EP0458845A1 - Granulat aus waschmittelzusatzmitteln und dessen herstellung. - Google Patents
Granulat aus waschmittelzusatzmitteln und dessen herstellung.Info
- Publication number
- EP0458845A1 EP0458845A1 EP90903319A EP90903319A EP0458845A1 EP 0458845 A1 EP0458845 A1 EP 0458845A1 EP 90903319 A EP90903319 A EP 90903319A EP 90903319 A EP90903319 A EP 90903319A EP 0458845 A1 EP0458845 A1 EP 0458845A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- granulate
- core
- shell
- detergent additive
- granulate according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000008187 granular material Substances 0.000 title claims abstract description 93
- 239000003599 detergent Substances 0.000 title claims abstract description 41
- 239000000654 additive Substances 0.000 title claims abstract description 37
- 230000000996 additive effect Effects 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000011230 binding agent Substances 0.000 claims abstract description 18
- 239000011253 protective coating Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 16
- 229920003043 Cellulose fiber Polymers 0.000 claims abstract description 11
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 6
- 239000003979 granulating agent Substances 0.000 claims abstract description 5
- 239000011257 shell material Substances 0.000 claims description 49
- 102000004190 Enzymes Human genes 0.000 claims description 26
- 108090000790 Enzymes Proteins 0.000 claims description 26
- 229940088598 enzyme Drugs 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000428 dust Substances 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 108091005804 Peptidases Proteins 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 108700023418 Amidases Proteins 0.000 claims description 2
- 239000004382 Amylase Substances 0.000 claims description 2
- 102000013142 Amylases Human genes 0.000 claims description 2
- 108010065511 Amylases Proteins 0.000 claims description 2
- 108010059892 Cellulase Proteins 0.000 claims description 2
- 239000004367 Lipase Substances 0.000 claims description 2
- 102000004882 Lipase Human genes 0.000 claims description 2
- 108090001060 Lipase Proteins 0.000 claims description 2
- 102000004316 Oxidoreductases Human genes 0.000 claims description 2
- 108090000854 Oxidoreductases Proteins 0.000 claims description 2
- 239000004365 Protease Substances 0.000 claims description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 2
- 102000005922 amidase Human genes 0.000 claims description 2
- 235000019418 amylase Nutrition 0.000 claims description 2
- 229940106157 cellulase Drugs 0.000 claims description 2
- 235000019421 lipase Nutrition 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 abstract description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 20
- 239000005995 Aluminium silicate Substances 0.000 description 17
- 235000012211 aluminium silicate Nutrition 0.000 description 17
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 17
- 108010020132 microbial serine proteinases Proteins 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 150000001720 carbohydrates Chemical class 0.000 description 13
- 239000003760 tallow Substances 0.000 description 13
- 230000003287 optical effect Effects 0.000 description 12
- 239000000843 powder Substances 0.000 description 10
- 229910052938 sodium sulfate Inorganic materials 0.000 description 10
- 235000011152 sodium sulphate Nutrition 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000007844 bleaching agent Substances 0.000 description 8
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 8
- 229910052801 chlorine Inorganic materials 0.000 description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 8
- 239000011241 protective layer Substances 0.000 description 8
- 239000002516 radical scavenger Substances 0.000 description 8
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical compound CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- 239000000440 bentonite Substances 0.000 description 4
- 229910000278 bentonite Inorganic materials 0.000 description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 4
- -1 fatty acid esters Chemical class 0.000 description 4
- 230000002797 proteolythic effect Effects 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 229920002556 Polyethylene Glycol 300 Polymers 0.000 description 3
- 108010056079 Subtilisins Proteins 0.000 description 3
- 102000005158 Subtilisins Human genes 0.000 description 3
- 235000006708 antioxidants Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229910019093 NaOCl Inorganic materials 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- 239000004133 Sodium thiosulphate Substances 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 239000001166 ammonium sulphate Substances 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- 150000000994 L-ascorbates Chemical class 0.000 description 1
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007771 core particle Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229940096898 glyceryl palmitate Drugs 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- LMAZKPOSWVOFGY-FBAUPLQOSA-N orine Natural products CO[C@H]1C[C@H](O[C@H]2CC[C@]3(C)[C@H]4C[C@@H](OC(=O)C=Cc5ccccc5)[C@]6(C)[C@@](O)(CC[C@]6(O)[C@]4(O)CC=C3C2)[C@H](C)OC(=O)C=Cc7ccccc7)O[C@H](C)[C@H]1O LMAZKPOSWVOFGY-FBAUPLQOSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38672—Granulated or coated enzymes
Definitions
- the enzyme containing granulate described in Danish patent application No. 4368/88 comprises a core surrounded by a coating comprising cellulose fibres or artificial fibres in an amount of 1.5 to 40% by weight, based on the dry weight of the granulate except for the core, a binder in an amount of 0 to 15% by weight, based on the dry weight of the granulate, except for the core, a filler, and one or more granulating agents, whereby the core and/or the coating contains an enzyme.
- the invention is a further development of the special embodiment of the invention described in Danish patent application No. 4368/88, which comprises an enzyme in either the core or the shell.
- the shell or the core in the detergent additive granulate according to the invention does not necessarily contain an enzyme; but the core contains one detergent additive (which may be an enzyme, here identified as the primary detergent additive) , and the shell contains another detergent additive (which may be another enzyme, here identified as the secondary detergent additive) .
- the primary detergent additive should be protected against the secondary detergent additive and/or environmental factors ,- ⁇ e.g. in cases where an enzyme is degraded by a bleaching agent and humidity in the atmosphere, or vice versa
- there is a need for an effective separation between the primary and secondary detergent additives during storage there is a need for a granulate with high physical strength, and for a. corresponding method of production, which is easily controllable and adapted for an industrial scale.
- the filler consists of or comprises inorganic salts.
- the shell is surrounded by a final dust suppressing coating. This is advantageous in those cases where the shell tends to produce an unacceptable amount of dust.
- This final dust suppressing coating can also in certain cases serve as a further protective coating.
- Example 1 is granulated in a Lodige mixer FM 50 with pure water as granulating agent as described in US patent No. 4.106.991, Example 1.
- the granulate is dried on a fluid bed to a water content below 1% and finally siftet to get a product with particle range 300 ⁇ m to 900 ⁇ m.
- Example 7 kg of a granulate produced as described in Example 1 with particle size between 300-900 ⁇ m is coated with a layer of glyceryl stearate/palmitate Grindtek MSP 90 (melting point 68°C) and bentonite ASB 350 ECC in the following manner.
- the granulate is heated to 75-80°C in a 20 1 heat jacketed Lodige mixer which temperature is kept during the whole coating process.
- the heated granulate is mixed and sprayed with 700 g melted MSP90 followed by a powdering with 1000 g bentonite followed by spraying with 210 g* * MSP90 followed by powdering with 1000 g MSP90 followed by spraying with 210 g MSP90.
- the granulate is finally cooled to room temperature on a fluid bed and siftet between 300 and 1000 ⁇ m.
- a granulate with an inner core containing an optical brightener and an outer shell containing a proteolytic enzyme with the core and the shell separated by a protective layer is produced in the following manner.
- the granulate is finally dried to a water content below 1% and siftet between 300 and 1000 ⁇ m.
- Example 3 7 kg of granulate as produced as described in Example 3 is coated with a layer of sodium thiosulphate and kaolin by a conventionel fluid bed coating process.
- 280 g sodium thiosulphate and 280 g kaolin SPESWHITE ECC are dissolved/dispersed in 1000 g of water and sprayed onto the 7 kg of granulate in a Glatt WSG 5 fluid bed with continuous layering and drying.
- the granulate has a proteolytic activity of 5.2 KNPU/g.
- the stability test is made at a temperature of 37°C and a humidity of 70%.
- a granulate with an inner core containing TAED and 5 an outer shell containing a proteolytic enzyme with the core and the shell separated by a protective layer was produced in the following manner.
- the shell was supplied with a continuous self- regulating loss-in-weight powder dosing system with a powder dosing rate of 20 kg/h and with a total of 2.6 kg of an
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK780/89 | 1989-02-20 | ||
DK078089A DK78089D0 (da) | 1989-02-20 | 1989-02-20 | Detergentholdigt granulat og fremgangsmaade til fremstilling deraf |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0458845A1 true EP0458845A1 (de) | 1991-12-04 |
EP0458845B1 EP0458845B1 (de) | 1992-12-23 |
Family
ID=8097473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90903319A Expired EP0458845B1 (de) | 1989-02-20 | 1990-02-16 | Granulat aus waschmittelzusatzmitteln und dessen herstellung |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0458845B1 (de) |
JP (1) | JP2801395B2 (de) |
AT (1) | ATE83797T1 (de) |
DE (1) | DE69000662T2 (de) |
DK (2) | DK78089D0 (de) |
ES (1) | ES2036904T3 (de) |
WO (1) | WO1990009428A1 (de) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002061427A1 (en) | 2001-01-31 | 2002-08-08 | Novozymes A/S | Method of analysing granular composition by fluorescence analysis |
WO2003080827A2 (en) | 2002-03-27 | 2003-10-02 | Novozymes A/S | Granules with filamentous coatings |
WO2004033083A2 (en) | 2002-10-09 | 2004-04-22 | Novozymes A/S | A method for improving particle compositions |
WO2004067739A2 (en) | 2003-01-27 | 2004-08-12 | Novozymes A/S | Stabilization of granules |
WO2007098756A1 (en) | 2006-03-02 | 2007-09-07 | Novozymes A/S | High capacity encapsulation process |
WO2008017661A1 (en) | 2006-08-07 | 2008-02-14 | Novozymes A/S | Enzyme granules for animal feed |
WO2009118329A1 (en) | 2008-03-28 | 2009-10-01 | Novozymes A/S | Triggered release system |
EP2143338A1 (de) | 2004-09-27 | 2010-01-13 | Novozymes A/S | Enzymgranulat |
WO2011000924A1 (en) | 2009-07-03 | 2011-01-06 | Abbott Products Gmbh | Spray-dried amylase, pharmaceutical preparations comprising the same and use |
WO2011098579A1 (en) | 2010-02-12 | 2011-08-18 | University Of Newcastle Upon Tyne | Bacterial deoxyribonuclease compounds and methods for biofilm disruption and prevention |
EP2537918A1 (de) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Verbraucherprodukte mit lipasenhaltigen beschichteten Partikeln |
US8802087B2 (en) | 2004-03-22 | 2014-08-12 | Abbott Products Gmbh | Pharmaceutical compositions of lipase-containing products, in particular of pancreation |
US9198871B2 (en) | 2005-08-15 | 2015-12-01 | Abbott Products Gmbh | Delayed release pancreatin compositions |
EP3072399A1 (de) | 2006-08-07 | 2016-09-28 | Novozymes A/S | Enzymgranulat für tierfutter |
WO2017102477A1 (en) * | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | Multi step washing process |
US10072256B2 (en) | 2006-05-22 | 2018-09-11 | Abbott Products Gmbh | Process for separating and determining the viral load in a pancreatin sample |
WO2020053238A1 (en) | 2018-09-11 | 2020-03-19 | Novozymes A/S | Stable granules for feed compositions |
US10704037B2 (en) | 2005-07-29 | 2020-07-07 | Abbott Products Gmbh | Processes for the manufacture and use of pancreatin |
US11266607B2 (en) | 2005-08-15 | 2022-03-08 | AbbVie Pharmaceuticals GmbH | Process for the manufacture and use of pancreatin micropellet cores |
WO2022074166A1 (en) | 2020-10-07 | 2022-04-14 | Novozymes A/S | New granules for animal feed |
Families Citing this family (98)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4322229A1 (de) * | 1993-07-05 | 1995-01-12 | Cognis Bio Umwelt | Umhüllte Enzymzubereitung für Wasch- und Reinigungsmittel |
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JPS58179492A (ja) * | 1982-04-12 | 1983-10-20 | Dainichi Seika Kogyo Kk | 洗剤用酵素粒剤およびその製造方法 |
JPS6192570A (ja) * | 1984-10-12 | 1986-05-10 | Showa Denko Kk | 酵素造粒法 |
JPS61168698A (ja) * | 1985-01-22 | 1986-07-30 | 昭和電工株式会社 | 洗剤用複合酵素粒剤 |
AU8317487A (en) * | 1987-04-17 | 1988-10-20 | Ecolab Inc. | Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches |
DK435687D0 (da) * | 1987-08-21 | 1987-08-21 | Novo Industri As | Enzymholdigt granulat og fremgangsmaade til fremstilling deraf |
-
1989
- 1989-02-20 DK DK078089A patent/DK78089D0/da not_active Application Discontinuation
-
1990
- 1990-02-16 DE DE9090903319T patent/DE69000662T2/de not_active Expired - Fee Related
- 1990-02-16 DK DK90903319.3T patent/DK0458845T3/da active
- 1990-02-16 JP JP2503460A patent/JP2801395B2/ja not_active Expired - Fee Related
- 1990-02-16 EP EP90903319A patent/EP0458845B1/de not_active Expired
- 1990-02-16 WO PCT/DK1990/000043 patent/WO1990009428A1/en active IP Right Grant
- 1990-02-16 AT AT90903319T patent/ATE83797T1/de not_active IP Right Cessation
- 1990-02-16 ES ES199090903319T patent/ES2036904T3/es not_active Expired - Lifetime
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WO2011098579A1 (en) | 2010-02-12 | 2011-08-18 | University Of Newcastle Upon Tyne | Bacterial deoxyribonuclease compounds and methods for biofilm disruption and prevention |
WO2013003025A1 (en) | 2011-06-20 | 2013-01-03 | The Procter & Gamble Company | Consumer products with lipase comprising coated particles |
EP2537918A1 (de) | 2011-06-20 | 2012-12-26 | The Procter & Gamble Company | Verbraucherprodukte mit lipasenhaltigen beschichteten Partikeln |
WO2017102477A1 (en) * | 2015-12-18 | 2017-06-22 | Henkel Ag & Co. Kgaa | Multi step washing process |
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Also Published As
Publication number | Publication date |
---|---|
JP2801395B2 (ja) | 1998-09-21 |
DK78089D0 (da) | 1989-02-20 |
EP0458845B1 (de) | 1992-12-23 |
DE69000662D1 (de) | 1993-02-04 |
ES2036904T3 (es) | 1993-06-01 |
DE69000662T2 (de) | 1993-04-22 |
ATE83797T1 (de) | 1993-01-15 |
JPH04503369A (ja) | 1992-06-18 |
WO1990009428A1 (en) | 1990-08-23 |
DK0458845T3 (da) | 1993-03-29 |
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