EP0405238B1 - Composition fixateur photographique granulée et sa préparation - Google Patents
Composition fixateur photographique granulée et sa préparation Download PDFInfo
- Publication number
- EP0405238B1 EP0405238B1 EP90111254A EP90111254A EP0405238B1 EP 0405238 B1 EP0405238 B1 EP 0405238B1 EP 90111254 A EP90111254 A EP 90111254A EP 90111254 A EP90111254 A EP 90111254A EP 0405238 B1 EP0405238 B1 EP 0405238B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fixative
- bleach
- granulated
- granulate
- photographic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/264—Supplying of photographic processing chemicals; Preparation or packaging thereof
- G03C5/265—Supplying of photographic processing chemicals; Preparation or packaging thereof of powders, granulates, tablets
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/38—Fixing; Developing-fixing; Hardening-fixing
Definitions
- the present invention relates to a granular, photographic fixing agent and a method for producing such a fixing agent which can be quickly dissolved.
- Photographic fixing agents and bleach-fixing agents usually contain a thiosulfate as the fixing substance, which is intended to dissolve undeveloped silver halide and silver halide which has newly formed by bleaching the metallic silver from the photographic material.
- thiosulfate ammonium thiosulfate [(NH4) 2S2O3] is largely used due to its fast fixing reaction, but this has a serious disadvantage. Powders of this substance bake when standing, even in the absence of atmospheric moisture, to form solid lumps that have to be crushed with difficulty and are difficult to dose then when the ammonium thiosulfate powder is mixed with the other components of the fixing or bleach-fixing bath.
- the sodium thiosulfate used as an alternative is also disadvantageous because it dissolves poorly in water and forms crusts on the bottom of the fixing or bleach-fixing bath.
- the fixing or bleach-fixing agent is largely offered and used in a liquid formulation.
- this has the disadvantage of increased costs due to water ballast.
- the object of the invention is to provide a form of assembly for ammonium thiosulfate which is firm and yet easy to dose and which dissolves quickly in the bath.
- granulated fixing agents can be prepared by grinding a thiosulfate together with a disulfite and optionally other solid substances such that the maximum of the particle diameter distribution curve is less than 10 ⁇ m, the ground particles are subjected to powder agglomeration and the granules are dried in vacuo , if necessary mixed with the granules of the bleaching agent and packed in a water vapor-tight manner.
- the granules of the solid components of a photographic fixing or bleach-fixing agent produced in this way are mechanically stable, of uniform grain size, show a high dissolution rate and unlimited durability, are dust-free and free-flowing.
- Preferred thiosulfates are alkali, in particular sodium, and ammonium thiosulfate.
- Alkali and ammonium disulfite are suitable as disulfites.
- the solid constituents are usually comminuted to particle sizes of ⁇ 10 ⁇ m by jet milling.
- the powder agglomeration is preferably carried out in a fluidized bed, granulation liquid, for example 200 ml of water per kg of powder and, if appropriate, some binder, for example corn starch, being added to the particles to be agglomerated.
- the average particle diameter of the granules should preferably be ⁇ 150 ⁇ m and is in particular 150 to 3000 ⁇ m.
- thiosulfate granules are complexing agents such as ethylenediaminetetraacetic acid (EDTA) and agents for adjusting the desired pH such as sodium carbonate.
- EDTA ethylenediaminetetraacetic acid
- granules are preferably produced separately from the fixing agent and bleaching agent and mixed with one another.
- the granules of the bleaching agent contain an iron (III) complex or an iron (III) complex salt, for example an ammonium iron complex salt from EDTA, the propylenediamine tetraacetic acid (PDTA), diethylenetriaminepentaacetic acid (DTPA) or nitrilotriacetic acid (NTA) and optionally free complexing agents, for example EDTA, PDTA, DTPA or NTA.
- an iron (III) complex or an iron (III) complex salt for example an ammonium iron complex salt from EDTA, the propylenediamine tetraacetic acid (PDTA), diethylenetriaminepentaacetic acid (DTPA) or nitrilotriacetic acid (NTA) and optionally free complexing agents, for example EDTA, PDTA, DTPA or NTA.
- the granules of the bleaching agent are preferably produced in the same way as the granules of the fixing agent and in particular have an average particle diameter in the same range.
- the agent according to the invention preferably contains 35 to 85% by weight of thiosulfate, 5 to 15% by weight of disulfite and, in the case of a bleach-fixing agent, 30 to 50% by weight of iron (III) complex or iron (III) complex salt.
- the bleach-fix bath granules are produced by mixing two individual granules A and B. The following quantities of substance are used per liter of ready-to-use solution:
- the chemicals listed under A are - in the specified mixing ratio - crushed in a so-called Alexander mill to about 1 mm grain size and then in an air jet mill to a particle size of 5 ⁇ m, ground.
- the ground material is then granulated in portions of approximately 500 grams on a commercially available fluidized bed granulator (Strea-1 laboratory device from Aeromatic, Bubendorf / Switzerland).
- the colorless product obtained does not clump and is non-dusting and free-flowing.
- the chemicals listed under B are mixed and granulated in the same granulator (as in A) by spraying on 50% by weight ammonium iron EDTA solution, which contains excess ammonia, in about 7 minutes. 200 ml of this solution are sprayed onto 600 g of mixture B at room temperature.
- Granules A and B are mixed to produce the ready-to-use mixed granulate.
- the mixture of 91.1 g of granules A and 57.8 g of granules B gives the amount of mixed granules required for 1 liter of bleach-fixing bath.
- the mixed granulate is free-flowing, free-flowing and non-dusting. With stirring, it dissolves in water at room temperature in 45 seconds to a dark red solution. This is no different from a second sample made from the same amount of the corresponding powdered chemicals.
- the mixed granulate, packed airtight and moisture-proof, has an unlimited shelf life.
- the photographic effectiveness corresponds entirely to a bleach-fix bath which was produced from non-granulated chemicals according to the same recipe.
- the mixture After comminution in the so-called Alexander mill, the mixture is ground in an air jet mill to an average particle size of approximately 5 ⁇ m.
- the colorless granules are dust-free, free-flowing and non-clumping. Sealed in aluminum-coated bags, it has an unlimited shelf life. It dissolves in water with stirring within about 10 seconds to a colorless and clear solution with a pH of 7.3.
- this solution corresponds entirely to a second one, which was produced from the same chemicals without granulation using the same recipe.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Detergent Compositions (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
Claims (7)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3933226 | 1989-05-10 | ||
DE3920920 | 1989-06-27 | ||
DE19893920920 DE3920920A1 (de) | 1989-06-27 | 1989-06-27 | Granuliertes, fotografisches fixiermittel und seine herstellung |
DE19893933226 DE3933226A1 (de) | 1989-10-05 | 1989-10-05 | Granuliertes, fotografisches fixiermittel und seine herstellung |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0405238A1 EP0405238A1 (fr) | 1991-01-02 |
EP0405238B1 true EP0405238B1 (fr) | 1992-08-19 |
Family
ID=25882361
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90111254A Expired - Lifetime EP0405238B1 (fr) | 1989-06-27 | 1990-06-14 | Composition fixateur photographique granulée et sa préparation |
Country Status (4)
Country | Link |
---|---|
US (1) | US5055384A (fr) |
EP (1) | EP0405238B1 (fr) |
JP (1) | JPH0339735A (fr) |
DE (1) | DE59000265D1 (fr) |
Families Citing this family (65)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0479262B1 (fr) * | 1990-10-02 | 1997-08-13 | Fuji Photo Film Co., Ltd. | Procédé de traitement d'un matériau photographique pour la photographie en couleur |
US5780211A (en) * | 1991-05-01 | 1998-07-14 | Konica Corporation | Processing composition in the tablet form for silver halide photographic light-sensitive material |
DE69231432T2 (de) * | 1991-05-31 | 2001-02-22 | Konishiroku Photo Ind | Verarbeitungsverfahren für lichtempfindliche fotografische Schwarzweiss-Silberhalogenidmaterialien |
JPH0593989A (ja) * | 1991-10-03 | 1993-04-16 | Konica Corp | 写真用処理剤の包装材料 |
JP3088155B2 (ja) * | 1991-10-21 | 2000-09-18 | 富士写真フイルム株式会社 | 写真用処理剤 |
DE69226238T2 (de) * | 1991-11-06 | 1998-11-19 | Konishiroku Photo Ind | Tablettenförmiges Behandlungsmittel und Methode zur Verarbeitung photographischer lichtempfindlicher Silberhalogenidmaterialien |
US5270154A (en) * | 1992-01-31 | 1993-12-14 | Fuji Hunt Photographic Chemicals Inc. | Method of making flowable alkaline thiosulfate/alkaline sulfite and the product thereof |
JPH05289248A (ja) * | 1992-04-08 | 1993-11-05 | Konica Corp | 写真用処理剤 |
JPH0627619A (ja) * | 1992-05-13 | 1994-02-04 | Fuji Photo Film Co Ltd | カラー写真用漂白定着組成物 |
JP2929339B2 (ja) * | 1992-07-16 | 1999-08-03 | コニカ株式会社 | 白黒写真用処理剤 |
JPH0643604A (ja) * | 1992-07-25 | 1994-02-18 | Konica Corp | ハロゲン化銀写真感光材料の処理方法 |
JPH0659404A (ja) * | 1992-08-12 | 1994-03-04 | Konica Corp | ハロゲン化銀写真感光材料の現像処理方法及び処理剤 |
JP2934997B2 (ja) * | 1993-01-21 | 1999-08-16 | コニカ株式会社 | 黒白ハロゲン化銀写真感光材料の処理方法 |
US5480768A (en) * | 1993-02-17 | 1996-01-02 | Konica Corporation | Method for processing exposed silver halide photographic light-sensitive material using a solid processing composition replenisher |
DE69400979T2 (de) * | 1993-05-10 | 1997-06-12 | Konishiroku Photo Ind | Tablette zur Verarbeitung eines farbphotographischen lichtempfindlichen Materials |
US5409805A (en) * | 1993-07-29 | 1995-04-25 | Konica Corporation | Solid processing agent for silver halide photographic light-sensitive materials |
US5557362A (en) | 1994-06-16 | 1996-09-17 | Konica Corporation | Silver halide photosensitive material automatic developing apparatus |
JPH0869098A (ja) | 1994-08-31 | 1996-03-12 | Konica Corp | ハロゲン化銀写真感光材料用自動現像機 |
US5624793A (en) * | 1994-11-11 | 1997-04-29 | Konica Corporation | Method of manufacturing solid processing composition for silver halide photographic light-sensitive materials |
JPH08160588A (ja) | 1994-12-06 | 1996-06-21 | Konica Corp | ハロゲン化銀写真感光材料用自動現像機 |
US5618658A (en) * | 1995-02-22 | 1997-04-08 | Fuji Hunt Photographic Chemicals, Inc. | Process for producing an ammonium thiosulfate product |
JP3574986B2 (ja) | 1996-01-16 | 2004-10-06 | コニカミノルタホールディングス株式会社 | ハロゲン化銀写真感光材料用固体処理剤及びハロゲン化銀写真感光材料の処理方法 |
US5922521A (en) * | 1998-03-26 | 1999-07-13 | Eastman Kodak Company | Uniformly mixed dry photographic processing composition and method of preparation |
JP5588597B2 (ja) | 2007-03-23 | 2014-09-10 | 富士フイルム株式会社 | 導電性材料の製造方法及び製造装置 |
EP2009977A3 (fr) | 2007-05-09 | 2011-04-27 | FUJIFILM Corporation | Film protecteur électromagnétique et filtre optique |
US8765170B2 (en) | 2008-01-30 | 2014-07-01 | The Procter & Gamble Company | Personal care composition in the form of an article |
CN102006852B (zh) | 2008-04-16 | 2013-07-17 | 宝洁公司 | 制品形式的不起泡个人护理组合物 |
EP2355776B1 (fr) | 2008-12-08 | 2017-11-15 | The Procter and Gamble Company | Substrat solide poreux soluble et complexes de parfums particulaires inorganiques se situant en surface |
US8466099B2 (en) | 2008-12-08 | 2013-06-18 | The Procter & Gamble Company | Process of making an article for dissolution upon use to deliver surfactants |
EP2355772B1 (fr) | 2008-12-08 | 2016-11-09 | The Procter and Gamble Company | Composition d'hygiène personnelle sous la forme d'un article à structure solide soluble et poreuse |
CN102325517B (zh) | 2008-12-08 | 2015-06-17 | 宝洁公司 | 具有可溶性多孔固体结构制品形式的个人护理组合物 |
EP2509564B1 (fr) | 2009-12-08 | 2013-11-20 | The Procter and Gamble Company | Substrat solide poreux pouvant être dissous et revêtement résidant en surface comprenant des microsphères de matrice |
WO2011071969A1 (fr) | 2009-12-08 | 2011-06-16 | The Procter & Gamble Company | Substrat solide, poreux et soluble et revitalisant capillaire à base d'un tensioactif cationique |
US8349341B2 (en) | 2009-12-08 | 2013-01-08 | The Procter & Gamble Company | Porous, dissolvable solid substrate and a surface resident coating of cationic surfactant conditioner |
EP2536386A1 (fr) | 2010-02-16 | 2012-12-26 | The Procter & Gamble Company | Substrat solide soluble poreux et revêtement de surface comprenant du pyrithione de zinc |
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US20180163325A1 (en) | 2016-12-09 | 2018-06-14 | Robert Wayne Glenn, Jr. | Dissolvable fibrous web structure article comprising active agents |
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CN103582474A (zh) | 2011-05-27 | 2014-02-12 | 宝洁公司 | 可溶性固体毛发着色制品 |
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CN114796017A (zh) | 2014-04-22 | 2022-07-29 | 宝洁公司 | 可溶性固体结构体形式的组合物 |
JP7028877B2 (ja) | 2017-01-27 | 2022-03-02 | ザ プロクター アンド ギャンブル カンパニー | 溶解性固形構造体形態の組成物 |
JP6882519B2 (ja) | 2017-01-27 | 2021-06-02 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 発泡性凝集粒子を含む溶解性固形構造体形態の組成物 |
CN110650723A (zh) | 2017-05-16 | 2020-01-03 | 宝洁公司 | 可溶性固体结构形式的调理毛发护理组合物 |
JP1629688S (fr) | 2018-07-16 | 2019-04-15 | ||
US11666514B2 (en) | 2018-09-21 | 2023-06-06 | The Procter & Gamble Company | Fibrous structures containing polymer matrix particles with perfume ingredients |
EP3989913A1 (fr) | 2019-06-28 | 2022-05-04 | The Procter & Gamble Company | Articles fibreux solides solubles contenant des tensioactifs anioniques |
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USD939359S1 (en) | 2019-10-01 | 2021-12-28 | The Procter And Gamble Plaza | Packaging for a single dose personal care product |
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USD962050S1 (en) | 2020-03-20 | 2022-08-30 | The Procter And Gamble Company | Primary package for a solid, single dose beauty care composition |
USD941051S1 (en) | 2020-03-20 | 2022-01-18 | The Procter And Gamble Company | Shower hanger |
USD965440S1 (en) | 2020-06-29 | 2022-10-04 | The Procter And Gamble Company | Package |
WO2022027067A1 (fr) | 2020-07-31 | 2022-02-03 | The Procter & Gamble Company | Sachet fibreux soluble dans l'eau contenant des granules pour soins capillaires |
EP4196234A1 (fr) | 2020-08-11 | 2023-06-21 | The Procter & Gamble Company | Compositions d'après-shampooing à rinçage propre contenant de l'ésylate de valinate de brassicyle (bve) |
CN116456957A (zh) | 2020-08-11 | 2023-07-18 | 宝洁公司 | 含有芸苔油醇缬氨酸酯乙磺酸盐的低粘度毛发调理剂组合物 |
MX2023001045A (es) | 2020-08-11 | 2023-02-16 | Procter & Gamble | Composiciones acondicionadoras humectantes para el cabello que contienen esilato de valinato de brassicilo. |
BR112023003531A2 (pt) | 2020-09-10 | 2023-04-11 | Procter & Gamble | Artigo sólido dissolúvel contendo ativos antibacterianos |
WO2022119783A1 (fr) | 2020-12-01 | 2022-06-09 | The Procter & Gamble Company | Compositions aqueuses de conditionneur capillaire contenant des agents actifs antipelliculaires solubilisés |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2543086A (en) * | 1947-11-22 | 1951-02-27 | Eastman Kodak Co | Method of preparing dustless photographic fixing powders |
GB1099790A (en) * | 1966-02-01 | 1968-01-17 | Goldschmidt Ag Th | Flowable ammonium thiosulfate and method for its manufacture |
DE1911609C3 (de) * | 1969-03-07 | 1975-10-16 | Hoechst Ag, 6000 Frankfurt | Fotografische Fixiersalzmischung |
BE758333A (fr) * | 1969-11-03 | 1971-04-01 | Eastman Kodak Co | Nouvelle composition photographique de |
JPS511425A (en) * | 1974-06-18 | 1976-01-08 | Matsushita Electric Ind Co Ltd | Azobenzenjudotaino seizohoho |
JPS51151135A (en) * | 1975-06-09 | 1976-12-25 | Fuaburika Kimufuoto | Method of producing black and white movie and photographic film treating special composition developing reagent |
JPS54133332A (en) * | 1978-04-07 | 1979-10-17 | Oriental Photo Ind Co Ltd | Preparation of powdered bleaching agent for photograph |
JPS6132848A (ja) * | 1984-07-26 | 1986-02-15 | Konishiroku Photo Ind Co Ltd | 写真処理剤封入袋 |
JP2556339B2 (ja) * | 1987-09-29 | 1996-11-20 | コニカ株式会社 | 長期処理安定性を有する写真処理剤及び写真感光材料の処理方法 |
DE3830023A1 (de) * | 1988-09-03 | 1990-03-15 | Agfa Gevaert Ag | Granulierter, farbfotografischer entwickler und seine herstellung |
-
1990
- 1990-06-13 US US07/537,893 patent/US5055384A/en not_active Expired - Fee Related
- 1990-06-14 EP EP90111254A patent/EP0405238B1/fr not_active Expired - Lifetime
- 1990-06-14 DE DE9090111254T patent/DE59000265D1/de not_active Expired - Fee Related
- 1990-06-26 JP JP2165822A patent/JPH0339735A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
DE59000265D1 (de) | 1992-09-24 |
JPH0339735A (ja) | 1991-02-20 |
EP0405238A1 (fr) | 1991-01-02 |
US5055384A (en) | 1991-10-08 |
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