CN109456826A - 一种拉拔免磷化处理的高碳钢盘条的拉拔液 - Google Patents

一种拉拔免磷化处理的高碳钢盘条的拉拔液 Download PDF

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CN109456826A
CN109456826A CN201811240290.1A CN201811240290A CN109456826A CN 109456826 A CN109456826 A CN 109456826A CN 201811240290 A CN201811240290 A CN 201811240290A CN 109456826 A CN109456826 A CN 109456826A
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steel wire
parkerized
wire rod
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carbon steel
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陆由东
王辉
毛科人
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Changzhou Jun He Science And Technology Co Ltd
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Abstract

本发明属于拉拔液技术领域，特别是一种拉拔免磷化处理的高碳钢盘条的拉拔液，包括以下组成与组分：植物油酸5.0～10.0％；醇胺3.0～5.0％；乳化剂3.0～8.0％；酰胺3.0～5.0％；极压剂1.0～5.0％；聚四氟乙烯1.0～3.0％；杀菌剂1.0～2.0％；去离子水余量。采用本发明所述的拉拔液，可以拉拔免磷化处理的高碳钢盘条，润滑作用明显，性能稳定，且极大减少了对环境的污染。

Description

一种拉拔免磷化处理的高碳钢盘条的拉拔液
技术领域
本发明拉拔液技术领域，特别是涉及一种拉拔免磷化处理的高碳钢盘条的拉拔液。
背景技术
弹簧钢丝、钢丝绳用的钢丝一般都用60-72钢或者硬度更高的碳钢钢盘条拉拔而成。特别是在高速拉拔时，高质量的润滑载体极为重要，它关系到拉拔后钢丝的表面质量、力学性能、模具消耗和劳动生产率。目前，金属制品生产普遍采用磷化作为钢丝拉拔前的表面预处理方式。这种磷化膜的特点是高抗防腐蚀性、高润滑性。在钢丝或钢管高速高压的情况下面不易拉毛或拉断。常用的在线磷化工艺流程为：放线→热处理→酸洗→水洗→热水洗→磷化→皂化→烘干。不仅工艺复杂，而且过程产生大量的磷化废渣和大量的含磷的废水，给环境带来了极大的污染。
因此，发明一种免磷化处理的拉拔液就成为大势所趋。
发明内容
本发明的目的是提供一种可以拉拔免磷化处理的高碳钢盘条的拉拔液。采用本发明所述的拉拔液，可以拉拔免磷化处理的高碳钢盘条，润滑作用明显，性能稳定，且极大减少了对环境的污染。
解决上述技术问题的技术方案如下：
一种拉拔免磷化处理的高碳钢盘条的拉拔液，按照质量分数计，包括以下组成与组分：
进一步地说，植物油酸为妥尓油酸、蓖麻油酸、椰子油酸、妥尓油、菜籽油酸中的至少一种。
进一步地说，醇胺为三乙醇胺、二乙醇胺、单乙醇胺、异丙醇胺中至少一种。
进一步地说，聚四氟乙烯为粒径在2-20μm的聚四氟乙烯的粉末。由于盘条没有做磷化的前道处理，盘条和磨具产生的摩擦力远比传统拉拔要高，拉拔时产生瞬间高温也高，拉拔液中加入润滑性较好的聚四氟乙烯，从而避免钢丝表面毛糙和磨具的磨损。聚四氟乙烯分子间的范德华引力小，容易产生键间滑动，故聚四氟乙烯具有很低的摩擦系数及不粘性，摩擦系数在已知固体材料中是最低的，摩擦系数为0.13-0.16，而且聚四氟乙烯的熔点在300℃以上，能耐拉拔产生的高温。
进一步地说，所述的乳化剂为脂肪醇聚乙烯醚、石油磺酸钠、斯盘、吐温中的至少一种。乳化剂的加入使得拉拔液具有较好的分散、清洗、润湿等性能。
进一步地说，所述的杀菌剂为山梨酸、三嗪、山梨酸钾、吡啶硫酮钠、丙酸钙、丙酸钠、脱氢乙酸、双乙酸钠、富马酸二甲酯、乳酸链球菌素、霉灵、氯甲酚、羟苯丙酯、羟苯甲酯中的至少两种。保证拉拔液长时间性能稳定。
进一步地说，酰胺为甲酰胺、乙酰胺、丙酰胺、己酰胺中的任意一种。
进一步地说，所述的极压剂为氯化石蜡。极压剂保证了优良的润滑作用。
制备该拉拔液的方法，具体包括以下步骤：
⑴按照上述配方的重量份，用电子天平准确称取植物油酸和醇胺；
⑵配制基础溶液：按照配方，准确量取去离子水，将步骤⑴所得植物油酸和醇胺倒入其中，搅拌溶解后，即配制成基础溶液；
⑶按照上述的重量份准确称取酰胺、乳化剂、极压剂、聚四氟乙烯和杀菌剂，依次加入步骤⑵所得的基础溶液中，充分搅拌待全部溶解后静置30分钟，即得拉拔液。
本发明的有益效果：
本发明提供了一种拉拔免磷化处理的高碳钢盘条的拉拔液，以去离子水作为溶剂，分散性非常好，可以拉拔免磷化处理的高碳钢盘条，润滑作用明显，性能稳定，且极大减少了对环境的污染。
具体实施方式
下面结合具体实施方式对本发明作进一步详细的说明。
实施例1：
一种拉拔免磷化处理的高碳钢盘条的拉拔液，包括以下组成与组分：菜籽油酸5.0g；三乙醇胺3.0g；石油磺酸钠3.0g；甲酰胺3.0g；氯化石蜡1.0g；粒径在2-20μm的聚四氟乙烯的粉末1.0g；山梨酸0.25g、三嗪0.25g、山梨酸钾0.25g、吡啶硫酮钠0.25g；去离子水83g。
制备方法是：
⑴按照上述配方的重量份，用电子天平准确称取植物油酸和醇胺；
⑵配制基础溶液：按照配方，准确量取去离子水，将步骤⑴所得植物油酸和醇胺倒入其中，搅拌溶解后，即配制成基础溶液；
⑶按照上述的重量份准确称取酰胺、乳化剂、极压剂、聚四氟乙烯和杀菌剂，依次加入步骤⑵所得的基础溶液中，充分搅拌待全部溶解后静置30分钟，即得拉拔液。
实施例2：
一种拉拔免磷化处理的高碳钢盘条的拉拔液，包括以下组成与组分：蓖麻油酸1.0g、椰子油酸4.0g、妥尓油4.0g、菜籽油酸1.0g；二乙醇胺2.5g、单乙醇胺2.5g；石油磺酸钠4.0g、斯盘4.0g；乙酰胺5.0g；氯化石蜡5.0g；粒径在2-20μm的聚四氟乙烯的粉末3.0g；丙酸钙、丙酸钠2.0g；去离子水62g。
制备方法同实施例1。
实施例3：
一种拉拔免磷化处理的高碳钢盘条的拉拔液，包括以下组成与组分：蓖麻油酸2.0g、椰子油酸5.5g；单乙醇胺1.5g、异丙醇胺3.0g；脂肪醇聚乙烯醚5.0g；丙酰胺4.0g；氯化石蜡3.0g；粒径在2-20μm的聚四氟乙烯的粉末2.0g；脱氢乙酸0.3g、双乙酸钠0.3g、富马酸二甲酯0.3g、乳酸链球菌素0.3g、霉灵0.3g；去离子水72.5g。
制备方法同实施例1。
实施例4：
一种拉拔免磷化处理的高碳钢盘条的拉拔液，包括以下组成与组分：妥尓油酸9.0g；二乙醇胺2.0g、异丙醇胺2.0g；吐温4.0g；己酰胺4.0g；氯化石蜡3.0g；粒径在2-20μm的聚四氟乙烯的粉末2.0g；氯甲酚、羟苯丙酯、羟苯甲酯1.8g；去离子水72.2g。
制备方法同实施例1。
采用本发明所述的拉拔液，可以拉拔免磷化处理的高碳钢盘条，润滑作用明显，性能稳定，且极大减少了对环境的污染。
以上所述，仅是本发明的较佳实施例，并非对本发明做任何形式上的限制，凡是依据本发明的技术实质上对以上实施例所作的任何简单修改、等同变化，均落入本发明的保护范围之内。

Claims (8)

1.一种拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，按照质量分数计，包括以下组成与组分：
2.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的植物油酸为妥尓油酸、蓖麻油酸、椰子油酸、妥尓油、菜籽油酸中的至少一种。
3.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的醇胺为三乙醇胺、二乙醇胺、单乙醇胺、异丙醇胺中至少一种。
4.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的聚四氟乙烯为粒径在2-20μm的聚四氟乙烯的粉末。
5.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的乳化剂为脂肪醇聚乙烯醚、石油磺酸钠、斯盘、吐温中的至少一种。
6.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的杀菌剂为山梨酸、三嗪、山梨酸钾、吡啶硫酮钠、丙酸钙、丙酸钠、脱氢乙酸、双乙酸钠、富马酸二甲酯、乳酸链球菌素、霉灵、氯甲酚、羟苯丙酯、羟苯甲酯中的至少两种。
7.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的酰胺为甲酰胺、乙酰胺、丙酰胺、己酰胺中的任意一种。
8.根据权利要求1所述的拉拔免磷化处理的高碳钢盘条的拉拔液，其特征在于，所述的极压剂为氯化石蜡。
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