EP0854763B1 - Verfahren zur herstellung einer intermetallischen verbindung - Google Patents
Verfahren zur herstellung einer intermetallischen verbindung Download PDFInfo
- Publication number
- EP0854763B1 EP0854763B1 EP96945136A EP96945136A EP0854763B1 EP 0854763 B1 EP0854763 B1 EP 0854763B1 EP 96945136 A EP96945136 A EP 96945136A EP 96945136 A EP96945136 A EP 96945136A EP 0854763 B1 EP0854763 B1 EP 0854763B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reinforcing member
- intermetallic
- alfin
- aluminium
- join
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 229910002804 graphite Inorganic materials 0.000 claims description 12
- 239000010439 graphite Substances 0.000 claims description 12
- 229910001018 Cast iron Inorganic materials 0.000 claims description 10
- 230000003014 reinforcing effect Effects 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 4
- 238000005266 casting Methods 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims 3
- 238000007654 immersion Methods 0.000 claims 1
- 239000000155 melt Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005087 graphitization Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000027455 binding Effects 0.000 description 2
- 238000009739 binding Methods 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F7/00—Casings, e.g. crankcases or frames
- F02F7/0085—Materials for constructing engines or their parts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
- F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
- F05C2201/00—Metals
- F05C2201/02—Light metals
- F05C2201/021—Aluminium
Definitions
- the invention is concerned with a method of manufacture an intermetallic connection between an engine component made of an aluminum-based alloy and one Reinforcing part made of austenitic cast iron, the casting technology be connected to each other. Appropriate procedures are particularly isolated for the introduction of ring carriers also for inserting trough edge reinforcements in diesel engines applied.
- the invention is therefore concerned with the problem that Strength of the intermetallic bond between the casting and Reinforcement part regardless of the use of a GGG or GGL material to increase.
- An essential area of application for the invention lies in the production of pistons with reinforcement parts austenitic cast iron, with the reinforcement parts are preferably ring bearers.
- the glow of the reinforcement parts must be in an oven atmosphere with oxidizing and reducing components, about the emergence of concentration differences through Diffusion of the nickel to the surface and the formation of To avoid iron oxides on the surface as much as possible a surface thus formed in the subsequent process steps is disturbing.
- a reinforcement part made of austenitic cast material 1 with lamellar graphite formation is connected to a piston material AlSi12CuNiMg 2 by an Alfin layer 3.
- the austenitic cast material is edge-graphitized in the area of the alfin bond to a depth of approx. 100-150 ⁇ m.
- the de-graphitization is carried out by annealing the cast material in exogas, at temperatures of at least 800 ° C and preferably at temperatures> 1000 ° C.
- the CO 2 and CO content and the dew point must be set so that there is a good decarburizing effect in order to achieve short annealing times. In the present case, the glow time was 25 minutes.
- Alfin layer 3 are in place of the compact graphite flakes only loosened up, not coherent, pearl-cord-shaped Detect oxides that affect strength the Alfin layer is not, or at least significantly less impact as the graphite flakes of an unannealed austenitic cast iron.
- FIG. 2 A conventional alfin layer is shown in FIG. 2 only for comparison shown.
- the Alfin layer 4 is clear there recognizably interspersed with graphite lamellae that bind the alfin weaken because they act as defects.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19537847A DE19537847A1 (de) | 1995-10-11 | 1995-10-11 | Bewehrungsteil, dessen Grundwerkstoff austenitisches Gußeisen ist |
DE19537847 | 1995-10-11 | ||
PCT/DE1996/001808 WO1997013597A2 (de) | 1995-10-11 | 1996-09-20 | Verfahren zur herstellung einer intermetallischen verbindung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0854763A2 EP0854763A2 (de) | 1998-07-29 |
EP0854763B1 true EP0854763B1 (de) | 1999-09-01 |
Family
ID=7774578
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96945136A Expired - Lifetime EP0854763B1 (de) | 1995-10-11 | 1996-09-20 | Verfahren zur herstellung einer intermetallischen verbindung |
Country Status (6)
Country | Link |
---|---|
US (1) | US6112802A (ja) |
EP (1) | EP0854763B1 (ja) |
JP (1) | JPH11514931A (ja) |
BR (1) | BR9610925A (ja) |
DE (2) | DE19537847A1 (ja) |
WO (1) | WO1997013597A2 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU773579B2 (en) * | 2000-08-10 | 2004-05-27 | Breville Pty Ltd | Improvements in forming metallic laminates |
DE10103596A1 (de) * | 2001-01-26 | 2002-08-01 | Bruehl Eisenwerk | Verfahren zur Herstellung eines aus wenigstens zwei unterschiedlichen Metallwerkstoffen gebildeten Gußwerkstücks |
DE10103896A1 (de) * | 2001-01-30 | 2002-08-08 | Mahle Gmbh | Verfahren zur Vorbehandlung eines Ringträgers vor dem Alfinieren |
DE10137436C2 (de) * | 2001-07-31 | 2003-07-31 | Ks Kolbenschmidt Gmbh | Voralfinieren von Eingußteilen |
DE10153306B4 (de) * | 2001-10-31 | 2010-07-15 | Daimler Ag | Verfahren zum Eingießen eines Einlegeteils |
DE10157478A1 (de) * | 2001-11-23 | 2003-06-05 | Fne Gmbh | Metall-Verbundwerkstoff und Verfahren zur Herstellung eines Metall-Verbundwerkstoffs |
DE10205798A1 (de) * | 2002-02-13 | 2003-09-04 | Federal Mogul Wiesbaden Gmbh | Einsatzteil in ein Ober-und/oder Unterteil oder eine Versteifungsrippe eines Lagerstuhls |
AU2003208246A1 (en) * | 2002-03-18 | 2003-09-29 | Karl Merz | Method and device for the alfin processing of components |
DE102012011992A1 (de) * | 2012-06-16 | 2013-12-19 | Volkswagen Aktiengesellschaft | Metallisches Gussbauteil und Verfahren zur Herstellung eines metallischen Gussbauteils |
DE102012220645B3 (de) * | 2012-11-13 | 2014-04-03 | Federal-Mogul Nürnberg GmbH | Kolben für einen Verbrennungsmotor und Verfahren zu dessen Herstellung |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1048677B (de) * | 1959-01-15 | Mahle-Werk Gesellschaft mit be schrankter Haftung, Fellbach (Wurtt) | Verfahren zum Aufbringen eines Aluminium- bzw Alummiumoxyduberzuges auf aus einer Eisenlegierung - z B Gußeisen - bestehende und mit Leichtmetall im Druckgießverfahren zu umgießende Em lagestucke | |
US2620530A (en) * | 1945-02-07 | 1952-12-09 | United Engine & Machine Co | Manufacture of pistons |
DE901104C (de) * | 1949-11-10 | 1954-01-07 | Fairchild Engine And Airplane | Verbundgussstueck und Verfahren zu dessen Herstellung |
US2550879A (en) * | 1949-11-10 | 1951-05-01 | Fairchild Engine & Airplane | Bimetallic piston |
US2775493A (en) * | 1953-11-27 | 1956-12-25 | Gillett & Eaton Inc | Piston with head insert and process of making it |
JPS5125214B2 (ja) * | 1973-02-09 | 1976-07-29 | ||
CH645562A5 (en) * | 1980-06-19 | 1984-10-15 | Sulzer Ag | Process for welding workpieces of nodular cast iron |
JPS59185567A (ja) * | 1983-04-08 | 1984-10-22 | Usui Internatl Ind Co Ltd | 接着結合してなる鋳鉄部材の前処理方法 |
IT1183114B (it) * | 1985-01-11 | 1987-10-05 | Ass Eng Italia | Pistone d'alluminio o di lega d'alluminio per motori a combustione interna |
SU1507532A1 (ru) * | 1987-10-13 | 1989-09-15 | Научно-исследовательский институт автотракторных материалов | Способ изготовлени отливок поршн из алюминиевого сплава с чугунной вставкой |
DE4010474A1 (de) * | 1990-03-31 | 1991-10-02 | Kolbenschmidt Ag | Leichtmetallkolben |
DE4019983A1 (de) * | 1990-06-22 | 1992-01-02 | Kolbenschmidt Ag | Leichtmetallkolben |
US5333668A (en) * | 1991-12-09 | 1994-08-02 | Reynolds Metals Company | Process for creation of metallurgically bonded inserts cast-in-place in a cast aluminum article |
DE4221448A1 (de) * | 1992-06-30 | 1994-01-13 | Mahle Gmbh | Bewehrungsmaterial für Kolben von Verbrennungsmotoren |
-
1995
- 1995-10-11 DE DE19537847A patent/DE19537847A1/de not_active Withdrawn
-
1996
- 1996-09-20 WO PCT/DE1996/001808 patent/WO1997013597A2/de active IP Right Grant
- 1996-09-20 DE DE59602965T patent/DE59602965D1/de not_active Expired - Fee Related
- 1996-09-20 US US09/051,050 patent/US6112802A/en not_active Expired - Fee Related
- 1996-09-20 EP EP96945136A patent/EP0854763B1/de not_active Expired - Lifetime
- 1996-09-20 JP JP9514613A patent/JPH11514931A/ja active Pending
- 1996-09-20 BR BR9610925A patent/BR9610925A/pt not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
Technische Mitteilungen,Heft 8,49.Jahrgang,aug.1956,Seiten 381-384: Uber das al-Fin-Verfahren Erfahrungen und Verwendungen, von Dipl.Phys. W.Thiele,Frankfurt a.M. * |
Also Published As
Publication number | Publication date |
---|---|
WO1997013597A2 (de) | 1997-04-17 |
EP0854763A2 (de) | 1998-07-29 |
JPH11514931A (ja) | 1999-12-21 |
BR9610925A (pt) | 1999-06-29 |
WO1997013597A3 (de) | 1997-06-05 |
DE59602965D1 (de) | 1999-10-07 |
DE19537847A1 (de) | 1997-04-17 |
US6112802A (en) | 2000-09-05 |
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