EP0453899B1 - Verwendung von Alkylcarbonsäure-dimethylamiden als Kristallisationsinhibitoren - Google Patents

Verwendung von Alkylcarbonsäure-dimethylamiden als Kristallisationsinhibitoren Download PDF

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Publication number
EP0453899B1
EP0453899B1 EP91105830A EP91105830A EP0453899B1 EP 0453899 B1 EP0453899 B1 EP 0453899B1 EP 91105830 A EP91105830 A EP 91105830A EP 91105830 A EP91105830 A EP 91105830A EP 0453899 B1 EP0453899 B1 EP 0453899B1
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EP
European Patent Office
Prior art keywords
formula
acid dimethylamide
weight
phenyl
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP91105830A
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German (de)
English (en)
French (fr)
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EP0453899A1 (de
Inventor
Heinz-Otto Dr. Horstmann
Uwe Dr. Priesnitz
Ulrich Dr. Engelhardt
Karl Dr. Reizlein
Klaus Dr. Wangermann
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Bayer AG
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Bayer AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur

Definitions

  • the present invention relates to the new use of certain alkylcarboxylic acid dimethylamides for preventing crystallization when applying aqueous spray liquors based on certain pesticidal active ingredients.
  • filters and nozzles are present in sprayers which are usually used for the application of aqueous formulations of plant treatment agents.
  • suction filters between the suction part and tank pump and also pressure filters, which are arranged after the pump in the pressure area.
  • nozzle filters can be included, which are located directly in front of the spray nozzles. All of these filters, as well as the nozzles, can more or less easily become blocked by crystallizing active ingredient when applying aqueous spray liquors based on solid active ingredients.
  • azole derivatives mentioned below are fungicidally active and can be applied to plants and / or their habitat in the form of aqueous spray liquors: 1- (4-chlorophenyl) -4,4-dimethyl-3- (1,2,4-triazol-1-yl-methyl) -pentan-3-ol (tebuconazole), 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-one (triadimphone), 1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-ol (triadimenol), 1- (4-phenylphenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-ol (bitertanol), 1- (2-chlorophenyl) -2- (1-chloro-cycloprop-1-
  • Surfactants such as alkylaryl polyglycol ethers can be used to produce such spray liquors.
  • alkylcarboxylic acid dimethylamides of the formula (I) in aqueous and non-aqueous formulations based on fungicidally active azole derivatives of the formulas (II) to (V) has a number of advantages.
  • the alkylcarboxylic acid dimethylamides are substances that are easy to handle and are also available in larger quantities. Furthermore, the use of the substances of the formula (I) prevents that when spraying aqueous formulations which contain active substances of the formulas (II) to (V), both the filters and the nozzles of the spraying devices become blocked. It is also advantageous that alkylcarboxylic acid dimethylamides of the formula (I) have no undesirable side effects in crop protection.
  • the alkylcarboxylic acid dimethylamides which can be used according to the invention are defined by the formula (I).
  • R represents straight-chain or branched alkyl having 5 to 19 carbon atoms, preferably having 5 to 11 carbon atoms.
  • the substances can be used both individually and in the form of mixtures.
  • the mixture known under the trade name Hallcomid which consists on average of 5% of hexanecarboxylic acid dimethylamide, 50% octanecarboxylic acid dimethylamide, 40% decanecarboxylic acid dimethylamide and 5% of dodecanecarboxylic acid dimethylamide, can be used with particular preference.
  • alkylcarboxylic acid dimethylamides of the formula (I) are already known.
  • the azole derivatives contained in the aqueous spray liquors which can be used according to the invention are defined by the formulas (II) to (V). One or more of the following azole derivatives can be contained.
  • the active compounds of the formulas (II) to (V) and their use for combating phytopathogenic fungi are known (cf. EP-A 0 040 345, US-A 4 551 469, EP-B 0 015 756, EP-A 0 068 813 , EP-A 0 297 345, DE-A 3 406 993, DE-C 2 324 010, DE-C 2 201 063, DE-A 2 838 847, DE-A 3 010 560 and DE-A 2 821 971) .
  • the active compounds of the formulas (II) to (V) can be used in customary formulations.
  • the application is preferably carried out in the form of aqueous spray liquors.
  • the spray liquors which can be used according to the invention may also contain one or more further active compounds.
  • Compounds with fungicidal properties are preferred.
  • additional active substances N, N-dimethyl-N'-phenyl- (N'-fluorodichloromethylthio) sulfamide (dichlofluanid), N, N-dimethyl- (N'-fluorodichloromethylthio) -N '- (4-methylphenyl) sulfamide (tolylfluanid), N-trichloromethylmercapto-4-cyclohexene-1,2-di arboxamide (Captan), N- (1,1,2,2-tetrachloroethyl-sulfenyl) cis-4-cyclohexene-1,2-dicarboxamide (Captafol), N-trichloromethylthio-phthalimide (Fo
  • Suitable additives which can be present in the spray liquors which can be used according to the invention are surface-active substances, organic diluents, water, acids, cold stabilizers and adhesives.
  • Nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, alkylaryl polyglycol ethers, alkyl sulfonates, alkylarylsulfonates, alkyl sulfates and aryl sulfonates are suitable as surface-active substances.
  • the emulsifiers can be used individually or in a mixture.
  • Polyoxyethylene sorbitan monolaurate with an average of 20 oxyethylene units per molecule Polyoxyethylene sorbitan monopalmitate with an average of 20 oxyethylene units per molecule
  • Polyoxyethylene sorbitan monostearate with an average of 20 oxyethylene units per molecule Sorbitan monolaurate, Sorbitan monopalmitate, Sorbitan monostearate
  • Polyoxyethylene oleyl ether with an average of 20 oxyethylene units per molecule Bis- [ ⁇ -methyl- (4-methyl-benzyl)] phenyl polyglycol ether with an average of 27 oxyethylene units per molecule
  • Bis- (4-methyl-benzyl) phenyl polyglycol ether with average 27 oxyethylene units per molecule
  • the emulsifiers from the group of alkylaryl polyglycol ethers used in practice are generally mixtures of several compounds, in particular they are mixtures of substances which are characterized by the degree of substitution on the phenyl ring connected to the oxyethylene unit and the number of the oxyethylene units. This means that the number of substituents on the phenyl ring is also a fractional number. Examples include substances for which the following average compositions result:
  • ketones such as methyl isobutyl ketone and cyclohexanone
  • amides such as dimethylformamide
  • cyclic compounds such as N-methyl-pyrrolidone, N-octyl-pyrrolidone, N-dodecyl-pyrrolidone, N-dodecyl-caprolactam and butyrolactone
  • strongly polar solvents such as dimethyl sulfoxide
  • aromatic hydrocarbons such as xylene
  • esters such as propylene glycol monomethyl ether acetate, adipic acid dibutyl ester, acetic acid hexyl ester, acetic acid heptyl ester, citric acid tri-n-butyl ester and phthal
  • Water may also be present in the spray liquors which can be used according to the invention before dilution.
  • Acids which can be used in the spray liquors which can be used according to the invention are all inorganic and organic acids which can normally be used for such purposes. Aliphatic are preferred and aromatic hydroxycarboxylic acids, such as citric acid, salicylic acid, tartaric acid and ascorbic acid, and inorganic acids, such as phosphoric acid. All of the substances normally suitable for this purpose can be contained as cold stabilizers in the spray liquors which can be used according to the invention. Urea, glycerol and propylene glycol are preferred.
  • Adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and lecithins, and also synthetic phospholipids are preferred.
  • Other additives can be mineral and vegetable oils.
  • the spray liquors which can be used according to the invention each contain water.
  • the active substance concentrations can be varied within a certain range in the spray liquors which can be used according to the invention.
  • the active ingredient concentrations are between 0.0001 and 3 percent by weight, preferably between 0.001 and 2 percent by weight.
  • the ratio of active ingredient of the formulas (II) to (V) to alkylcarboxylic acid dimethylamide of the formula (I) can also be varied within a certain range.
  • the weight ratio of active ingredient from group (A) to alkylcarboxylic acid dimethylamide of the formula (I) is between 1: 0.2 and 1: 5, preferably between 1: 0.6 and 1: 2.
  • the amounts of further active ingredients or additives can be varied within a substantial range in the spray liquors which can be used according to the invention. They are of the order of magnitude as is usually the case in such aqueous spray liquors.
  • the spray liquors which can be used according to the invention are prepared by customary methods.
  • the procedure is that a concentrate is first prepared by combining the required components in any order at temperatures between 10 and 30 ° C. and mixing them homogeneously and, if necessary, filtering the resulting mixture.
  • the concentrated formulation is mixed with the desired amount of water, if appropriate with stirring and / or pumping, in such a way that the formulation is uniformly and finely dispersed in water.
  • alkylcarboxylic acid dimethylamide of the formula (I) when the concentrate is diluted with water to give the ready-to-use spray mixture.
  • alkylcarboxylic acid dimethylamides of the formula (I) in aqueous spray liquors based on active compounds of the formulas (II) to (V), the crystallization of active compound is both in the concentrated, commercially available formulation and when the aqueous spray liquors prepared therefrom are applied in the filters and outlet openings of the spraying devices either completely prevented or prevented to the extent that the application of the spray liquors is not impaired.
  • Fig. 1 shows in 25-fold magnification the crystal deposition that occurs on the sieve when pumping through eight 250 ml batches of the spray mixture according to Example (1).
  • Fig. 2 shows in 25-fold magnification the crystal deposition that occurs on the sieve when pumping through eight 250 ml batches of the spray mixture according to Example (2).
  • Fig. 3 shows in 25-fold magnification the crystal deposition that occurs on the sieve when pumping through eight 250 ml batches of the spray mixture according to Example (3).
  • Fig. 4 shows in 25-fold magnification the crystal deposition that occurs on the sieve when pumping through eight 250 ml batches of the spray mixture according to Example (4).
  • Fig. 5 shows in 25-fold magnification the crystal deposition that occurs on the sieve when pumping through eight 250 ml batches of the spray mixture according to Example (A).

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP91105830A 1990-04-27 1991-04-12 Verwendung von Alkylcarbonsäure-dimethylamiden als Kristallisationsinhibitoren Expired - Lifetime EP0453899B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4013522 1990-04-27
DE4013522A DE4013522A1 (de) 1990-04-27 1990-04-27 Verwendung von alkylcarbonsaeure-dimethylamiden als kristallisationsinhibitoren

Publications (2)

Publication Number Publication Date
EP0453899A1 EP0453899A1 (de) 1991-10-30
EP0453899B1 true EP0453899B1 (de) 1993-12-29

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EP91105830A Expired - Lifetime EP0453899B1 (de) 1990-04-27 1991-04-12 Verwendung von Alkylcarbonsäure-dimethylamiden als Kristallisationsinhibitoren

Country Status (11)

Country Link
US (1) US5206225A (ja)
EP (1) EP0453899B1 (ja)
JP (1) JP2963233B2 (ja)
AU (1) AU638327B2 (ja)
BR (1) BR9101691A (ja)
CA (1) CA2041168C (ja)
DE (2) DE4013522A1 (ja)
DK (1) DK0453899T3 (ja)
ES (1) ES2062597T3 (ja)
HU (1) HU212623B (ja)
ZA (1) ZA913161B (ja)

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EP2033520A1 (en) 2007-09-07 2009-03-11 Cognis IP Management GmbH Use of biocide compositions for wood preservation
DE202007018969U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (I)
DE202007018968U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (II)
DE202007018967U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (III)
EP2147599A1 (en) 2008-07-23 2010-01-27 Cognis IP Management GmbH Agricultural compositions
EP2269451A1 (en) 2009-06-24 2011-01-05 Cognis IP Management GmbH Biocide compositions (III)
EP2292092A1 (en) 2009-09-02 2011-03-09 Cognis IP Management GmbH Biocide compositions comprising esters of ketocarboxylic acids
WO2011060890A1 (en) 2009-11-17 2011-05-26 Cognis Ip Management Gmbh Biocide compositions comprising carbamates
EP2335480A1 (en) 2009-12-15 2011-06-22 Cognis IP Management GmbH Biocide compositions comprising derivatives of pyroglutamic acid
EP2364590A1 (en) 2010-03-09 2011-09-14 Cognis IP Management GmbH Biocide compositions comprising valerolactone or its derivatives
EP2364591A1 (en) 2010-03-09 2011-09-14 Cognis IP Management GmbH Biocide compositions comprising dicarboxylic acid alkylamides
US8389579B2 (en) 2007-02-22 2013-03-05 Cognis Ip Management Gmbh Biocide compositions (I)
US8461081B2 (en) 2007-02-23 2013-06-11 Cognis Ip Management Gmbh Herbicidal compositions containing glyphosate
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Cited By (19)

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US8580712B2 (en) 2006-12-19 2013-11-12 Rhodia Operations Bis(dialkylamide) compounds and diverse applications thereof
US8389579B2 (en) 2007-02-22 2013-03-05 Cognis Ip Management Gmbh Biocide compositions (I)
DE202007018969U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (I)
DE202007018968U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (II)
DE202007018967U1 (de) 2007-02-22 2009-12-31 Cognis Ip Management Gmbh Agrochemische Zusammensetzungen mit Milchsäureverbindungen (III)
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HUT58454A (en) 1992-03-30
AU7596691A (en) 1991-11-07
ES2062597T3 (es) 1994-12-16
DK0453899T3 (da) 1994-03-07
DE4013522A1 (de) 1991-10-31
US5206225A (en) 1993-04-27
CA2041168A1 (en) 1991-10-28
ZA913161B (en) 1992-01-29
BR9101691A (pt) 1991-11-26
HU212623B (en) 1996-09-30
DE59100762D1 (de) 1994-02-10
EP0453899A1 (de) 1991-10-30
JPH04225901A (ja) 1992-08-14
JP2963233B2 (ja) 1999-10-18
CA2041168C (en) 1997-09-30
AU638327B2 (en) 1993-06-24
HU911427D0 (en) 1991-11-28

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