EP0899325A3 - Weichspülmittelzusammemsetzung - Google Patents

Weichspülmittelzusammemsetzung Download PDF

Info

Publication number
EP0899325A3
EP0899325A3 EP98810753A EP98810753A EP0899325A3 EP 0899325 A3 EP0899325 A3 EP 0899325A3 EP 98810753 A EP98810753 A EP 98810753A EP 98810753 A EP98810753 A EP 98810753A EP 0899325 A3 EP0899325 A3 EP 0899325A3
Authority
EP
European Patent Office
Prior art keywords
und
alkyl
rest
formula
der formel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98810753A
Other languages
English (en)
French (fr)
Other versions
EP0899325B1 (de
EP0899325A2 (de
Inventor
Alfred HÖHENER
Roland Frick
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
BASF Schweiz AG
Original Assignee
Ciba Geigy AG
Ciba Spezialitaetenchemie Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Geigy AG, Ciba Spezialitaetenchemie Holding AG filed Critical Ciba Geigy AG
Priority to EP98810753A priority Critical patent/EP0899325B1/de
Publication of EP0899325A2 publication Critical patent/EP0899325A2/de
Publication of EP0899325A3 publication Critical patent/EP0899325A3/de
Application granted granted Critical
Publication of EP0899325B1 publication Critical patent/EP0899325B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3951—Bleaching agents combined with specific additives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0063—Photo- activating compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/168—Organometallic compounds or orgometallic complexes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/30—Amines; Substituted amines ; Quaternized amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40—Specific cleaning or washing processes
    • C11D2111/46—Specific cleaning or washing processes applying energy, e.g. irradiation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Beschrieben wird eine Weichspülmittelzusammensetzung, enthaltend
  • (a) ein wasserlösliches Zn, Fe(ll), Ca, Mg, Na, K, Al, Si(lV), P(V), Ti(lV), Ge(lV), Cr(VI), Ga(lll), Zr(lV), In(III), Sn(lV) oder Hf(VI) Phthalocyanin; und
  • (b) eine quaternäre Ammoniumverbindung der Formel
    Figure 80000001
    worin
  • R1 und R2 unabhängig voneinander C1-C5-Alkyl; oder Hydroxy-C1-C5-Alkyl;
  • A und B einen C8-C20-Fettsäurerest; den Rest der Formel
    Figure 80000002
    oder den Rest der Formel
    Figure 80000003
  • B C1-C5-Alkyl; einen C8-C20-Fettsäurerest; den Rest der Formel (1a) oder den Rest der Formel (1b);
  • R3, R4 und R5 unabhängig voneinander einen C8-C20-Fettsäurerest;
  • X1- ein für Weichmacher kompatibles Anion;
    und
  • m, n und p eine Zahl von 0 bis 5;
    • bedeuten.
    Mit der erfindungsgemässen Zusammensetzung werden gute Bleicheffekte auf angeschmutzten Textilgeweben erzielt.
    EP98810753A 1997-08-15 1998-08-06 Weichspülmittelzusammemsetzung Expired - Lifetime EP0899325B1 (de)

    Priority Applications (1)

    Application Number Priority Date Filing Date Title
    EP98810753A EP0899325B1 (de) 1997-08-15 1998-08-06 Weichspülmittelzusammemsetzung

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    EP97810573 1997-08-15
    EP97810573 1997-08-15
    EP98810753A EP0899325B1 (de) 1997-08-15 1998-08-06 Weichspülmittelzusammemsetzung

    Publications (3)

    Publication Number Publication Date
    EP0899325A2 EP0899325A2 (de) 1999-03-03
    EP0899325A3 true EP0899325A3 (de) 1999-07-21
    EP0899325B1 EP0899325B1 (de) 2001-12-19

    Family

    ID=8230344

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP98810753A Expired - Lifetime EP0899325B1 (de) 1997-08-15 1998-08-06 Weichspülmittelzusammemsetzung

    Country Status (11)

    Country Link
    US (1) US6583105B1 (de)
    EP (1) EP0899325B1 (de)
    JP (1) JPH11172575A (de)
    KR (1) KR100505528B1 (de)
    AU (1) AU747856B2 (de)
    BR (1) BR9803753A (de)
    DE (1) DE59802506D1 (de)
    ES (1) ES2169492T3 (de)
    ID (1) ID20699A (de)
    NZ (1) NZ331196A (de)
    ZA (1) ZA987302B (de)

    Families Citing this family (14)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    ES2226324T3 (es) 1998-05-18 2005-03-16 Ciba Specialty Chemicals Holding Inc. Granulados solubles en agua de compuestos ftalocianina.
    EP0959123B1 (de) * 1998-05-18 2004-07-28 Ciba SC Holding AG Wasserlösliche Granulate von Phthalocyaninverbindungen
    MXPA01008951A (es) * 1999-03-05 2003-07-21 Univ Case Western Reserve Fotoblanqueadores liquidos hidrofobos.
    AU2003267010B2 (en) * 2002-09-04 2009-10-08 Basf Se Formulations comprising water-soluble granulates
    KR100554479B1 (ko) * 2002-09-11 2006-03-03 씨제이라이온 주식회사 염착 얼룩 방지 세탁용 착염
    KR100502955B1 (ko) * 2002-10-11 2005-07-21 씨제이라이온 주식회사 염착얼룩방지 세탁용 과립조성물
    US7345016B2 (en) * 2003-06-27 2008-03-18 The Procter & Gamble Company Photo bleach lipophilic fluid cleaning compositions
    DE602006004426D1 (de) * 2005-09-06 2009-02-05 Clariant Brazil S A Stabile wässrige Esterquat-Zusammensetztungen
    GB0717485D0 (en) * 2007-09-08 2007-10-17 Unilever Plc Improvements relating to fabric conditioners
    WO2009030601A1 (en) * 2007-09-08 2009-03-12 Unilever Plc Improvements relating to fabric conditioners
    CN103147267B (zh) * 2013-03-06 2015-07-15 浙江传化股份有限公司 一种低温练漂剂及其制备方法
    BR112017015471A2 (pt) 2015-01-19 2018-01-30 Diversey, Inc. auxiliar de secagem para produtos têxteis
    EP3805346B1 (de) * 2019-10-08 2024-08-14 The Procter & Gamble Company Verfahren zum waschen von stoffen
    US20240374769A1 (en) * 2023-05-09 2024-11-14 The Procter & Gamble Company Light activated cleaning composition

    Citations (4)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4240920A (en) * 1978-02-28 1980-12-23 The Procter & Gamble Company Detergent bleach composition and process
    US4255273A (en) * 1978-01-11 1981-03-10 The Procter & Gamble Company Fabric bleaching and stain removal compositions
    US4368053A (en) * 1980-02-29 1983-01-11 Ciba-Geigy Corporation Fabric conditioning compositions containing phthalocyanine substituted with quaternary ammonium group-containing sulphonamide photoactivator
    WO1997005202A1 (en) * 1995-07-25 1997-02-13 The Procter & Gamble Company Low hue photobleaches

    Family Cites Families (11)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    GB1408144A (en) 1972-06-02 1975-10-01 Procter & Gamble Ltd Bleaching process
    US4033718A (en) * 1973-11-27 1977-07-05 The Procter & Gamble Company Photoactivated bleaching process
    CA1064797A (en) 1975-04-03 1979-10-23 Brandon H. Wiers Photoactivated bleach-compositions and process
    CH630127A5 (de) 1977-03-25 1982-05-28 Ciba Geigy Ag Verfahren zum bleichen von textilien.
    EP0054992B1 (de) * 1980-12-22 1985-03-20 Unilever N.V. Einen Photoaktivator enthaltende Zusammensetzung mit verbesserter Bleichwirkung
    JP2855287B2 (ja) 1990-08-22 1999-02-10 ライオン株式会社 柔軟剤組成物
    ES2094795T3 (es) * 1990-11-02 1997-02-01 Ici Plc Ftalocianinas polisustituidas.
    JP3330200B2 (ja) 1993-09-14 2002-09-30 花王株式会社 液体漂白剤組成物
    WO1996002625A1 (en) * 1994-07-19 1996-02-01 The Procter & Gamble Company Perfumes for laundry and cleaning compositions
    IL116638A0 (en) 1995-01-12 1996-05-14 Procter & Gamble Method and compositions for laundering fabrics
    US5679661A (en) * 1995-07-25 1997-10-21 The Procter & Gamble Company Low hue photodisinfectants

    Patent Citations (4)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4255273A (en) * 1978-01-11 1981-03-10 The Procter & Gamble Company Fabric bleaching and stain removal compositions
    US4240920A (en) * 1978-02-28 1980-12-23 The Procter & Gamble Company Detergent bleach composition and process
    US4368053A (en) * 1980-02-29 1983-01-11 Ciba-Geigy Corporation Fabric conditioning compositions containing phthalocyanine substituted with quaternary ammonium group-containing sulphonamide photoactivator
    WO1997005202A1 (en) * 1995-07-25 1997-02-13 The Procter & Gamble Company Low hue photobleaches

    Also Published As

    Publication number Publication date
    AU8000698A (en) 1999-02-25
    KR100505528B1 (ko) 2005-11-09
    BR9803753A (pt) 1999-12-07
    EP0899325B1 (de) 2001-12-19
    ZA987302B (en) 1999-02-15
    NZ331196A (en) 2000-01-28
    US6583105B1 (en) 2003-06-24
    AU747856B2 (en) 2002-05-23
    JPH11172575A (ja) 1999-06-29
    DE59802506D1 (de) 2002-01-31
    ES2169492T3 (es) 2002-07-01
    EP0899325A2 (de) 1999-03-03
    ID20699A (id) 1999-02-18
    KR19990023559A (ko) 1999-03-25

    Similar Documents

    Publication Publication Date Title
    EP0899325A3 (de) Weichspülmittelzusammemsetzung
    GB1428061A (en) Detergent compatible fabric softening and anti-static compositions
    DE2530524C2 (de) Trockenes pulverförmiges oder in Form von Kügelchen vorliegendes Bleichmittel und dessen Verwendung
    DE69123869T2 (de) Weichmacherzusammensetzung enthaltende Alkanol ammonium-funktionelle Siloxane
    EP0203486B1 (de) Waschmittel mit Zusätzen zur Verhinderung der Farbstoff- und Aufhellerübertragung
    DE69117207T2 (de) Weichmacherzusammensetzungen enthaltende quartäre ammonium-funktionelle Siloxane
    DE2952822C2 (de)
    DE3069767D1 (en) Detergent compositions
    DE2617589A1 (de) Hydrophile polyurethane
    NL7915015A (nl) Wasmiddelen met laag fosfaatgehalte.
    DE2234650A1 (de) Proteolytische enzyme enthaltende wasch- und reinigungsmittelmischung
    CA1105659A (en) Fabric softener and anti-static compositions
    JPH11172575A5 (de)
    JPS58149378A (ja) 濃厚な繊維柔軟剤
    DE2160411A1 (de) Oberflachenaktive Verbindungen
    DE2060849A1 (de) Waschmittel zum gleichzeitigen Reinigen und Weichmachen
    DE3610933A1 (de) Zur anwendung im waschgang eines waschprogramms geeignete weichmachende/antistatische zusammensetzungen
    DE3437721A1 (de) Waschmittelzusatz
    JPH06313193A (ja) 液体洗浄剤組成物
    DE3536258A1 (de) Zum waschen und weichmachen von textilien in einem waessrigen waschmedium geeignete fluessige waschmittelzusammensetzung
    DE2857164A1 (de) Waschmittel
    IE860799L (en) Antistatic amides
    EP0103331A3 (en) Antistatic composition
    DE2431391B2 (de) Zweistufiges Waschverfahren für Textilien
    DE2637595A1 (de) Fluessiges waschmittel

    Legal Events

    Date Code Title Description
    PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

    Free format text: ORIGINAL CODE: 0009012

    AK Designated contracting states

    Kind code of ref document: A2

    Designated state(s): BE CH DE ES FR GB IT LI NL

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    PUAL Search report despatched

    Free format text: ORIGINAL CODE: 0009013

    AK Designated contracting states

    Kind code of ref document: A3

    Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    17P Request for examination filed

    Effective date: 19990719

    AKX Designation fees paid

    Free format text: BE CH DE ES FR GB IT LI NL

    17Q First examination report despatched

    Effective date: 20000524

    GRAG Despatch of communication of intention to grant

    Free format text: ORIGINAL CODE: EPIDOS AGRA

    GRAG Despatch of communication of intention to grant

    Free format text: ORIGINAL CODE: EPIDOS AGRA

    GRAH Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOS IGRA

    GRAH Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOS IGRA

    GRAA (expected) grant

    Free format text: ORIGINAL CODE: 0009210

    AK Designated contracting states

    Kind code of ref document: B1

    Designated state(s): BE CH DE ES FR GB IT LI NL

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: EP

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: IF02

    REF Corresponds to:

    Ref document number: 59802506

    Country of ref document: DE

    Date of ref document: 20020131

    GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

    Effective date: 20020319

    ET Fr: translation filed
    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FG2A

    Ref document number: 2169492

    Country of ref document: ES

    Kind code of ref document: T3

    PLBE No opposition filed within time limit

    Free format text: ORIGINAL CODE: 0009261

    STAA Information on the status of an ep patent application or granted ep patent

    Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

    26N No opposition filed
    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: NL

    Payment date: 20030704

    Year of fee payment: 6

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: BE

    Payment date: 20031009

    Year of fee payment: 6

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: BE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20040831

    BERE Be: lapsed

    Owner name: *CIBA SPECIALTY CHEMICALS HOLDING INC.

    Effective date: 20040831

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: NL

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20050301

    NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

    Effective date: 20050301

    BERE Be: lapsed

    Owner name: *CIBA SPECIALTY CHEMICALS HOLDING INC.

    Effective date: 20040831

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PFA

    Owner name: CIBA HOLDING INC.

    Free format text: CIBA SPECIALTY CHEMICALS HOLDING INC.#KLYBECKSTRASSE 141#4057 BASEL (CH) -TRANSFER TO- CIBA HOLDING INC.#KLYBECKSTRASSE 141#4057 BASEL (CH)

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: CH

    Payment date: 20090605

    Year of fee payment: 12

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PL

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: CH

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20100831

    Ref country code: LI

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20100831

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: GB

    Payment date: 20120831

    Year of fee payment: 15

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: FR

    Payment date: 20120914

    Year of fee payment: 15

    Ref country code: IT

    Payment date: 20120828

    Year of fee payment: 15

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: DE

    Payment date: 20121031

    Year of fee payment: 15

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: ES

    Payment date: 20120928

    Year of fee payment: 15

    GBPC Gb: european patent ceased through non-payment of renewal fee

    Effective date: 20130806

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: DE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20140301

    REG Reference to a national code

    Ref country code: FR

    Ref legal event code: ST

    Effective date: 20140430

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: IT

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20130806

    REG Reference to a national code

    Ref country code: DE

    Ref legal event code: R119

    Ref document number: 59802506

    Country of ref document: DE

    Effective date: 20140301

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: GB

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20130806

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: FR

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20130902

    REG Reference to a national code

    Ref country code: ES

    Ref legal event code: FD2A

    Effective date: 20140909

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: ES

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20130807