EP0161537A2 - Alcoxylates d'alcool gras ayant des groupes terminaux pour les procédés industriels de nettoyage spécialement pour le lavage de bouteilles et pour le nettoyage du métal - Google Patents

Alcoxylates d'alcool gras ayant des groupes terminaux pour les procédés industriels de nettoyage spécialement pour le lavage de bouteilles et pour le nettoyage du métal Download PDF

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Publication number
EP0161537A2
EP0161537A2 EP85104798A EP85104798A EP0161537A2 EP 0161537 A2 EP0161537 A2 EP 0161537A2 EP 85104798 A EP85104798 A EP 85104798A EP 85104798 A EP85104798 A EP 85104798A EP 0161537 A2 EP0161537 A2 EP 0161537A2
Authority
EP
European Patent Office
Prior art keywords
foam
surfactants
cleaning
formula
fatty alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP85104798A
Other languages
German (de)
English (en)
Other versions
EP0161537A3 (fr
Inventor
Wolf-Dieter Dr. Balzer
Klaus Dr. Lorenz
Helmut Wolf
Wolfgang Dr. Trieselt
Dieter Stoeckigt
Albert Dr. Hettche
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0161537A2 publication Critical patent/EP0161537A2/fr
Publication of EP0161537A3 publication Critical patent/EP0161537A3/fr
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions

Definitions

  • Highly alkaline cleaners are used to clean bottles in the beverage industry.
  • the alkali dissolves, neutralizes or saponifies beverage residues and residues and converts the label glue into a highly foaming, water-soluble form. All of these processes run with high mechanics and thus favor the already high tendency to foam of starch and sugar breakdown products.
  • European Patent No. 19173 describes low alkoxylated, also biodegradable, low-foaming surfactants. In comparison to the products according to the invention, however, these products very quickly lose their low-foaming, foam-suppressing properties if they are stored in the presence of alkali at higher temperatures or if they are tested for a long time.
  • the special compounds of the formula I surprisingly achieve high foam attenuation, although it is known to the person skilled in the art that only low foam attenuation can be obtained by methyl end group closure. They have good low-foaming properties and, according to the regulations in the Federal Law Gazette dated 30.01.77, Part 1, pages 244ff, can be classified as perfectly biodegradable surfactants.
  • the alcohol alkoxylates are prepared in a conventional manner and the alkoxylates obtained are then subsequently converted into the corresponding ether using an alkylating agent.
  • the processes for the preparation of these surfactants are known from the literature and do not require a general description. The specific preparation of some selected compounds is dealt with in the examples.
  • the properties of low-foaming, low-foam and alkali stability with an optimum biodegradability of at least 80% are achieved in accordance with the above-mentioned legal regulation.
  • the test for foam formation is carried out according to the impact method DIN 53 902, sheet 1, but modified to the extent that a perforated disc with 22 openings with a stroke number of 20 and a stroke cylinder with a content of 1500 ml are used.
  • the measure of the foam behavior is the foam height after 30 seconds.
  • the wetting capacity is tested according to DIN 53 001 in distilled water containing 2 g soda / 1 at 20 ° C.
  • the network capacity allows a statement about the application properties in the above-mentioned applications.
  • Good foam dampers are usually poor wetting agents and good wetting agents often foam very strongly.
  • the foam-damping behavior is tested in accordance with the different application once in the dishwasher under protein load ("egg test"), and secondly the foam-suppressing effect on alkylbenzenesulfonate is examined in the dynamic foam apparatus.
  • the test time is 12 minutes, with the number of revolutions per minute being calculated from the total number of revolutions after certain times.
  • the washing process is started at room temperature, after about 10 minutes the temperature of the rinsing water is 60 ° C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Detergent Compositions (AREA)
EP85104798A 1984-05-18 1985-04-20 Alcoxylates d'alcool gras ayant des groupes terminaux pour les procédés industriels de nettoyage spécialement pour le lavage de bouteilles et pour le nettoyage du métal Withdrawn EP0161537A3 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3418523 1984-05-18
DE19843418523 DE3418523A1 (de) 1984-05-18 1984-05-18 Endgruppenverschlossene fettalkoholalkoxylate fuer industrielle reinigungsprozesse, insbesondere fuer die flaschenwaesche und fuer die metallreinigung

Publications (2)

Publication Number Publication Date
EP0161537A2 true EP0161537A2 (fr) 1985-11-21
EP0161537A3 EP0161537A3 (fr) 1989-11-23

Family

ID=6236230

Family Applications (1)

Application Number Title Priority Date Filing Date
EP85104798A Withdrawn EP0161537A3 (fr) 1984-05-18 1985-04-20 Alcoxylates d'alcool gras ayant des groupes terminaux pour les procédés industriels de nettoyage spécialement pour le lavage de bouteilles et pour le nettoyage du métal

Country Status (5)

Country Link
US (1) US4624803A (fr)
EP (1) EP0161537A3 (fr)
JP (1) JPS60255898A (fr)
CA (1) CA1239560A (fr)
DE (1) DE3418523A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014936A1 (fr) * 1992-12-22 1994-07-07 Henkel Kommanditgesellschaft Auf Aktien Agents mouillants pour le pretraitement textile
WO1995011225A1 (fr) * 1993-10-22 1995-04-27 Basf Aktiengesellschaft Utilisation d'amide-alkoxylates d'acides gras bloques par des groupes terminaux
WO1995016015A1 (fr) * 1993-12-10 1995-06-15 Henkel Kommanditgesellschaft Auf Aktien Melanges detergents non ioniques
WO1996006905A1 (fr) * 1994-09-01 1996-03-07 Henkel Kommanditgesellschaft Auf Aktien Polyglycolethers d'alkyle et/ou d'alcenyle bloques par un groupe terminal methyle
WO1996014377A1 (fr) * 1994-11-02 1996-05-17 Henkel Kommanditgesellschaft Auf Aktien Procede de fabrication de tensioactifs non ioniques a groupes terminaux fermes
EP0894849A1 (fr) * 1997-07-29 1999-02-03 Basf Corporation Composition détergente à base de l'eau sans solvant contenant deux dérivés tensioactifs nonioniques
DE19920559A1 (de) * 1999-05-05 2000-11-16 Cognis Deutschland Gmbh Verfahren zur Herstellung von alkyl-endgruppenverschlossenen Alkyl- und/oder Alkenylethern
US6660706B1 (en) 1998-12-09 2003-12-09 Cognis Deutschland Gmbh & Co. Kg General purpose cleaners
US7332466B2 (en) 1997-09-05 2008-02-19 Cognis Deutschland Gmbh & Co. Kg Lightly-foaming tenside mixtures with hydroxy mixed ethers
US7871971B1 (en) 1998-11-09 2011-01-18 Cognis Ip Management Gmbh Machine dishwashing rinse agents and methods of using the same

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DE3643895A1 (de) * 1986-12-22 1988-06-30 Henkel Kgaa Fluessige nichtionische tensidmischungen
US4830769A (en) * 1987-02-06 1989-05-16 Gaf Corporation Propoxylated guerbet alcohols and esters thereof
EP0300019A1 (fr) * 1987-02-06 1989-01-25 Gaf Corporation Alcools propoxyles de guerbet et leurs esters
US4836949A (en) * 1987-04-03 1989-06-06 Johnson & Johnson Consumer Products, Inc. Liquid detergent compositions with phosphate ester solubilizers
DE3800490A1 (de) * 1988-01-11 1989-07-20 Henkel Kgaa Verwendung ausgewaehlter endgruppenverschlossener fettalkoholethoxylate fuer schaumarme, kalt spritzbare reinigungsmittel
US4988462A (en) * 1988-04-29 1991-01-29 Lever Brothers Company, Division Of Conopco, Inc. Non-aqueous cleaning compositions containing bleach and capped nonionic surfactant
GB2219596A (en) * 1988-06-09 1989-12-13 Procter & Gamble Liquid automatic dishwashing compositions having enhanced stability
US4988452A (en) * 1988-06-09 1991-01-29 The Procter & Gamble Company Liquid automatic dishwashing detergent compositions containing bleach-stable nonionic surfactant
US4859358A (en) * 1988-06-09 1989-08-22 The Procter & Gamble Company Liquid automatic dishwashing compositions containing metal salts of hydroxy fatty acids providing silver protection
AU3982789A (en) * 1988-07-05 1990-02-05 Olin Corporation Anionic surfactant addition products of maleic or fumaric acid and a poly(ethoxylated) alcohol
GB8906820D0 (en) * 1989-03-23 1989-05-10 Ici Plc Novel chemical compounds and their use as low foam surfactants and antifoamingagents
US5104563A (en) * 1990-02-12 1992-04-14 Anchor Michael J Low molecular weight polypropylene surfactants which interact with anionic and nonionic surfactants
US5064561A (en) * 1990-05-09 1991-11-12 Diversey Corporation Two-part clean-in-place system
ES2106068T3 (es) * 1990-06-11 1997-11-01 Ciba Geigy Ag Auxiliares textiles acuosos, no siliconados, que generan poca espuma, obtencion y utilizacion de los mismos.
DE4105602A1 (de) * 1991-02-22 1992-08-27 Basf Ag Verwendung einer mischung aus mindestens zwei alkoxylierten alkoholen als schaumdaempfender tensidzusatz in reinigungsmitteln fuer maschinell ablaufende reinigungsprozesse
US5273677A (en) * 1992-03-20 1993-12-28 Olin Corporation Rinse aids comprising ethoxylated-propoxylated surfactant mixtures
KR100263399B1 (ko) * 1992-04-10 2000-08-01 도키와 후미카츠 발효용 소포제, l-아미노산 생산배지 및 l-아미노산의 제조방법
US5330581A (en) * 1992-08-26 1994-07-19 Nalco Chemical Company Use of caustic and surfactant as a cleaner for recycled plastic
US5571446A (en) * 1995-07-27 1996-11-05 Diversey Corporation Anionic stabilized enzyme based clean-in-place system
US5750483A (en) 1995-12-06 1998-05-12 Basf Corporation Non-phosphate machine dishwashing compositions containing polycarboxylate polymers and nonionic graft copolymers of vinyl acetate and polyalkylene oxide
EP0778340A3 (fr) 1995-12-06 1999-10-27 Basf Corporation Compositions exemptes de phosphate pour le lavage en lave-vaisselle contenant des copolymères à base de produits d'addition d'oxyde d'alkylène d'alcool allylique et d'acide acrylique
TW349994B (en) * 1996-12-02 1999-01-11 Kao Corp Surface activator composition
TW528798B (en) * 1996-12-02 2003-04-21 Kao Corp Surfactant composition
JPH11349983A (ja) * 1998-06-10 1999-12-21 Asahi Denka Kogyo Kk 洗浄剤
JP2002105489A (ja) * 2000-10-02 2002-04-10 Daisan Kogyo Kk 硬表面用酸性洗浄剤
MXPA05002890A (es) * 2002-09-18 2005-06-22 Ecolab Inc Aditivo para utilizarse en composiciones de lavado de botellas.
US20040235680A1 (en) * 2002-09-18 2004-11-25 Ecolab Inc. Conveyor lubricant with corrosion inhibition
GB0304788D0 (en) * 2003-03-03 2003-04-09 Laporte Performance Chemicals Foam control agent
US7399730B2 (en) 2004-04-02 2008-07-15 Aquatrols Corporation Of America, Inc. Enhancing plant productivity by improving the plant growth medium environment with alkyl ethers of methyl oxirane-oxirane copolymer surfactants
JP2008007617A (ja) * 2006-06-29 2008-01-17 Sanyo Chem Ind Ltd アルカリ洗浄剤用低起泡性界面活性剤
EP2236665A4 (fr) * 2008-01-22 2012-12-12 Lion Corp Détergent pour pâte kraft et procédé de production de pâte kraft avec celui-ci
JP5468762B2 (ja) * 2008-10-14 2014-04-09 株式会社 資生堂 台所用液体洗浄剤組成物
JP2016530349A (ja) * 2013-07-03 2016-09-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 自動食器洗浄のための配合物における、ポリエーテル化合物の存在下で酸基含有モノマーを重合することによって得ることができるゲル様ポリマー組成物の使用の方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2841621A (en) * 1956-05-22 1958-07-01 Rohm & Haas Alkenyloxypolyethoxyethyl alkyl ethers
EP0019173A1 (fr) * 1979-05-10 1980-11-26 BASF Aktiengesellschaft Utilisation d'alcools alcoxylés comme tensioactifs biodégradables et peu moussants dans des agents de lavage pour vaisseller pour des lave-vaisselles
EP0034275A1 (fr) * 1980-02-14 1981-08-26 BASF Aktiengesellschaft Produits d'addition d'oxyde d'éthylène butoxylés à des alcools supérieurs comme tensides pauvres en mousse dans détergents de rinçage et de nettoyage
DE3048642A1 (de) * 1980-12-23 1982-07-15 Hoechst Ag, 6000 Frankfurt "tensidgemisch zur reinigung harter oberlaechen"

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US3444242A (en) * 1968-03-04 1969-05-13 Economics Lab Surface active agents
GB1445716A (en) * 1973-04-24 1976-08-11 Diversey Ltd Cleaning compositions
FR2278762A1 (fr) * 1974-07-16 1976-02-13 Sifrance Procede de stabilisation de detergents contenant de la soude et des agents de surface non ioniques et produit obtenu
US3956401A (en) * 1975-03-10 1976-05-11 Olin Corporation Low foaming, biodegradable, nonionic surfactants
JPS5552386A (en) * 1978-10-12 1980-04-16 Kao Corp Stabilizing agent for mixed fuel
DE3018149A1 (de) * 1980-05-12 1981-11-19 Henkel KGaA, 4000 Düsseldorf Verwendung von alkylpolyglykolethermischformale zur schaumverhuetung
DE3018135A1 (de) * 1980-05-12 1981-11-19 Henkel KGaA, 4000 Düsseldorf Verfahren zur herstellung von polyglykolethermischformalen und neue polyglykolethermischformale
US4375565A (en) * 1980-11-13 1983-03-01 Basf Aktiengesellschaft Low-foaming, biodegradable alkoxylation products terminated with glycerine ether radicals, and a process for their preparation
US4366326A (en) * 1981-03-06 1982-12-28 Basf Aktiengesellschaft Oxyalkylated fatty alcohols having end groups blocked by reaction with propylene
US4390465A (en) * 1981-06-22 1983-06-28 Fremont Industries, Inc. Low temperature composition for plating pretreatment of ferrous metals
DE3315951A1 (de) * 1983-05-02 1984-11-08 Henkel KGaA, 4000 Düsseldorf Verwendung von polyglykolethern als schaumdrueckende zusaetze in schaumarmen reinigungsmitteln

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2841621A (en) * 1956-05-22 1958-07-01 Rohm & Haas Alkenyloxypolyethoxyethyl alkyl ethers
EP0019173A1 (fr) * 1979-05-10 1980-11-26 BASF Aktiengesellschaft Utilisation d'alcools alcoxylés comme tensioactifs biodégradables et peu moussants dans des agents de lavage pour vaisseller pour des lave-vaisselles
EP0034275A1 (fr) * 1980-02-14 1981-08-26 BASF Aktiengesellschaft Produits d'addition d'oxyde d'éthylène butoxylés à des alcools supérieurs comme tensides pauvres en mousse dans détergents de rinçage et de nettoyage
DE3048642A1 (de) * 1980-12-23 1982-07-15 Hoechst Ag, 6000 Frankfurt "tensidgemisch zur reinigung harter oberlaechen"

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994014936A1 (fr) * 1992-12-22 1994-07-07 Henkel Kommanditgesellschaft Auf Aktien Agents mouillants pour le pretraitement textile
US5677273A (en) * 1992-12-22 1997-10-14 Schmid; Karl-Heinz Wetting agents for the pretreatment of textiles
WO1995011225A1 (fr) * 1993-10-22 1995-04-27 Basf Aktiengesellschaft Utilisation d'amide-alkoxylates d'acides gras bloques par des groupes terminaux
US5766612A (en) * 1993-10-22 1998-06-16 Basf Aktiengesellschaft Use of endgroup-capped fatty amide alkoxylates
US5707956A (en) * 1993-12-10 1998-01-13 Henkel Kommanditgesellschaft Auf Aktien Nonionic detergent mixtures based on specific mixed ethers
WO1995016015A1 (fr) * 1993-12-10 1995-06-15 Henkel Kommanditgesellschaft Auf Aktien Melanges detergents non ioniques
WO1996006905A1 (fr) * 1994-09-01 1996-03-07 Henkel Kommanditgesellschaft Auf Aktien Polyglycolethers d'alkyle et/ou d'alcenyle bloques par un groupe terminal methyle
US5811594A (en) * 1994-09-01 1998-09-22 Henkel Kommanditgesellschaft Auf Aktien Methyl-end-capped alkyl and/or alkenyl polyglycol ethers
WO1996014377A1 (fr) * 1994-11-02 1996-05-17 Henkel Kommanditgesellschaft Auf Aktien Procede de fabrication de tensioactifs non ioniques a groupes terminaux fermes
US5847229A (en) * 1994-11-02 1998-12-08 Henkel Kommanditgesellschaft Auf Aktien Process for the production of end-capped nonionic surfactants
EP0894849A1 (fr) * 1997-07-29 1999-02-03 Basf Corporation Composition détergente à base de l'eau sans solvant contenant deux dérivés tensioactifs nonioniques
US7332466B2 (en) 1997-09-05 2008-02-19 Cognis Deutschland Gmbh & Co. Kg Lightly-foaming tenside mixtures with hydroxy mixed ethers
US7871971B1 (en) 1998-11-09 2011-01-18 Cognis Ip Management Gmbh Machine dishwashing rinse agents and methods of using the same
US6660706B1 (en) 1998-12-09 2003-12-09 Cognis Deutschland Gmbh & Co. Kg General purpose cleaners
DE19920559A1 (de) * 1999-05-05 2000-11-16 Cognis Deutschland Gmbh Verfahren zur Herstellung von alkyl-endgruppenverschlossenen Alkyl- und/oder Alkenylethern

Also Published As

Publication number Publication date
US4624803A (en) 1986-11-25
CA1239560A (fr) 1988-07-26
EP0161537A3 (fr) 1989-11-23
DE3418523A1 (de) 1985-11-21
JPS60255898A (ja) 1985-12-17

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