EP0881324A2 - Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques - Google Patents

Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques Download PDF

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Publication number
EP0881324A2
EP0881324A2 EP98108748A EP98108748A EP0881324A2 EP 0881324 A2 EP0881324 A2 EP 0881324A2 EP 98108748 A EP98108748 A EP 98108748A EP 98108748 A EP98108748 A EP 98108748A EP 0881324 A2 EP0881324 A2 EP 0881324A2
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EP
European Patent Office
Prior art keywords
surfactants
alkyl
anionic
group
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP98108748A
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German (de)
English (en)
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EP0881324A3 (fr
Inventor
Ferdinand Kümmeler
Klaus Dr. Walz
Michael Pirkotsch
Josef Pfeiffer
Fritz Lesszinsky
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Bayer AG
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Bayer AG
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Priority claimed from DE19736923A external-priority patent/DE19736923A1/de
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0881324A2 publication Critical patent/EP0881324A2/fr
Publication of EP0881324A3 publication Critical patent/EP0881324A3/fr
Withdrawn legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/622—Sulfonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004—General aspects of dyeing
    • D—TEXTILES; PAPER
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0024—Dyeing and bleaching in one process
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6136—Condensation products of esters, acids, oils, oxyacids with oxiranes
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    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621—Compounds without nitrogen
    • D06P1/627—Sulfates
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    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/6428—Compounds containing aminoxide groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/647—Nitrogen-containing carboxylic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65125—Compounds containing ester groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D06P3/241—Polyamides; Polyurethanes using acid dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/24—Polyamides; Polyurethanes
    • D06P3/26—Polyamides; Polyurethanes using dispersed dyestuffs
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/904—Mixed anionic and nonionic emulsifiers for dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/907—Nonionic emulsifiers for dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/908—Anionic emulsifiers for dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/913—Amphoteric emulsifiers for dyeing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/913—Amphoteric emulsifiers for dyeing
    • Y10S8/914—Amino carboxylic acids

Definitions

  • the present invention relates to a method that it in synthetic fibers or textile materials made from it, with mineral oil additives, silicone oil additives or both are permitted, in one operation at the same time to remove these additives and such synthetic fibers or from them Coloring textile materials.
  • the fibers or textile materials are used treated in an aqueous liquor, the essential ingredients a) one or more Surfactant (s) from the group of anionic and amphoteric surfactants, b) one or several dye (s) and c) optionally one or more further substance (s) the group of nonionic surfactants, terpene hydrocarbons, terpene alcohols and their esters with lower carboxylic acids, the sorbitol ester and their Oxalkylates, fatty acid ethanolamides, alkyl polyglycosides and solvents included.
  • This treatment is in the pH range from 4.0 to 7.5, at final temperatures in the range of 80-110 ° C and at a liquor ratio of 1: 5 to 1: 100.
  • Synthetic fibers to be treated according to the invention are, for example, polyamide fibers, made of polyamide-6 (Perlon and others) or polyamide-66 (nylon and others), Polyester fibers, polyurethane fibers and other known to those skilled in the art and their Mixtures with each other and their mixtures with other fibers of vegetable and animal Origin.
  • the method according to the invention particularly relates to fibers of polyamides and of polyurethanes and their mixtures with one another and their Mixtures with fibers of vegetable and animal origin, particularly preferred Wise fibers made of polyamide, polyurethane or polyamide / polyurethane mixtures.
  • Textile materials made from it are twisted or other textile-mechanical treated yarns and knitted fabrics, knitted fabrics or woven fabrics made therefrom.
  • combined yarns are used, for example, a polyurethane fiber and a crimped or uncrimped Include polyamide fiber.
  • the method according to the invention is accordingly characterized by the coloring of synthetic fibers containing Avivage or textile materials made from them.
  • the process is carried out under the conditions specified below.
  • Suitable amphoteric surfactants for the process according to the invention are amine oxides, betaines and sulfobetaines which contain a C 10 -C 22 hydrocarbon radical, or mixtures thereof.
  • betaines those of the formula (C 10 -C 22 alkyl) ⁇ N ⁇ (R 1 ) 2 ⁇ CH 2 COO ⁇
  • Particularly preferred amine oxides are those of the formula (C 10 -C 22 alkyl) ⁇ N ⁇ (R 1 ) 2 ⁇ O
  • betaines (II) are: dodecyldimethylbetaine, cocoalkyldimethylbetaine, Tetradecyldimethylbetaine, octadecyldimethylbetaine, talc fatty alkyldimethylbetaine, Oleyl-dimethyl-betaine, cocoalkyl-bis-hydroxyethyl-betaine, stearyl-bis-hydroxyethyl-betaine, Tallow fatty alkyl bis-hydroxyethyl betaine.
  • Suitable amine oxides (IV) are e.g. Dodecyl dimethyl amine oxide, Cocoalkyldimethylamine oxide, tetradecyldimethylamine oxide, octadecyldimethylamine oxide, Tallow fatty alkyl dimethyl amine oxide, oleyl dimethyl amine oxide, coconut alkyl bis-hydroxyethyl amine oxide, Stearyl-bis-hydroxyethyl-amine oxide, tallow fatty alkyl-bis-hydroxyethyl-amine oxide.
  • Suitable anionic surfactants are, for example, sulfation products of C 10 -C 22 -alkanols, -alkenols or their reaction products with 1-50 units of ethylene oxide (EO), preferably 1-40 units of EO. These sulfated products can be present as alkali metal, alkaline earth metal, ammonium, amine or ethanolamine salts.
  • Other anionic surfactants are soaps from C 12 -C 18 fatty acids, mersolates and alkylbenzenesulfonic acids, which are in the form of the abovementioned salts.
  • Suitable anionic surfactants are polyether carboxylates of the formulas C 8 -C 20 -alk (en) yl- (O-CH 2 -CH 2 -) x -O-CH 2 -COO-M, where X is preferably from 2 to 30 of 3-10, and M represents an equivalent of one of the above salt-forming cations.
  • Amphoteric and anionic surfactants of the type mentioned above are used in many different ways Used in the field of textile treatment and are known to those skilled in the art.
  • Manufactured textile materials contain additives from mineral oils and silicone oils or to remove their mixtures without the simultaneous coloring the synthetic fibers or the textile materials. Rather, it will be surprisingly achieved colorations of high uniformity.
  • Mineral oils are for example Paraffin oils in the viscosity range of 10-40 mPa.s; Silicone oils are, for example, M oils in the viscosity range of 3-100 mPa.s.
  • anionic Surfactants are preferably able to wash off mineral oil finishers while Amphoteric surfactants are cheaper when removing silicone oil additives.
  • Amphoteric surfactants are cheaper when removing silicone oil additives.
  • polyamide / polyurethane or polyester / polyurethane one is therefore preferred mixtures of anionic and amphoteric Use surfactants.
  • the treatment liquor also contains dyes, preferably those from the group of Acid dyes, metal complex dyes or disperse dyes. All these Dyes are known to the person skilled in the art and require no further explanation.
  • the treatment liquor optionally contains one or more further substances from the group of nonionic surfactants, terpene hydrocarbons, terpene alcohols and their esters with lower carboxylic acids, for example C 1 -C 4 carboxylic acids, preferably acetic acid, the sorbitol ester or mannitol ester and their oxalkylates, the Fatty acid ethanol amides, alkyl polyglycosides and solvents.
  • nonionic surfactants terpene hydrocarbons, terpene alcohols and their esters with lower carboxylic acids, for example C 1 -C 4 carboxylic acids, preferably acetic acid, the sorbitol ester or mannitol ester and their oxalkylates, the Fatty acid ethanol amides, alkyl polyglycosides and solvents.
  • Nonionic surfactants are, for example, alcohols, such as alcohols from fat chemistry or oxo alcohols, or almines or carboxylic acids from fat chemistry 9-13 carbon atoms, with 3-10 units of EO and optionally with 2-5 Units of propylene oxide (PO) have been implemented. Among these implementation products the alcohols of the number of carbon atoms mentioned are preferred. Such non-ionic Surfactants are known to the person skilled in the art and require no further explanation.
  • terpene hydrocarbon for example limonene, orange terpene, ⁇ -terpine, balsam terpin oil B, diterpene DS, diterpene B, diterpene A, limonene DL, piperitone, pine oil 70; as terpene alcohol and esters thereof with lower carboxylic acids, for example pineol terpinylacetate, terpineol may be mentioned.
  • Sorbitol esters or mannitol esters are, for example, those with saturated or unsaturated C 12 -C 18 fatty acids; at the same time, their oxalkylates, for example with 2-40 units of EO and optionally 2-10 units of PO, are suitable.
  • Fatty acid ethanolamides for example, have an alkyl radical with 12-18 C atoms.
  • Alkyl polyglycosides for example, have an alkyl radical with 8-12 C atoms.
  • Solvents come, for example, isopropanol, methoxypropanol and others solvents known to the person skilled in the art in question.
  • Preferred polyether carboxylates are, for example, carboxy-methylated emulsifier made from technical lauryl alcohol (C 12 with proportions up to C 18 ) with 4 to 8 mol EO; preferred alkyl polyglycosides have 8-10 C atoms; preferred anionic surfactants are C 12 -C 18 alkyl sulfates with 0-40 units of ethylene oxide. Preferred nonionic surfactants are C 9 -C 13 alcohols with 3-10 units of ethylene oxide.
  • Preferred fatty acid ethanolamides are mixtures with alkyl radicals with 12-18 C atoms.
  • Typical fleet approaches from this are then, for example (without dyes): 0.2 g / l amphoteric surfactant (I) or 0.4 g / l Alkyl polyglucoside 0.2 g / l anionic surfactant (I) 0.4 g / l anionic surfactant (I) 0.06 g / l Lime 0.2 g / l Fatty acid monoethanolamide 0.06 g / l not.
  • Surfactant rest water 0.06 g / l Solvents rest water
  • the treatment according to the invention of the synthetic fibers or textiles produced therefrom Materials with a surcharge on finishing for simultaneous execution of Coloring is in the pH range from 4.0 to 7.5, at end temperatures in the range from 80-110 ° C and with liquor ratios from 1: 5 to 1: 100, preferably 1: 5 to 1:10, carried out.
  • conventional equipment such as wide washing machines, Use drum dyeing machines, cotton washing machines and cotton dyeing machines.
  • the final temperatures are after heating from room temperature reached. It is used with heating rates of 0.5 to 8 ° C / min. worked.
  • Combinations of surfactants a) and other substances c) according to the invention the one allow simultaneous coloring according to the invention (here preliminary tests without dyes); is specified in the last column of the table according to the invention Liquor treatment still remaining avivage content (as petroleum ether (PE) extract); untreated raw material for comparison.
  • the raw materials are socks made of polyamide / polyurethane mixed fibers
  • As examples I to IV are raw materials with various Original content of avivage used and the remaining one afterwards Avivage content indicated.
  • the compositions given are concentrates with the parts specified as parts by weight or in% by weight. From this concentrate 1 g / l wash liquor are used.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)
  • Detergent Compositions (AREA)
EP98108748A 1997-05-26 1998-05-14 Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques Withdrawn EP0881324A3 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE19721906 1997-05-26
DE19721906 1997-05-26
DE19736923A DE19736923A1 (de) 1997-05-26 1997-08-25 Verfahren zum gleichzeitigen Avivage-Entfernen und Einfärben von Synthesefasern
DE19736923 1997-08-25

Publications (2)

Publication Number Publication Date
EP0881324A2 true EP0881324A2 (fr) 1998-12-02
EP0881324A3 EP0881324A3 (fr) 1999-12-01

Family

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EP98108748A Withdrawn EP0881324A3 (fr) 1997-05-26 1998-05-14 Procédé pour teindre et enlever simultanément les agents d'avivage des fibres synthétiques

Country Status (5)

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US (1) US6099594A (fr)
EP (1) EP0881324A3 (fr)
JP (1) JPH10325086A (fr)
CN (1) CN1200421A (fr)
CA (1) CA2238259A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2794476A1 (fr) * 1999-06-07 2000-12-08 Rhodia Chimie Sa Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles
WO2013041810A1 (fr) * 2011-09-22 2013-03-28 Arcadophta Composition de coloration ophtalmique à toxicité réduite stable et pouvant être stérilisée

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6500215B1 (en) * 2000-07-11 2002-12-31 Sybron Chemicals, Inc. Utility of selected amine oxides in textile technology
WO2002092905A1 (fr) * 2001-05-16 2002-11-21 James Jung Composition acceleratrice de teinture et procede d'utilisation de celle-ci
CN103205903A (zh) * 2013-03-14 2013-07-17 浙江理工大学 一种可见光响应自清洁催化纤维及制备方法
TWI586714B (zh) * 2016-06-24 2017-06-11 萬能學校財團法人萬能科技大學 一種尼龍纖維材料的染色組成物及使用其之染色程序
CN112458769A (zh) * 2020-11-16 2021-03-09 五邑大学 一种纯棉染色面料复染剂及其制备方法

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DE1519519A1 (de) * 1965-04-29 1970-01-15 Glanzstoff Ag Verfahren zum Faerben von Textilien aus Gemischen von Wolle und synthetischem Material
DE2148701A1 (de) * 1970-09-29 1972-03-30 Ici Ltd Textilbehandlungsverfahren
GB2079328A (en) * 1980-07-03 1982-01-20 Sandoz Ltd Textile treatment process

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EP0204656A1 (fr) * 1985-05-14 1986-12-10 Ciba-Geigy Ag Procédé de teinture de matiére textile hydrophobe
DE3903926A1 (de) * 1989-02-10 1990-08-16 Henkel Kgaa Faerbereihilfsmittel
ES2115042T3 (es) * 1992-02-06 1998-06-16 Ciba Geigy Ag Procedimiento para teñir fibras naturales o sinteticas de poliamida.

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DE1519519A1 (de) * 1965-04-29 1970-01-15 Glanzstoff Ag Verfahren zum Faerben von Textilien aus Gemischen von Wolle und synthetischem Material
DE2148701A1 (de) * 1970-09-29 1972-03-30 Ici Ltd Textilbehandlungsverfahren
GB2079328A (en) * 1980-07-03 1982-01-20 Sandoz Ltd Textile treatment process

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Title
CHEMICAL ABSTRACTS, vol. 81, no. 14, 7. Oktober 1974 (1974-10-07) Columbus, Ohio, US; abstract no. 79299, NAMIKI, HIROSHI ET AL: "Dyeing textile fabrics composed of polyester fiber" XP002117834 & JP 48 042274 B (TEIJIN LTD.) 11. Dezember 1973 (1973-12-11) *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2794476A1 (fr) * 1999-06-07 2000-12-08 Rhodia Chimie Sa Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles
WO2000075416A1 (fr) * 1999-06-07 2000-12-14 Rhodia Chimie Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles
WO2013041810A1 (fr) * 2011-09-22 2013-03-28 Arcadophta Composition de coloration ophtalmique à toxicité réduite stable et pouvant être stérilisée
FR2980363A1 (fr) * 2011-09-22 2013-03-29 Arcadophta Composition a toxicite reduite d'au moins un colorant stable et pouvant etre sterilisee

Also Published As

Publication number Publication date
JPH10325086A (ja) 1998-12-08
US6099594A (en) 2000-08-08
CN1200421A (zh) 1998-12-02
CA2238259A1 (fr) 1998-11-26
EP0881324A3 (fr) 1999-12-01

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