EP0280143B1 - Agent de nettoyage liquide - Google Patents

Agent de nettoyage liquide Download PDF

Info

Publication number
EP0280143B1
EP0280143B1 EP88102172A EP88102172A EP0280143B1 EP 0280143 B1 EP0280143 B1 EP 0280143B1 EP 88102172 A EP88102172 A EP 88102172A EP 88102172 A EP88102172 A EP 88102172A EP 0280143 B1 EP0280143 B1 EP 0280143B1
Authority
EP
European Patent Office
Prior art keywords
alkyl
detergent
weight
carbon atoms
alkyl radical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP88102172A
Other languages
German (de)
English (en)
Other versions
EP0280143A1 (fr
Inventor
Klaus-Dieter Dr. Wisotzki
Ortburg Guirr
Peter Dr. Jeschke
Klaus Dr. Schumann
Karl-Heinz Dr. Schmid
Manfred Dr. Biermann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6321726&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0280143(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to AT88102172T priority Critical patent/ATE66958T1/de
Publication of EP0280143A1 publication Critical patent/EP0280143A1/fr
Application granted granted Critical
Publication of EP0280143B1 publication Critical patent/EP0280143B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds

Definitions

  • Liquid cleaning agents usually consist of aqueous solutions of synthetic anionic and / or nonionic surfactants and conventional additives. They are particularly used for cleaning hard surfaces, for example glass, ceramic materials, plastics, painted and polished surfaces.
  • An important area of application for liquid detergents is the manual washing of eating and cooking utensils. The dishes are usually cleaned at slightly elevated temperatures of around 35 to 45 ° C in very dilute liquors. The cleaning power of an agent is generally assessed by the consumer the better and the longer the cleaning liquor foams. Because of the contact of the hands with the cleaning liquor over a longer period of time, the skin-friendliness of the agent is of particular importance when washing dishes manually. For these reasons, the expert makes different considerations when selecting the components and the composition of an agent for the manual cleaning of dishes than with liquid detergents for other hard surfaces.
  • alkyl ether sulfates that is to say salts of sulfated adducts of about 2 to 5 moles of ethylene oxide with fatty alcohols of about 10 to 18, preferably 12 to 16 carbon atoms in the aliphatic residue have good foaming and cleaning power as well as skin-friendly properties.
  • the commercially available, manual dishwashing detergents also known as dishwashing detergents
  • dishwashing detergents therefore generally represent aqueous solutions of such alkyl ether sulfates in conjunction with other surfactants, in particular alkylbenzenesulfonates, and solubilizers, colorants and fragrances.
  • Swiss patent 354 195 discloses liquid detergents for manual dishwashing, which are a combination of an alkyl ether sulfate and a nonionic surfactant of the fatty acid alkanolamide type from mono- or dialkanolamides with no more than 3 carbon atoms in each alkanol residue of saturated fatty acids with 10 to 14 Contain carbon atoms, together with water, solubilizers, colors and fragrances.
  • European patent application 70 076 discloses foaming liquid detergents containing anionic surfactants, alkyl glucosides and amine oxides or fatty acid alkanolamides, the alkyl glucosides being alkyl oligoglucosides which contain the glucose unit about 1.5 to 10 times. This value is an average value and also takes into account the presence of alkyl monoglucosides in a corresponding proportion. Alkyl glucosides with a degree of oligomerization of higher than 2 are found to be particularly suitable.
  • German patent application P 35 34 082.7 describes a liquid cleaning agent for the manual cleaning of dishes, containing synthetic anionic surfactants of the sulfonate and / or sulfate surfactant type, fatty acid alkanolamides and fatty alkyl glucosides, which is characterized in that it contains fatty alkyl glucosides of the fatty alkyl monoglucoside type contains on average less than 2 glucoside units per fatty alkyl radical, in particular 1 to 1.4 glucoside units.
  • Detergents especially dishwashing detergents, containing di-n-alkyl sulfosuccinates have long been known.
  • liquid dishwashing detergents which contain alkyl ether sulfates and sulfosuccinates, preferably di-n-octyl sulfosuccinate, and, if appropriate, further surfactants are described in German patent specification 23 17 076.
  • aqueous mixture of alkyl sulfosuccinates and alkyl ether sulfates is also known from European patent application 124367. It also describes aqueous solutions of alkyl sulfosuccinates alone and of alkyl sulfosuccinates in a mixture with alkyl benzene sulfonates.
  • foaming and cleaning power of liquid optionally aqueous cleaning agents which are specifically designed for the manual cleaning of dishes and which essentially contain alkyl glucosides having 10 to 18 carbon atoms in the alkyl radical and 1 to 5 glucose units in the molecule, can be enhanced by adding di-alkylsulfosuccinates with 7 to 9, in particular 8, carbon atoms in the alkyl radical.
  • the alkyl radical can be straight-chain or branched.
  • the proportion of di-alkyl sulfosuccinates is 20 to 90, preferably 50 to 80 parts by weight, based on the total surfactant content of 15 to 50% by weight in the product. They are present as alkali, especially as sodium salts.
  • the proportion of alkyl glucosides with 10 to 18, preferably 12 to 14 carbon atoms in the alkyl radical and with 1 to 5, preferably 1 to 1.4 glucose units (GE) in the molecule in the agents according to the invention is accordingly 10 to 80, preferably 20 to 50 parts by weight. based on the total surfactant content of 15 to 50 wt .-% in the product.
  • anionic surfactants preferably alkyl ether sulfates or alkyl sulfates - and amphoteric surfactants such as.
  • B Acylamidopropyldimethylammoniumbetain performance improvements in washability and improvements in storage stability can be achieved.
  • compositions according to the invention are preferably free from the proportions of anionic surfactants based on petrochemicals, such as, for example, which are generally customary for such compositions.
  • anionic surfactants based on petrochemicals, such as, for example, which are generally customary for such compositions.
  • Alkanolamines, polyols, such as ethylene glycol, 1,2-propylene glycol or glycerol and, for example, hydrotropic alkali-alkylbenzenesulfonates with 1 to 3 carbon atoms in the alkyl radical, such as sodium cumolsulfonate, can serve as solubilizers, for example for small amounts of dye and perfume oil.
  • the amounts used are then generally between 1 and 10 percent by weight, based on the total agent.
  • solvents such as low molecular weight alkanols with 1 to 4 carbon atoms in the molecule, preferably ethanol and isopropyl alcohol.
  • solvents such as low molecular weight alkanols with 1 to 4 carbon atoms in the molecule, preferably ethanol and isopropyl alcohol.
  • the amounts used are also 3 to 15 percent by weight, based on the total agent.
  • Viscosity regulators such as urea, sodium chloride, ammonium chloride, magnesium chloride and sodium citrate can also be used individually or in combination.
  • Other common optional additives are corrosion inhibitors, preservatives, dyes and perfume oils.
  • a remainder, to be calculated for a total of 100 percent by weight, for the total composition consists of water.
  • liquid cleaning agents according to the invention according to the following examples were obtained by stirring the individual constituents together and allowing the mixture to stand until there were no bubbles.
  • the sodium salts were used as sulfosuccinates.
  • the plate test is described in this example.
  • the amount of 27 g of di-isooctylsulfosuccinate was stirred at room temperature with 15 g of isopropanol in 55 g of water. And with further stirring, 3 g of C 12/14 alkyl glucoside with 1.1 glucose units (GE) were added in the molecule.
  • the product was clear and had a viscosity of 30 mPas determined according to Höppler at 20 ° C.
  • saucers were coated with 2 g of melted beef tallow (test soil A). Then 8 liters of tap water (16 ° d) at 50 ° C was placed in a bowl.
  • a solution of 10 g of di-isooctylsulfosuccinate, 4 g of C 12/14 alkyl glucoside GE, 1.4.6 g of C 12/14 alkyl ether sulfate with 2 ethylene oxide groups, 10 g of isopropanol and 70 g of water was, according to Example 1, in a plate test with 0 , 6 g detergent / l rinsing solution. Of the plates soiled with test soil (B), 27 plates were rinsed clean. However, if 2 g of the alkyl ether sulfate were replaced by 2 g of C 8/18 acylamidopropyldimethylammonium betaine (Dehyton K®), 30 plates were rinsed clean.
  • test series also carried out in analogy to Example 1, show the influence of the degree of oligomerization of the C 12/14 alkyl glucoside on the rinsing performance in combination with di-n-octylsulfosuccinate. Note the decrease in the rinsing performance with increasing degree of oligomerization of the alkyl glucoside in mixed soiling (B).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Claims (5)

  1. Produit de nettoyage liquide, éventuellement aqueux, pour le nettoyage de la vaisselle à la main, contenant essentiellement des alkylglucosides ayant de 10 à 18 atomes de carbone dans le radical alkyle et comportant de 1 à 5 unités glucose dans la molécule, caractérisé en ce qu'il contient en outre des di-alkylsulfosuccinates ayant de 7 à 9 atomes de carbone dans le radical alkyle.
  2. Produit selon la revendication 1, caractérisé en ce que les di-alkylsulfosuccinates contiennent 8 atomes de carbone dans le radical alkyle et se trouvent sous forme de sels alcalins, en particulier de sodium.
  3. Produit selon la revendication 1 ou 2, caractérisé en ce que le radical alkyle des sulfosuccinates est à chaîne droite ou ramifiée.
  4. Produit selon l'une quelconque des revendications 1 à 3, caractérisé en ce que les alkylglucosides comportent essentiellement de 12 à 14 atomes de carbone dans le radical alkyle et de 1 à 1,4 unités glucose dans la molécule.
  5. Produit selon l'une quelconque des revendications 1 à 4, caractérisé en ce que l'akylglucoside est présent en une quantité de 10 à 80, de préférence de 20 à 50 parties en poids, et le di-alkylsulfosuccinate est présent en une quantité de 20 à 90, de préférence de 50 à 80 parties en poids, dans chaque cas par rapport à une teneur totale en agents tensioactifs du produit de nettoyage allant de 15 à 50 % en poids.
EP88102172A 1987-02-25 1988-02-15 Agent de nettoyage liquide Expired - Lifetime EP0280143B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88102172T ATE66958T1 (de) 1987-02-25 1988-02-15 Fluessiges reinigungsmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3706015 1987-02-25
DE19873706015 DE3706015A1 (de) 1987-02-25 1987-02-25 Fluessiges reinigungsmittel

Publications (2)

Publication Number Publication Date
EP0280143A1 EP0280143A1 (fr) 1988-08-31
EP0280143B1 true EP0280143B1 (fr) 1991-09-04

Family

ID=6321726

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88102172A Expired - Lifetime EP0280143B1 (fr) 1987-02-25 1988-02-15 Agent de nettoyage liquide

Country Status (9)

Country Link
US (1) US4839098A (fr)
EP (1) EP0280143B1 (fr)
JP (1) JPS63225697A (fr)
AT (1) ATE66958T1 (fr)
BR (1) BR8800782A (fr)
CA (1) CA1333767C (fr)
DE (2) DE3706015A1 (fr)
ES (1) ES2024562B3 (fr)
GR (1) GR3002651T3 (fr)

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DE3827778A1 (de) * 1988-08-16 1990-02-22 Henkel Kgaa Pastenfoermiges wasch- und reinigungsmittel und verfahren zur herstellung
JPH0742476B2 (ja) * 1988-09-08 1995-05-10 花王株式会社 低刺激性洗浄剤組成物
US5015414A (en) * 1988-09-08 1991-05-14 Kao Corporation Low-irritant detergent composition containing alkyl saccharide and sulfosuccinate surfactants
JP2526105B2 (ja) * 1988-09-20 1996-08-21 花王株式会社 洗浄剤組成物
DE3838808A1 (de) * 1988-11-17 1990-05-23 Henkel Kgaa Wasch- und reinigungsmittel, enthaltend ein tensidgemisch aus alkylglykosiden und aniontensiden
JPH05504780A (ja) * 1989-05-18 1993-07-22 ヘンケル・コーポレイション スルホスクシネート洗浄剤組成物
US6087320A (en) * 1989-09-14 2000-07-11 Henkel Corp. Viscosity-adjusted surfactant concentrate compositions
WO1991004313A1 (fr) * 1989-09-14 1991-04-04 Henkel Corporation Compositions tensio-actives anioniques et amphoteres a viscosite reduite
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DE4005959A1 (de) * 1990-02-26 1991-08-29 Huels Chemische Werke Ag Fluessiges, schaeumendes reinigungsmittel
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DE4019790A1 (de) * 1990-06-21 1992-01-02 Henkel Kgaa Fluessige alkylglykosidhaltige tensidmischung
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US5480586A (en) * 1991-04-15 1996-01-02 Colgate-Palmolive Co. Light duty liquid detergent compostion comprising a sulfosuccinamate-containing surfactant blend
US5565146A (en) * 1991-04-15 1996-10-15 Cologate-Palmolive Co. Light duty liquid detergent compositions
AU661682B2 (en) * 1991-04-15 1995-08-03 Colgate-Palmolive Company, The Light duty liquid detergent compositions
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EP0647262A4 (fr) * 1992-06-16 1998-04-29 Henkel Corp Compositions de concentres de tensioactifs a viscosite controlee.
CA2152923A1 (fr) * 1993-01-12 1994-07-21 Allen D. Urfer Detergent pour lave-vaisselle
US5518647A (en) * 1993-12-20 1996-05-21 Colgate-Palmolive Company Foaming liquid emulsion composition
ZA951012B (en) * 1994-02-14 1996-08-08 Colgate Palmolive Co Composition
DE4435387C2 (de) * 1994-10-04 1997-08-14 Henkel Kgaa Pumpfähige wäßrige Tensidkonzentrate
DE19615271A1 (de) * 1996-04-18 1997-10-23 Huels Chemische Werke Ag Tensidhaltige Reinigungsmittel in Form einer Mikroemulsion
US6245401B1 (en) 1999-03-12 2001-06-12 Kimberly-Clark Worldwide, Inc. Segmented conformable breathable films
PE20000627A1 (es) 1998-05-30 2000-07-26 Kimberly Clark Co Material absorbente
US6107268A (en) * 1999-04-16 2000-08-22 Kimberly-Clark Worldwide, Inc. Sorbent material
US6355583B1 (en) 1998-05-30 2002-03-12 Kimberly-Clark Worldwide, Inc. Multi-functional sorbent material
DE19956236A1 (de) * 1999-11-23 2001-05-31 Cognis Deutschland Gmbh Schaumarme Tensidkonzentrate für den Einsatz im Bereich der Förderung des Pflanzenwachstums
US7259131B2 (en) * 2004-07-20 2007-08-21 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mild, moisturizing cleansing compositions
US7041627B2 (en) * 2004-07-20 2006-05-09 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mild, moisturizing sulfosuccinate cleansing compositions
US20060019847A1 (en) * 2004-07-20 2006-01-26 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mild, moisturizing cleansing compositions with improved storage stability
CA2573692A1 (fr) * 2004-07-23 2006-02-23 The Procter & Gamble Company Composition de detergent liquide pour le nettoyage ameliore des graisses a basse temperature et le nettoyage de taches d'amidon
US8062676B2 (en) * 2005-08-02 2011-11-22 Thomas Besendorfer Pesticide composition
JP5659038B2 (ja) * 2011-02-21 2015-01-28 花王株式会社 食器洗浄用洗浄剤組成物
BR112022016702A2 (pt) * 2020-03-17 2022-10-11 Kao Corp Composição de tensoativo, agente de controle de formação de espuma, e método para controlar o desempenho de formação de espuma de uma composição de tensoativo
CN112662487B (zh) * 2021-01-21 2022-03-11 福建省佑达环保材料有限公司 一种tft基板减薄抛光后清洗剂

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US3925224A (en) * 1973-04-17 1975-12-09 Church & Dwight Co Inc Detergent additive composition
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EP0070074A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions moussantes contenant des agents tensio-actifs
GB2133793A (en) * 1983-01-21 1984-08-01 Unilever Plc Detergent active dialkylsulphosuccinate mixture

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US3925224A (en) * 1973-04-17 1975-12-09 Church & Dwight Co Inc Detergent additive composition
GB2015325A (en) * 1978-02-24 1979-09-12 Woinarski P A Containers with bail handles
EP0070074A2 (fr) * 1981-07-13 1983-01-19 THE PROCTER & GAMBLE COMPANY Compositions moussantes contenant des agents tensio-actifs
GB2133793A (en) * 1983-01-21 1984-08-01 Unilever Plc Detergent active dialkylsulphosuccinate mixture

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Stache: Tensid-Taschenbuch, 2. Auflage, Seite 302 *

Also Published As

Publication number Publication date
US4839098A (en) 1989-06-13
ES2024562B3 (es) 1992-03-01
CA1333767C (fr) 1995-01-03
DE3864538D1 (de) 1991-10-10
GR3002651T3 (en) 1993-01-25
EP0280143A1 (fr) 1988-08-31
ATE66958T1 (de) 1991-09-15
JPS63225697A (ja) 1988-09-20
BR8800782A (pt) 1988-10-04
DE3706015A1 (de) 1988-11-17

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