Classifications

• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
  • C07C63/14—Monocyclic dicarboxylic acids
  • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
  • C07C63/26—1,4 - Benzenedicarboxylic acid
  • C07C63/28—Salts thereof
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
  • C07C55/02—Dicarboxylic acids
  • C07C55/08—Malonic acid
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
  • C07C55/02—Dicarboxylic acids
  • C07C55/10—Succinic acid
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
  • C07C55/02—Dicarboxylic acids
  • C07C55/14—Adipic acid
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
  • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
  • C07C57/13—Dicarboxylic acids
  • C07C57/145—Maleic acid
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
  • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
  • C07C57/13—Dicarboxylic acids
  • C07C57/15—Fumaric acid
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
  • C07C63/14—Monocyclic dicarboxylic acids
  • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
  • C07C63/16—1,2 - Benzenedicarboxylic acid
  • C07C63/20—Salts thereof
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
  • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
  • C07C63/14—Monocyclic dicarboxylic acids
  • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
  • C07C63/24—1,3 - Benzenedicarboxylic acid
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
  • C08K3/20—Oxides; Hydroxides
  • C08K3/22—Oxides; Hydroxides of metals

Definitions

• the invention relates to basic
• Calcium aluminum hydroxide dicarboxylates a process for their preparation and their use as stabilizers for halogen-containing thermoplastic resins, in particular polyvinyl chloride.
• Thermoplastic, halogen-containing resins, especially PVC, are unstable to the effects of heat and light. So occurs already in the processing of z. B.
• costabilizers such as epoxies, organic sulfur compounds, polyols and phosphites are also added.
• Basic lead compounds are preferably used to stabilize PVC items such as pipes, plates, profiles and cable insulation.
• the most common basic lead compounds are of the sulfate, phosphite or stearate type.
• DE-PS 12 19 223 and DE-OS 24 19 379 teach that PVC cable insulation preferably with 2-basic
• Lead phthalate must be stabilized as this connection gives the cable excellent electrical properties.
• EP-A-0 313 113 mentions that 4-basic
• Lead fumarate is the most effective basic lead compound for stabilizing soft-set halogen-containing vinyl polymer compositions. According to EP-A-0 319 086, 5-basic lead fumarate gives PVC moldings greater stability and a better degree of whiteness than other known ones
• EP-A-0256 872 describes the use of hydrotalkite and a ⁇ -diketone for the stabilization of PVC resins. It was too
• Stabilization systems however, have disadvantages compared to stabilizers containing heavy metals. In this way, they usually do not achieve the required long-term stability. A good initial color and sufficient color retention can only be achieved by using large amounts of expensive "color improvers".
• the metal-containing costabilizers are disadvantages compared to stabilizers containing heavy metals. In this way, they usually do not achieve the required long-term stability. A good initial color and sufficient color retention can only be achieved by using large amounts of expensive "color improvers".
• Hydrotalkite and zeolite are disadvantageous in that they are used in the processing of e.g. PVC necessary processing temperatures split off volatile components, which leads to the formation of bubbles in the molded part. Furthermore, e.g. Polyol and / or zeolite stabilized PVC moldings water, which leads to considerable problems in further processing.
• the invention has for its object to provide new compounds and a process for their preparation, which are particularly suitable as a stabilizer for halogen-containing polymers, without having the above-mentioned disadvantages of the known stabilizers, in particular as non-toxic.
• A is an aliphatic, aromatic or
• x is preferably 3-6 and m is preferably 2-4.
• the dicarboxylic acid anions indicated with A are derived, for example, from malonic acid, succinic acid,
• Adipic acid fumaric acid, maleic acid, phthalic acid,
• Isophthalic acid, terephthalic acid and pyridinedicarboxylic acids are preferred.
• the fumarate and phthalate anions are preferred
• Calcium aluminum hydroxide dicarboxylates according to the invention give halogen-containing, thermoplastic resins and the molded parts produced therefrom, heat stability comparable to that of basic lead compounds.
• the initial colors and the color retention of e.g. Rigid PVC moldings that are stabilized with one of the new compounds according to the invention are the same moldings that are known
• the reaction product can be separated from the aqueous reaction medium by known methods, preferably by filtration. Working up the separated
• the reaction product also takes place in a manner known per se, for example by washing the filter cake with water and drying the washed residue
• Both a finely divided, active aluminum hydroxide in combination with sodium hydroxide and a sodium aluminate can be used for the reaction.
• Calcium can be used in the form of finely divided calcium oxide or hydroxide or mixtures thereof.
• reaction temperatures are preferably between about 25 and 100.degree. C., more preferably between about 40 and 85.degree. C.
• Catalysts or accelerators are not required, but can be used if appropriate.
• the water of crystallization can be wholly or partly by thermal
• Compounds are coated in a known manner with surface-active agents.
• Calcium aluminum hydroxide dicarboxylates, halogen-containing, thermoplastic resins can be stabilized. Manufactured in a known manner are particularly suitable for this
• organotin compounds organic phosphites
• organic phosphites examples of such additives are: organotin compounds, organic phosphites,
• Plasticizers pigments and fillers. The invention is illustrated by the examples below.
• the mixtures used in the following examples are homogenized and plasticized on a laboratory rolling mill at 180 ° C. for 5 minutes.
• the approximately 1 mm thick skin thus produced becomes 15 mm square sample sheets
• Cut edge length The sample sheets are annealed in a warming cabinet at 190 °. One leaflet is taken every 10 minutes and attached to a test card. This process is repeated until the test leaves are discolored black.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Applications Claiming Priority (2)

Publications (1)

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• 1990
  • 1990-02-01 DE DE4002988A patent/DE4002988A1/de active Granted
• 1991
  • 1991-01-07 US US07/916,106 patent/US5241094A/en not_active Expired - Fee Related
  • 1991-01-17 JP JP3503062A patent/JPH05503931A/ja active Pending
  • 1991-01-17 EP EP91903195A patent/EP0513087A1/de not_active Withdrawn
  • 1991-01-17 CA CA002074821A patent/CA2074821A1/en not_active Abandoned
  • 1991-01-17 WO PCT/EP1991/000077 patent/WO1991011421A1/de not_active Application Discontinuation
  • 1991-01-17 KR KR1019920701803A patent/KR927003502A/ko not_active Application Discontinuation
  • 1991-01-17 AU AU70727/91A patent/AU7072791A/en not_active Abandoned
  • 1991-01-22 ZA ZA91458A patent/ZA91458B/xx unknown
  • 1991-01-29 CS CS91200A patent/CS20091A2/cs unknown
  • 1991-01-31 PT PT96618A patent/PT96618A/pt unknown
  • 1991-01-31 IE IE032991A patent/IE910329A1/en unknown
  • 1991-02-01 CN CN91101125A patent/CN1054417A/zh active Pending

Non-Patent Citations (1)

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