EP0172758A1 - Zusammensetzungen von Zusätzen vor allem verwendbar zur Verbesserung der Filtriereigenschaften von Petrol-Mitteldestillaten in der Kälte - Google Patents
Zusammensetzungen von Zusätzen vor allem verwendbar zur Verbesserung der Filtriereigenschaften von Petrol-Mitteldestillaten in der Kälte Download PDFInfo
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- EP0172758A1 EP0172758A1 EP85401312A EP85401312A EP0172758A1 EP 0172758 A1 EP0172758 A1 EP 0172758A1 EP 85401312 A EP85401312 A EP 85401312A EP 85401312 A EP85401312 A EP 85401312A EP 0172758 A1 EP0172758 A1 EP 0172758A1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/146—Macromolecular compounds according to different macromolecular groups, mixtures thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1625—Hydrocarbons macromolecular compounds
- C10L1/1633—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds
- C10L1/1641—Hydrocarbons macromolecular compounds homo- or copolymers obtained by reactions only involving carbon-to carbon unsaturated bonds from compounds containing aliphatic monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/234—Macromolecular compounds
- C10L1/236—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof
- C10L1/2364—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derivatives thereof homo- or copolymers derived from unsaturated compounds containing amide and/or imide groups
Definitions
- the invention relates to the combined use of additives having synergistic properties on the cold filterability of middle petroleum distillates, in particular diesel fuels. It also relates to the compositions of petroleum middle distillates comprising these combinations of additives.
- branched polyethylene in middle distillates does not make it possible to obtain satisfactory properties of cold filterability; the same applies to various copolymers based on ethylene and another co-monomer such as, for example, vinyl acetate, olefins-a, esters or diesters having an olefinic double bond.
- compositions in which one of the constituents is an ethylene copolymer.
- US Patent 3,640,691 associates a paraffinic minor fraction, containing n-paraffins of 24 to 40 carbon atoms, with ethylene / vinyl acetate copolymers.
- French patent FR 2 061 457 combines two copolymers, of different molecular weights, based on ethylene and vinyl acetate.
- Japanese patent JP.57.209.995 describes a synergistic action between a residual heavy oil and a copolymer of ethylene and of carboxylic acid ester having ethylenic bonds.
- European patent EP 0.074.208 describes a synergistic action on the limit temperature of filterability of fuel oils between, on the one hand, a copolymer of ethylene and alkoxy-alkyl (meth) acrylate and, on the other hand On the other hand, an ethylene copolymer associated either with a vinyl ester or with an alkyl ester of an unsaturated acid.
- US Patent 3,961,916 teaches the synergy between two copolymers, both composed of ethylene copolymerized with either vinyl esters or alkyl (meth) acrylates.
- US Patent 4,153,424 describes the synergistic effect of a copolymer of ethylene and alkyl acrylates combined with a homo or co-polymer of alkyl acrylate and / or methacrylate.
- compositions have also been described comprising three different compounds.
- the Japanese patent JP 56,043,391 describes the synergistic action of a chlorinated polyethylene, a branched polyethylene, and an alkenyl succinamide.
- US Patent 3,982,909 teaches the synergistic effect of three components: A) a mono-amide or mono-esterified derivative of unsaturated dicarboxylic acid;
- compositions in which one of the constituents is polyethylene are polyethylene.
- US Pat. No. 3,640,824 associates a highly branched polyethylene of molecular mass in number greater than 6,000 with a microcrystalline wax, and / or with naphthalene, and / or with asphaltenes.
- US Patent 3,166,387 describes the synergistic action of low molecular weight polyethylene associated with a secondary or tertiary amine salt of carboxylic acid.
- R represents a monovalent saturated aliphatic radical of 1 to 30 carbon atoms
- Z is chosen from the groups -NH-, -NR'- in which R 'represents a monovalent saturated aliphatic radical of 1 to 30 carbon atoms, and l oxygen atom -0-, n is an integer from 2 to 4, m is zero or an integer from 1 to 4; and R "represents a divalent saturated aliphatic radical of 1 to 18 carbon atoms.
- the constituent (B) more particularly has a number average molecular weight of 1,000 to 10,000.
- the copolymers considered for the formation of constituent (B) more particularly comprise a proportion of 15 to 40% by moles of units deriving from ⁇ -olefins, from 20 to 70% by moles of units deriving from unsaturated ⁇ , ⁇ -dicarboxylic compound and from 15 to 40 mol% of units derived from an alkyl ester of unsaturated monocarboxylic acid.
- the linear ⁇ -olefins used in the composition of the polymers contain, for example, from 16 to 30 carbon atoms.
- mixtures of linear olefins of 20 to 24 carbon atoms, of 24 to 28 carbon atoms are used or alternatively sections containing about 20% by weight of olefin-a of at most 28 carbon atoms and about 80% by weight of ⁇ -olefins of 30 carbon atoms or more.
- the unsaturated a, S-dicarboxylic compounds used in the composition of the copolymer are more particularly dicarboxylic acids such as maleic acid, or alkylmaleic acids, for example methylmaleic (or citraconic) acid.
- These compounds can also consist of alkyl diesters of these dicarboxylic acids, in particular methyl, ethyl or propylic diesters, or alternatively of the anhydrides corresponding to these dicarboxylic acids.
- Anhydrides will be preferred, and more particularly maleic anhydride.
- the alkyl esters of unsaturated monocarboxylic acids are more particularly the acrylates and alkyl methacrylates of 4 to 30 carbon atoms, for example butyl, ethylhexyl, decyl, dodecyl, hexadecyl acrylates, octadecyl and eicosyl. Mention may also be made of the acrylates and methacrylates of industrial alcohol fractions containing on average 12 carbon atoms (lauryl acrylate and methacrylate) or 18 carbon atoms (stearyl acrylate and methacrylate), as well as more alcohol fractions heavy, rich in alcohols having 20 or 22 carbon atoms.
- the vinyl esters of saturated aliphatic monocarboxylic acids are more particularly vinyl esters of monocarboxylic acids of 2 to 22 carbon atoms.
- R represents a monovalent saturated aliphatic radical, comprising from 1 to 30 carbon atoms.
- Z may, depending on the case, be an oxygen atom or represent a divalent group -NH- or -NR'-, R 'being a monovalent aliphatic radical, preferably linear, comprising from 1 to 30 carbon atoms and preferably of 12 to 24 carbon atoms, n is an integer from 2 to 4, and m can have the value zero, when Z is NH, or be an integer from 1 to 4, in all cases.
- the compounds of formula (I) above can consist of primary amines of formula R-NH 2 (in this case, in formula (I), Z represents the group -NH-, and the value of m is zero) .
- the radical R is linear and contains from 12 to 24 carbon atoms.
- these amines mention may be made of: dodecylamine, tetradecylamine, hexadecylamine, octadecylamine, eicosylamine and docosylamine.
- the compounds of formula (I) can also consist of polyamines derived from saturated aliphatic amines corresponding to the formula: which corresponds to the general formula (I) in which Z represents the group -NH-; m can have a value of 1 to 4 and n a value of 2 to 4, preferably 3.
- the radical R is linear and contains from 12 to 24 carbon atoms.
- the compounds of formula (I) can also consist of polyamines corresponding to the formula:
- Z represents -NR '- and where R and R', identical or different, are each an alkyl radical having from 1 to 24 and preferably from 8 to 24 carbon atoms, R and R '' containing both of them preferably from 16 to 32 carbon atoms; n has a value of 2 to 4 and m a value of 1 to 4.
- N, N-diethyl-1,2-diamino ethane N, N-diisopropyldiamino-1,2 ethane, N, N-1,2-dibutyl diamino-ethane, N, N- 1,4-diethyl-diamino butane, N, N-dimethyl-diamino-1,3 propane, N, N-diethyl-diamino-1,3 propane, N, N-dioctyl-diamino-1,3 propane , N, N-didécyldiamino-1,3 propane, N, N-didodécyl-diamino-1,3 propane, N, N-dissetradécyl-diamino-1,3 propane, N, N - dihexadécyldiamino-1, 3 propane, N, N-dioctadecyldi
- the compounds of formula (I) can consist of ether-amines corresponding more particularly to the formula: which corresponds to the general formula (I) in which Z is an oxygen atom; preferably, the radical R is linear and contains from 12 to 24 carbon atoms, m is an integer from 1 to 4 and n is an integer from 1 to 4, preferably 2 or 3.
- ether-amines that may be mentioned as specific compounds: 2-methoxy-ethylamine, 3-methoxy-propylamine, 4-methoxy-butylamine, 3-ethoxypropylamine, 3-octyloxypropylamine, decyloxy- 3 propylamine, hexadecyloxy-3 propylamine, éicosylox y- 3 propylamine, docosyloxy 3-propylamine, N- (3-octyloxy propyl) 1,3-diaminopropane, N- (3-decyloxy propyl) diamino -1.3 propane, (2, trimetyl, 4.6 d c yl) oxy-3 propylamine and N - [(trimethyl-2,4,6 decyl) oxy-3 propyl] diamino-1,3 propane.
- the compound with a primary amine function involved in the preparation of component B of the additive compositions of the invention may also consist of an amino alcohol of formula (II): where R "represents a divalent saturated, linear or branched, preferably linear, preferably linear aliphatic radical containing from 1 to 18 carbon atoms.
- the preparation of the constituents (B) of the additive compositions of the invention is generally carried out in two stages: first the terpolymers are prepared, then the condensation of the compound of formula (I) is carried out thereon and / or (II).
- the terpolymers can be prepared, in the first step, according to conventional radical polymerization methods, for example in the presence of an initiator of the azobisisobutyronitrile or peroxide type, in solution in a hydrocarbon solvent, such as for example cyclohexane, 'isooctane, dodecane, benzene, toluene, xylene, or diisopropylbenzene or even tetrahydrofuran or dioxane.
- a hydrocarbon solvent such as for example cyclohexane, 'isooctane, dodecane, benzene, toluene, xylene, or diisopropylbenzene or even tetrahydrofuran or dioxane.
- hydrocarbon fractions with b.p. point u r- relatively high lition such as kerosene or diesel.
- the amount of solvent used will generally be such that the concentration by weight of dry matter is between 25 and 70% and preferably in the vicinity of 60%.
- the copolymerization reaction in the presence of the radical initiator, is carried out at a temperature of 70 to 200 ° C and preferably from 80 to 130 ° C. Depending on the operating conditions, the duration of the reaction can range from 2 to 14 hours.
- a solution of copolymers is obtained in the form of a viscous liquid of light yellow color.
- the compound of formula (I) or (II) is condensed on the copolymer formed in the first step, according to any usual method.
- the compound of formula (I) or (II) is generally added in a molar proportion corresponding substantially to the proportion of diacid, of diester, or of unsaturated anhydride brought into play in the preparation of the copolymer.
- This proportion can be for example from 0.9 to 1.1 mole of compound ( I ) or ( II ) per mole of dicarboxylic compound .
- the reaction is carried out by heating the mixture to a temperature of between 75 and 130 ° C, preferably between 80 and 100 ° C, the duration of the reaction being between approximately 1 and 6 hours, a duration of the order of 2 hours usually being sufficient.
- the reaction of the products of formula (I) or (II) on the units (b) of the copolymer gives rise to imide groups (succinimides), this reaction being accompanied by the formation of water or alcohol depending on the nature of the functions dicarboxylates of (b) (diacid, anhydride or diester). It is possible, if desired, to remove the volatile products formed from the reaction mixture, either by entrainment with an inert gas such as nitrogen, for example by azeotropic distillation with the chosen solvent.
- an inert gas such as nitrogen
- Another particular mode of synthesis of the constituents (B) of the additive compositions considered in the invention may consist, in certain cases, in carrying out the radical copolymerization of one or more alkyl esters of unsaturated monocarboxylic acids with a mixture ⁇ -olefins and N-substituted maleimides, the latter being obtained by prior reaction of the compounds of formula (I) or (II) with maleic anhydride or one of its abovementioned derivatives.
- the additive compositions of the invention comprising at least one component (A) and at least one component (B) as defined above, are used in particular to improve the cold filterability properties of middle distillates of petroleum with respect to which each of the constituents (A) and (B) used in isolation has only a very reduced effect. It therefore seems that each of the constituents (A) and (B) exerts on the properties of the other a synergistic action, the mechanism of which has not been clearly elucidated.
- this action manifests itself appreciably when the ratio between the weight quantities of the constituents (A) and (B) is between 1/20 and 20/1 and, preferably, from 1/5 to 5/1.
- the combinations of additives (A) and (B) are generally added to these gas oil cuts at overall weight concentrations, between 20 and 2,000 ppm, and more particularly between 50 and 500 ppm.
- To formulate the diesel fuel compositions of the invention it is possible to add the constituents (A) and (B) directly to the diesel fuel by a simple mixing operation. However, it is often advantageous to introduce them in the form of "mother solutions" prepared beforehand: they may be two separate solutions in the same solvent, or in two solvents different ; or a solution of the two constituents.
- the solvent (s) can consist, for example, of solvents of aromatic character, such as for example toluene, xylenes, di-isopropylbenzene, an petroleum fraction of aromatic character having the desired distillation range.
- the “mother solutions” can contain, for example, from 20 to 60% by weight of additives.
- the additive compositions of the invention which are effective in contrast to the conventional additives in enlarged cuts, that is to say those having for example a distillation range of 160 - 370 ° C and more, on the one hand are always so if they are used in a "narrow" cut whose distillation range is for example 225 ° C - 360 ° C and more, that is to say an enlarged cut which has removed the light fraction (kerosene), on the other hand simultaneously inhibit the sedimentation of n-paraffins in gas oils doped at rest, although the n-paraffins are constituted by the heaviest n-paraffins of the distillable fraction of the crude.
- compositions of the invention therefore make it possible to considerably improve the cold filterability properties of middle petroleum distillates, thus making it possible to use as gas oils and fuels cuts of distillates with a higher boiling end point, which represents a obvious economic interest.
- gas oil cuts used are those which appear in Table I; they are characterized according to the distillation ASTM-D-1160; their density is also indicated in table I. One of them is a narrow section, another is a section enlarged; the others are intermediate cuts. They are designated by G1, ... G6.
- concentrations of components (A) and (B) of the additives are expressed in weight proportions of pure products, expressed in parts per million (ppm), it being understood that the compositions can be used in the diluted state.
- filterability limit temperature (T.L.F.) are carried out according to the European standard EN116 of August 1981.
- the number average molecular weight of the terpolymer is 2470.
- the fatty amine is a cut of primary amines whose alkyl chains contain in approximate molar proportions: 1 Z of C 14 , 28% of C 16 and 71% of C 18 . It is used at the rate of 1 molar equivalent.
- the amine is condensed on the terpolymer by heating at 90 ° C for two hours. The solution obtained, adjusted to 30% by weight of dry matter, constitutes the mother solution of B 1 .
- the limit filterability temperature of each of the diesel fuel cuts without additives or additives was determined as indicated in Table II below. (hs TLF are in ° C). These values of the filterability limit temperature for each of the cuts of gas oils treated show that the reductions obtained with the mixtures A 1 + B 1 and A 2 + B according to the invention are very much higher than the values which one might have expected (synergistic effect).
- the overall concentration of additives A 1 + B 1 is 100 ppm in diesel.
- Table III gives the results of the TLF determinations for the various tests; The values obtained for the G 4 diesel cut in example 1 are also given in this table (tests la, 1b, 1d, le).
- the diesel fuel G 1 described in table I is used.
- G 5 by three additives 1, 2 and 3 at a concentration of 50 ppm.
- Additives 1 and 2 correspond to conventional commercial additives.
- Additive 3 corresponds to the composition of the additive of the invention, as described in Example 3.
- TLF values are given in the following table V (in ° C) :
- test pieces are hermetically sealed and then left to stand in a cold room at -10 ° C for one week.
- Table VII indicates the compositions chosen for the constituents (B).
- the terpolymer is formed by a molar equivalent of each of the three unsaturated compounds: olefins-a, maleic anhydride, ester of unsaturated acid. On this terpolymer is condensed a molar equivalent of the compound with primary amine function.
- - cut C 24-28 , of average molecular mass 364 consists of 1% of olefins- ⁇ in C 22 , 30% of olefins-a in C 24 , 39% of olefins- ⁇ in C 26 , 20% of olefins- ⁇ in C 28 , 10% of olefins- ⁇ in C 30 and higher.
- the C 15 -C 20 cut of average molecular weight 244 contains odd and even olefins-about 1% in C 14 , 17% in C 15 , 1 8% in C 16 , 17% in C 17 , 17% in C 18 , 15% in C 19 , 12% in C 20 and 3% in C 21 ,
- esters of unsaturated acids are methacrylates or acrylates: the MAS cut was described in Example 1.
- AEH denotes 2-ethylhexyl acrylate.
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Lubricants (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85401312T ATE31424T1 (de) | 1984-07-10 | 1985-06-28 | Zusammensetzungen von zusaetzen vor allem verwendbar zur verbesserung der filtriereigenschaften von petrolmitteldestillaten in der kaelte. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8410979 | 1984-07-10 | ||
FR8410979A FR2567536B1 (fr) | 1984-07-10 | 1984-07-10 | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0172758A1 true EP0172758A1 (de) | 1986-02-26 |
EP0172758B1 EP0172758B1 (de) | 1987-12-16 |
Family
ID=9305990
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85401312A Expired EP0172758B1 (de) | 1984-07-10 | 1985-06-28 | Zusammensetzungen von Zusätzen vor allem verwendbar zur Verbesserung der Filtriereigenschaften von Petrol-Mitteldestillaten in der Kälte |
Country Status (10)
Country | Link |
---|---|
US (1) | US4664676A (de) |
EP (1) | EP0172758B1 (de) |
JP (1) | JPS6136397A (de) |
AT (1) | ATE31424T1 (de) |
CA (1) | CA1262406A (de) |
DE (1) | DE3561206D1 (de) |
DK (1) | DK311685A (de) |
FR (1) | FR2567536B1 (de) |
IN (1) | IN165554B (de) |
NO (1) | NO852742L (de) |
Cited By (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2592387A1 (fr) * | 1985-12-30 | 1987-07-03 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole |
FR2592658A1 (fr) * | 1986-01-09 | 1987-07-10 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole. |
FR2592888A1 (fr) * | 1986-01-10 | 1987-07-17 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole |
EP0283293A1 (de) * | 1987-03-18 | 1988-09-21 | Exxon Chemical Patents Inc. | Verwendung von Tieftemperaturfliessverbesserern in Destillatbrennstoffölen |
EP0455206A1 (de) * | 1990-04-30 | 1991-11-06 | SOCIETA' ITALIANA ADDITIVI PER CARBURANTI S.r.l. | Von Raffinierungsverfahren herführende und bei niedrigen Temperaturen verbesserte Eigenschaften zeigende Zusammensetzungen flüssiger Kohlenwasserstoffe |
EP0485773A1 (de) * | 1990-11-14 | 1992-05-20 | BASF Aktiengesellschaft | Erdölmitteldestillate mit verbesserten Fliesseigenschaften in der Kälte |
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JP2508783B2 (ja) * | 1988-01-26 | 1996-06-19 | 日本油脂株式会社 | 燃料油用流動性向上剤 |
US4964879A (en) * | 1989-03-27 | 1990-10-23 | Texaco Inc. | Middle distillate fuel containing deposit inhibitor |
US5110489A (en) * | 1989-06-27 | 1992-05-05 | Exxon Research And Engineering Company | Water resistant grease composition |
US5110490A (en) * | 1989-06-27 | 1992-05-05 | Exxon Research And Engineering Company | Water resistant grease composition |
GB9200694D0 (en) * | 1992-01-14 | 1992-03-11 | Exxon Chemical Patents Inc | Additives and fuel compositions |
DE4330971A1 (de) * | 1993-09-13 | 1995-03-16 | Basf Ag | Copolymerisate sowie deren Reaktionsprodukte mit Aminen als Kraftstoff- und Schmierstoffadditiv |
DE4430294A1 (de) * | 1994-08-26 | 1996-02-29 | Basf Ag | Polymermischungen und ihre Verwendung als Zusatz für Erdölmitteldestillate |
FR2735494B1 (fr) * | 1995-06-13 | 1997-10-10 | Elf Antar France | Additif bifonctionnel de tenue a froid et composition de carburant |
US6846338B2 (en) * | 1997-07-08 | 2005-01-25 | Clariant Gmbh | Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters |
US20090090047A1 (en) * | 2007-10-04 | 2009-04-09 | Baker Hughes Incorporated | Additive Useful for Stabilizing Fuel Oils |
US20090090655A1 (en) * | 2007-10-04 | 2009-04-09 | Baker Hughes Incorporated | Additive Useful for Stabilizing Crude Oil |
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- 1985-06-28 EP EP85401312A patent/EP0172758B1/de not_active Expired
- 1985-06-28 AT AT85401312T patent/ATE31424T1/de not_active IP Right Cessation
- 1985-06-28 DE DE8585401312T patent/DE3561206D1/de not_active Expired
- 1985-07-08 NO NO852742A patent/NO852742L/no unknown
- 1985-07-08 DK DK311685A patent/DK311685A/da not_active Application Discontinuation
- 1985-07-10 IN IN524/MAS/85A patent/IN165554B/en unknown
- 1985-07-10 US US06/753,507 patent/US4664676A/en not_active Expired - Fee Related
- 1985-07-10 JP JP15334485A patent/JPS6136397A/ja active Granted
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EP0100248A1 (de) * | 1982-06-04 | 1984-02-08 | Institut Français du Pétrole | Kopolymere mit funktionellen Gruppen auf Stickstoffbasis, vor allem verwendbar als trübungspunkterniedrigende Zusätze für Mitteldestillatkohlenwasserstoffe und diese Kopolymere enthaltende Mitteldestillatkohlenwasserstoffzusammensetzungen |
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Cited By (50)
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FR2592387A1 (fr) * | 1985-12-30 | 1987-07-03 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole |
FR2592658A1 (fr) * | 1986-01-09 | 1987-07-10 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole. |
FR2592888A1 (fr) * | 1986-01-10 | 1987-07-17 | Inst Francais Du Petrole | Compositions d'additifs destinees notamment a ameliorer les proprietes de filtrabilite a froid des distillats moyens de petrole |
EP0283293A1 (de) * | 1987-03-18 | 1988-09-21 | Exxon Chemical Patents Inc. | Verwendung von Tieftemperaturfliessverbesserern in Destillatbrennstoffölen |
US4882034A (en) * | 1987-03-18 | 1989-11-21 | Exxon Chemical Patents Inc. | Crude oil or fuel oil compositions |
EP0455206A1 (de) * | 1990-04-30 | 1991-11-06 | SOCIETA' ITALIANA ADDITIVI PER CARBURANTI S.r.l. | Von Raffinierungsverfahren herführende und bei niedrigen Temperaturen verbesserte Eigenschaften zeigende Zusammensetzungen flüssiger Kohlenwasserstoffe |
US5189231A (en) * | 1990-04-30 | 1993-02-23 | Societa' Italiana Additivi Per Carburanti S.R.L. | Compositions of liquid hydrocarbons from refining endowed with improved behavior at low temperatures |
EP0485773A1 (de) * | 1990-11-14 | 1992-05-20 | BASF Aktiengesellschaft | Erdölmitteldestillate mit verbesserten Fliesseigenschaften in der Kälte |
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WO2010073233A2 (fr) | 2008-12-23 | 2010-07-01 | Total Raffinage Marketing | Carburant de type gazole pour moteur diesel a fortes teneurs en carbone d'origine renouvelable et en oxygene |
WO2011001352A1 (fr) | 2009-07-03 | 2011-01-06 | Total Raffinage Marketing | Terpolymere ethylene/acetate de vinyle/esters insatures comme additif ameliorant la tenue a froid des hydrocarbures liquides comme les distillats moyens et les carburants ou combustibles |
WO2012085865A1 (fr) | 2010-12-23 | 2012-06-28 | Total Raffinage Marketing | Résines alkylphénol-aldéhyde modifiées, leur utilisation comme additifs améliorant les propriétés a froid de carburants et combustibles hydrocarbonés liquides |
WO2012107454A1 (fr) | 2011-02-08 | 2012-08-16 | Total Raffinage Marketing | Compositions liquides pour marquer les carburants et combustibles hydrocarbones liquides, carburants et combustibles les contenant et procede de detection des marqueurs |
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Also Published As
Publication number | Publication date |
---|---|
ATE31424T1 (de) | 1988-01-15 |
FR2567536B1 (fr) | 1986-12-26 |
US4664676A (en) | 1987-05-12 |
JPS6136397A (ja) | 1986-02-21 |
IN165554B (de) | 1989-11-11 |
DE3561206D1 (en) | 1988-01-28 |
FR2567536A1 (fr) | 1986-01-17 |
EP0172758B1 (de) | 1987-12-16 |
CA1262406A (fr) | 1989-10-24 |
DK311685D0 (da) | 1985-07-08 |
DK311685A (da) | 1986-01-11 |
JPH0531599B2 (de) | 1993-05-12 |
NO852742L (no) | 1986-01-13 |
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