EP1076675A1 - Melange ignifuge de resines de copolymere greffe de caoutchouc modifie/polycarbonate, a faible teneur en fluor - Google Patents

Melange ignifuge de resines de copolymere greffe de caoutchouc modifie/polycarbonate, a faible teneur en fluor

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Publication number
EP1076675A1
EP1076675A1 EP99915331A EP99915331A EP1076675A1 EP 1076675 A1 EP1076675 A1 EP 1076675A1 EP 99915331 A EP99915331 A EP 99915331A EP 99915331 A EP99915331 A EP 99915331A EP 1076675 A1 EP1076675 A1 EP 1076675A1
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EP
European Patent Office
Prior art keywords
composition
fluoropolymer
monomers
γçö
flame retardant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP99915331A
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German (de)
English (en)
Inventor
Lambertus Johannes Van Den Helder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
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Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of EP1076675A1 publication Critical patent/EP1076675A1/fr
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Definitions

  • the invention relates to flame retardant resin compositions that are based on blends of polycarbonate resin and rubber modified graft copolymers and that have a low halogen content.
  • compositions containing an aromatic polycarbonate resin a graft copolymer, a fluoropolymer and a phosphorus containing flame retardant compound are known and have been found to exhibit good flame retardency and good heat resistance, see for example, coassigned U.S. Patent Number 5,204,394.
  • the compositions in the '394 patent contain, for example, from 0.2 to 0.5 parts by weight (pbw) per 100 parts by weight polytetrafluoroethylene per 100 pbw of the composition.
  • the amount of fluorine that may be contained in a composition is limited by government regulations, such as, for example, DIN/ VDE 0472, Part 815, Test B, which limits allowable fluorine content to less than or equal to 0.1 percent by weight fluorine.
  • a thermoplastic resin composition that exhibits the high performance and good flame retardant properties of the compositions disclosed in the '394 patent and that exhibit a low fluorine content are desired.
  • thermoplastic resin composition of the present invention comprises: (a) an aromatic polycarbonate resin, (b) a rubber modified graft copolymer comprising a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase, (c) a phosphorus containing flame retardant compound, and
  • composition of the present invention meets the low fluorine content requirements of DIN/ VDE 0472 Part 815, Test B yet unexpectedly provides high performance and good flame retardant properties.
  • the thermoplastic resin composition of the present invention is comprises, based on 100 pbw of the composition, from 60 to 95 pbw, more preferably from 75 to 95 pbw, even more preferably from 80 to 90 pbw, of the polycarbonate resin, from 1 to 15 pbw, more preferably from 4 to 10 pbw, even more preferably from 5 to 7 pbw, of the rubber modified graft copolymer, from 3 to 15 pbw, more preferably from 5 to 12 pbw, even more preferably from 8 to 10 pbw, of the phosphorus containing flame retardant compound, and wherein the amount of fluoropolymer is effective to provide a fluorine content of from 0.038 to 0.1 pbw, more preferably from 0.05 to 0.1 pbw, even more preferably from 0.08 to 0.1 pbw, fluorine.
  • Aromatic polycarbonate resins suitable for use as the polycarbonate resin component of the thermoplastic resin composition of the present invention are known compounds whose preparation and properties have been described, see, generally, U.S. Patent Nos. 3,169,121, 4,487,896 and 5,411,999, the respective disclosures of which-are each incorporated herein by reference.
  • the aromatic polycarbonate resin component of the present invention is the reaction product of a dihydric phenol according to the structural formula (I):
  • A is a divalent aromatic radical, with a carbonate precursor and contains structural units according to the formula (II):
  • divalent aromatic radical includes those divalent radicals containing a single aromatic ring such as phenylene, those divalent radicals containing a condensed aromatic ring system such as, for example, naphthlene, those divalent radicals containing two or more aromatic rings joined by a non-aromatic linkage, such as for example, an alkylene, alkylidene or sulf onyl group, any of which may be substituted at one or more sites on the aromatic ring with, for example, a halo group or (C ⁇ -C ⁇ )alkyl group.
  • A is a divalent aromatic radical according to the formula (XXI):
  • Suitable dihydric phenols include, for example, one or more of 2, 2-bis- (4-hydroxyphenyl) propane (“bisphenol A”), 2,2-bis(3,5-dimethyl-4- hydroxyphenyl)propane, bis(4-hydroxyphenyl) methane, 4,4-bis(4- hydroxyphenyl)heptane, 3,5,3',5'-tetrachloro-4,4'-dihydroxyphenyl)propane, 2,6-dihydroxy naphthalene, hydroquinone, 2,4'-dihydroxyphenyl sulfone.
  • the dihydric phenol is bisphenol A.
  • the carbonate precursor is one or more of a carbonyl halide, a carbonate ester or a haloformate.
  • Suitable carbonyl halides include, for example, carbonyl bromide and carbonyl chloride.
  • Suitable carbonate esters include, such as for example, diphenyl carbonate, dichlorophenyl carbonate, dinaphthyl carbonate, phenyl tolyl carbonate and ditolyl carbonate.
  • Suitable haloformates include, for example, bishaloformates of a dihydric phenols, such as, for example, hydroquinone, or glycols, such as, for example, ethylene glycol, neopentyl glycol.
  • the carbonate precursor is carbonyl chloride.
  • Suitable aromatic polycarbonate resins include linear aromatic polycarbonate resins and branched aromatic polycarbonate resins.
  • Suitable linear aromatic polycarbonates resins include, e.g., bisphenol A polycarbonate resin.
  • Suitable branched polycarbonates are known and are made by reacting a polyfunctional aromatic compound with a dihydric phenol and a carbonate precursor to form a branched polymer, see generally, U. S. Patent Nos. 3,544,514, 3,635,895 and 4,001,184, the respective disclosures of which are incorporated herein by reference.
  • the polyfunctional compounds are generally aromatic and contain at least three functional groups which are carboxyl, carboxylic anhydrides, phenols, haloformates or mixtures thereof, such as, for example, l,l,l-tri(4-hydroxyphenyl)ethane, 1,3,5,-trihydroxy- benzene, trimellitic anhydride, trimellitic acid, trimellityl trichloride, 4- chloroformyl phthalic anhydride, pyromellitic acid, pyromellitic dianhydride, mellitic acid, mellitic anhydride, trimesic acid, benzophenonetetracarboxylic acid, benzophenone-tetracar boxy lie dianhydride.
  • functional groups which are carboxyl, carboxylic anhydrides, phenols, haloformates or mixtures thereof, such as, for example, l,l,l-tri(4-hydroxyphenyl)ethane, 1,3,5,-trihydroxy- benzene,
  • the preferred polyfunctional aromatic compounds are l,l,l-tri(4-hydroxyphenyl)ethane, trimellitic anhydride or trimellitic acid or their haloformate derivatives.
  • the polycarbonate resin component of the present invention is a linear polycarbonate resin derived from bisphenol A and phosgene.
  • the weight average molecular weight of the polycarbonate resin is from about 10,000 to about 200,000 grams per mole (“g/mol"), as determined by gel permeation chromatography relative to polystyrene.
  • Such resins typically exhibit an intrinsic viscosity of about 0.3 to about 1.5 deciliters per gram in methylene chloride at 25°C.
  • Polycarbonate resins are made by known methods, such as, for example, interfacial polymerization, transesterif ication, solution polymerization or melt polymerization.
  • Copolyester-carbonate resins are also suitable for use as the aromatic polycarbonate resin component of the present invention.
  • Copolyester- carbonate resins suitable for use as the aromatic polycarbonate resin component of the thermoplastic resin composition of the present invention are known compounds whose preparation and properties have been described, see, generally, U.S. Patent Nos. 3,169,121, 4,430,484 and 4,487,896, the respective disclosures of which are each incorporated herein by reference.
  • Copolyester-carbonate resins comprise linear or randomly branched polymers that contain recurring carbonate groups, carboxylate groups and aromatic carbocyclic groups in the polymer chain, in which at least some of the carbonate groups are bonded directly to the ring carbon atoms of the aromatic carbocyclic groups.
  • the copolyester-carbonate resin component of the present invention is derived from a carbonate precursor, at least one dihydric phenol and at least one dicarboxylic acid or dicarboxylic acid equivalent.
  • the dicarboxylic acid is one according to the formula (IV): -6-
  • A' is alkylene, alkylidene, cycloaliphatic or aromatic and is preferably a non-substituted phenylene radical or a substituted phenylene radical that is substituted at one or more sites on the aromatic ring , wherein each of such substituent groups is independently (Q-C ⁇ ) alkyl, and the copolyester carbonate resin comprises first structural units according to formula (II) above and second structural units according to formula (V):
  • A' is defined as above.
  • Suitable carbonate precursors and dihydric phenols are those disclosed above.
  • Suitable dicarboxylic acids include, for example, phthalic acid, isophthalic acid, terephthalic acid, dimethyl terephthalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, dimethyl malonic acid, 1,12-dodecanoic acid, s-l,4-cyclohexane dicarboxylic acid, £ ⁇ ms-l,4-cyclohexane dicarboxylic acid, 4,4'- bisbenzoic acid, naphthalene-2,6-dicarboxylic acid.
  • Suitable dicarboxylic acid equivalents include, for example, anhydride, ester or halide derivatives of the above disclosed dicarboxylic acids, such as, for example, phthalic anhydride, dimethyl terephthalate, succinyl chloride.
  • the dicarboxylic acid is an aromatic dicarboxylic acid, more preferably one or more of terephthalic acid and isophthalic acid.
  • the ratio of ester bonds to carbonate bonds present in the copolyester carbonate resin is from 0.25 to 0.9 ester bonds per carbonate bond.
  • the copolyester-carbonate copolymer has a weight average molecular weight of from about 10,000 to about 200,000 g/mol.
  • Copolyester-carbonate resins are made by known methods, such as, for example, interfacial polymerization, transesterification, solution polymerization or melt polymerization. Rubber Modified Thermoplastic Resin
  • Rubber modified thermoplastic resins suitable as the rubber modified thermoplastic resin of the present invention comprise a discontinuous elastomeric phase dispersed in a continuous rigid thermoplastic phase, . wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the elastomeric phase.
  • Suitable materials for use as the elastomeric phase are polymers those having a glass transition temperature (T g ) of less than or equal to 25°C, more preferably less than or equal to 0 °C, and even more preferably less than or equal to -30°C.
  • T g glass transition temperature
  • the Tg of a polymer is the Tg value of polymer as measured by differential scanning calorimetry (heating rate 20° C/ minute, with the Tg value being determined at the inflection point).
  • the elastomer phase comprises a polymer having repeating units derived from one or more monoethylenically unsaturated monomers selected from conjugated diene monomers, non- conjugated diene monomers or (Q ⁇ -G ⁇ 2) alkyl (meth)acrylate monomers
  • Suitable conjugated diene monomers include, e.g., 1,3-butadiene, isoprene, 1,3-heptadiene, methyl-l,3-pentadiene, 2,3-dimethylbutadiene, 2- ethyl-l,3-pentadiene, 1,3-hexadiene, 2, 4, hexadiene, dichlorobutadiene, bromobutadiene and dibromobutadiene as well as mixtures of conjugated -8-
  • the conjugated diene monomer is 1,3-butadiene.
  • Suitable non-conjugated diene monomers include, e.g., ethylidene norbornene, dicyclopentadiene, hexadiene or phenyl norbornene.
  • (G[-Ci2)alkyl means a straight or branched alkyl substituent group having from 1 to 12 carbon atoms per group and includes, e.g., methyl, ethyl, n-butyl, sec-butyl, t-butyl, n-propyl, iso-propyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl and dodecyl, and the terminology "(meth)acrylate monomers” refers collectively to acrylate monomers and methacrylate monomers.
  • (meth)acrylate monomers include ( [-Ci2)alkyl acrylate monomers, e.g., ethyl acrylate, butyl acrylate, iso-pentyl acrylate, n-hexyl acrylate, 2-ethyl hexyl acrylate, and their (C ⁇ -Ci2)alkyl methacrylate analogs such as, e.g., methyl methacrylate, ethyl methacrylate, propyl methacrylate, iso-propyl methacrylate, butyl methacrylate, hexyl methacrylate, decyl methacrylate.
  • [-Ci2)alkyl acrylate monomers e.g., ethyl acrylate, butyl acrylate, iso-pentyl acrylate, n-hexyl acrylate, 2-ethyl hexyl acrylate, and their (C ⁇ -Ci2)
  • the elastomeric phase may, optionally, include up to about 25 percent by weight ("wt%") of one or more monomers selected from (C2-Cs)olefin monomers, vinyl aromatic monomers and monoethylenically unsarurated nitrile monomers.
  • (C.2-C8)olefin monomers means a compound having from 2 to 8 carbon atoms per molecule and having a single site of ethylenic unsaturation per molecule.
  • Suitable (C2-Cs)olefin monomers include, e.g., ethylene, propene, 1-butene, 1-pentene, heptene.
  • Suitable vinyl aromatic monomers include, e.g., styrene and substituted styrenes having one or more alkyl, alkoxyl, hydroxyl or halo substituent group attached to the aromatic ring, including, e.g., -methyl styrene, p-methyl styrene, vinyl toluene, vinyl xylene, trimethyl styrene, butyl styrene, chlorostyrene, dichlorostyrene, bromostyrene, p-hydroxystyrene, methoxystyrene and vinyl-substituted condensed aromatic ring structures, such as, e.g., vinyl naphthalene, vinyl anthracene, as well as mixtures of vinyl aromatic monomers.
  • the term "monoethylenically unsaturated nitrile monomer” means an acyclic compound that includes a single nitrile group and a single site of ethylenic unsaturation per molecule and includes, e.g., acrylonitrile, methacrylonitrile, ⁇ - chloro acrylonitrile.
  • the elastomeric phase may, optionally, include a minor amount, e.g., up to 5 wt%, of repeating units derived from a polyethylenically unsaturated "crosslinking" monomer, e.g., butylene diacrylate, divinyl benzene, butene diol dimethacrylate, trimethylolpropane tri(meth)acrylate.
  • crosslinking e.g., butylene diacrylate, divinyl benzene, butene diol dimethacrylate, trimethylolpropane tri(meth)acrylate.
  • polyethylenically unsaturated means having two or more sites of ethylenic unsaturation per molecule.
  • the elastomeric phase may, particularly in those embodiments wherein the elastomeric phase has repeating units derived from alkyl (meth)acrylate monomers, include a minor amount, e.g., up to 5 wt% of repeating units derived from a polyethylenically unsaturated "graftlinking" monomer.
  • Suitable graftlinking monomers include those monomers having a first site of ethylenic unsaturation with a reactivity similar to that of the monoethylenically unsaturated monomers from which the respective substrate or superstrate is derived and a second site of ethylenic unsaturation with a relative reactivity that is substantially different from that of the monoethylenically unsaturated monomers from which the elastomeric phase is derived so that the first site reacts during synthesis of the elastomeric phase and the second site is available for later reaction under different reaction conditions, e.g., during synthesis of the rigid thermoplastic phase.
  • graftlinking monomers include, e.g., allyl methacrylate, diallyl maleate, triallyl cyanurate.
  • the elastomeric phase comprises from 60 to 100 wt% repeating units derived from one or more conjugated diene monomers and from 0 to 40 wt% repeating units derived from one or more monomers selected from vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers, such as, for example, a styrene-butadiene copolymer, an acrylonitrile-butadiene copolymer or a styrene-butadiene- acrylonitrile copolymer.
  • the elastomeric phase comprises repeating units derived from one or more (Ci-Ci2)alkyl acrylate monomers.
  • the rubbery polymeric substrate comprises from 40 to 95 wt% repeating units derived from one or more (C ⁇ -Ci2)alkyl acrylate monomers, more preferably from one or more monomers selected from ethyl acrylate, butyl acrylate and n-hexyl acrylate.
  • the elastomeric phase is made by aqueous emulsion polymerization in the presence of a free radical initiator, e.g., an azonitrile initiator, an organic peroxide initiator, a persulfate initiator or a redox initiator system, and, optionally, in the presence of a chain transfer agent, e.g., an alkyl mercaptan and coagulated to form particles of elastomeric phase material.
  • the emulsion polymerized particles of elastomeric phase material have a weight average particle size of 50 to 800 ran, more preferably, of from 100 to 500 nm, as measured by light transmission.
  • the size of emulsion polymerized elastomeric particles may optionally be increased by mechanical or chemical agglomeration of the emulsion polymerized particles, according to known techniques.
  • the rigid thermoplastic resin phase comprises one or more thermoplastic polymers and exhibits a T g of greater than 25°C, preferably greater than or equal to 90°C and even more preferably greater than or equal to 100°C.
  • the rigid thermoplastic phase comprises a polymer or a mixture of two or more polymers each having repeating units derived from one or more monomers selected from the group consisting of ( l-Ci 2)cdkyl (meth)acrylate monomers, vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers.
  • Suitable (C ⁇ -Ci2)alkyl (meth)acrylate monomers, vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers are those set forth above in the description of the elastomeric phase.
  • rigid thermoplastic phase comprises one or more vinyl aromatic polymers.
  • Suitable vinyl aromatic polymers comprise at least 50 wt% repeating units derived from one or more vinyl aromatic monomers.
  • the rigid thermoplastic resin phase comprises a vinyl aromatic polymer having first repeating units derived from one or more vinyl aromatic monomers and having second repeating units derived from one or more monoethylenically unsaturated nitrile monomers.
  • the rigid thermoplastic phase is made according to known processes, e.g., mass polymerization, emulsion polymerization, suspension polymerization or combinations thereof, wherein a at least a portion of the rigid thermoplastic phase is chemically bonded, i.e., "grafted" to the elastomeric phase via reaction with unsaturated sites present in the elastomeric phase.
  • the unsaturated sites in the elastomeric phase are provided, e.g., by residual unsaturated sites in repeating units derived from a -12-
  • At least a portion of the rigid thermoplastic phase is made by an aqueous emulsion or aqueous suspension polymerization reaction in the presence of elastomeric phase and a polymerization initiator system, e.g., a thermal or redox initiator system.
  • a polymerization initiator system e.g., a thermal or redox initiator system.
  • thermoplastic phase is made by a mass polymerization process, wherein particles of the material from which the elastomeric phase is to be formed are dispersed in a mixture of the monomers from which the rigid thermoplastic phase is to be formed and the monomers of the mixture are then polymerized to form the rubber modified thermoplastic resin.
  • the amount of grafting that takes place between the rigid thermoplastic phase and the elastomeric phase varies with the relative amount and composition of the elastomeric phase.
  • from 10 to 90 wt%, preferably from 30 to 80 wt%, even more preferably 65 to 80 wt% of the rigid thermoplastic phase is chemically grafted to the elastomeric phase and from 10 to 90 wt%, preferably from 20 to 70 wt%, more preferably from 20 to 35 wt% of the rigid thermoplastic phase remains "free, i.e., non-grafted.
  • the rigid thermoplastic phase of the rubber modified thermoplastic resin may be formed: (i) solely by polymerization carried out in the presence of the elastomeric phase or (ii) by addition of one or more separately polymerized rigid thermoplastic polymers to a rigid thermoplastic polymer that has been polymerized in the presence of the elastomeric phase.
  • less than 10 pbw, more preferably less than 5 pbw of separately polymerized rigid thermoplastic polymer is added per 100 pbw of the thermoplastic resin composition of the present invention. Most preferably no -13-
  • thermoplastic resin composition of the present invention separately polymerized rigid thermoplastic polymer is added to the thermoplastic resin composition of the present invention.
  • the rubber modified thermoplastic resin comprises an elastomeric phase comprising a polymer having repeating units derived from one or more conjugated diene monomers, and, optionally, further comprising repeating units derived from one or more monomers selected from vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers
  • the rigid thermoplastic phase comprises a polymer having repeating units derived from one or more monomers selected from vinyl aromatic monomers and monoethylenically unsaturated nitrile monomers.
  • Each of the polymers of the elastomeric phase and of the rigid thermoplastic resin phase of the rubber modified thermoplastic resin may, provided that the T g limitation for the respective phase is satisfied, optionally include up to 10 wt% of third repeating units derived from one or more other copolymerizable monomers such as, e.g., monoethylenically unsaturated carboxylic acids such as, e.g., acrylic acid, methacrylic acid, itaconic acid, hydroxy(C ⁇ -Ci2)a.kyl (meth)acrylate monomers such as, e.g., hydroxyethyl methacrylate; (C4-Ci2)cycloalkyl (meth)acrylate monomers such as e.g., cyclohexyl methacrylate; (meth)acrylamide monomers such as e.g., acrylamide and methacrylamide; maleimide monomers such as, e.g., N-alkyl maleimides, N-aryl
  • (C4- Ci2) c y l° a lkyl means a cyclic alkyl substituent group having from 4 to 12 carbon atoms per group and the term “(meth)acrylamide” refers collectively to acrylamides and methacrylamides. -14-
  • Suitable fluoropolymers and methods for making such fluoropolymers are known, see, e.g., U.S Patent Nos. 3,671,487, 3,723,373 and 3,383,092.
  • Suitable fluoropolymers include homopolymers and copolymers that comprise repeating units derived from one or more fluorinated olefin monomers.
  • fluorinated olefin monomer means an olefin monomer that includes at least one fluorine atom substituent.
  • Suitable fluorinated olefin homopolymers include e.g., poly(tetra- fluoroethy lene), poly (hexafluoroethy lene) .
  • Suitable fluorinated olefin copolymers include copolymers comprising repeating units derived from two or more fluorinated olefin copolymers such as , e.g., poly(tetrafluoroethylene-hexafluoroethylene), and copolymers comprising repeating units derived from one or more fluorinated monomers and one or more non-fluorinated monoethylenically unsaturated monomers that are copolymerizable with the fluorinated monomers such as, e.g., poly(tetrafluoroethylene-ethylene-propylene) copolymers.
  • Suitable non- fluorinated monoethylenically unsaturated monomers include e.g., olefin monomers such as, e.g., ethylene, propylene butene, acrylate monomers such as e.g., methyl methacrylate, butyl acrylate, vinyl ethers, such as, e.g., -15-
  • cyclohexyl vinyl ether ethyl vinyl ether, n-butyl vinyl ether, vinyl esters such as, e.g., vinyl acetate, vinyl versatate.
  • the fluoropolymer is a poly(tetrafluoroethylene) homopolymer ("PTFE").
  • PTFE poly(tetrafluoroethylene) homopolymer
  • a fluoropolymer is added to the rubber modified thermoplastic resin in the form of a fluoropolymer additive that comprises particles of fluoropolymer encapsulated in a second polymer.
  • the fluoropolymer additive comprises from 30 to 70 wt%, more preferably 40 to 60 wt%, of the fluoropolymer and from 30 to 70 wt%, more preferably 40 to 60 wt%, of the second polymer.
  • the fluoropolymer additive is made by combining a fluoropolymer, in the form of an aqueous dispersion of fluoropolymer particles, with a second polymer, precipitating the combined fluoropolymer particles and second polymer and then drying the precipitate to form the fluoropolymer additive.
  • the fluoropolymer particles range in size from 50 to 500 nanometers ("nm"), as measured by electron microscopy.
  • the fluoropolymer additive is made by emulsion polymerization of one or more monoethylenically unsaturated monomers in the presence of the aqueous fluoropolymer dispersion of the present invention to form a second polymer in the presence of the fluoropolymer. Suitable monoethylenically unsaturated monomers are disclosed above.
  • the emulsion is then precipitated, e.g., by addition of sulfuric acid.
  • the precipitate is dewatered, e.g., by centrifugation, and then dried to form a fluoropolymer additive that comprises fluoropolymer and an associated second polymer.
  • the dry emulsion polymerized fluoropolymer additive is in the form of a free-flowing powder.
  • lkyl (meth)acrylate monomers comprise one or more monomers selected from vinyl aromatic monomers, monoethylenically unsaturated nitrile monomer and (C ⁇ -Ci2) a lkyl (meth)acrylate monomers.
  • the second polymer comprises repeating units derived from styrene and acrylonitrile. More preferably, the second polymer comprises from 60 to 90 wt% repeating units derived from styrene and from 10 to 40 wt% repeating units derived from acrylonitrile.
  • the emulsion polymerization reaction mixture may optionally include emulsified or dispersed particles of a third polymer, such as, e.g., an emulsified butadiene rubber latex.
  • a third polymer such as, e.g., an emulsified butadiene rubber latex.
  • the emulsion polymerization reaction is initiated using a conventional free radical initiator such as, e.g., an organic peroxide compound, such as e.g., benzoyl peroxide, a persulfate compound, such as, e.g., potassium persulfate, an azonitrile compound such as e.g., 2,2'-azobis-2,3,3-trimethylbutyronitrile, or a redox initiator system, such as, e.g., a combination of cumene hydroperoxide, ferrous sulfate, tetrasodium pyrophosphate and a reducing sugar or sodium formaldehyde sulfoxylate.
  • a conventional free radical initiator such as, e.g., an organic peroxide compound, such as e.g., benzoyl peroxide, a persulfate compound, such as, e.g., potassium persulfate, an azonitrile compound
  • a chain transfer agent such as, e.g., a (C -C ⁇ 3 ) alkyl mercaptan compound such as nonyl mercaptan, t-dodecyl mercaptan, may, optionally, be added to the reaction vessel during the polymerization reaction to reduce the molecular weight of the second polymer. In a preferred embodiment, no chain transfer agent is used.
  • the stabilized fluoropolymer dispersion is charged to a reaction vessel and heated with stirring.
  • the initiator system and the one or more monoethylenically unsaturated monomers are then charged to the reaction vessel and heated to polymerize the monomers in the presence of the fluoropolymer particles of the dispersion to thereby form the second polymer.
  • the second polymer exhibits a weight average molecular weight ("M w ”) of from 75 x 10 3 to 800 x 10 3 , a number average molecular weight (“M n ”) of from 30 x 10 3 to 200 x 10 3 and a polydispersity (M /M n ) of less than or equal to 6.
  • M w weight average molecular weight
  • M n number average molecular weight
  • M /M n polydispersity
  • Phosphorus-containing compounds suitable as the phosphorus- containing flame retardant compound of the present invention are known compounds including monophosphate esters such as, for example, triphenyl phosphate, tricresyl phosphate, tritolyl phosphate, diphenyl ' tricresylphosphate, phenyl bisdodecyl phosphate, ethyl diphenyl phosphate, as well as diphosphate esters and oligomeric phosphates such as, for example, resorcinol diphosphate, diphenyl hydrogen phosphate, bisphenol A diphosphate, 2-ethylhexyl hydrogen phosphate.
  • monophosphate esters such as, for example, triphenyl phosphate, tricresyl phosphate, tritolyl phosphate, diphenyl ' tricresylphosphate, phenyl bisdodecyl phosphate, ethyl diphenyl phosphate, as
  • Suitable oligomeric phosphate compounds are set forth in coassigned U.S. Patent Number 5,672,645, to Johannes C. Gossens et al for a "Polymer Mixture Having Aromatic Polycarbonate, Styrene Containing Copolymer and/ or Graft Copolymer and a Flame Retardant, Articles Formed Therefrom", the disclosure of which is hereby incorporated herein by reference.
  • the phosphorus-containing compound of the present invention is an oligomer compound according to the structural formula (IV): -18-
  • Ri, R2, R3 and R are each independently aryl, which may be optionally substituted with halo or alkyl
  • X is arylene, optionally substituted with halo or alkyl
  • a, b, c and d are each independently 0 or 1
  • n is an integer of from 1 to 5.
  • aryl means a monovalent radical containing one or more aromatic rings per radical, which may optionally be substituted on the one or more aromatic rings with one or more alkyl groups, each preferably (C -C 6 )alkyl and which, in the case wherein the radical contains two or more rings, may be fused rings.
  • arylene means a divalent radical containing one or more aromatic rings per radical, which may optionally be substituted on the one or more aromatic rings with one or more alkyl groups, each preferably (C -C ⁇ )alkyl and which, in the case wherein the divalent radical contains two or more rings, the rings may be may be fused or may be joined by a non- aromatic linkages, such as for example, an alkylene, alkylidene, any of which may be substituted at one or more sites on the aromatic ring with a halo group or (C -C 6 )alkyl group.
  • X is a residue derived from resorcinol or hydroquinone.
  • Rl, R2, R3 and R4 are each phenyl, a, b, c and d are each 1, X is phenylene and n is 2 or wherein the phosphate containing compound is a blend of phosphorus containing oligomers with n having an average value of from 1 to 2, more preferably from 1.2 to 1.7. -19-
  • thermoplastic resin composition of the present invention may optionally also contain various conventional additives, such as:
  • antioxidants such as, e.g., organophosphites , e.g., tris(nonyl- phenyl) ⁇ hosphite, (2,4,6-tri-tert-buty lphenyl)(2-buty 1-2-ethy 1-1,3- propanediol)phosphite, bis(2,4-di-t-butylphenyl)pentaerythritol diphosphite or distearyl pentaerythritol diphosphite, as well as alkylated monophenols, polyphenols, alkylated reaction products of polyphenols with dienes, such as, e.g., butylated reaction products of para-cresol and dicyclopentadiene, alkylated hydroquinones, hydroxylated thiodiphenyl ethers, alkylidene-bisphenols, benzyl compounds, acylaminophenols, esters of beta-(3,5
  • esters of thioalkyl or thioaryl compounds such as, e.g., distearylthiopropionate, dilaurylthiopropionate, ditridecylthiodipropionate, amides of beta-(3,5-di-tert-butyl-4- hydroxyphenol)-propionic acid;
  • UV absorbers and light stabilizers such as, e.g., (i) 2-(2'- hydroxyphenyl)-benzotriazoles, 2-Hydroxy-benzophenones; (ii) esters of substituted and unsubstituted benzoic acids, (iii) acrylates, (iv) nickel compounds; (3) metal deactivators, such as, e.g., N,N'-diphenyloxalic acid diamide,
  • peroxide scavengers such as, e.g., (C ⁇ o-C.2 ⁇ ) a lkyl esters of ⁇ - thiodipropionic acid, mercapto benzimidazole; -20-
  • basic co-stabilizers such as, e.g., melamine, polyvinylpyrrolidone, triallyl cyanurate; urea derivatives, hydrazine derivatives; amines, polyamides, polyurethanes; (7) sterically hindered amines such as, e.g., triisopropanol amine or the reaction product of 2,4-dichloro-6-(4-morpholinyl)-l, 3, 5-triazine with a polymer of 1, 6-diamine, N, N'-Bis(-2, 2, 4, 6-tetramethyl-4- piperidenyl) hexane;
  • basic co-stabilizers such as, e.g., melamine, polyvinylpyrrolidone, triallyl cyanurate; urea derivatives, hydrazine derivatives; amines, polyamides, polyurethanes; (7) sterically hindered amines such as, e.g.
  • neutralizers such as magnesium stearate, magnesium oxide, zinc oxide, zinc stearate, hydrotalcite;
  • fillers and reinforcing agents such as, e.g., silicates, Ti0 2 , glass fibers, carbon black, graphite, calcium carbonate, talc, mica;
  • additives such as, e.g., lubricants such as , e.g., pentaerythritol tetrastearate, EBS wax, silicone fluids, plasticizers, optical brighteners, pigments, dyes, colorants, flameproofing agents; anti-static agents; blowing agents;
  • lubricants such as , e.g., pentaerythritol tetrastearate, EBS wax, silicone fluids, plasticizers, optical brighteners, pigments, dyes, colorants, flameproofing agents; anti-static agents; blowing agents;
  • thermoplastic resin composition of the present invention is made by combining and mixing the components of the composition of the present invention under conditions suitable for the formation of a blend of the components, such as for example, by melt mixing using, for example, a two- roll mill, a Banbury mixer or a single screw or twin-screw extruder, and, optionally, then reducing the composition so formed to particulate form, e.g., by pelletizing or grinding the composition.
  • thermoplastic resin composition of the present invention can be molded into useful shaped articles by a variety of means such as injection molding , extrusion, rotational molding, blow molding and thermoforming to form articles such as, for example, computer and business machine housings, home appliances.
  • thermoplastic resin compositions of Examples 1-2 of the present invention and of Comparative Examples C1-C3 were as follows: PC-1 Branched polycarbonate resin derived from bisphenol A, phosgene and having a weight average molecular weight of about 32,000 g/mol.
  • PC-2 Linear polycarbonate resin derived from bisphenol A, phosgene and trimellitic trichlorite and having a weight average molecular weight of about 31,000 g/mol.
  • ABS Emulsion polymerized acrylonitrile-butadiene-styrene
  • graft copolymer comprising 50 pbw of a discontinuous elastomeric phase (butadiene) and 50 pbw of a rigid thermoplastic phase (copolymer of 75 pbw styrene and 25 pbw acrylonitrile);
  • TSAN Additive made by copolymerizing styrene and acrylonitrile in the presence of an aqueous dispersion of PTFE (50 wt% PTFE, 50wt% styrene-acrylonitrile copolymer).
  • PTFE 50 wt% PTFE, 50wt% styrene-acrylonitrile copolymer
  • RDP Resorcinol diphosphate (Rheofos RDP, from FMC Corporation, Ltd.).
  • compositions were made by combining the above-listed components in the relative amounts (in pbw) set forth in TABLE I in a twin -22-
  • compositions were then injection molded at 255°C into a 60°C mold to form samples for testing.
  • melt volume rate was measured according to ISO 1133 at 260°C using a 5 kilogram weight
  • notched impact Izod performance was measured according to ISO 180
  • Vicat B temperature was measured according to ISO 306 tensile properties were measured according to ISO 527
  • flame retardant properties were measured according to UL 94 and CSTBNF P92505.
  • the compositions were evaluated for compliance with DIN/ VDE 0472, Part 815, Test B which requires a fluorine content of less than or equal to 0.1 wt%.
  • composition of the present invention meets the low fluorine content requirements of DIN/ VDE 0472 Part 815, Test B, yet unexpectedly provides high performance and good flame retardant properties.

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Abstract

La présente invention concerne une composition de résine thermoplastique contenant une résine de polycarbonate aromatique, un copolymère greffé de caoutchouc modifié comprenant une phase élastomère discontinue dispersée dans une phase thermoplastique rigide continue, dans laquelle au moins une portion de la phase thermoplastique rigide est chimiquement greffée à la phase élastomère, un composé ignifuge contenant du phosphore, et un polymère fluoré en une quantité suffisante à améliorer le pouvoir ignifuge de la composition, pourvu que la teneur en fluor de la composition ne dépasse pas 0,1 % en poids.
EP99915331A 1998-05-01 1999-04-08 Melange ignifuge de resines de copolymere greffe de caoutchouc modifie/polycarbonate, a faible teneur en fluor Withdrawn EP1076675A1 (fr)

Applications Claiming Priority (3)

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US71640 1993-06-03
US7164098A 1998-05-01 1998-05-01
PCT/US1999/007727 WO1999057198A1 (fr) 1998-05-01 1999-04-08 Melange ignifuge de resines de copolymere greffe de caoutchouc modifie/polycarbonate, a faible teneur en fluor

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DE10010941A1 (de) 2000-03-06 2001-09-13 Bayer Ag Flammwidrige Polycarbonat-Formmassen
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KR100650910B1 (ko) 2004-10-13 2006-11-27 제일모직주식회사 난연성 열가소성 수지 조성물
US7446144B2 (en) 2005-09-14 2008-11-04 Bayer Materialscience Llc Thermoplastic molding composition and articles thermoformed therefrom
WO2007078083A1 (fr) 2005-12-30 2007-07-12 Cheil Industries Inc. Composition de résine thermoplastique de polycarbonate ininflammable présentant de bonnes propriétés d'aptitude au moulage par extrusion et de résistance aux chocs
DE102006012990A1 (de) 2006-03-22 2007-09-27 Bayer Materialscience Ag Flammgeschützte schlagzähmodifizierte Polycarbonat-Zusammensetzungen
KR100885819B1 (ko) 2007-12-18 2009-02-26 제일모직주식회사 굴절률이 우수한 분지형 아크릴계 공중합체 및 그 제조방법
KR101004040B1 (ko) 2007-12-18 2010-12-31 제일모직주식회사 상용성이 향상된 난연 내스크래치 열가소성 수지 조성물
KR100902352B1 (ko) 2008-03-13 2009-06-12 제일모직주식회사 상용성이 향상된 열가소성 수지 조성물
KR100886348B1 (ko) 2008-04-14 2009-03-03 제일모직주식회사 상용성이 개선된 난연 내스크래치 열가소성 수지 조성물
KR101188349B1 (ko) 2008-12-17 2012-10-05 제일모직주식회사 투명성 및 내스크래치성이 향상된 폴리카보네이트계 수지 조성물
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