lubricants are applied by immersion in the treatment bath, just as in the case of the above-described conversion coatings, followed by the production of a solid lubricating coating by evaporation of the water in a drying process.
  • wet-method water-based lubricants Japanese Published (Examined or Kokoku) .
  • Patent Application Number Sho 58-30358 (30, 358/1983) discloses a "lubricant for the cold- or hot-working of metal tubing comprising the blend of small amounts of dispersant, surfactant, and solid lubricant in a bicarbonate (solids) main component".
  • this lubricant has to date not achieved widespread use as a substitute for conversion treatments.
  • An example of the dry-method water-based lubricants is a "lubricant composition comprising a blend of solid lubricant and conversion film-forming agent in a base of water-soluble polymer or its water-based emulsion" that is disclosed in Japanese Laid Open (Kokai or Unexamined) Patent Application Number Sho 52-20967 (20,967/1977). This example notwithstanding, dry-method water-based lubricants equivalent to conversion treatments have not been obtained.
  • EP 0,303,734 describes lubricating compositions for the plastic working of metals.
  • the compositions typically comprise calcium stearate, sodium tetraborate and polyvinylalcohol.
  • GB 1,322,838 discloses an aqueous lubricant composition comprising sodium stearate, sodium borate, and a vinyl acetate-acrylic ester copolymer latex.
  • US 2,957,825 discloses an aqueous solution for coating metal articles, said solution comprising sodium stearate, polyvinylalcohol, boric acid and sodium thiosulphate.
  • composition for preparing metal for subsequent cold working is also taught in US 3,974,674.
  • the composition comprises borax, sodium stearate and a water-soluble film forming polymer, specifically a polyvinylalcohol in which part of the hydroxyl groups have been modified by reaction with maleic anhydride.
  • a major object of the present invention is to provide a lubricant composition for the plastic working of metals that does not require a phosphate undercoating that is waterborne, that requires only a simple application process consisting of immersion or spraying followed by drying, and that, at least in its most preferred embodiments, provides a lubricating performance equivalent to that afforded by formation of a phosphate conversion coating on a metal workpiece and application of a lubricant composition to the conversion coating.
  • Embodiments of the invention include liquid working compositions that are suitable for directly treating metals surfaces, dried solid lubricating coatings formed by drying such working compositions and metal workpieces bearing such solid lubricating coatings, concentrate compositions for which working compositions can be formed by dilution with water and/or by mixing with other concentrate compositions, lubricated metal plastic working processes lubricated by a dried composition according to the invention, and processes for preparing metal objects for plastic cold working by providing them with a solid lubricating coating by drying onto the metal objects a liquid coating of a working liquid composition according to the invention.
  • liquid composition which when dried forms a solid lubricant for the plastic working of metals, said liquid composition besides water comprising the following components:
  • the synthetic resin (A) used in the lubricant composition according to the present invention has the ability to form a coating that has a film strength and adherence sufficient to withstand plastic working operations.
  • These resins can be either water-soluble or water-dispersible, and this particular property is preferably selected based on the intended use. For example, a water-soluble synthetic resin would be selected when the coating is to be washed away after plastic working, while a water-dispersible synthetic resin would be selected when resistance to water is required.
  • the synthetic resin used by the present invention is dissolved or dispersed in the composition according to the present invention. Known surfactants can be used as necessary to effect dispersion. Although ordinarily, for convenience and economy, only a single resin type will be used in a composition according to the invention, two or more types of resins may be mixed and/or two distinct resins of the same type may be mixed in a composition according to the invention.
  • Polyvinyl alcohols are usually prepared by the hydrolysis of polyvinyl acetates, and the invention can use completely hydrolyzed polyvinyl alcohols as well as polyvinyl alcohols having a degree of hydrolysis down to 50 %.
  • the polyvinyl alcohol category includes hydrolyzed copolymers of a mixture of ethylene and vinyl acetate in which at least 50 mole percent of the mixture is vinyl acetate and in which sufficient vinyl acetate residues have been hydrolyzed so that at least 50 mole percent of the total of vinyl alcohol, vinyl acetate, and ethylene residues in the polymer are (formally) vinyl alcohol residues.
  • the molecular weight of the polyvinyl alcohol is preferably from 300 to 2,000 as measured by gel permeation chromatography.
  • Polyvinylpyrrolidone resins suitable for use in the invention can be synthesized by the polymerization of N-vinyl-2-pyrrolidone.
  • the resulting polymer preferably has a molecular weight from 500 to 1,000 as measured by gel permeation chromatography.
  • the resins afforded by the polymerization of at least one type of acrylic monomers are examples of acrylic resins suitable for use in the invention.
  • the invention also encompasses acrylic resins that are copolymers containing at least 30 mole percent of acrylic monomer units selected from the aforementioned acrylic monomers and at least one selection from other ethylenic monomers such as styrene, methylstyrene, vinyl acetate, vinyl chloride, vinyltoluene, and ethylene.
  • the molecular weight of the acrylic resin is preferably from 1,000 to 1,000,000 and more preferably from 100,000 to 600,000, in each case as measured by gel permeation chromatography.
  • Vinyl acetate resins suitable for use in the invention can be prepared by the polymerization of vinyl acetate.
  • the term "vinyl acetate resin” encompasses partially hydrolyzed homopolymers of vinyl acetate in which less than 50 mole percent of the initially vinyl acetate residues have been hydrolyzed and vinyl acetate-ethylene copolymers containing at least 50 mole percent of vinyl acetate residues.
  • the vinyl acetate resin preferably has a molecular weight from 200 to 2,000 as measured by gel permeation chromatography.
  • Epoxy resins can be exemplified most prominently by the bisphenol-type epoxy resins ⁇ and particularly by the bisphenol-A epoxy resins that conform to the general formula: Such resins are afforded by the reaction of epichlorohydrin and a bisphenol and particularly bisphenol-A (the formal systematic name of which is "2,2-bis(4-hydroxyphenyl)propane").
  • epoxy resins can be exemplified by the novolac epoxy resins afforded by the glycidyl etherification of the phenolic hydroxyl moieties in a phenolic novolac resin, the glycidyl esters of aromatic carboxylic acids, and the so-called peracid epoxy resins produced by epoxidation with peracid of the double bond in an ethylenically unsaturated compound.
  • the subject epoxy resins can also be exemplified by the adducts of ethylene oxide or propylene oxide on the resin backbone of any of the above-noted other types of epoxy resins and by the glycidyl ethers of polyhydric alcohols.
  • the bisphenol-A epoxy resins are the most preferred among the preceding examples.
  • the epoxy resin preferably has a molecular weight of 350 to 5,000 as measured by gel permeation chromatography.
  • Urethane resins are synthetic resins that contain the urethane bond (NHCOO).
  • urethane resins suitable for the present purposes can be prepared by the polyaddition of a polyisocyanate compound bearing at least two isocyanate groups and a polyol bearing at least two active hydrogens.
  • the polyol used in this reaction can be exemplified by polyester polyols and polyether polyols.
  • the polyester polyols can be exemplified by the hydroxyl-terminated polyesters afforded by the reaction, for example, of a low molecular weight polyol and a polybasic acid.
  • the low molecular weight polyol can be, for example, ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, neopentyl glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, 3-methylpentanediol, hexamethylene glycol, hydrogenated bisphenol-A, trimethylolpropane, and glycerol.
  • the polybasic acid can be, for example, succinic acid, glutaric acid, adipic acid, sebacic acid, phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, tetrahydrophthalic acid, endomethylenetetrahydrophthalic acid, and hexahydrophthalic acid.
  • Polyether polyols can be exemplified by the higher ethylene oxide and/or propylene oxide adducts of low molecular weight polyols such as ethylene glycol, diethylene glycol, triethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, neopentyl glycol, 1,2-butylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, 3-methyl-pentanediol, hexamethylene glycol, bisphenol-A, hydrogenated bisphenol-A, trimethylolpropane, and glycerol; by polyether polyols such as polyethylene glycol, polypropylene glycol, and polymers of mixed ethylene and propylene glycols; and by polycaprolactone polyols, polyolefin polyols, and polybutadiene polyols.
  • low molecular weight polyols such as ethylene glycol, diethylene glycol, triethylene glycol
  • the polyisocyanate can be, for example, an aliphatic, alicyclic, or aromatic polyisocyanate. Specific examples thereof are tetramethylene diisocyanate, hexamethylene diisocyanate, lysine diisocyanate ester, hydrogenated xylylene diisocyanate, 1,4-cyclohexylene diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, 2,4'-dicyclohexylmethane diisocyanate, isophorone diisocyanate, 3,3'-dimethoxy-4,4'-biphenylene diisocyanate, 1,5-naphthalene diisocyanate, 1,5-tetrahydronaphthalene diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, 4,4'-diphenylmethane diisocyanate, 2,4'-diphenylmethane
  • a urethane resin used in the invention preferably has a molecular weight of 500 to 500,000 when measured by gel permeation chromatography.
  • Phenolic resins suitable for use in the invention can be obtained by reaction of formaldehyde with at least one phenol selected from, for example, phenol, cresol, and xylenol.
  • the phenolic resin can be a novolac or resole resin.
  • the use of a novolac resin requires the co-use of, for example, hexamethylenetetramine as curing agent.
  • Phenolic resin coatings are cured by the drying process discussed below. The molecular weight of the phenolic resin is not critical.
  • the water-soluble synthetic resins can be acquired already formulated as the aqueous solution, while the water-insoluble synthetic resins can be acquired already formulated as a dispersion in which the resin is dispersed in water using a surfactant that, depending on the particular embodiment, can also be used for dispersion of the lubricating agent, vide infra.
  • the water-soluble inorganic salt component (B) as described above preferably is homogeneously dissolved in the solution and independently preferably uniformly precipitates with the synthetic resin during drying.
  • Preferred salts exhibiting the desired behavior are one or more selections from the group consisting of sulfate salts, borate salts, molybdate salts, vanadate salts, and tungstate salts. These may be used individually or in combinations of two or more selections.
  • Examples thereof are sodium sulfate, potassium sulfate, sodium borate, sodium tetraborate, potassium borate, potassium tetraborate, ammonium borate, ammonium tetraborate, ammonium molybdate, sodium molybdate, sodium tungstate, and sodium vanadate.
  • the ⁇ water-soluble inorganic salt component (B) ⁇ / ⁇ synthetic resin component (A) weight ratio ⁇ calculated on a solids basis, must be from 0.25:1 to 9:1.
  • the solid coating will not be hard enough when this weight ratio falls below 0.25:1 and the metal workpiece will as a result suffer from seizure and/or scarring.
  • this weight ratio exceeds 9:1, the solid lubricating coating formed will suffer from a reduced adherence and a reduced ability to follow the workpiece, during any deformation thereof, which results in facile delamination of the film during the working operation and hence in a reduction in lubrication.
  • This (B)/(A) weight ratio is preferably from 0.3:1 to 8:1 and is more preferably from 0.5:1 to 7:1.
  • the characteristics of the produced film can be adjusted by varying the ⁇ water-soluble inorganic salt ⁇ / ⁇ water-soluble or -dispersible synthetic resin weight ratio ⁇ , and an optimal weight ratio will exist as a function of the severity of the working or rubbing.
  • the film becomes harder with an increasing proportion of water-soluble inorganic salt, and while this results in a better resistance to loading it also results in a reduced adherence by the film.
  • the (B)/(A) weight ratio calculated as the solids weight ratio, is preferably from 1.5:1 to 9:1, more preferably from 2:1 to 8:1, and even more preferably from 2:1 to 7:1.
  • the weight ratio under consideration is preferably from 0.25:1 to 2:1 and more preferably from 0.3:1 to 2:1.
  • the synthetic resin and water-soluble inorganic salt are preferably present in quantities such that the combined amount of the two substances (total solids) is from 1 to 20 percent by weight of a liquid composition according to the invention. This value is more preferably from 1 to 15 percent by weight and even more preferably from 3 to 10 percent by weight.
  • lubricating agent component (C) is preferably generally present in the subject composition.
  • the lubricating agent component should be stable in aqueous solution and should not impair the film strength.
  • this component are metal soaps, waxes, polytetrafluoroethylene, oils, and refractory solid lubricants.
  • the metal soaps can be specifically exemplified by calcium stearate, aluminum stearate, barium stearate, lithium stearate, and zinc stearate;
  • the waxes can be specifically exemplified by polyethylene waxes, polypropylene waxes, camauba wax, beeswax, and paraffin waxes;
  • the polytetrafluoroethylene can be specifically exemplified by polytetrafluoroethylenes having a degree of polymerization of about 1 million to 10 million.
  • the oils can be specifically exemplified by vegetable oils, mineral oils, and synthetic oils.
  • the vegetable oils can be exemplified by palm oil, rapeseed oil, and castor oil; the mineral oils can be exemplified by machine oil, turbine oil, and spindle oil; and the synthetic oils can be exemplified by ester oils and silicone oils.
  • refractory solid lubricants are graphite, molybdenum disulfide, boron nitride, fluorinated graphite, and mica.
  • Lubricating agent component (C) will generally be present in a composition according to the present invention in dispersed or emulsified form.
  • the lubricating agent concentration in a liquid working composition according to the invention is preferably from 1 to 20 percent by weight, more preferably from 1 to 10 percent by weight, and even more preferably from 2 to 7 percent by weight.
  • a content below 1 percent by weight can result in high film friction and hence in a strong tendency for seizure to occur, while a content in excess of 20 percent by weight may cause the film to suffer from a reduced adherence.
  • composition containing components (A) and (B) and lubricating agent and water a first preferred embodiment thereof contains 0.3 to 10.0 percent by weight (as solids) of urethane resin as component (A), 1.0 to 10.0 percent by weight borate salt as component (B), lubricating agent, and water with a (B)/(A), calculated as the solids weight ratio, in the range from 0.25:1 to 9:1.
  • a content of at least 0.3 percent by weight is preferred in order to avoid a decline in film adherence, while a content no greater than 10.0 percent by weight is preferred in order to avoid a decline in film hardness that would increase the likelihood of seizure.
  • a content of at least 1.0 percent by weight is preferred in order to prevent the film from having an inadequate hardness that would result in scarring and seizure of the metal workpiece, while a content no greater than 10.0 percent by weight is preferred in order to avoid a loss in film adherence and extensibility that would result in facile delamination of the film during the working operation and hence in a loss of lubricating performance.
  • the composition preferably contains, as at least part of its content of component (C), a material selected from the group consisting of molybdenum disulfide, graphite, polytetrafluoroethylene, boron nitride, mica, fluorinated graphite, and mixtures of any two or more of molybdenum disulfide, graphite, polytetrafluoroethylene, boron nitride, mica, and fluorinated graphite.
  • This material should be stable in the lubricating solid coating formed and should function to assist the high-load lubrication performance.
  • the concentration of this material in a liquid composition according to the invention is preferably from 1 to 20 percent by weight, more preferably from 1 to 10 percent by weight, and even more preferably from 1 to 5 percent by weight. Contents below 1 percent by weight risk an inadequate resistance to seizure, while contents in excess of 20 percent by weight risk a reduced adherence. 1 If, on the other hand, a liquid lubricant composition according to the invention is intended for use only in processes where there is relatively light plastic working, refractory solid lubricants (i.e., those other than polytetrafluoroethylene that are noted in this sentence) are preferably omitted from any component (C) that is present in the lubricant composition according to the invention.
  • refractory solid lubricants i.e., those other than polytetrafluoroethylene that are noted in this sentence
  • the subject composition preferably also contains an extreme-pressure additive when it is intended to be used in very severe plastic working operations.
  • This extreme-pressure additive should be stable in the lubricating solid coating formed and should exhibit an extreme-pressure activity at the tool-to-metal contact surface produced by the working operation.
  • extreme-pressure additives are sulfur-containing, organomolybdenum, phosphorus-containing, and chlorine-containing extreme-pressure additives, such as olefin sulfides, sulfide esters, sulfites, thiocarbonates, chlorinated fatty acids, phosphate esters, phosphite esters, molybdenum dithiocarbamate (hereinafter usually abbreviated as "MoDTC”), molybdenum dithiophosphate (hereinafter usually abbreviated as "MoDTP”), and zinc dithiophosphate (hereinafter usually abbreviated as ZnDTP).
  • MoDTC molybdenum dithiocarbamate
  • MoDTP molybdenum dithiophosphate
  • ZnDTP zinc dithiophosphate
  • the content of extreme-pressure additive component (D) when this component is present is preferably from 0.5 to 5 percent by weight and more preferably from 1 to 3 percent by weight.
  • a content below 0.5 percent by weight risks an inadequate extreme-pressure activity, while a content in excess of 5 percent by weight risks a reduced film adherence.
  • the extreme-pressure additive is selected from the group consisting of sulfur-containing extreme-pressure additives, organomolybdenum extreme-pressure additives, phosphorus-containing extreme-pressure additives, and chlorine-containing extreme-pressure additives, and mixtures of any two or more of sulfur-containing extreme-pressure additives, organomolybdenum extreme-pressure additives, phosphorus-containing extreme-pressure additives, and chlorine-containing extreme-pressure additives.
  • Nonionic, anionic, amphoteric, and cationic surfactants can be used when a surfactant is required to disperse or emulsify the synthetic resin, solid lubricant, other lubricating agent, and/or extreme-pressure additive.
  • the nonionic surfactant is not particularly critical and can be exemplified by polyoxyethylene alkyl ethers, polyoxyalkylene (ethylene and/or propylene) alkylphenyl ethers, the polyoxyethylene alkyl esters composed of polyethylene glycol (or ethylene oxide) and a higher fatty acid such as a C 12 to C 18 fatty acid, and the polyoxyethylene sorbitan alkyl esters composed of sorbitan, polyethylene glycol, and a higher fatty acid such as a C 12 to C 18 fatty acid.
  • the anionic surfactant is also not particularly critical and can be exemplified by fatty acid salts, the salts of sulfate esters, sulfonate salts, the salts of phosphate esters, and the salts of dithiophosphate esters.
  • the amphoteric surfactant is likewise not particularly critical and can be exemplified by amino acid-type and betaine-type carboxylate salts, sulfate ester salts, sulfonate salts, and phosphate ester salts.
  • the cationic surfactant is again not particularly critical and can be exemplified by aliphatic amine salts and quaternary ammonium salts. These surfactants can be used individually or in combinations of two or more.
  • the technique for preparing the lubricant composition according to the present invention is not particularly critical as long as the resulting lubricant composition can satisfy the various conditions and specifications given hereinabove.
  • the presence of any of component (C) and/or (D) as described above in a liquid composition according to the invention is preferably effected by mixing this component in the form of its waterbome dispersion or waterbome emulsion with the other components.
  • an aqueous solution or aqueous dispersion of the synthetic resin is added with vigorous stirring to an aqueous solution of the inorganic salt; a dispersion or emulsion of the solid lubricant, other lubricating agent, and/or extreme-pressure additive is prepared using surfactant and water as required; and the two intermediates are then combined with stirring.
  • the preferred technique is to first blend the optional solid lubricant, other lubricating agent, and/or extreme-pressure additive (when one or more of these is used) into the composition comprising components (A) and (B) and water, then to apply the resulting product, which is in liquid form, as a coating to the metal workpiece, and then to dry the liquid coating to produce a solid coating according to the invention on the workpiece before it is worked.
  • the preferred technique comprises application of the composition comprising components (A) and (B) and water to the metal workpiece, drying to produce a film that functions as a carrier and partial lubricant itself, and carrying out the plastic working operation with the additional application to the carrier film (for example, by dusting) of the optional solid lubricant, other lubricating agent, and/or extreme-pressure additive at each stage of the working operation.
  • a lubricant composition according to the present invention preferably additionally contains solid lubricant, other lubricating agent, and/or extreme-pressure additive as necessary when used in particular for the single-stage plastic working of metals, but also as desired in the case of multistage plastic working.
  • a lubricant composition according to the present invention can be used as the lubricant that is employed during the cold plastic working (e.g., wire drawing, pipe drawing, forging) of metals such as iron, steel, copper, copper alloys, aluminum, aluminum alloys, titanium, and titanium alloys.
  • the shape of the metal is not particularly critical since the invention contemplates the working of not only stock such as bar and block, but also formed articles (gears and shaft toes) after hot forging.
  • the surface of the metal workpiece is preferably cleaned by a pretreatment comprising, in the order given, degreasing (an alkaline degreaser can generally be used), a water rinse, an acid rinse (carried out using, for example, hydrochloric acid, in order to remove the oxide scale on the metal and thereby improve film adherence), and a second water rinse.
  • degreasing an alkaline degreaser can generally be used
  • a water rinse an acid rinse (carried out using, for example, hydrochloric acid, in order to remove the oxide scale on the metal and thereby improve film adherence), and a second water rinse.
  • the acid rinse and the ensuing water rinse can be omitted when metal oxide scaling is not present.
  • the lubricant composition according to the present invention can be applied to the metal workpiece by the usual methods, such as dipping, spraying, and pouring.
  • the application method needs only to provide a thorough coverage of the metal surface with the lubricant composition, and the application time is not otherwise a critical factor.
  • a liquid lubricant composition according to the invention must be dried after its application before it is used to provide lubrication. While drying can be effected by standing at ambient temperature, drying is optimally carried out generally at from 60 to 150 °C for 10 to 60 minutes.
  • the post-coating, post-drying film coating weight afforded by the invention composition is preferably at least 1 g/m 2 from the standpoint of preventing seizure, but preferably does not exceed 30 g/m 2 based on cost considerations.
  • a more preferred range is from 5 to 20 g/m 2 , while an even more preferred range is from 8 to 15 g/m 2 .
  • Lubricant compositions were prepared using the proportions reported in the tables below. Each composition was prepared by dissolving the water-soluble inorganic salt in water followed by dissolution of the phenolic resin with thorough stirring. A cleaned and dried Bowden test specimen (SPC steel sheet, 150 mm x 75 mm x 1.0 mm) was dipped in the particular lubricant composition for 30 seconds, dried at 100 °C for 30 minutes, and then dusted over its entirety with calcium stearate powder (from Nippon Yushi Kabushiki Kaisha) before being submitted to Bowden testing.
  • SPC steel sheet 150 mm x 75 mm x 1.0 mm
  • the coating weight in g/m 2 was calculated from the weight difference before and after application of the lubricant composition.
  • the Bowden test used a test load of 5 kilograms (this unit being hereinafter usually abbreviated as "kg"), a test temperature of room temperature (i.e., 18-23°C, and a 5 millimeters in diameter steel test sphere.
  • the friction coefficient and number of strokes to seizure was measured in the Bowden test.
  • the average friction coefficient reported in the tables is the average of the friction coefficients measured for the five strokes preceding and the five strokes after the stroke equal to one-half of the number of stokes to seizure.
  • Lubricant compositions were prepared using the proportions reported in the tables below. Each lubricant composition was prepared by dissolving the water-soluble inorganic salt in water followed by the dissolution with thorough stirring of the urethane resin, polyvinyl alcohol, phenolic resin, or acrylic resin.
  • the particular lubricating agent i.e., polyethylene wax dispersion, calcium stearate dispersion, polytetrafluoroethylene, or palm oil emulsion, as reported in the tables was then added with stirring to give the lubricant composition.
  • the Bowden test specimens (SPC steel sheet, 150 millimeters x 75 millimeters x 1.0 millimeter) , cleaned and dried as described for Examples 1 to 3, were dipped in the particular lubricant composition for 30 seconds and dried at 100 °C for 30 minutes and then submitted to Bowden testing.
  • the Bowden test and pretreatment of the Bowden test specimen were carried out as described for Examples 1 to 3.
  • the backward punch test used a 200-ton crank press.
  • the dies 2 in Figure 1 were set to bind the circumference of the cylindrical test specimens 1 as illustrated in Figure 1, and the specimen was then subjected to a downward stroke from a punch 3 also shown in Figure 1.
  • the punch had a diameter designed to give a 50 % cross section reduction of the test specimens 1 and to produce a cup-like molding as shown in Figures 3a through 3b.
  • the lower dead point of the press was adjusted to give a 10 millimeters residual margin at the bottom of the test specimen.
  • the dies were SKD11; the punch was HAP40, with an outside diameter of 21.21 millimeters; the punch depths were 12, 16, 20, 24, 28, 32, 36, 40, 44, 48, 52, 56, and 60 millimeters, respectively, for the thirteen sizes of test specimens in order of increasing heights of the test specimens, and the working rate of the punch was 30 strokes/minute.
  • Backward punch testing was run on the test specimens in order of increasing height until damage occurred to the worked surface.
  • the good punch depth was designated as the largest inside height of the test specimen cup at which the inner surface remained undamaged.
  • Bowden test specimens and backward punch test specimens as described for Examples 4 to 17 were subjected to conversion treatment and then reactive soap lubrication treatment using the conditions reported in the tables.
  • the resulting test specimens were subjected to Bowden testing and backward punch testing also as described for Examples 4 to 17.
  • Lubricant compositions were prepared using the proportions and materials reported in the tables. After following the procedure described for Examples 4 to 17, a refractory solid lubricant or an extreme-pressure additive as specified in the tables was added after the particular solid lubricant or extreme-pressure additive had been preliminarily dispersed into water, using an amount of polyoxyalkylene alkylphenyl ether nonionic surfactant that corresponded to 2 percent of the weight of the solid lubricant or extreme-pressure additive being dispersed.
  • the percent by weight reported for each component in the tables is the percent by weight of the identified component itself. Thus, in the case of aqueous dispersions as an example, this value will not include the water and surfactant used for the dispersion.
  • the lubricant composition according to the present invention for application to the plastic working of metals has the ability to form a highly lubricating film through a simple process. This composition also produces only small amounts of wastes and provides a good working environment.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Metal Extraction Processes (AREA)

Claims (8)

  1. Composition liquide qui, lorsqu'elle est séchée, forme un lubrifiant solide pour le travail plastique des métaux, ladite composition liquide comprenant, en plus de l'eau, les composants suivants :
    (A) une ou un mélange de plusieurs de l'une des résines synthétiques dissoutes et/ou dispersées suivantes, en l'occurrence la polyvinyl pyrrolidone, les résines acryliques, les résines d'acétate de vinyle, les résines époxy, les résines d'uréthane et/ou les résines phénoliques ;
    (B) un ou plusieurs sels minéraux hydrosolubles dissous ; et
    (C) un agent lubrifiant étant l'un ou un mélange de plus d'un des composants suivants, en l'occurrence des savons métalliques, des cires, du polytétrafluoroéthylène et/ou des huiles ;
    et dans laquelle
    les composants (A) et (B) sont présents dans la composition dans des quantités telles que le rapport en poids entre le composant (B) par rapport au composant (A) se situe dans la plage de 0,25:1,0 à 9:1,0 ; et
    ledit composant (C) se situe dans la plage de 1 à 20 pour-cent en poids de la composition liquide totale.
  2. Composition liquide selon la revendication 1, dans laquelle le composant (A) comprend une ou plusieurs résines d'uréthane dissoutes et/ou dispersées.
  3. Composition liquide selon la revendication 2, dans laquelle le ou les sels minéraux hydrosolubles utilisés est/sont un ou plusieurs sels d'acide sulfurique, acide borique, acide molybdique, acide vanadique et/ou acide tungstique.
  4. Composition liquide selon la revendication 2 ou la revendication 3, dans laquelle :
    - la résine uréthane dans le composant (A) est présente en une quantité dans la plage de 0,3 à 10,0 pour-cent en poids de la composition liquide totale ; et
    - le composant (B) comprend un ou des sels d'un ou de plusieurs acides boriques dans une quantité dans la plage de 1,0 à 10,0 pour-cent en poids de la composition totale.
  5. Composition liquide selon l'une quelconque des revendications précédentes, qui comprend en outre au moins l'un des composants suivants :
    - une quantité dans la plage de 1 à 20 pour-cent en poids de la composition liquide totale du lubrifiant solide choisi parmi disulfure de molybdène, graphite, nitrure de bore, mica, graphite fluoré et leurs mélanges ; et
    - une quantité dans la plage de 0,5 à 5 pour cent en poids de la composition liquide totale d'un ou de plusieurs des additifs extrême pression suivants, en l'occurrence des additifs extrême pression contenant du soufre, additifs extrême pression organomolybdène, additifs extrême pression contenant du phosphore et additifs extrême pression contenant du chlore.
  6. Composition concentrée qui peut être diluée à l'eau uniquement pour produire une composition liquide de travail selon l'une quelconque des revendications précédentes.
  7. Procédé pour la préparation d'un objet métallique pour le travail plastique à froid dans lequel, avant de commencer le travail à froid, on procède à l'application d'un lubrifiant solide sur ledit objet par un procédé comprenant les opérations consistant à :
    (i) former un revêtement liquide sur la surface de l'objet métallique à travailler à froid d'une composition liquide telle que définie dans l'une quelconque des revendications 1 à 5 ; et
    (ii) sécher le revêtement liquide formé dans l'opération (i) pour former ledit revêtement de lubrifiant solide.
  8. Procédé selon la revendication 7, dans lequel le revêtement de lubrifiant solide est formé avec un poids de revêtement dans la plage de 5 à 20 g/m2.
EP99927194A 1998-06-09 1999-06-09 Composition et procede pour l'enrobage de metaux avec un plastique lubrifie Expired - Lifetime EP1093510B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP17660298 1998-06-09
JP17660298 1998-06-09
PCT/US1999/012364 WO1999064544A1 (fr) 1998-06-09 1999-06-09 Composition et procede pour l'enrobage de metaux avec un plastique lubrifie

Publications (3)

Publication Number Publication Date
EP1093510A1 EP1093510A1 (fr) 2001-04-25
EP1093510A4 EP1093510A4 (fr) 2002-06-05
EP1093510B1 true EP1093510B1 (fr) 2006-03-29

Family

ID=16016446

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99927194A Expired - Lifetime EP1093510B1 (fr) 1998-06-09 1999-06-09 Composition et procede pour l'enrobage de metaux avec un plastique lubrifie

Country Status (11)

Country Link
EP (1) EP1093510B1 (fr)
KR (1) KR20000006017A (fr)
CN (1) CN1148437C (fr)
AT (1) ATE321831T1 (fr)
AU (1) AU763155B2 (fr)
CA (1) CA2334716C (fr)
DE (1) DE69930628T2 (fr)
ES (1) ES2257053T3 (fr)
IN (1) IN192718B (fr)
TW (1) TW444056B (fr)
WO (1) WO1999064544A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202200006158A1 (it) * 2022-03-29 2023-09-29 Condoroil Chemical S R L Processo per produrre un rivestimento per operazioni di deformazione a freddo esente da boro

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW588108B (en) 2000-08-07 2004-05-21 Nihon Parkerizing Aqueous lubricant for plastic working of metallic material and method for forming lubricant film
CN1214095C (zh) * 2000-08-07 2005-08-10 日本帕卡濑精株式会社 用于金属材料塑性加工的水性润滑剂以及润滑薄膜的处理方法
TW587096B (en) * 2000-08-11 2004-05-11 Nihon Parkerizing Greases component containing in aqueous composition for forming protective membranes
US20030176294A1 (en) * 2000-09-05 2003-09-18 Mamoru Yamamoto Aqueous one step type lubricanting agent for efficient cold forging
US6689831B1 (en) 2000-11-01 2004-02-10 Mcmillen Mark Chromium-free, curable coating compositions for metal substrates
JP4164230B2 (ja) 2000-12-21 2008-10-15 株式会社メックインターナショナル 架橋錯体含有潤滑剤
KR20020051280A (ko) * 2000-12-22 2002-06-28 이구택 윤활성이 우수한 수지용액
JP2002317191A (ja) * 2001-04-19 2002-10-31 Nippon Parkerizing Co Ltd 金属材料加工用潤滑剤、及びその処理方法
KR100714084B1 (ko) * 2001-05-15 2007-05-02 한라공조주식회사 금속가공유제 및 이를 이용한 금속가공방법
JP2003055682A (ja) * 2001-08-17 2003-02-26 Nippon Parkerizing Co Ltd 保護皮膜処理剤および保護皮膜を有する金属材料
TW571000B (en) * 2001-10-19 2004-01-11 Nihon Parkerizing Methods of preparing metal wires for plastic processing
CN100510039C (zh) 2002-03-25 2009-07-08 日本帕卡濑精株式会社 用金属皂涂覆的粒子、其制品及制备方法、润滑涂层形成剂及润滑涂层
JP2004092688A (ja) 2002-08-29 2004-03-25 Koyo Seiko Co Ltd 樹脂製プーリ
JP4124719B2 (ja) * 2003-11-27 2008-07-23 日産自動車株式会社 潤滑皮膜を有する歯車部品の製造方法
KR100679242B1 (ko) * 2005-04-22 2007-02-05 한국마그네슘기술연구조합 마그네슘합금 압출용 윤활제 및 그 제조방법
JP3872492B2 (ja) * 2005-06-01 2007-01-24 日本パーカライジング株式会社 固体に対する水系潤滑皮膜処理剤
EP2450423B1 (fr) * 2009-06-29 2019-05-15 Nihon Parkerizing Co., Ltd. Lubrifiant à base aqueuse utilisable en plasturgie présentant une remarquable résistance à la corrosion et matériau métallique présentant une remarquable aptitude au traitement plasturgique
CN101811173A (zh) * 2010-04-28 2010-08-25 启东尤希路化学工业有限公司 无石墨高性能环境友好型热锻加工液
JP5806673B2 (ja) * 2010-09-30 2015-11-10 日本精線株式会社 冷間圧造用ステンレス鋼線
WO2012133453A1 (fr) * 2011-03-28 2012-10-04 日本パーカライジング株式会社 Lubrifiant solide
CN102504910A (zh) * 2011-11-28 2012-06-20 镇江中孚复合材料有限公司 一种用作减摩添加剂的钼掺杂二硒化钨纳米片及其制备方法
CN103351918A (zh) * 2013-06-19 2013-10-16 安徽富华电子集团有限公司 一种水性拉丝润滑剂及其制备方法
CN103351920A (zh) * 2013-06-19 2013-10-16 安徽富华电子集团有限公司 一种铜线高速细拉丝润滑液及其制备方法
CN103351915A (zh) * 2013-06-19 2013-10-16 安徽富华电子集团有限公司 一种金属拉丝润滑剂及其制备方法
WO2015005978A1 (fr) 2013-07-11 2015-01-15 Houghton Technical Corp. Compositions et leur utilisation pour le façonnage des métaux
CN103878550B (zh) * 2014-03-25 2016-03-02 南方风机股份有限公司 一种有/无法兰的黄铜套的加工工艺
CN103865362B (zh) * 2014-03-31 2016-01-20 方倩 一种耐磨阻燃斜盘的制备方法
CN105838909A (zh) * 2016-05-27 2016-08-10 沧州市东众特种合金制造有限公司 无溶剂无铝铝合金添加剂的制备方法
CN106118839A (zh) * 2016-06-23 2016-11-16 苏州洪河金属制品有限公司 一种水基润滑防锈的金属切削液及其制备方法
EP3309855A1 (fr) * 2016-10-12 2018-04-18 H & T Marsberg GmbH & Co. KG Boîtier de batterie et procédé de formage à froid pour sa fabrication
CN107723074A (zh) * 2017-11-15 2018-02-23 苏州新区特氟龙塑料制品厂 一种特氟龙润滑油添加剂
CN109054951B (zh) * 2018-09-06 2022-01-04 武汉材料保护研究所有限公司 一种铝合金板材冲压成形加工用固体润滑膜及其制备方法
CN109456826A (zh) * 2018-10-24 2019-03-12 常州君合科技股份有限公司 一种拉拔免磷化处理的高碳钢盘条的拉拔液
TWI679070B (zh) * 2019-04-09 2019-12-11 金允成企業股份有限公司 鋁合金管件鍛抽成型方法
CN110305728B (zh) * 2019-08-07 2021-12-17 上海工程技术大学 一种高分子塑性成形用润滑剂及制备方法
CN110560963B (zh) * 2019-08-21 2021-09-03 中国船舶重工集团公司第七二五研究所 一种无镀铜光亮焊丝的生产工艺
CN111395491B (zh) * 2020-05-07 2021-03-16 广东中立建设有限公司 市政雨污分流管道的施工方法
CN112708499B (zh) * 2020-12-24 2023-01-24 东莞市颖兴金属表面处理材料有限公司 可循环使用的钢材拉拔润滑剂、制备方法及使用方法
CN116751502A (zh) * 2023-06-14 2023-09-15 陕西星航智钛新材料有限公司 一种用于钛合金丝材的耐拉拔涂层及其制备方法与应用
CN118341927A (zh) * 2024-04-22 2024-07-16 广东韶铸精锻有限公司 一种多段温锻线

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE23184E (en) * 1948-10-08 1949-12-20 Precoated material and dry lubri
US2957825A (en) * 1956-10-15 1960-10-25 Devex Corp Powdered soap lubricant containing inorganic sulfur salts
BE573670A (fr) * 1958-10-14
JPS494108B1 (fr) * 1970-08-15 1974-01-30
US3974674A (en) * 1973-01-12 1976-08-17 Man-Gill Chemical Company Composition for and method for preparation of metal for subsequent cold working
JPS6474295A (en) * 1987-08-21 1989-03-20 Akad Wissenschaften Ddr Lubricant and its use
JPH0747756B2 (ja) * 1989-08-09 1995-05-24 日本電装株式会社 金属の冷間塑性加工用水系潤滑処理液
JPH04236300A (ja) * 1991-01-17 1992-08-25 Hanano Shoji Kk プランジャー装置用粉末潤滑剤
JPH0517795A (ja) * 1991-07-17 1993-01-26 Hanano Shoji Kk アルミニウム合金鍛造用粉末潤滑剤
AU1064595A (en) * 1994-11-11 1996-06-06 Ecoform Umformtechnik Gmbh Solid lubricant and method for its preparation
US5547595A (en) * 1995-02-07 1996-08-20 Henkel Corporation Aqueous lubricant and process for cold forming metal, particularly pointing thick-walled metal tubes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT202200006158A1 (it) * 2022-03-29 2023-09-29 Condoroil Chemical S R L Processo per produrre un rivestimento per operazioni di deformazione a freddo esente da boro

Also Published As

Publication number Publication date
CA2334716C (fr) 2009-08-18
KR20000006017A (ko) 2000-01-25
EP1093510A1 (fr) 2001-04-25
ATE321831T1 (de) 2006-04-15
AU4416299A (en) 1999-12-30
CN1148437C (zh) 2004-05-05
DE69930628T2 (de) 2007-02-01
EP1093510A4 (fr) 2002-06-05
AU763155B2 (en) 2003-07-17
WO1999064544A1 (fr) 1999-12-16
CA2334716A1 (fr) 1999-12-16
IN192718B (fr) 2004-05-15
DE69930628D1 (de) 2006-05-18
CN1243150A (zh) 2000-02-02
ES2257053T3 (es) 2006-07-16
TW444056B (en) 2001-07-01

Similar Documents

Publication Publication Date Title
EP1093510B1 (fr) Composition et procede pour l'enrobage de metaux avec un plastique lubrifie
US6455476B1 (en) Composition and process for lubricated plastic working of metals
JP3881129B2 (ja) 金属材料の塑性加工用潤滑剤組成物
EP0917559B1 (fr) Lubrifiant aqueux pour le fa onnage plastique a froid des metaux
US6194357B1 (en) Waterborne lubricant for the cold plastic working of metals
EP1454965B1 (fr) Agent de traitement servant a former un revetement protecteur et materiau metallique comportant ce revetement protecteur
US7414012B2 (en) Aqueous lubricant for plastic working of metallic material and method for forming lubricant film
JP2000309793A (ja) 金属材料塑性加工用水系潤滑剤
US20030130137A1 (en) Aqueous lubricant for plactic working of metallic material and method of lubricant film processing
JP5224251B2 (ja) 金属材料の水性塑性加工用潤滑剤組成物
JP3145441B2 (ja) 潤滑性塗料
JP5549957B1 (ja) 水性冷間塑性加工用潤滑剤組成物
EP2220200B1 (fr) Lubrifiant de formage à froid anticorrosion en film sec
AU5167996A (en) Aqueous lubricant and process for cold forming metal, particularly pointing thick-walled metal tubes
JPWO2002020704A1 (ja) 高能率冷間鍛造用水系一工程型潤滑剤
US4800033A (en) Process for the non-cutting reshaping of metals, and lubricant compositions for this process
JP2000167981A (ja) 接着性、耐型カジリ性に優れたアルカリ可溶型有機皮膜被覆鋼板
JP2008075094A (ja) 金属材料の塑性加工用水系潤滑剤組成物
JP2004083781A (ja) 金属材料の塑性加工用水系潤滑剤組成物
JP2006161126A (ja) 化成処理性に優れた潤滑処理鋼板
JP2014043537A (ja) 非鉄金属材料の水性塑性加工用潤滑剤組成物
JPH08259979A (ja) 高潤滑性防錆油及びこれを塗布した金属板
Stefanovic et al. Development of new lubricants for metal forming
JP4768926B2 (ja) 導電性・潤滑性・耐摩耗性に優れた金属向け塗料組成物、金属塗装材及びその製品
JPH02140294A (ja) 耐黒変化表面処理鋼板

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20010109

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE DE ES FI FR GB IT SE

A4 Supplementary search report drawn up and despatched

Effective date: 20020424

AK Designated contracting states

Kind code of ref document: A4

Designated state(s): AT BE DE ES FI FR GB IT SE

RIC1 Information provided on ipc code assigned before grant

Free format text: 7C 10M 173/02 A, 7C 10M 173/02 J, 7C 10M 125:10 J, 7C 10M 125:22 J, 7C 10M 125:26 J, 7C 10M 129:40 J, 7C 10M 143:02 J, 7C 10M 145:04 J, 7C 10M 145:12 J, 7C 10M 145:14 J, 7C 10M 145:18 J, 7C 10M 145:20 J, 7C 10M 147:02 J, 7C 10M 149:10 J, 7C 10M 149:18 J, 7C 10M 159:06 J, 7C 10N 40:24 Z, 7C 10N 50:02 Z

17Q First examination report despatched

Effective date: 20030327

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: HENKEL CORPORATION

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE DE ES FI FR GB IT SE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060329

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060329

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69930628

Country of ref document: DE

Date of ref document: 20060518

Kind code of ref document: P

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060629

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2257053

Country of ref document: ES

Kind code of ref document: T3

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20070102

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20060329

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 17

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 18

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20170621

Year of fee payment: 19

Ref country code: GB

Payment date: 20170620

Year of fee payment: 19

Ref country code: FR

Payment date: 20170621

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20170622

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20170724

Year of fee payment: 19

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 69930628

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20180609

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180630

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190101

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180609

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180609

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20190916

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180610