CN1200421A - 合成纤维同时洗脱整理剂和染色的方法 - Google Patents
合成纤维同时洗脱整理剂和染色的方法 Download PDFInfo
- Publication number
- CN1200421A CN1200421A CN98108928A CN98108928A CN1200421A CN 1200421 A CN1200421 A CN 1200421A CN 98108928 A CN98108928 A CN 98108928A CN 98108928 A CN98108928 A CN 98108928A CN 1200421 A CN1200421 A CN 1200421A
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- Prior art keywords
- surfactant
- parts
- betaine
- synthetic fiber
- anion
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- 239000012209 synthetic fiber Substances 0.000 title claims abstract description 22
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- 235000007586 terpenes Nutrition 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 21
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 17
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- 150000004665 fatty acids Chemical class 0.000 claims abstract description 4
- 239000004094 surface-active agent Substances 0.000 claims description 116
- 239000003795 chemical substances by application Substances 0.000 claims description 30
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 23
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- 238000000034 method Methods 0.000 claims description 22
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- 150000001412 amines Chemical class 0.000 claims description 17
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- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 claims description 2
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- 244000060011 Cocos nucifera Species 0.000 description 4
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- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008186 active pharmaceutical agent Substances 0.000 description 2
- 150000001388 alpha-terpinene derivatives Chemical class 0.000 description 2
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
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- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 2
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- 239000003925 fat Substances 0.000 description 2
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- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 150000002729 menthone derivatives Chemical class 0.000 description 2
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 2
- 229940055577 oleyl alcohol Drugs 0.000 description 2
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 2
- 239000011297 pine tar Substances 0.000 description 2
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 229940116411 terpineol Drugs 0.000 description 2
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 2
- IIYFAKIEWZDVMP-UHFFFAOYSA-N tridecane Chemical compound CCCCCCCCCCCCC IIYFAKIEWZDVMP-UHFFFAOYSA-N 0.000 description 2
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 2
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- WUOACPNHFRMFPN-VIFPVBQESA-N (R)-(+)-alpha-terpineol Chemical compound CC1=CC[C@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-VIFPVBQESA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KKMIHKCGXQMFEU-UHFFFAOYSA-N 2-[dimethyl(tetradecyl)azaniumyl]acetate Chemical compound CCCCCCCCCCCCCC[N+](C)(C)CC([O-])=O KKMIHKCGXQMFEU-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
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- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
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- 241000018646 Pinus brutia Species 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
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- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
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- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
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- 238000001354 calcination Methods 0.000 description 1
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
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- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 125000000396 limonene group Chemical group 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- UTTVXKGNTWZECK-UHFFFAOYSA-N n,n-dimethyloctadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+](C)(C)[O-] UTTVXKGNTWZECK-UHFFFAOYSA-N 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- KPRZOPQOBJRYSW-UHFFFAOYSA-N o-hydroxybenzylamine Natural products NCC1=CC=CC=C1O KPRZOPQOBJRYSW-UHFFFAOYSA-N 0.000 description 1
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- 230000001590 oxidative effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- KIWATKANDHUUOB-UHFFFAOYSA-N propan-2-yl 2-hydroxypropanoate Chemical compound CC(C)OC(=O)C(C)O KIWATKANDHUUOB-UHFFFAOYSA-N 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 229950006451 sorbitan laurate Drugs 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000012192 staining solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001180 sulfating effect Effects 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 229940057402 undecyl alcohol Drugs 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
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Abstract
对用矿物油整理剂、硅油整理剂或这两种整理剂整理过的合成纤维和合成纤维纺织材料可以用一种溶液同时洗脱这些整理剂并染色,该溶液含有如下物料作为基本成分:a)阴离子和/或两性表面活性剂,b)染料,以及c)任意选自由非离子表面活性剂、萜烯烃类/醇类、山梨醇酯类和它们的烷氧基化合物、脂肪酸乙醇酰胺类、烷基聚苷类和溶剂组成的一类化合物。该处理在pH4.0—7.5,于80—110℃温度下并以浴比5∶1—100∶1的条件进行。
Description
本发明涉及对用矿物油整理剂、硅油整理剂或这两种整理剂整理过的合成纤维或合成纤维纺织材料同时进行整理剂洗脱和染色的一步工艺法。这一方法通过用含有如下物料作为基本成分的水溶液处理纤维或纺织材料而完成：a)一种或多种选自由阴离子和两性表面活性剂组成的一类表面活性剂，b)一种或多种染料以及c)任选还含有一种或多种选自由非离子表面活性剂、萜烯烃类、萜烯醇类及它们与低级羧酸的酯类、山梨醇酯类和它们的烷氧基化合物、脂肪酸乙醇酰胺类、烷基聚苷类和溶剂组成的一类化合物。该处理在pH范围4.0-7.5，最终温度范围80-110℃，以及浴比5∶1-100∶1条件下进行。
可按照本发明处理的合成纤维例子为聚酰胺纤维，例如锦纶-6(贝纶和其他)或锦纶6，6、聚酯纤维、聚氨基甲酸乙酯纤维和其他本专业普通技术人员已知的纤维、和它们相互或各自的混合纤维，以及它们与植物和动物来源的其他纤维的混合纤维。本发明的方法特别涉及聚酰胺类组成的纤维和聚氨基甲酸乙酯类所组成的纤维，并涉及它们各自或彼此的混合纤维，以及它们与植物及动物来源的纤维的混合纤维。特别优选的是聚酰胺、聚氨基甲酸乙酯或聚酰胺/聚氨基甲酸乙酯混合物组成的纤维。将合成纤维纺织材料搓捻，或经其它机械纺织处理纱线和制成针织品或纺织品。对某些用途，例如生产袜子，则使用例如含有聚氨基甲酸乙酯纤维和卷曲的或未卷曲的聚酰胺纤维的混合纱。
为了改进纤维及由此制得的纱线的加工性能，给它们提供一种整理剂，该整理剂随后也存在于由此制得的纺织材料上。对于合成纤维来说，整理剂常见的是一种矿物油或一种硅油。然而，这些油性整理剂由于引起明显的污斑而影响纤维、纱和纺织材料的染色。从而，必需在染色工艺之前通过洗涤除去矿物油或硅油整理剂。这种预洗涤原则上是已知的，并且在已知的设备中进行。这一分离洗涤的缺点主要是需时间较长(洗涤约80-90分钟)，需配置为此目的的分离设备，为这一工艺还需要工作人员，且产生必须排放的大量额外废水，以及在分离操作中为加热和冷却的能量消耗。染色工艺直至洗涤后才能进行，必须付出上述各项更新费用方能实施。
现已发现，如果所用的溶液包含有一种或多种选自由阴离子表面活性剂和两性表面活性剂组成的一类表面活性剂。并且还有任选一种或多种选自由非离子表面活性剂、萜烯烃类、萜烯醇类及它们与低级羧酸的酯类、山梨醇酯类和它们的烷氧基化合物、脂肪酸乙醇酰胺类、烷基聚苷类和溶剂组成的一类化合物，以及一种或多种染料，则可在同一时间，同一溶液，以一步法进行迄今的分离预洗涤和染色工艺。
因此，本发明提供了一种对用矿物油整理剂、硅油整理剂或这两种整理剂整理过的合成纤维或合成纤维纺织材料同时进行整理剂洗脱和染色的工艺方法，该方法包括用一种水溶液处理这些合成纤维或合成纤维纺织材料，该水溶液含有如下物料作为基本成分：
a)一种或多种选自由阴离子和两性表面活性剂组成的一类表面活性
剂，
b)一种或多种选自由酸性染料、金属配合物染料和分散染料组成的
一类染料，以及
c)任选一种或多种选自由非离子表面活性剂、萜烯烃类、萜烯醇类及它们与低级羧酸的酯类、山梨醇/甘露糖醇酯类及它们的烷氧基化合物、脂肪酸乙醇酰胺类、烷基聚苷类和溶剂组成物的一类化合物，处理时的pH范围为4.0-7.5，最终温度范围80-110℃，浴比为5∶1-100∶1。
因此，本发明的方法涉及使经整理剂处理而载有整理剂的合成纤维或纺织材料染色。在这一方法中，分离除去矿物油或硅油整理剂或这两种整理剂和染色仅在一种溶液中进行。本发明的方法在下文详细说明的条件下进行。
本发明方法合适的两性表面活性剂为含有C10-C22烃基的氧化胺、甜菜碱和磺基甜菜碱或它们的混合物。
优选的两性表面活性剂是下式的甜菜碱
其中X为单键或-CO-NH-(C2-C3烷基)-，以及R1和R2彼此独立地为氢、甲基或羟乙基。
这些甜菜碱包括下式此类化合物：氧化胺中，优选下式的此类化合物：其中X，R1和R2各自是如上所定义的。
特别优选的氧化胺是下式此类化合物：
合适甜菜碱(II)的具体例为：十二烷基-二甲基甜菜碱、椰子烷基-二甲基甜菜碱、十四烷基-二甲基甜菜碱、十八烷基-二甲基甜菜碱、牛油烷基-二甲基甜菜碱、油基-二甲基甜菜碱、椰子烷基-双-羟乙基甜菜碱、硬脂酰-双-羟乙基甜菜碱、牛油烷基-双-羟乙基甜菜碱。
合适氧化胺(IV)的具体例为：例如十二烷基-二甲基氧化胺、椰子烷基-二甲基氧化胺、十四烷基-二甲基氧化胺、十八烷基-二甲基氧化胺、牛油烷基-二甲基氧化胺、油基-二甲基氧化胺、椰子烷基-双-羟乙基氧化胺、硬脂酰-双-羟乙基氧化胺、牛油烷基-双-羟乙基氧化胺。
合适的阴离子表面活性剂例如为C10-C22链烷醇、链烯醇的硫酸化产物，或它们与1-50单元环氧乙烷(EO)，优选1-40单位EO的反应产物。这些硫酸化产品可以以碱金属、碱土金属、铵、胺或乙醇胺的盐类存在。其他的阴离子表面活性剂是C12-C18脂肪酸皂类、烷基磺酸盐和烷基苯磺酸(它们以上述盐的形式存在)。其他合适的阴离子表面活性剂是化学式为C8-C20烷(链烯)基-(O-CH2-CH2-)x-O-CH2-COO-M的聚醚类羧酸盐，其中x是2-30，优选为3-10，而M为一种上述成盐阳离子等价物。
上述各种两性和阴离子表面活性剂广泛地在纺织品处理的领域中使用，并为本领域的普通技术人员所公知。
通过使用上述两性和阴离子表面活性剂及进一步任选其他化合物，可以消除经整理剂处理的上述合成纤维或纺织材料上的矿物油、硅油或矿物/硅油整理剂，而不会影响同时进行对合成纤维或纺织材料的染色。实际上，意外地达到了高均匀度的染色。矿物油整理剂经常在聚酰胺和聚酯纤维的场合下使用，而硅油整理剂经常在聚氨基甲酸乙酯纤维的场合下使用。矿物油例如是粘度范围为10-40mPa.s的石蜡油；硅油例如是粘度范围为3-100mPa.s的M级油。已发现，阴离子表面活性剂消除矿物油整理剂较好，而两性表面活性剂对消除硅油整理剂较佳。从而，在混合纤维场合下，例如聚酰胺/聚氨基甲酸乙酯或聚酯/聚氨基甲酸乙酯，可以使用阴离子和两性表面活性剂的混合物。
处理溶液另外还包含有染料，优选酸性染料、金属配合物染料或分散染料。所有这些染料均为本领域普通技术人员已知的，不需作进一步说明。
处理溶液任选地还含有一种或多种选自由非离子表面活性剂、萜烯烃类、萜烯醇类及它们与低级羧酸，例如C1-C4羧酸，优选乙酸形成的酯类、山梨醇/甘露糖醇酯类及它们的烷氧基化合物、脂肪酸乙醇酰胺类、烷基聚苷类和溶剂组成的物类的化合物。
非离子表面活性剂例如是有9-13个碳的脂肪化学醇或羰基合成醇之类的醇，或脂肪化学胺或羧酸，它们已与3-10个单位EO并任选另加2-5个环氧丙烷(PO)反应过。在这些反应产物中，优选上述碳原子数的醇类。这些非离子表面活性剂是本领域普通技术人员已知的，从而不需作进一步说明。
萜烯烃例如是苎烯、橙萜烯、α-萜品烯、香脂萜品油B、二萜烯DS、二萜烯B、二萜烯A、苎烯DL、薄荷酮、松油70；有关萜烯醇类及其与低级羧酸的酯类，此处可提到的例如是松醇、乙酸萜品酯、萜品醇。山梨醇/甘露糖醇酯类例如是其与饱和或不饱和C12-C18脂肪酸形成的酯类；而例如它们与2-40单位EO和任选2-10单位PO形成的烷氧基化合物也是适用的。
脂肪酸乙醇酰胺具有例如一个12-18个碳原子的烷基。烷基聚苷具有例如一个8-12个碳原子的烷基。可能的溶剂例如为异丙醇、甲氧基丙醇和其他本领域普通技术人员已知的溶剂。
优选的聚醚羧酸酯例如是由工业产品级月桂醇(C12，含有直至C18的馏份)与4-8mol EO组成的羧甲基化乳化剂；优选的烷基聚苷具有8-10个碳原子；优选的阴离子表面活性剂是含0-40单位环氧乙烷的C12-C18烷基硫酸盐。优选的非离子表面活性剂为含3-10单位环氧乙烷的C9-C13醇。优选的脂肪酸乙醇酰胺为具有12-18个碳原子烷基的混合物。
本发明的处理染液使用化合物之量如下所述：
a)阴离子和/或两性表面活性剂的量为每升洗涤/染色溶液含0.05～2g，优选每升0.1～1g，当使用阴离子和两性表面活性剂两种时，其重量比为9∶1～1∶9。
b)对很宽范围内不同深浅色调而言，每升溶液含一种或多种染料0.01～1g，优选0.03～0.3g/l；
c)0-1g/l阳离子表面活性剂和/或0-1g/l萜烯烃/萜烯醇/其酯类和/或0-1g/l山梨醇酯/甘露糖醇酯/其烷氧基化合物和/或0-2g/l脂肪酸乙醇酰胺和/或0-1g/l烷基聚苷和/或0-2g/l溶剂。
如果可得到现成可用的表面活性剂a)和化合物c)的混合物/组合物，则该混合物/组合物的用量为每升溶液及染料中含0.5至3g。
以此为基础，例如两种批料中各组成如下(无染料)：
0.2g/l两性表面活性剂(I)或0.4g/l烷基聚苷
0.2g/1阴离子表面活性剂(I) 0.4g/1阴离子表面活性剂(I)
0.06g/l苎烯 0.2g/l脂肪酸单乙醇酰胺
0.06g/l非离子表面活性剂
0.06g/l溶剂 余量：水
余量：水
为了同时进行染色，本发明对载有整理剂的合成纤维或合成纤维纺织材料的处理是在pH范围4.0-7.5，最终温度范围80-110℃，并于浴比为5∶1-100∶1，优选5∶1-10∶1条件下进行的。可使用常规的设备，如平幅洗涤机、转筒染色机、棉布洗涤机和棉布染色机。最终温度在由室温加热后达到。所用的加热速率范围为0.5～8℃/分钟。
在处理溶液和一种或多种染料中使用的优选表面活性剂a)和化合物c)的组合物为：
(i)甜菜碱或氧化胺、阴离子表面活性剂、一种或多种非离子表面活性剂，以及加有或未加萜烯烃/醇和加有或未加溶剂，或
(ii)甜菜碱或氧化胺、阴离子表面活性剂、一种或多种非离子表面活性剂，以及加有或未加脂肪酸乙醇酰胺。实施例实施例1-41和I-IV
根据本发明同时染色用的新的表面活性剂a)和化合物c)的组合物(此处为初步实验、不含染料)；表中最后一栏报导了与未处理的原料相比，用本发明溶液处理后留存的残余整理剂含量(即石油醚(PE)提取物)。原料为聚酰胺/聚氨基甲酸乙酯混合纤维织成的短袜。实施例I-IV使用了具有不同原始整理剂含量的原材料，并列出了留存的整理剂含量。所列出的组合物是以重量份数计或以％(重量)计的浓缩物。各种浓缩物以每升洗涤液1g之量使用。
表中名称的索引：
甜菜碱1＝式(II)的牛油-双(羟乙基)甜菜碱
表面活性剂A＝含15mol EO的十六烷基氨甲基酚
表面活性剂B＝含30mol EO的C12-C18醇，硫酸化的钠盐
表面活性剂C＝含3mol EO的异十三烷醇和含9mol EO的异十三烷
醇混合物
甜菜碱2＝二甲基椰子胺与ClCH2COONa反应形成的式(II)甜菜
碱
表面活性剂D＝含11mol EO的羧甲基化月桂醇
表面活性剂E＝含4mol EO的异十三烷醇
表面活性剂F＝十二烷基苯磺酸，钙盐(33份正丁醇中含67份)
表面活性剂G＝含6mol EO的羧甲基化月桂醇
表面活性剂H＝在环己醇/甲氧基丙醇中的十二烷基硫酸氨基乙醇盐
表面活性剂I＝聚醚硅氧烷(来自Th.Goldschmidt的Tegopren 5878)表面活性剂J＝烷基聚苷表面活性剂K＝Marlowet 1072表面活性剂L＝含6mol PO的乙基己醇表面活性剂M＝含5mol EO和含7mol EO的月桂醇羧甲基化混合物
(1∶1)表面活性剂N＝分别含5mol EO和5mol PO的壬/十一醇表面活性剂O＝Glucopon(浓度65％)表面活性剂P＝C12-C18脂肪酸单乙醇酰胺DAS＝洗涤活性物质
洗袜组合物
实施例42短袜染色(现有方法)材料：聚酰胺/聚氨基甲酸乙酯机器：具有液体注入器和700升液体容量的转鼓染色机(Drll &
| 实施例No. | 由表面活性剂a)和化合物c)组成 | 短袜PE提取物 |
| I原材料 | 2.42 | |
| 1 | 2.6份乳酸，64份甜菜碱，8份甲氧基丙醇，8份苎烯，16份表面活性剂A，1.4份H2O | 1.66 |
| 2 | 1.3份乳酸，64份甜菜碱，8份甲氧基丙醇，8份苎烯，16份表面活性剂A，2.7份H2O | 1.76 |
| 3 | 17.6份苎烯，30.3份甜菜碱，10.1份甲氧基丙醇，30.3份表面活性剂B，1.6份乳酸，10.1份表面活性剂A | 1.74 |
| 4 | 5.6份橙萜烯，16.7份甜菜碱，5.6份甲氧基丙醇，16.7份表面活性剂B，5份乳液，5.6份表面活性剂C，44.8份H2O | 1.59 |
| 5 | 5.7份乙酸萜品酯K，17份甜菜碱，5.7份甲氧基丙醇，17份表面活性剂B，4份乳酸，5.7份表面活性剂C，44.9份H2O | 1.41 |
| 6 | 5.8份α-萜品烯，17.3份甜菜碱，5.8份甲氧基丙醇，17.3份表面活性剂B，2.2份乳酸，5.8份表面活性剂C，45.8份H2O | 1.36 |
| 7 | 5.7份香脂萜品油B，17.2份甜菜碱，5.7份甲氧基丙醇，17.2份表面活性剂B，2.5份乳酸，5.7份表面活性剂C，46.0份H2O | 1.33 |
| 8 | 5.8份二聚戊烯DS，17.3份甜菜碱，5.8份甲氧基丙醇，17.3份表面活性剂B，2.2份乳酸，5.8份表面活性剂C，45.8份H2O | 1.35 |
| 9 | 5.6份二聚戊烯B，16.7份甜菜碱，5.6份甲氧基丙醇，16.7份表面活性剂B，5份乳酸，5.6份表面活性剂C，44.8份H2O | 1.35 |
| 实施例No. | 由表面活性剂a)和化合物c)组成 | 短袜PE提取物 |
| 10 | 5.8份二聚戊烯A，17.3份甜菜碱，5.8份甲氧基丙醇，17.3份表面活性剂B，2.2份乳酸，5.8份表面活性剂C，45.8份H2O | 1.30 |
| 11 | 5.7份苎烯DL，17.2份甜菜碱，5.7份甲氧基丙醇，17.2份表面活性剂B，2.5份乳酸，5.7份表面活性剂C，46.0份H2O | 1.26 |
| 12 | 5.7份橙油萜烯，17.2份甜菜碱，5.7份甲氧基丙醇，17.2份表面活性剂B，2.5份乳酸，5.7份表面活性剂C，46.0份H2O | 0.99 |
| 13 | 5.4份薄荷酮，17份甜菜碱，5.4份甲氧基丙醇，17份表面活性剂B，7.6份乳酸，5.7份表面活性剂C，43.1份H2O | 1.24 |
| 14 | 5.4份松油70C，16.3份甜菜碱，5.4份甲氧基丙醇，16.3份表面活性剂B，7.8份乳酸，5.4份表面活性剂C，43.4份H2O | 1.52 |
| 15 | 5.4份萜品醇，16.3份甜菜碱，5.4份甲氧基丙醇，16.3份表面活性剂B，7.8份乳酸，5.4份表面活性剂C，43.4份H2O | 1.58 |
| II原材料 | 3.76 | |
| 16 | 19.7份甜菜碱2，5.9份甲氧基丙醇，5.9份苎烯，17.6份表面活性剂B，5.9份表面活性剂C，45.0份H2O | 1.58 |
| III原材料 | 5.35 | |
| 16a | 19.7份甜菜碱2，5.9份甲氧基丙醇，5.9份苎烯，17.6份表面活性剂B，5.9份表面活性剂C，45.0份H2O | 2.08 |
| No. | 组合 | 所用的g/l | PE提取物％ | 除去的Si％ |
| pH4.5/98℃染液 | ||||
| 17 | 50％表面活性剂D，50％表面活性剂E | 0.84DAS | 1.43 | |
| 18 | 50％表面活性剂D，50％表面活性剂F | 0.84DAS | 1.37 | |
| 19 | 41.7％表面活性剂D，41.7％表面活性剂E，13.3％矿物油(来自Esso)，3.3％聚二甲基硅氧烷 | 0.84DAS | 1.54 | |
| 20 | 50％表面活性剂G，50％表面活性剂F | 0.84DAS | 1.56 | |
| 21 | 50％表面活性剂E，50％表面活性剂H | 0.84DAS | 1.65 | |
| 22 | 50％表面活性剂I，50％表面活性剂H | 0.84DAS | 1.35 | |
| 23 | 50％表面活性剂J，50％表面活性剂H | 0.84DAS | 1.22 | |
| 24 | 50％表面活性剂D，50％表面活性剂F(重复No.18) | 0.84DAS | 1.56 | |
| 25 | 8％脱水山梨醇月桂酸酯，8％表面活性剂D，4％月桂酸钠，8％异丙醇，H2O(72％) | 0.84DAS | 1.66 | |
| 26 | 8％脱水山梨醇硬脂酸酯，8％表面活性剂D，4％月桂酸钠，8％异丙醇，H2O(72％) | 0.84DAS | 1.53 | |
| 27 | 44.1％表面活性剂E，44.1％表面活性剂H，11.8％工业月桂醇(C12-C18) | 0.84DAS | 1.71 | |
| 28 | 28.6％脱水山梨醇油酸酯，28.6％表面活性剂D，14.3％月桂酸钠，28.6％表面活性剂H | 0.84DAS | 1.94 | |
| 29 | 30.8％脱水山梨醇油酸酯，30.8％表面活性剂K，15.4％月桂酸钠，15.4％表面活性剂L，7.7％乳酸异丙酯 | 0.84DAS | 2.28 | |
| No. | 组合 | 所用的g/l | PE提取物％ | 除去的Si％ |
| 30 | 50％表面活性剂M，50％表面活性剂F | 0.84DAS | 1.29 | |
| 31 | 66.7％表面活性剂M，33.3％表面活性剂F(50％表面活性剂M转换) | 0.84DAS | 1.40 | |
| 32 | 29.1％脱水山梨醇油酸酯，29.1％表面活性剂K，14.5％月桂酸钠，18.2％表面活性剂N，H2O(9.1％) | 0.84DAS | 1.76 | |
| 33 | 表面活性剂M | 0.84DAS | 1.50 | |
| 34 | 66.7％表面活性剂M，33.3％表面活性剂F(62％表面活性剂M转换) | 0.84DAS | 1.41 | |
| 35 | 80％表面活性剂M，20％表面活性剂F | 0.84DAS | 1.41 | |
| pH4.5/80℃预洗涤 | ||||
| 2.45 | ||||
| IV原材料 | ||||
| 36 | 氧化十八基二甲胺，在异丙醇/H2O中40％浓度 | 1 | 1.08 | 84 |
| 37 | 月桂基二甲胺甜菜碱，软化处理的水中22％浓度 | 1 | 1.4 | 67 |
| 38 | 16.5％氧化月桂基二甲胺/25％表面活性剂L/58.5％H2O | 1 | 1.67 | 69 |
| 39 | 19.5％十八基二甲胺甜菜碱/19.5％异丁醇/3.2％NaCl/57.8％H2O/异丙醇混合物 | 1 | 1.24 | 81 |
| 40 | 40％表面活性剂O/40％表面活性剂H/20％表面活性剂P | 1 | 1.61 | 86 |
| 41 | 20％表面活性剂O/60％表面活性剂H/20％表面活性剂L | 1 | 1.53 | 74 |
Lohmann)浴比：按70kg材料计为10∶1预洗涤：
1g/l表面活性剂N
1g/l煅烧的碳酸钠
起始温度：25℃
升温速率：4℃/分
最高温度：80℃
处理时间：15′
溶液排放
于40℃的第一冲洗槽
排液/抛干
于40℃的第二冲洗槽
排液/抛干
总时间：80-90分钟染色：
0.5g/l含矿物油的消泡剂混合物
1g/l牛油磺酸盐，Na盐，含19 EO的油醇
4％由含15 EO的烷基氨甲基酚和壬基酚、甲醛，和六亚甲基二胺
与60mol EO的缩合物组成的匀染剂
0.5g/l硫酸二氢钠
}pH6.5
0.25ml/l 80％乙酸
0.004％ Telon黄色或A.Y.240或A.Y.242＝黄A3RL 3RL micro
0.002％ Telon 红 FRL micro A.R.337 A.R.299＝宝石红 ASB
0.0021％ Telon 兰 BRL micro A.B.324 A.B.264＝兰 AFN
起始温度：25℃
加热速率：1℃/分
}73分钟
最高温度：98℃
在98℃染色时间：30分，+30分
冷却、排出染液、漂洗、为改进牢度可能进行的后处理、整理。
总时间：103-120分钟实施例43短袜染色(本发明方法)
材料：聚酰胺/聚氨基甲酸乙酯
机器：具有液体注入器和700升液体容量的转鼓染色机(Drll &
Lohmann)
浴比：以70kg材料计为10∶1洗涤和染色(同一染液)
1g/l本发明实施例16的组合物
0.5g/l含矿物油的消泡剂混合物
1g/l牛油磺酸钠盐，含有19EO的油醇
4％实施例42的匀色剂
0.5g/l磷酸二氢钠
0.25ml/l 80％乙酸
0.004％Telon 黄 3RL micro
0.002％ Telon 红 FRL micro
0.0021％ Telon 兰 BRL micro
起始温度：25℃
加热速率：1℃/分
最高温度：98℃
98℃时染色时间：30分，+30分
冷却、排液、漂洗、改进牢度可能进行的后处理、整理。
总时间：103-120分；省去80-90分
Claims (7)
1.一种对用矿物油整理剂、硅油整理剂或两种整理剂整理过的合成纤维或合成纤维纺织材料同时洗脱整理剂和染色的方法，该方法包括用如下物料作为基本成分的一种水溶液处理这些合成纤维或合成纤维纺织材料：
a)一种或多种选自由阴离子和两性表面活性剂组成的一类表面活性
剂，
b)一种或多种选自由酸性染料、金属配合物染料和分散染料组成的
一类染料，以及
c)任意一种或多种选自由非离子表面活性剂、萜烯烃类、萜烯醇类、
山梨醇/甘露糖醇酯类和它们的烷氧基化合物、脂肪酸乙醇酰胺、
烷基聚苷和溶剂组成的一类化合物，该处理在pH范围4.0-7.5，最终温度范围80-110℃以及浴比5∶1-100∶1条件下进行。
2.权利要求1所述的方法，其中所用浴比范围为5∶1-10∶1。
3.权利要求1所述的方法，其中所用的两性表面活性剂为下式的甜菜碱：其中X为单键或-CO-NH-(C2-C3烷基)-，而R1和R2彼此独立地为氢、甲基或羟乙基。
4.权利要求3所述的方法，其中使用下式的甜菜碱作为两性表面活性剂：
5.权利要求1所述的方法，其中所用的两性表面活性剂是一种如下式的氧化胺：
其中X，R1和R2各自是如权利要求3所定义的。
6.权利要求5的方法，其中使用下式的一种氧化胺：
7.权利要求1所述的方法，其中水溶液除染料外还包含有如下表面活性剂a)和化合物c)的组合物之一种：
(i)甜菜碱或氧化胺类、阴离子表面活性剂、一种或多种非离子
表面活性剂以及加有或未加萜烯烃/醇和加有或未加溶剂，或
(ii)甜菜碱或氧化胺类、阴离子表面活性剂、一种或多种非离子
表面活性剂以及加有或未加脂肪酸乙醇酰胺，
(iii)阴离子表面活性剂、一种或多种非离子表面活性剂以及加有
或未加脂肪酸乙醇酰胺。
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19721906.3 | 1997-05-26 | ||
| DE19721906 | 1997-05-26 | ||
| DE19736923.5 | 1997-08-25 | ||
| DE19736923A DE19736923A1 (de) | 1997-05-26 | 1997-08-25 | Verfahren zum gleichzeitigen Avivage-Entfernen und Einfärben von Synthesefasern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1200421A true CN1200421A (zh) | 1998-12-02 |
Family
ID=26036832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98108928A Pending CN1200421A (zh) | 1997-05-26 | 1998-05-25 | 合成纤维同时洗脱整理剂和染色的方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US6099594A (zh) |
| EP (1) | EP0881324A3 (zh) |
| JP (1) | JPH10325086A (zh) |
| CN (1) | CN1200421A (zh) |
| CA (1) | CA2238259A1 (zh) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2794476B1 (fr) * | 1999-06-07 | 2001-11-16 | Rhodia Chimie Sa | Utilisation de derives terpeniques polyalcoxyles dans le traitement de fibres textiles |
| US6500215B1 (en) | 2000-07-11 | 2002-12-31 | Sybron Chemicals, Inc. | Utility of selected amine oxides in textile technology |
| US6602304B2 (en) | 2001-05-16 | 2003-08-05 | James Jung | Dye-accelerant composition and process for using same |
| FR2980363B1 (fr) * | 2011-09-22 | 2014-11-28 | Arcadophta | Composition a toxicite reduite d'au moins un colorant stable et pouvant etre sterilisee |
| CN103205903A (zh) * | 2013-03-14 | 2013-07-17 | 浙江理工大学 | 一种可见光响应自清洁催化纤维及制备方法 |
| TWI586714B (zh) * | 2016-06-24 | 2017-06-11 | 萬能學校財團法人萬能科技大學 | 一種尼龍纖維材料的染色組成物及使用其之染色程序 |
| CN112458769A (zh) * | 2020-11-16 | 2021-03-09 | 五邑大学 | 一种纯棉染色面料复染剂及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1519519A1 (de) * | 1965-04-29 | 1970-01-15 | Glanzstoff Ag | Verfahren zum Faerben von Textilien aus Gemischen von Wolle und synthetischem Material |
| GB1335984A (en) * | 1970-09-29 | 1973-10-31 | Ici Ltd | Treatment of textile materials |
| JPS4842274B1 (zh) * | 1970-10-01 | 1973-12-11 | ||
| IT1209873B (it) * | 1980-07-03 | 1989-08-30 | Sandoz Ag | Procedimento per la sbozzimatura ela tintura simultanee di materie tessili con coloranti reattivi |
| EP0204656A1 (de) * | 1985-05-14 | 1986-12-10 | Ciba-Geigy Ag | Verfahren zum Färben von hydrophobem Fasermaterial |
| DE3903926A1 (de) * | 1989-02-10 | 1990-08-16 | Henkel Kgaa | Faerbereihilfsmittel |
| DE59308190D1 (de) * | 1992-02-06 | 1998-04-09 | Ciba Geigy Ag | Verfahren zum Färben von natürlichen oder synthetischen Polyamidfasern |
-
1998
- 1998-05-14 EP EP98108748A patent/EP0881324A3/de not_active Withdrawn
- 1998-05-20 US US09/081,757 patent/US6099594A/en not_active Expired - Fee Related
- 1998-05-21 JP JP10155404A patent/JPH10325086A/ja active Pending
- 1998-05-22 CA CA002238259A patent/CA2238259A1/en not_active Abandoned
- 1998-05-25 CN CN98108928A patent/CN1200421A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0881324A2 (de) | 1998-12-02 |
| EP0881324A3 (de) | 1999-12-01 |
| JPH10325086A (ja) | 1998-12-08 |
| CA2238259A1 (en) | 1998-11-26 |
| US6099594A (en) | 2000-08-08 |
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