EP0483053A1 - Moyen de décontamination et procédé de dissolution des surfaces radioactivement contaminées de composants métalliques - Google Patents

Moyen de décontamination et procédé de dissolution des surfaces radioactivement contaminées de composants métalliques Download PDF

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Publication number
EP0483053A1
EP0483053A1 EP91810731A EP91810731A EP0483053A1 EP 0483053 A1 EP0483053 A1 EP 0483053A1 EP 91810731 A EP91810731 A EP 91810731A EP 91810731 A EP91810731 A EP 91810731A EP 0483053 A1 EP0483053 A1 EP 0483053A1
Authority
EP
European Patent Office
Prior art keywords
contaminated
lead
oxidizing agent
decontamination
hydrogen peroxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP91810731A
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German (de)
English (en)
Other versions
EP0483053B1 (fr
Inventor
Jozef Hanulik
Jean-Francois Equey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Recytec SA
Original Assignee
Recytec SA
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Filing date
Publication date
Application filed by Recytec SA filed Critical Recytec SA
Publication of EP0483053A1 publication Critical patent/EP0483053A1/fr
Application granted granted Critical
Publication of EP0483053B1 publication Critical patent/EP0483053B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10—Other heavy metals
    • G—PHYSICS
    • G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00—Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/001—Decontamination of contaminated objects, apparatus, clothes, food; Preventing contamination thereof
    • G21F9/002—Decontamination of the surface of objects with chemical or electrochemical processes
    • G21F9/004—Decontamination of the surface of objects with chemical or electrochemical processes of metallic surfaces
EP91810731A 1990-10-26 1991-09-16 Moyen de décontamination et procédé de dissolution des surfaces radioactivement contaminées de composants métalliques Expired - Lifetime EP0483053B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH3429/90A CH682023A5 (fr) 1990-10-26 1990-10-26
CH3429/90 1990-10-26

Publications (2)

Publication Number Publication Date
EP0483053A1 true EP0483053A1 (fr) 1992-04-29
EP0483053B1 EP0483053B1 (fr) 1995-03-01

Family

ID=4255784

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91810731A Expired - Lifetime EP0483053B1 (fr) 1990-10-26 1991-09-16 Moyen de décontamination et procédé de dissolution des surfaces radioactivement contaminées de composants métalliques

Country Status (11)

Country Link
US (1) US5340505A (fr)
EP (1) EP0483053B1 (fr)
JP (1) JPH04285898A (fr)
CA (2) CA2054236A1 (fr)
CH (1) CH682023A5 (fr)
CS (1) CS325391A3 (fr)
DE (1) DE59104768D1 (fr)
ES (1) ES2071278T3 (fr)
FI (1) FI914870A (fr)
HU (1) HU212234B (fr)
RU (1) RU2029400C1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996014640A1 (fr) * 1994-11-04 1996-05-17 British Nuclear Fuels Plc Procedes de decontamination
US5805654A (en) * 1997-04-08 1998-09-08 Wood; Christopher J. Regenerative LOMI decontamination process
US5901368A (en) * 1997-06-04 1999-05-04 Electric Power Research Institute Radiolysis-assisted decontamination process
US6320675B1 (en) 1997-07-15 2001-11-20 Canon Kabushiki Kaisha Image processing apparatus and method and storage medium
CN112176393A (zh) * 2020-09-28 2021-01-05 中核四川环保工程有限责任公司 一种电化学去污电解液及其制备方法和应用

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5724668A (en) * 1995-11-07 1998-03-03 Electronic Power Research Institute Method for decontamination of nuclear plant components
US6147274A (en) * 1996-11-05 2000-11-14 Electric Power Research Insitute Method for decontamination of nuclear plant components
US7384529B1 (en) 2000-09-29 2008-06-10 The United States Of America As Represented By The United States Department Of Energy Method for electrochemical decontamination of radioactive metal
FR2873848B1 (fr) 2004-08-02 2006-11-17 Tech En Milieu Ionisant Stmi S Procede de decontamination d'objets en plomb
US20100010285A1 (en) * 2008-06-26 2010-01-14 Lumimove, Inc., D/B/A Crosslink Decontamination system
JP6220114B2 (ja) * 2011-11-30 2017-10-25 荏原工業洗浄株式会社 放射性セシウム固体状被汚染物の除染方法及び装置
RU2502567C1 (ru) * 2012-07-27 2013-12-27 Федеральное государственное унитарное предприятие "Российский Федеральный ядерный центр - Всероссийский научно-исследовательский институт экспериментальной физики" - ФГУП "РФЯЦ-ВНИИЭФ" Способ удаления металлических покрытий с поверхности деталей из радиоактивного химически активного металла
JP6403517B2 (ja) * 2014-09-25 2018-10-10 三菱重工業株式会社 放射性廃棄物除染方法
RU2646535C1 (ru) * 2017-04-12 2018-03-06 Федеральное государственное унитарное предприятие "Научно-исследовательский институт Научно-производственное объединение "ЛУЧ" (ФГУП "НИИ НПО "ЛУЧ") Способ переработки отходов ядерного производства

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB891670A (en) * 1957-09-04 1962-03-14 English Electric Co Ltd Improvements in and relating to the removing of scale from silicon iron and other metals
US3565707A (en) * 1969-03-03 1971-02-23 Fmc Corp Metal dissolution
US3873362A (en) * 1973-05-29 1975-03-25 Halliburton Co Process for cleaning radioactively contaminated metal surfaces
WO1986007184A1 (fr) * 1985-05-28 1986-12-04 Jozef Hanulik Moyen pour la decontamination de materiaux contamines metalliques ou renfermant du ciment, son procede de fabrication et son utilisation

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US1899734A (en) * 1930-01-18 1933-02-28 American Sheet & Tin Plate Removal of oxids from ferrous metal
US2154451A (en) * 1934-12-17 1939-04-18 Du Pont Bright dip
GB891760A (en) * 1957-07-08 1962-03-21 Derek Richard Stuckey Improvements in or relating to sleeved garments
US3080323A (en) * 1959-04-07 1963-03-05 Purex Corp Ltd Composition for radioactive decontamination and descaling of cobalt alloys
BE670521A (fr) * 1964-10-05 1900-01-01
US3341304A (en) * 1966-04-08 1967-09-12 Billie J Newby Separation of uranium from uranium dioxide-zirconium dioxide mixtures
US3409413A (en) * 1967-08-11 1968-11-05 Atomic Energy Commission Usa Method of dissolving aluminum-clad thoria target elements
US3668131A (en) * 1968-08-09 1972-06-06 Allied Chem Dissolution of metal with acidified hydrogen peroxide solutions
SU398702A1 (ru) * 1970-04-29 1973-09-27 Раствор для стравливания гальванических покрытий сплавами олово—свинец
DE2058766A1 (de) * 1970-11-30 1972-05-31 Siemens Ag Verfahren zur Reinigung von metallischen Oberflaechen,insbesondere radioaktiv verseuchten Oberflaechen
US3891741A (en) * 1972-11-24 1975-06-24 Ppg Industries Inc Recovery of fission products from acidic waste solutions thereof
US3986970A (en) * 1973-05-02 1976-10-19 The Furukawa Electric Co., Ltd. Solution for chemical dissolution treatment of tin or alloys thereof
US3965237A (en) * 1975-04-11 1976-06-22 The United States Of America As Repesented By The United States Energy Research And Development Administration Dissolution process for ZrO2 -UO2 -CaO fuels
DE2553569C2 (de) * 1975-11-28 1985-09-12 Kernforschungszentrum Karlsruhe Gmbh, 7500 Karlsruhe Verfahren zur Verfestigung von radioaktiven wäßrigen Abfallstoffen durch Sprühkalzinierung und anschließende Einbettung in eine Matrix aus Glas oder Glaskeramik
BE838533A (fr) * 1976-02-13 1976-05-28 Procede de sechage des solutions contenant de l'acide borique
CH619807A5 (fr) * 1976-04-07 1980-10-15 Foerderung Forschung Gmbh
DE2910677C2 (de) * 1979-03-19 1983-12-22 Kraftwerk Union AG, 4330 Mülheim Verfahren zur Behandlung von borhaltigen radioaktiven Konzentraten aus Abwässern von Druckwasserreaktoren
US4217192A (en) * 1979-06-11 1980-08-12 The United States Of America As Represented By The United States Department Of Energy Decontamination of metals using chemical etching
US4443269A (en) * 1979-10-01 1984-04-17 Health Physics Systems, Inc. Tool decontamination method
JPS57164984A (en) * 1981-04-06 1982-10-09 Metsuku Kk Exfoliating solution for tin or tin alloy
CH653466A5 (de) * 1981-09-01 1985-12-31 Industrieorientierte Forsch Verfahren zur dekontamination von stahloberflaechen und entsorgung der radioaktiven stoffe.
US4686019A (en) * 1982-03-11 1987-08-11 Exxon Research And Engineering Company Dissolution of PuO2 or NpO2 using electrolytically regenerated reagents
US4530723A (en) * 1983-03-07 1985-07-23 Westinghouse Electric Corp. Encapsulation of ion exchange resins
US4620947A (en) * 1983-10-17 1986-11-04 Chem-Nuclear Systems, Inc. Solidification of aqueous radioactive waste using insoluble compounds of magnesium oxide
US4537666A (en) * 1984-03-01 1985-08-27 Westinghouse Electric Corp. Decontamination using electrolysis
US4701246A (en) * 1985-03-07 1987-10-20 Kabushiki Kaisha Toshiba Method for production of decontaminating liquid
JPS6267500A (ja) * 1985-09-20 1987-03-27 日立プラント建設株式会社 放射能汚染物の化学的除染方法及び装置
CH679158A5 (fr) * 1989-07-20 1991-12-31 Recytec S A C O Orfigest S A
JPH0375386A (ja) * 1989-08-18 1991-03-29 Metsuku Kk 錫又は錫‐鉛合金の剥離方法
US5084253A (en) * 1989-11-13 1992-01-28 Nuclear Metals, Inc. Method of removing niobium from uranium-niobium alloy

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB891670A (en) * 1957-09-04 1962-03-14 English Electric Co Ltd Improvements in and relating to the removing of scale from silicon iron and other metals
US3565707A (en) * 1969-03-03 1971-02-23 Fmc Corp Metal dissolution
US3873362A (en) * 1973-05-29 1975-03-25 Halliburton Co Process for cleaning radioactively contaminated metal surfaces
WO1986007184A1 (fr) * 1985-05-28 1986-12-04 Jozef Hanulik Moyen pour la decontamination de materiaux contamines metalliques ou renfermant du ciment, son procede de fabrication et son utilisation

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996014640A1 (fr) * 1994-11-04 1996-05-17 British Nuclear Fuels Plc Procedes de decontamination
US5805654A (en) * 1997-04-08 1998-09-08 Wood; Christopher J. Regenerative LOMI decontamination process
US5901368A (en) * 1997-06-04 1999-05-04 Electric Power Research Institute Radiolysis-assisted decontamination process
US6320675B1 (en) 1997-07-15 2001-11-20 Canon Kabushiki Kaisha Image processing apparatus and method and storage medium
US6721067B2 (en) 1997-07-15 2004-04-13 Canon Kabushiki Kaisha Processing apparatus and method and storage medium
CN112176393A (zh) * 2020-09-28 2021-01-05 中核四川环保工程有限责任公司 一种电化学去污电解液及其制备方法和应用
CN112176393B (zh) * 2020-09-28 2021-09-21 中核四川环保工程有限责任公司 一种电化学去污电解液及其制备方法和应用
US11342092B2 (en) 2020-09-28 2022-05-24 China Nuclear Sichuan Environmental Protection Engineering Co., Ltd. Electrolyte for electrochemical decontamination and preparation method and application thereof

Also Published As

Publication number Publication date
DE59104768D1 (de) 1995-04-06
CS325391A3 (en) 1992-06-17
HU913363D0 (en) 1992-01-28
CA2054236A1 (fr) 1992-04-27
HU212234B (en) 1996-04-29
EP0483053B1 (fr) 1995-03-01
FI914870A (fi) 1992-04-27
US5340505A (en) 1994-08-23
CH682023A5 (fr) 1993-06-30
RU2029400C1 (ru) 1995-02-20
HUT69460A (en) 1995-09-28
JPH04285898A (ja) 1992-10-09
FI914870A0 (fi) 1991-10-16
CA2054234A1 (fr) 1992-04-27
ES2071278T3 (es) 1995-06-16

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