GB891670A - Improvements in and relating to the removing of scale from silicon iron and other metals - Google Patents

Improvements in and relating to the removing of scale from silicon iron and other metals

Info

Publication number
GB891670A
GB891670A GB2792457A GB2792457A GB891670A GB 891670 A GB891670 A GB 891670A GB 2792457 A GB2792457 A GB 2792457A GB 2792457 A GB2792457 A GB 2792457A GB 891670 A GB891670 A GB 891670A
Authority
GB
United Kingdom
Prior art keywords
fluoborate
metals
solution
silicon iron
treatment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2792457A
Inventor
Robert Geoffrey Popple
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
English Electric Co Ltd
Original Assignee
English Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by English Electric Co Ltd filed Critical English Electric Co Ltd
Priority to GB2792457A priority Critical patent/GB891670A/en
Publication of GB891670A publication Critical patent/GB891670A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/086Iron or steel solutions containing HF

Abstract

Metals (particularly silicon iron) are descaled by treatment with an aqueous solution having a pH of 3-9 and containing a fluoborate which on hydrolysis gives off hydrofluoric acid and boric acid. The solution preferably contains a cation which forms a readily soluble fluoborate and a less soluble fluosilicate: the preferred fluoborate is thus potassium fluoborate. The solution may also contain ammonium fluoride; a wetting agent such as cetyl pyridinium bromide, the sodium salt of an alkylated naphthalene sulphonate or the sodium salt of secondary dodecyl sulphate; and an inhibitor such as thiourea. Treatment is preferably effected by boiling with air or steam agitation.
GB2792457A 1957-09-04 1957-09-04 Improvements in and relating to the removing of scale from silicon iron and other metals Expired GB891670A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2792457A GB891670A (en) 1957-09-04 1957-09-04 Improvements in and relating to the removing of scale from silicon iron and other metals

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2792457A GB891670A (en) 1957-09-04 1957-09-04 Improvements in and relating to the removing of scale from silicon iron and other metals

Publications (1)

Publication Number Publication Date
GB891670A true GB891670A (en) 1962-03-14

Family

ID=10267481

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2792457A Expired GB891670A (en) 1957-09-04 1957-09-04 Improvements in and relating to the removing of scale from silicon iron and other metals

Country Status (1)

Country Link
GB (1) GB891670A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2148942A (en) * 1983-10-31 1985-06-05 Nihon Parkerizing Process for treating aluminium surfaces
EP0157382A1 (en) * 1984-04-02 1985-10-09 PARKER CHEMICAL COMPANY (a Delaware company) Process and an aqueous acid cleaning solution for the cleaning of aluminium surfaces
WO1986007184A1 (en) * 1985-05-28 1986-12-04 Jozef Hanulik Agent for decontaminating contaminated metal materials or cement-containing materials, production method and utilization
EP0483053A1 (en) * 1990-10-26 1992-04-29 Recytec S.A. Decontaminating agent and process for dissolving radioactively contaminated surfaces of metallic components
US5128266A (en) * 1989-06-30 1992-07-07 Firma Recytec Sa Method for testing the radioactivity of objects containing metal or concrete
EP0596273A1 (en) * 1992-11-02 1994-05-11 POLIGRAT Holding GmbH Product for pickling surfaces of chromium-nickel steel or chromium steel and its use
USRE34613E (en) * 1985-05-28 1994-05-24 Recytec Sa Process for decontaminating radioactively contaminated metal or cement-containing materials
CN102628848A (en) * 2012-04-19 2012-08-08 武汉钢铁(集团)公司 Method for measuring content of iron in silicon steel surface oxidation layer

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2148942A (en) * 1983-10-31 1985-06-05 Nihon Parkerizing Process for treating aluminium surfaces
EP0157382A1 (en) * 1984-04-02 1985-10-09 PARKER CHEMICAL COMPANY (a Delaware company) Process and an aqueous acid cleaning solution for the cleaning of aluminium surfaces
WO1986007184A1 (en) * 1985-05-28 1986-12-04 Jozef Hanulik Agent for decontaminating contaminated metal materials or cement-containing materials, production method and utilization
US4828759A (en) * 1985-05-28 1989-05-09 Jozef Hanulik Process for decontaminating radioactivity contaminated metallic materials
US4933113A (en) * 1985-05-28 1990-06-12 Recytec Sa Process for the processing of contaminated boric acid
US5008044A (en) * 1985-05-28 1991-04-16 Recytec Sa Process for decontaminating radioactively contaminated metal or cement-containing materials
USRE34613E (en) * 1985-05-28 1994-05-24 Recytec Sa Process for decontaminating radioactively contaminated metal or cement-containing materials
US5128266A (en) * 1989-06-30 1992-07-07 Firma Recytec Sa Method for testing the radioactivity of objects containing metal or concrete
EP0483053A1 (en) * 1990-10-26 1992-04-29 Recytec S.A. Decontaminating agent and process for dissolving radioactively contaminated surfaces of metallic components
EP0596273A1 (en) * 1992-11-02 1994-05-11 POLIGRAT Holding GmbH Product for pickling surfaces of chromium-nickel steel or chromium steel and its use
CN102628848A (en) * 2012-04-19 2012-08-08 武汉钢铁(集团)公司 Method for measuring content of iron in silicon steel surface oxidation layer

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