EP0054895A1 - Mélange d'agents surfactifs pour le nettoyage de surfaces dures - Google Patents

Mélange d'agents surfactifs pour le nettoyage de surfaces dures Download PDF

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Publication number
EP0054895A1
EP0054895A1 EP81110472A EP81110472A EP0054895A1 EP 0054895 A1 EP0054895 A1 EP 0054895A1 EP 81110472 A EP81110472 A EP 81110472A EP 81110472 A EP81110472 A EP 81110472A EP 0054895 A1 EP0054895 A1 EP 0054895A1
Authority
EP
European Patent Office
Prior art keywords
cleaning
surfactant
range
oxide units
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP81110472A
Other languages
German (de)
English (en)
Other versions
EP0054895B1 (fr
Inventor
Wolfgang Klinger
Eckhard Milewski
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT81110472T priority Critical patent/ATE8659T1/de
Publication of EP0054895A1 publication Critical patent/EP0054895A1/fr
Application granted granted Critical
Publication of EP0054895B1 publication Critical patent/EP0054895B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C11D1/8355—Mixtures of non-ionic with cationic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the invention relates to a surfactant mixture for the mechanical cleaning of hard surfaces, in particular bottles and dishes in the alkaline to highly alkaline range of the cleaning liquor.
  • the system must also be as low-foam or foam-free as possible, since excessive foam formation can lead to malfunctions in the operating behavior of the system, for example if it is in the foam layer accumulating dirt cannot be discharged sufficiently. Additional tendencies towards foam formation are caused by the impurities carried in by the items to be cleaned, especially by protein-containing residues on the items to be cleaned. In the case of bottle cleaning, this also applies in particular to the labels to be removed, through which the glue residues and residues of printing inks, including the surfactant auxiliaries contained in the latter, are introduced into the cleaning liquor.
  • non-ionic surfactants with low-foaming characteristics as cleaning agents for hard surfaces in alkaline baths. These are in particular addition products of ethylene oxide and / or propylene oxide with amines, longer-chain fatty alcohols or alkylphenols, polyglycol ether formals or acetals or block copolymers of ethylene and propylene oxide.
  • Such surfactant systems can be adjusted, in particular, by suitable variation of the ethylene oxide and propylene oxide proportions to the lowest possible foam tendency and increased cleaning action, an excess weight of the propylene oxide favoring the former property and an excess weight of the ethylene oxide promoting the latter property.
  • the object was therefore to improve the dirt-holding capacity of such mixtures without having to accept the disadvantage of substantivity.
  • non-ionic surfactants used as a component
  • Such an average can be an integer or a fraction.
  • the ratio of the ethylene oxide to propylene oxide units should preferably be in the range from 0.8 to 1.5.
  • Polyglycol ether formals of the general formula these formals contain ethylene oxide units and, if appropriate, propylene oxide units, it being possible for these to be statistically distributed or incorporated in blocks if both are present.
  • Such polyglycol ether formals can be prepared, for example from the corresponding polyglycol ethers, alcohols and formaldehyde, as described in DE-OS 25 23 588.
  • R 1 is an alkyl radical with 6 to 18 C atoms, preferably with 8 to 14 C atoms
  • R 2 is an alkyl radical with 1 to 4 C atoms, preferably the n-butyl radical
  • c is a statistical mean in the range from 6 to 12 preferably from 6 to 10
  • d has a statistical mean in the range from 0 to 3, preferably 0.
  • non-ionic component can also be any organic component.
  • a P olyalkylenglykoldialkylether of formula be, which contains ethylene oxide and optionally propylene oxide units, which can be arranged randomly or in blocks.
  • R 1 is an alkyl radical with 6 to 18 C atoms, preferably with 8 to 14 C atoms
  • R 3 is an alkyl radical with 1 to 4 C atoms, preferably the tert-butyl radical
  • c is a statistical mean in the range from 6 to 12, preferably from 7 to 10
  • d has a statistical mean in the range from 0 to 3, preferably 0.
  • non-ionic surfactants can also be present as mixtures within groups A 1 ), A 2 ) or A 3 ) or else between groups A 1 ), A 2 ) and / or A 3 ).
  • the non-ionic surfactants of group A 1 ) are preferred.
  • the surfactant mixture contains a quaternary ammonium compound B) of the formula as a cationic component in which R 4 and R 5 , identical or different, are an alkyl radical with 1 to 8 C atoms, preferably with 4 to 6 C atoms, R 6 is an alkyl radical with 1 to 8 C atoms, preferably 1 to 6 C atoms , and R 7 is an alkyl radical having 1 to 4 carbon atoms or a benzyl radical.
  • A is an anion, preferably a chloride or bromide anion or one of the formula CH 3 OSO 3 - .
  • composition of the surfactant mixture is essential for the advantageous properties.
  • the ratio of components A: B should be in the range from 20:80 to 95: 5% by weight, preferably 40:60 to 85:15% by weight. -%, lie.
  • the surfactant mixtures can be used as a mixture of components A + B in undiluted, liquid form. However, they can also be used in the form of aqueous concentrates, for example for better meterability, if appropriate also with the addition of an organic solvent. Components A and B can of course also be added separately to the aqueous cleaning liquor.
  • the application concentration is expediently 0.05 to 10 g of the mixture A + B per liter of cleaning liquor, preferably 0.1 to 2 g per liter.
  • the application concentrations mentioned are non-critical statements, since the amount depends to a certain extent on the type of surface to be cleaned and on the type and extent of the impurities.
  • further additives and auxiliaries can be added to the surfactant mixtures according to the invention in the production of commercially available formulations.
  • these include dyes, fragrances, corrosion inhibitors and disinfectants.
  • the known builders which are optionally also complexing agents, should also be mentioned here.
  • the condensed phosphates such as tripolyphosphates and in particular pentasodium triphosphate, come into consideration.
  • these are complex-forming aminopolycarboxylic acids and their salts, such as, in particular, alkali metal salts of nitrilotriacetic acid and ethylenediaminetetraacetic acid, and also also complex-forming hydroxycarboxylic acids and polymeric carboxylic acids, such as citric acid, tartaric acid and the like.
  • Another class of complexing builders are polyphosphonic acid salts, such as the alkali salts of aminophosphonic acid.
  • builders such as silicates, for example sodium metasilicate, carbonates, bicarbonates, borates and citrates, can also be added. With the aid of such additives, the surfactant mixtures according to the invention can optionally be converted into powder form and can also be used in this form.
  • the surfactant mixtures according to the invention are suitable for the mechanical cleaning of hard surfaces in alkaline liquors. This applies to cleaning in household dishwashers and so-called commercial cleaning systems.
  • the mixtures are particularly suitable for industrial cleaning systems for hard surfaces, for example dishwashing and bottle washing systems, which are subject to high mechanical liquor movements in continuous operation and in highly alkaline liquors at pH values of> 10, preferably? 12, work.
  • the necessary alkaline additives preferably sodium or potassium hydroxide for the highly alkaline pH range of the liquor, can be dissolved in the aqueous cleaning liquor before the surfactant mixture according to the invention is introduced. However, they can also be added directly to the surfactant mixture and metered together with it.
  • the alkaline agent is expediently added in the form of powder, flakes or cookies.
  • the mixtures according to the invention have the low foaming tendency which is indispensable for industrial cleaning systems and which, as a rule, makes the addition of additional defoamers superfluous.
  • foam-suppressing agents Only in the case of extremely high movements of the liquor or in the presence of soiling with an extremely high tendency towards foaming can the addition of foam-suppressing agents be expedient, which must have the required stability to alkali.
  • foam-suppressing agents are, for example, orthophosphoric acid esters, ethylenediamine condensation products with ethylene oxide and propylene oxide and also fatty alcohols.
  • the surfactant mixtures according to the invention as cleaning agents for the mechanical cleaning of hard surfaces, in particular with regard to the high demands placed on industrial cleaning systems, also have the following significant advantages: the mixtures are not only resistant to alkali, but also stable in storage with alkali for long periods. They have an extraordinarily low tendency to foam formation not only at the working temperatures of such cleaning systems, that is, above about 40 ° C, but also at low temperatures, so that when refilled with cold water and heating there is no formation of disruptive foam, which then foams or can lead to disturbances in the circulation of the system.
  • the excellent dirt absorption capacity allows long service lives in the system until it is refilled without impairing the cleaning effect.
  • the surfactant mixtures used in the following examples contain the following components (C 7-11 etc. means chain cut R 1 in the range mentioned):
  • Non-ionic surfactants of the formula A 2 are non-ionic surfactants of the formula A 2 ):
  • Non-ionic surfactants of formula A 3 :
  • the dirt absorption capacity by checking the foam tendency when contaminated with dirt is determined by adding a test foam to the cleaning liquor.
  • a wheat beer export wheat beer from the strictly brewery Raitenhaslach-Barghausen
  • the foam formation is measured at 65 ° C (column 4 of the table).
  • Drop formation indicates substantivity on the bottle walls (column 5 of the table).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP81110472A 1980-12-23 1981-12-16 Mélange d'agents surfactifs pour le nettoyage de surfaces dures Expired EP0054895B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT81110472T ATE8659T1 (de) 1980-12-23 1981-12-16 Tensidgemisch zur reinigung harter oberflaechen.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19803048642 DE3048642A1 (de) 1980-12-23 1980-12-23 "tensidgemisch zur reinigung harter oberlaechen"
DE3048642 1980-12-23

Publications (2)

Publication Number Publication Date
EP0054895A1 true EP0054895A1 (fr) 1982-06-30
EP0054895B1 EP0054895B1 (fr) 1984-07-25

Family

ID=6120064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81110472A Expired EP0054895B1 (fr) 1980-12-23 1981-12-16 Mélange d'agents surfactifs pour le nettoyage de surfaces dures

Country Status (6)

Country Link
US (1) US4443363A (fr)
EP (1) EP0054895B1 (fr)
JP (1) JPS58109598A (fr)
AT (1) ATE8659T1 (fr)
CA (1) CA1160534A (fr)
DE (2) DE3048642A1 (fr)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0235774A2 (fr) * 1986-03-05 1987-09-09 Henkel Kommanditgesellschaft auf Aktien Mélanges liquides de composés tensio-actifs
WO1991017233A1 (fr) * 1990-05-09 1991-11-14 Henkel Kommanditgesellschaft Auf Aktien Utilisation d'une combinaison de tensio-actifs ioniques et non ioniques
WO1995002666A1 (fr) * 1993-07-12 1995-01-26 Henkel Kommanditgesellschaft Auf Aktien Liquides de rinçage pour le nettoyage mecanique de surfaces dures
WO1995010586A1 (fr) * 1993-10-08 1995-04-20 Henkel Kommanditgesellschaft Auf Aktien Detergents legerement moussants
WO1996023050A1 (fr) * 1995-01-24 1996-08-01 Jeyes Group Plc Compositions detersives
WO1998045392A1 (fr) * 1997-04-04 1998-10-15 Benckiser Consumer Products, Inc. Adjuvant de rinçage antimicrobien a usage sanitaire
WO1998055578A1 (fr) * 1997-06-06 1998-12-10 Henkel Kommanditgesellschaft Auf Aktien Detergent faiblement moussant
WO2000050551A1 (fr) * 1999-02-22 2000-08-31 The Procter & Gamble Company Compositions detergentes pour lave-vaisselle comportant des surfactants non ioniques selectionnes
WO2007087846A1 (fr) * 2006-01-20 2007-08-09 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage desemulsifiant pour surfaces techniques
WO2009050035A1 (fr) 2007-10-15 2009-04-23 Chemetall Gmbh Composition nettoyante pour surfaces métalliques
EP2253741A3 (fr) * 2006-04-18 2014-01-08 Chemetall GmbH Procédé de nettoyage désémulsifiant de surfaces métalliques
WO2021224018A1 (fr) 2020-05-06 2021-11-11 Syngenta Crop Protection Ag Co-émulsifiant qui forme aisément des micelles dans l'eau

Families Citing this family (36)

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Publication number Priority date Publication date Assignee Title
DE3418523A1 (de) * 1984-05-18 1985-11-21 Basf Ag, 6700 Ludwigshafen Endgruppenverschlossene fettalkoholalkoxylate fuer industrielle reinigungsprozesse, insbesondere fuer die flaschenwaesche und fuer die metallreinigung
DE3439519A1 (de) * 1984-10-29 1986-04-30 Henkel KGaA, 4000 Düsseldorf Verfahren zur verbesserung des korrosionsverhaltens von desinfektionsmittelloesungen
DE3501775A1 (de) * 1985-01-21 1986-07-24 Henkel KGaA, 4000 Düsseldorf Neue kationtenside auf der basis von quartaeren ammoniumverbindungen und ihre verwendung in reinigungsmitteln
US4606850A (en) * 1985-02-28 1986-08-19 A. E. Staley Manufacturing Company Hard surface cleaning composition and cleaning method using same
US4647314A (en) * 1985-03-05 1987-03-03 Drew Chemical Corporation Rinse water additive
USH269H (en) * 1985-03-11 1987-05-05 A. E. Staley Manufacturing Company Disinfectant and/or sanitizing cleaner compositions
DE3620011A1 (de) * 1986-06-13 1987-12-17 Henkel Kgaa Neue kationtenside auf der basis von quartaeren ammoniumverbindungen und ihre verwendung in reinigungsmitteln
US5569411A (en) * 1986-08-08 1996-10-29 Colgate-Palmolive Co. Liquid household cleaning composition with insect repellent
US5573700A (en) * 1986-08-08 1996-11-12 Colgate-Palmolive Co. Liquid household cleaning composition with insect repellent
KR960002629B1 (ko) * 1987-06-25 1996-02-24 가오 가부시끼가이샤 금속 세정제
US5091102A (en) * 1988-11-15 1992-02-25 Nordico, Inc. Method of making a dry antimicrobial fabric
US5094770A (en) * 1988-11-15 1992-03-10 Nordico, Inc. Method of preparing a substantially dry cleaning wipe
US4946617A (en) * 1988-11-15 1990-08-07 Nordico, Inc. Substantially dry cleaning wipe capable of rendering a cleaned surface static free
US5185088A (en) * 1991-04-22 1993-02-09 The Procter & Gamble Company Granular fabric softener compositions which form aqueous emulsion concentrates
US5250230A (en) * 1991-12-20 1993-10-05 Henkel Corporation Composition and process for cleaning metals
WO1993014181A1 (fr) * 1992-01-06 1993-07-22 Olin Corporation Composition nettoyante, aqueuse et biodegradable pour filtres contenant un agent tensioactif ethoxyle/propoxyle, de l'acide carboxylique et un solvant
WO1994007979A1 (fr) * 1992-09-28 1994-04-14 The Procter & Gamble Company Procede d'utilisation d'un adoucissant de tissu en particules solides dans un distributeur de dosage automatique
DE4243643C1 (fr) * 1992-12-22 1993-08-26 Henkel Kgaa, 4000 Duesseldorf, De
GB9322806D0 (en) * 1993-11-05 1993-12-22 Dow Europ Sa Aqueous alkaline composition
US5435935A (en) * 1993-11-22 1995-07-25 The Procter & Gamble Company Alkaline liquid hard-surface cleaning composition containing a quarternary ammonium disinfectant and selected dicarboxylate sequestrants
US6277805B1 (en) 1993-11-22 2001-08-21 The Procter & Gamble Co. Alkaline liquid hard-surface cleaning composition containing a quaternary ammonium disinfectant and selected dicarboxylate sequestrants
US6013615A (en) 1995-07-26 2000-01-11 The Clorox Company Antimicrobial hard surface cleaner
US5719118A (en) * 1995-10-30 1998-02-17 Tomah Products, Inc. Detergent compositions having polyalkoxylated amine foam stabilizers and method for cleaning including stabilized detergent foam
US6221822B1 (en) 1995-10-30 2001-04-24 Tomah Products, Inc. Detergent compositions having polyalkoxylated amine foam stabilizers
AU3942197A (en) * 1996-07-29 1998-02-20 John Somerville Armstrong A glasswashing composition
US5965514A (en) * 1996-12-04 1999-10-12 The Procter & Gamble Company Compositions for and methods of cleaning and disinfecting hard surfaces
DE19652680A1 (de) * 1996-12-18 1998-06-25 Clariant Gmbh Mischungen von Alkoxylaten mit schaumdämpfender und desinfizierender Wirkung und deren Verwendung in Reinigungsmitteln
JP4069962B2 (ja) 1997-03-20 2008-04-02 ザ プロクター アンド ギャンブル カンパニー 超吸収性材料を含んでなる清掃器具と共に使用する洗剤組成物及びこれら両方を含むキット
AU3495700A (en) * 1999-02-22 2000-09-14 Procter & Gamble Company, The Cleaning compositions containing selected nonionic surfactants
US6303557B1 (en) 1999-11-16 2001-10-16 S. C. Johnson Commercial Markets, Inc. Fast acting disinfectant and cleaner containing a polymeric biguanide
US6762162B1 (en) 2003-06-18 2004-07-13 S. C. Johnson & Son, Inc. Disinfecting cationic polymer cleaner comprising an acrylate cationic polymer
CN102676319B (zh) * 2012-05-14 2013-12-25 北京京东方光电科技有限公司 洗涤剂及其制备方法和应用
JP6126956B2 (ja) * 2013-09-17 2017-05-10 花王株式会社 衣料用洗浄剤組成物
JP6242195B2 (ja) * 2013-12-03 2017-12-06 花王株式会社 殺菌方法
WO2015088464A1 (fr) 2013-12-13 2015-06-18 Bicak Tugrul Cem Synthèse de monomères de morpholinium de diallyle purs à haut rendement et utilisation de l'effet antibactérien de leurs polymères spiro
JP6586920B2 (ja) * 2016-04-27 2019-10-09 日油株式会社 樹脂用プライマー塗装前処理剤組成物

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US3623988A (en) * 1970-06-08 1971-11-30 Continental Oil Co Use of polyether-substituted chlorohydrins as a low-foam, caustic stable cleaning agent
DE2432757A1 (de) * 1974-07-08 1976-01-29 Henkel & Cie Gmbh Als schauminhibitoren geeignete, hydroxylgruppen enthaltende polyaethylenglykol-diaether
US4065409A (en) * 1975-08-01 1977-12-27 Corporate Brands, Inc. Hard surface detergent composition

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GB873214A (en) * 1958-08-20 1961-07-19 British Nylon Spinners Ltd Non-ionic detergent compositions
DE2523588C2 (de) * 1975-05-28 1983-11-10 Hoechst Ag, 6230 Frankfurt Polyglykoläthermischformale und deren Verwendung als ätzalkalibeständige Netz-, Wasch- und Reinigungsmittel
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NO781898L (no) * 1977-06-09 1978-12-12 Ici Ltd Flytende vaskemiddelblanding.
US4284532A (en) * 1979-10-11 1981-08-18 The Procter & Gamble Company Stable liquid detergent compositions

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Publication number Priority date Publication date Assignee Title
US3623988A (en) * 1970-06-08 1971-11-30 Continental Oil Co Use of polyether-substituted chlorohydrins as a low-foam, caustic stable cleaning agent
DE2432757A1 (de) * 1974-07-08 1976-01-29 Henkel & Cie Gmbh Als schauminhibitoren geeignete, hydroxylgruppen enthaltende polyaethylenglykol-diaether
US4065409A (en) * 1975-08-01 1977-12-27 Corporate Brands, Inc. Hard surface detergent composition

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0235774A2 (fr) * 1986-03-05 1987-09-09 Henkel Kommanditgesellschaft auf Aktien Mélanges liquides de composés tensio-actifs
EP0235774A3 (en) * 1986-03-05 1990-05-23 Henkel Kommanditgesellschaft Auf Aktien Liquid surface-active mixtures
WO1991017233A1 (fr) * 1990-05-09 1991-11-14 Henkel Kommanditgesellschaft Auf Aktien Utilisation d'une combinaison de tensio-actifs ioniques et non ioniques
WO1995002666A1 (fr) * 1993-07-12 1995-01-26 Henkel Kommanditgesellschaft Auf Aktien Liquides de rinçage pour le nettoyage mecanique de surfaces dures
US5691300A (en) * 1993-07-12 1997-11-25 Henkel Kommanditgesellschaft Auf Aktien Rinse aids for the machine washing of hard surfaces
WO1995010586A1 (fr) * 1993-10-08 1995-04-20 Henkel Kommanditgesellschaft Auf Aktien Detergents legerement moussants
US5750486A (en) * 1993-10-08 1998-05-12 Henkel Kommanditgesellschaft Auf Aktien Low-foaming cleaning formulations
WO1996023050A1 (fr) * 1995-01-24 1996-08-01 Jeyes Group Plc Compositions detersives
WO1998045392A1 (fr) * 1997-04-04 1998-10-15 Benckiser Consumer Products, Inc. Adjuvant de rinçage antimicrobien a usage sanitaire
WO1998055578A1 (fr) * 1997-06-06 1998-12-10 Henkel Kommanditgesellschaft Auf Aktien Detergent faiblement moussant
US6187737B1 (en) 1997-06-06 2001-02-13 Henkel Kommanditgesellschaft Auf Aktien Low-foam detergent comprising a cationic surfactant and a glycol ether
WO2000050551A1 (fr) * 1999-02-22 2000-08-31 The Procter & Gamble Company Compositions detergentes pour lave-vaisselle comportant des surfactants non ioniques selectionnes
WO2007087846A1 (fr) * 2006-01-20 2007-08-09 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage desemulsifiant pour surfaces techniques
EP2253741A3 (fr) * 2006-04-18 2014-01-08 Chemetall GmbH Procédé de nettoyage désémulsifiant de surfaces métalliques
WO2009050035A1 (fr) 2007-10-15 2009-04-23 Chemetall Gmbh Composition nettoyante pour surfaces métalliques
US9464259B2 (en) 2007-10-15 2016-10-11 Chemetall Gmbh Cleaning composition for metal surfaces
WO2021224018A1 (fr) 2020-05-06 2021-11-11 Syngenta Crop Protection Ag Co-émulsifiant qui forme aisément des micelles dans l'eau

Also Published As

Publication number Publication date
DE3165129D1 (en) 1984-08-30
US4443363A (en) 1984-04-17
DE3048642A1 (de) 1982-07-15
EP0054895B1 (fr) 1984-07-25
ATE8659T1 (de) 1984-08-15
CA1160534A (fr) 1984-01-17
JPS58109598A (ja) 1983-06-29
JPH0345120B2 (fr) 1991-07-10

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