Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/0005—Other compounding ingredients characterised by their effect
  • C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/26—Organic compounds containing nitrogen
  • C11D3/32—Amides; Substituted amides
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/39—Organic or inorganic per-compounds
  • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
  • C11D3/3905—Bleach activators or bleach catalysts
  • C11D3/3907—Organic compounds
  • C11D3/3917—Nitrogen-containing compounds
  • C11D3/3927—Quarternary ammonium compounds

Definitions

• the present invention relates to a bleach or bleaching detergent composition containing a bleach activator having a cationic group.
• a chlorinated bleaching agent has disadvantages in that the fibers to which it is applicable are limited, i.e., it is not applicable to colored or patterned soft goods, materials, cloths, fabrics and the like, and that it has a peculiar odor, so that an oxygenic bleaching agent free from these disadvantages has recently been used widely.
• sodium percarbonate and sodium perborate are particularly utilized from the standpoint of bleaching performance and stability.
• the bleaching power of the oxygenic bleaching agent is poorer than that of a chlorinated bleaching agent, so that various bleach activators have been used together therewith.
• TAED tetraacetyl ethylene diamine
• acetoxybenzene sulfonic acid salts tetraacetyl glycoluril and glucose pentaacetate
• glucose pentaacetate tetraacetyl glycoluril
• glucose pentaacetate glucose pentaacetate
• European Patent Publication-A No. 403152 mentions a bleach activator represented by the following formula:
• a bleach or bleaching detergent composition containing such a compound which can form an organic peracid having a cationic group is applied to colored or patterned soft goods, materials, cloths, fabrics and the like, the discoloration of the soft goods, etc. cannot be acceptably inhibited, though the compound is excellent in bleach activating performance.
• the object of the present invention is to provide a bleach or bleaching detergent composition which is excellent in bleach activating performance and which hardly discolors colored or patterned soft goods, materials, cloths, fabrics and the like.
• composition which comprises hydrogen peroxide or a peroxide which liberates hydrogen peroxide in an aqueous solution thereof and compounds represented respectively by the following general formulae (I) and (II) at a specified ratio solves the aforementioned problems: in which R1 is, either a straight- or branched-chain, substituted or unsubstituted, alkyl having 1 to 20 carbon atoms or alkenyl having 2 to 20 carbon atoms, R2 and R3 are, each independently, an alkyl having 1 to 3 carbon atoms and A and B are, each independently, either a straight- or branched-chain, substituted or unsubstituted, alkylene having 2 to 20 carbon atoms, and in which R1, R2, R3 and A are defined above.
• the present invention has been accomplished on the basis of this finding.
• the present invention provides a bleach or bleaching detergent composition which comprises or essentially consists of:
• R1 in the formulae (I) and (II) is, preferably, either a straight- or branched-chain, alkyl having 1 to 20 carbon atoms and having at least one substituent selected from the group consisting of a hydroxyl group and a halogen atom or alkenyl having 2 to 20 carbon atoms and having at least one substituent selected from the group consisting of a hydroxyl group and a halogen atom.
• R1 in the formulae (I) and (II) is alkyl, it is preferably, either a straight- or branched-chain, alkyl having 1 to 9 carbon atoms.
• R1 in the formulae (I) and (II) is alkenyl, it is preferably a straight-chain alkenyl having 2 to 17 carbon atoms.
• a and B in the formulae (I) and (II) are preferably, each independently, a straight-chain alkylene having 2 to 10 carbon atoms.
• the molar ratio of component (a)/component (b) is in the range of preferably from 99.9/0.1 to 20/80, and more preferably from 99/1 to 50/50.
• the weight ratio of component (b)/component (c) is in the range of preferably from 100/0.1 to 100/4.
• the composition may further comprise at least one component selected from the group consisting of a bleach activator other than component (b), a surfactant, a divalent metal ion-sequestering agent, an alkaline agent, an inorganic electrolyte, an antiredeposition agent, an enzyme, a fluorescent dye, a stabilizer for the peroxide, a perfume and a coloring matter in their respective effective amounts.
• a bleach activator other than component (b) a surfactant, a divalent metal ion-sequestering agent, an alkaline agent, an inorganic electrolyte, an antiredeposition agent, an enzyme, a fluorescent dye, a stabilizer for the peroxide, a perfume and a coloring matter in their respective effective amounts.
• Component (a) according to the present invention is either hydrogen peroxide or a peroxide which can generate hydrogen peroxide in an aqueous solution thereof.
• a peroxide which can generate hydrogen peroxide in an aqueous solution thereof.
• the latter include sodium percarbonate, sodium tripolyphosphate/hydrogen peroxide adduct, sodium pyrophosphate/hydrogen peroxide adduct, urea/hydrogen peroxide adduct, 4Na2SO4 ⁇ 2H2O2 ⁇ NaCl, sodium perborate monohydrate, sodium perborate tetrahydrate, sodium peroxide and potassium peroxide, among which sodium percarbonate, sodium perborate monohydrate and sodium perborate tetrahydrate are preferable.
• Component (b) according to the present invention is a quaternary ammonium compound represented by the general formula (I) and examples thereof include the following compounds:
• an inorganic salt such as an alkali metal halide and an ammonium halide or an organic salt such as a quaternary ammonium halide is generally formed as a by-product.
• the bleach or bleaching detergent composition of the present invention may contain at least one of the above-mentioned inorganic salt and the above-mentioned organic salt in such an amount that it does not hinder the object of the present invention.
• the molar ratio of component (a) to component (b) is preferably in the range of from 99.9 : 0.1 to 20 : 80, and still more preferably from 99 : 1 to 50 : 50.
• Component (c) according to the present invention is an amide derivative represented by the general formula (II) and examples thereof include the following compounds:
• component (c) is used in an amount of from 0.01 to 5 parts by weight, preferably from 0.1 to 4 parts per 100 parts by weight of component (b). This range is critical, because when the amount of component (c) used is less than 0.01 part by weight per 100 parts by weight of the component (b), the discoloration of colored or patterned soft goods, materials, cloths, fabrics and the like in bleaching will not be sufficiently inhibited, while when it exceeds 5 parts by weight, bleaching performance will be hindered.
• the bleach or bleaching detergent composition of the present invention may contain a bleach activator other than component (b) and additives which are ordinarily added to a bleach or bleaching detergent composition, in addition to the above essential components (a), (b) and (c).
• a bleach activator other than component (b) and additives which are ordinarily added to a bleach or bleaching detergent composition, in addition to the above essential components (a), (b) and (c).
• additives are as follows:
• TAED tetraacetyl ethylene diamine
• acetoxybenzene sulfonic acid salts tetraacetyl glycolyl uril
• glucose pentaacetate a compound which reacts with hydrogen peroxide to form an organic peracid having a cationic group
• One or more builder components selected from among the following compounds, for example, alkali metal salts and alkanolamine salts which may be present in an amount of 0 to 50% by weight per the bleach or bleaching detergent composition of the present invention:
• silicates carbonates and sulfates, among which alkali metal salts, for example, Glauber's salt are preferable.
• polyethylene glycol polyvinyl alcohol, polyvinylpyrrolidone and carboxymethylcellulose.
• protease lipase, amylase and cellulase.
• salts of 4,4'-bis(2-sulfostyryl)-biphenyl salts of 4,4'-bis(4-chloro-3-sulfostyryl)-biphenyl, 2-(stylphenyl)naphthothiazole derivatives, 4,4'-bis(triazol-2-yl)stilbene derivatives and bis(triazinylamino)stilbene disulfonic acid derivatives.
• magnesium salts such as magnesium sulfate, magnesium silicate, magnesium chloride, magnesium silicofluoride, magnesium oxide and magnesium hydroxide; and silicates such as sodium silicate.
• the bleach or bleaching detergent composition according to the present invention exhibits not only an excellent bleaching effect but also an excellent detergency against sebum and mud dirts. Further, even when it is applied to colored or patterned soft goods, materials, cloths, fabrics and the like, it does not cause the discoloration of the soft goods, etc.. Furthermore, the bleach activator used in the bleach or bleaching detergent composition according to the present invention is biodegradable, being extremely safe for the human bodies.
• Bleach compositions were prepared according to the formulations specified in Table 1 and subjected to the following bleaching test and discoloration test:
• Nitto black tea (yellow package) was dipped in 3 l of deionized water, and was boiled for about 15 minutes and filtered through a desized bleached cotton cloth.
• a cotton shirting cloth # 2003 was dipped in the obtained filtrate, followed by boiling for about 15 minutes.
• the boiled liquid was taken off the fire and allowed to stand for about 2 hours.
• the cloth was dried spontaneously, washed with water until the washings became colorless, dehydrated, pressed and cut into a test piece of 10 cm ⁇ 10 cm. This test piece was used in the following determination.
• Each bleaching composition specified in Table 1 was added to 300 ml of water at 20°C so as to give an available oxygen content of 0.04%.
• the tea-stained cloth prepared above was dipped in the solution for 30 minutes, washed with water and dried.
• the rate of bleaching of the resulting cloth was determined according to the following formula: Rate of bleaching of tea-stained cloth:
• NDR-101 DP mfd. by Nippon Denshoku Kogyo
• Each bleach composition specified in Table 1 was dissolved in tap water at 40°C so as to give an available oxygen content of 0.04%.
• a cotton cloth dyed with a direct dye (Sumilight Supra Blue FBGL) was dipped in the solution prepared above, dried and examined for discoloration with a gray scale for discoloration according to JIS L 0804. Cases wherein the grade was 4.5 or above is shown by “o”; cases wherein the grade was 4 or above but below 4.5 is shown by " ⁇ "; cases wherein the grade was 3 or above but below 4 is shown by " ⁇ "; and cases wherein the grade was below 3 is shown by "x”. The results are set forth in Table 1.

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• Chemical & Material Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Organic Chemistry (AREA)
• Inorganic Chemistry (AREA)
• Detergent Compositions (AREA)

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Cited By (6)

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Citations (2)

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• 1991
  • 1991-05-09 JP JP3104216A patent/JP2908589B2/ja not_active Expired - Fee Related
• 1992
  • 1992-04-29 AU AU15233/92A patent/AU644732B2/en not_active Ceased
  • 1992-05-07 EP EP19920107693 patent/EP0512533A3/en not_active Withdrawn

Patent Citations (2)

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