EP0107103A2 - Form zur Herstellung langgestreckter Gegenstände - Google Patents

Form zur Herstellung langgestreckter Gegenstände Download PDF

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Publication number
EP0107103A2
EP0107103A2 EP83109778A EP83109778A EP0107103A2 EP 0107103 A2 EP0107103 A2 EP 0107103A2 EP 83109778 A EP83109778 A EP 83109778A EP 83109778 A EP83109778 A EP 83109778A EP 0107103 A2 EP0107103 A2 EP 0107103A2
Authority
EP
European Patent Office
Prior art keywords
mold
sealing means
cavity
organic material
members
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP83109778A
Other languages
English (en)
French (fr)
Other versions
EP0107103A3 (de
Inventor
Richard Gordon Angell
Kenneth Elton Hobbs
John Martin Konrad
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of EP0107103A2 publication Critical patent/EP0107103A2/de
Publication of EP0107103A3 publication Critical patent/EP0107103A3/de
Withdrawn legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C39/00—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor
    • B29C39/003—Shaping by casting, i.e. introducing the moulding material into a mould or between confining surfaces without significant moulding pressure; Apparatus therefor characterised by the choice of material
    • B29C39/006—Monomers or prepolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/0038—Moulds or cores; Details thereof or accessories therefor with sealing means or the like
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/24—Di-epoxy compounds carbocyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4284—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof together with other curing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/62—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00—Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3406—Components, e.g. resistors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00—Other particular articles
    • B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
    • B29L2031/3412—Insulators

Definitions

  • thermoset resin articles Due to the development of new processes for fabricating thermoset resin articles, the current state of the art molds are not entirely suitable for use in these processes.
  • D-13672 European Patent Application
  • U-13672 filed in the name of Union Carbide Corporation titled "A Process For Fabricating Thermoset Resin Articles'" and filed on the same day as this application, a process is described for fabricating thermoset resin articles.
  • Such process comprises the steps of: (a) providing in an accumulator zone, a liquid body of an epoxide containing organic material which is curable upon heating to a thermoset resin composition, the viscosity of'said liquid body being maintained essentially constant in the accumulator zone by keeping its temperature below that at which curing of said materials is substantial, (b) providing a heated closed mold from which essentially all of the air has been removed from the cavity of said mold, (c) injecting at least a portion of said liquid body under pressure into the closed mold to fill the cavity in the mold, (d) initiating the curing of said materials by subjecting the materials to a temperature in the mold above the temperature at which the curing of said materials is initiated, (e) maintaining a pressure on the curing material, (f) injecting additional of said materials to the mold cavity during the curing of said materials, and (g) opening said mold and removing the article therefrom.
  • thermoset resin articles It has now been found that the mold as subsequently described is essentially air tight when air is evacuated therefrom and able to withstand the pressures used in fabricating thermoset resin articles.
  • the Figure shows a side view of closed mold 1, comprised of a left half 2, and right half 3.
  • Grooves 4 and 4' contain an 0-ring.
  • the top plate 5 contains a circular groove which contains 0-ring 6, which forms a seal with the 0-ring contained in grooves 4 and 4'.
  • the bottom plate 7 contains a circular groove which contains 0-ring 8, which forms a seal with the 0-ring contained in grooves 4 and 4'.
  • a pin 9 sits inside the mold cavity (not shown) which allows the molding of a hollow article.
  • the curable epoxy resin containing compositions described in said European Patent Application comprises an epoxide resin, a polyol, a hardener and a particular catalyst.
  • the catalysts suitable for use include one or more amines such as pyridine-N-oxide, 1,4-diazabicyclo [2.2.2] octane, 2-methyl-imidazole, 2-phenyl-imidazole, 1-vinyl-2-methyl imidazole, 1-acetyle imidazole, quaternary ammonium or phosphonium compounds such as n-propyl triphenyl phosphonium bromide benzyl triphenyl phosphonium bromide and chloride, n-heptyl triphenyl phosphonium bromide, ethyl triphenyl phosphenium bromide and iodide, n-hexyl triphenyl phosphonium bromide; diamines, such as bis(dimethylaminoethyl) ether, and the like.
  • amines such as pyridine-N-oxide, 1,4-diazabicyclo [2.2.2] o
  • the catalysts are used in amounts of from about 0.5 to about 10 parts by weight per 100 parts by weight of resin.
  • the catalyst is a solid, it may be dissolved in a suitable solvent such as an alcohol or polyol.
  • suitable solvent such as an alcohol or polyol.
  • suitable solvent such as an alcohol or polyol.
  • Suitable cycloaliphatic epoxides are those having an average of more than one vicinal epoxy group per molecule.
  • the epoxy groups can be terminal epoxy groups or internal epoxy groups as exemplified by the cycloaliphatic epoxides which are subsequently described.
  • Particularly desirable cycloaliphatic epoxides are the cyclohexane diepoxides, that is epoxides having at least one cyclohexane ring to which is attached at least one vicinal epoxy group.
  • Suitable cycloaliphatic epoxides are the following:
  • Particularly desirable epoxides falling within the scope of Formula I, are those wherein R 1 through R 9 are hydrogen and R is alkylene . containing four to six carbon atoms.
  • Suitable cycloaliphatic epoxides are the following: and the like.
  • glycols suitable for use in this invention include polycaprolactone polyols as well as alkylene oxide adducts of polyhydroxyalkanes.
  • polycaprolactone polyols that can be used one can mention the reaction products of a polyhydroxyl compound having from 2 to 6 hydroxyl groups with caprolactone.
  • the manner in which these polycaprolactone polyol compositions are produced is shown in, for example, U.S. 3,169,945 and many such compositions are commercially available.
  • polycaprolactone polyols there are listed illustrative polycaprolactone polyols. The first column lists the organic functional initiator that is reacted with caprolactone and the average molecular weight of the polycaprolactone polyol is shown in the second column.
  • the preferred alkylene oxide adducts of polyhydroxyalkanes are of the following formula: wherein R 10 is alkane of 3 to 10 carbon atoms, preferably 3 carbon atoms, and n is an integer of from about 4 to about 25.
  • hardeners it is customary to add appropriate hardeners to epoxide compositions to effect cure.
  • suitable hardeners are the following:
  • Preferred hardeners include methyltetrahydrophthalic anhydride, hexahydrophthalic anhydride and methylhexahydrophthalic anhydride.
  • compositions are prepared by simply mixing the epoxide, glycol, catalyst hardener and other ingredients at room or higher temperatures in a suitable container. Also, the epoxide and glycol may be mixed in one container and the hardener, catalyst and/or accelerator in another container and these two mixed.
  • the temperature at which the mold is maintained is dependent upon the temperature at which the cure of the thermosettable organic materials supplied to the mold is initiated to produce a thermoset resin composition.
  • the initiation temperature is the temperature at which the components of the thermosettable organic materials inter-react to effect an exothermic reaction which cures the materials to a thermoset resin.
  • thermoset resin which is sufficient to initiate reaction resulting in a thermoset resin is dependent upon the particular thermoset organic materials. These materials undergo curing at temperatures from about 100°C to about 200°C. In considering the exothermic temperature of the reaction, it is desirable to utilize a mold temperature which nominally exceeds the initiation temperature by at least 10-20°C, thus, insuring a rapid initiation and a quick increase in the exotherm to produce a cured product in a minimum amount of time.
  • catalysts, initiators, etc are generally added to the thermosettable materials. The type of catalyst or initiator, as well as any promoter or activator supplied therewith, will greatly determine mold temperature.
  • the injection pressure will vary from about 2 to about 40 atmospheres during the molding operation.
  • the mold is used for molding 'elongated articles, particularly electrical parts such as bushings, insulators and the like.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
EP83109778A 1982-09-30 1983-09-29 Form zur Herstellung langgestreckter Gegenstände Withdrawn EP0107103A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US43036382A 1982-09-30 1982-09-30
US430363 1982-09-30

Publications (2)

Publication Number Publication Date
EP0107103A2 true EP0107103A2 (de) 1984-05-02
EP0107103A3 EP0107103A3 (de) 1984-10-31

Family

ID=23707231

Family Applications (1)

Application Number Title Priority Date Filing Date
EP83109778A Withdrawn EP0107103A3 (de) 1982-09-30 1983-09-29 Form zur Herstellung langgestreckter Gegenstände

Country Status (4)

Country Link
EP (1) EP0107103A3 (de)
JP (1) JPS5983608A (de)
AU (1) AU1974483A (de)
NO (1) NO833539L (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0132685A2 (de) * 1983-07-22 1985-02-13 Siemens Aktiengesellschaft Verfahren zur Herstellung von Epoxidharzformstoffen

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2750395A (en) * 1954-01-05 1956-06-12 Union Carbide & Carbon Corp Diepoxides
US2918444A (en) * 1957-08-08 1959-12-22 Union Carbide Corp Polyepoxide compositions
DE1188794B (de) * 1962-05-02 1965-03-11 Leybolds Nachfolger E Vorrichtung fuer eine Kunststoff-Spritzgiessmaschine
DE1196853B (de) * 1962-08-24 1965-07-15 Leybolds Nachfolger E Vorrichtung zur Erzeugung eines Vakuums in der Giessform einer Spritzgiessmaschine
DE1202966B (de) * 1963-05-31 1965-10-14 Leybolds Nachfolger E Evakuierbare Spritzgiessform
US3318822A (en) * 1959-07-21 1967-05-09 Ciba Ltd Epoxidized hydroaromatic acetals
DE1935051A1 (de) * 1969-07-10 1971-01-14 Continental Gummi Werke Ag Spritzgiessform fuer plastische Massen,insbesondere fuer Kautschukmischungen
DE3016130A1 (de) * 1980-04-23 1981-10-29 Siemens AG, 1000 Berlin und 8000 München Form zum vakuumgiessen von koerpern aus silikonkautschuk

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2750395A (en) * 1954-01-05 1956-06-12 Union Carbide & Carbon Corp Diepoxides
US2918444A (en) * 1957-08-08 1959-12-22 Union Carbide Corp Polyepoxide compositions
US3318822A (en) * 1959-07-21 1967-05-09 Ciba Ltd Epoxidized hydroaromatic acetals
DE1188794B (de) * 1962-05-02 1965-03-11 Leybolds Nachfolger E Vorrichtung fuer eine Kunststoff-Spritzgiessmaschine
DE1196853B (de) * 1962-08-24 1965-07-15 Leybolds Nachfolger E Vorrichtung zur Erzeugung eines Vakuums in der Giessform einer Spritzgiessmaschine
DE1202966B (de) * 1963-05-31 1965-10-14 Leybolds Nachfolger E Evakuierbare Spritzgiessform
DE1935051A1 (de) * 1969-07-10 1971-01-14 Continental Gummi Werke Ag Spritzgiessform fuer plastische Massen,insbesondere fuer Kautschukmischungen
DE3016130A1 (de) * 1980-04-23 1981-10-29 Siemens AG, 1000 Berlin und 8000 München Form zum vakuumgiessen von koerpern aus silikonkautschuk

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0132685A2 (de) * 1983-07-22 1985-02-13 Siemens Aktiengesellschaft Verfahren zur Herstellung von Epoxidharzformstoffen
EP0132685A3 (en) * 1983-07-22 1985-03-13 Siemens Aktiengesellschaft Method for the preparation of an epoxy resin moulding composition

Also Published As

Publication number Publication date
EP0107103A3 (de) 1984-10-31
AU1974483A (en) 1984-04-05
JPS5983608A (ja) 1984-05-15
NO833539L (no) 1984-04-02

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Inventor name: KONRAD, JOHN MARTIN