EP0090272A2 - Procédé de teinture égale de fibres de polyester par la méthode d'épuisement - Google Patents
Procédé de teinture égale de fibres de polyester par la méthode d'épuisement Download PDFInfo
- Publication number
- EP0090272A2 EP0090272A2 EP83102623A EP83102623A EP0090272A2 EP 0090272 A2 EP0090272 A2 EP 0090272A2 EP 83102623 A EP83102623 A EP 83102623A EP 83102623 A EP83102623 A EP 83102623A EP 0090272 A2 EP0090272 A2 EP 0090272A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dye
- dyeing
- liquor
- dyes
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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- 238000004043 dyeing Methods 0.000 title claims abstract description 102
- 238000000034 method Methods 0.000 title claims description 58
- 229920000728 polyester Polymers 0.000 title claims description 27
- 239000000975 dye Substances 0.000 claims abstract description 109
- 239000000463 material Substances 0.000 claims abstract description 17
- 239000004753 textile Substances 0.000 claims abstract description 17
- 239000000986 disperse dye Substances 0.000 claims abstract description 13
- 239000000835 fiber Substances 0.000 claims description 20
- 239000000049 pigment Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 238000003860 storage Methods 0.000 claims description 14
- 239000003960 organic solvent Substances 0.000 claims description 13
- 239000003086 colorant Substances 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 239000012209 synthetic fiber Substances 0.000 claims description 6
- 229920002994 synthetic fiber Polymers 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000002950 deficient Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 44
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 19
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 7
- 239000006185 dispersion Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- -1 Milchsäureethylester Chemical compound 0.000 description 4
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 3
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000009970 yarn dyeing Methods 0.000 description 3
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- HXDLWJWIAHWIKI-UHFFFAOYSA-N 2-hydroxyethyl acetate Chemical compound CC(=O)OCCO HXDLWJWIAHWIKI-UHFFFAOYSA-N 0.000 description 2
- JSGVZVOGOQILFM-UHFFFAOYSA-N 3-methoxy-1-butanol Chemical compound COC(C)CCO JSGVZVOGOQILFM-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- TUXJTJITXCHUEL-UHFFFAOYSA-N disperse red 11 Chemical compound C1=CC=C2C(=O)C3=C(N)C(OC)=CC(N)=C3C(=O)C2=C1 TUXJTJITXCHUEL-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- BSYVTEYKTMYBMK-UHFFFAOYSA-N tetrahydrofurfuryl alcohol Chemical compound OCC1CCCO1 BSYVTEYKTMYBMK-UHFFFAOYSA-N 0.000 description 2
- VDCOSJPGDDQNJH-JVSYPLCOSA-N (8s,9s,10r,11r,13s,14s)-11-hydroxy-13-methyl-1,2,6,7,8,9,10,11,12,14,15,16-dodecahydrocyclopenta[a]phenanthrene-3,17-dione Chemical compound O=C1CC[C@@H]2[C@H]3[C@H](O)C[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 VDCOSJPGDDQNJH-JVSYPLCOSA-N 0.000 description 1
- MLHQPPYBHZSBCX-UHFFFAOYSA-N 1-(2-hydroxyethoxy)propan-2-ol Chemical compound CC(O)COCCO MLHQPPYBHZSBCX-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- VGKYEIFFSOPYEW-UHFFFAOYSA-N 2-methyl-4-[(4-phenyldiazenylphenyl)diazenyl]phenol Chemical compound Cc1cc(ccc1O)N=Nc1ccc(cc1)N=Nc1ccccc1 VGKYEIFFSOPYEW-UHFFFAOYSA-N 0.000 description 1
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- ZLFVRXUOSPRRKQ-VHEBQXMUSA-N CI Pigment Red 3 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1\N=N\C1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-VHEBQXMUSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000001089 [(2R)-oxolan-2-yl]methanol Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000000010 aprotic solvent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229930188620 butyrolactone Natural products 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- 238000010016 exhaust dyeing Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical class C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/36—Material containing ester groups using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B23/00—Component parts, details, or accessories of apparatus or machines, specially adapted for the treating of textile materials, not restricted to a particular kind of apparatus, provided for in groups D06B1/00 - D06B21/00
- D06B23/20—Arrangements of apparatus for treating processing-liquids, -gases or -vapours, e.g. purification, filtration or distillation
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/90—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
- D06P1/92—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
- D06P1/928—Solvents other than hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
- D06P5/2066—Thermic treatments of textile materials
- D06P5/2072—Thermic treatments of textile materials before dyeing
Definitions
- the present invention relates to a process for the uniform dyeing of textile material from hydrophobic synthetic fibers, preferably polyester (PES) fibers, alone or as a component of mixtures with natural or other synthetic fibers using the exhaust method with heat-fixable colorants in a closed apparatus system under high temperature (HT) conditions at the increasing pressure as well as under atmospheric pressure, at temperatures between 90 ° and 140 ° C. from an aqueous medium by means of a moving liquor which is circulated in the dyeing system until the colorant is present the textile material is pulled up and fixed in it.
- HT high temperature
- the entire dyeing liquor, including the dye is heated to a dyeing temperature in a batch container separate from the actual dyeing vessel and then, with the help of relative overpressure, quickly transferred to the connected circulation dyeing machine, in which the fiber material arranged in the packing or slip-on system is located, which is in a preparatory step vented with flowing steam and at the same time had also been heated to about dyeing temperature.
- the complete condensation of the steam atmosphere is forced and the dyeing tank is completely filled with the pressed liquor.
- Disperse dyes in particular have proven themselves as colorants for the stated purpose.
- Disperse dyes which are known to contain no solubilizing groups in the molecule, are organic compounds with limited solubility in water, but with the proportionally low form in water of high affinity for polyester fibers.
- dyeing synthetic fibers from an aqueous phase takes place over the dispersed dye by adding appropriate additives, such as a relatively high amount of dispersant (to stabilize the Fleet) into a fine distribution, without which a spot-free and level coloring would not be possible.
- the actual dyeing process takes place through the adsorption of the dissolved monomolecular dye onto the surface of the PES fiber and through the subsequent diffusion into the interior of the fiber.
- the solution balance in the fleet which is disturbed during this exhaust process, becomes Compensation restored by redissolving dye from the dispersed state.
- the finish of the commercial dyes therefore has a great influence on the dyeing properties and accounts for about half of the dye production costs. Despite all of this, difficulties arise due to the different leveling behavior of disperse dyes in the PES pull-out dyeing.
- the present invention is based on the object of making dyes or pigments without a finish or without a binder accessible for all exhaust process variants for dyeing PES fibers from an aqueous bath and in this way to simplify the treatment measures.
- the focus here is on achieving level dyeings in a short time even with poorly leveling dyes and saving on expensive finishing costs.
- This object is achieved according to the invention in that dyes and / or pigments which are practically insoluble or sparingly soluble in water, without prior preparation by means of a finish aimed at suitable dyeing properties or in the absence of special binders, in one or more organic solvents which operate under dyeing conditions are sufficiently soluble in water or are miscible with it, and the solution thus obtained is then circulated into the Textile material is introduced, dye-free or dye-depleted aqueous liquor flowing through or around dyeing temperature.
- the claimed process advantageously makes use of the fact that when a water-insoluble dye dissolved in an organic solvent of the type defined above is introduced into water which is hot at about 130 ° C., surprisingly a higher proportion of dye remains in solution than from the dye dispersion during conventional heating to 130 ° C. goes into solution in the aqueous liquor.
- the idea of the invention on which the present case is based now consists of using this experimental finding directly for dyeing and metering the dye solution obtained in the above manner in portions into the circuit of a disturbing, aqueous liquor without dyeing at any temperature, so that under A exploitation 'of the increased concentration of the monomolecular dye results in a better levelness of the dyeings.
- dyestuffs are used as dyestuffs which meet the abovementioned conditions with regard to solubility.
- Such products are well known and are described in the Color Index, 3rd edition, volume 2 under the class name "Disperse Dyes”. According to their constitution, most disperse dyes belong to the azo, antrachinone or in a few cases to the nitro or quinophthalone compounds.
- the disperse dyes can advantageously be used in the unfinished state and can be used, for example, as press cakes, ie coming from the manufacture and not yet provided with the finish (unfinished fabrication (raw) goods).
- the present 'invention also enables those gefinishten disperse dyes, according to the usual exhaust difficult matter to dye are to dye with very good levelness.
- pigments can also be used, provided they meet the requirements with regard to solubility, especially organic pigments which, in the course of the new process, do not require a binder system as a mediator for their binding to the fiber, and those in the color index, Edition, Volume 3 are divided under the term "Pigments".
- Solvent Dyes in the Color Index, 3rd edition, volume 3 have also proven to be suitable according to the process.
- the dyes and / or pigments mentioned are dissolved in a solvent (of the type defined above) alone or in a mixture thereof in as high a concentration as possible and this concentrated dye solution is metered in portions at certain intervals , expediently distributed over several pumping cycles with changing flow direction, pressed into the aqueous dye liquor.
- a solvent of the type defined above
- this concentrated dye solution is metered in portions at certain intervals , expediently distributed over several pumping cycles with changing flow direction, pressed into the aqueous dye liquor.
- the entire amount required for dyeing can be added to the circulating liquor in one batch or in a few portions in the form of a concentrated solution, with less-level or poorly leveling dyes, it can be introduced in several portions certain time intervals or distributed over different circulation cycles.
- the reductive aftertreatment can be dispensed with and the coloring only needs to be rinsed.
- the present invention is technically easy to implement, because all existing zirhulation dyeing machines can be used for the new process and a controllable sluice device according to the known state of the art can be easily installed on the fleet circulation system of the dyeing machines.
- the blind liquor (without dye) can advantageously be heated to the dyeing temperature as quickly as possible.
- An additional batch container for heating the dyeing liquor, as in the isothermal rapid color process according to DE-PS 23 31 669, is unnecessary according to the invention.
- the claimed process can be carried out very safely and provides very reproducible dyeings because the dosage or the introduction of the dye solution can easily be controlled automatically, especially since modern dyeing machines already work under program control.
- the organic solvent in the residual liquor and the associated wastewater pollution appear to be disadvantageous compared to the conventional process for dyeing from aqueous dispersion.
- concentration of such a solvent in the liquor is very low (for example 0.3% by volume in Example 1), that in most cases no dispersing and leveling agents get into the waste water with the remaining liquor that if necessary, a reductive aftertreatment the dyeings can be dispensed with and therefore no alkali or sodium dithionite can get into the waste water, and that finally biodegradable organic solvents can be used.
- all HT dyeing machines with circulating liquor e.g. Cross-wound and tree dyeing machines, including those with separate batch tanks, as are otherwise used for isothermal dyeing processes, and also all HT jet dyeing machines are suitable.
- the dyeing apparatus of the same design working at cooking temperature under atmospheric pressure can also be considered.
- the concentrated dye solution can be introduced into the liquor circulation in various ways.
- the dosing is either carried out via a secondary or sample chamber or via a separate vessel. taken.
- Exemplary embodiments of such metering devices which can be used according to the invention are shown schematically in the drawings given below. This can be done, for example, with the aid of a bypass line which can be locked against the pressurized dyeing system and in which a batch or storage vessel is located Preparation and absorption of the dye solution is located.
- the distribution of the dye solution in the total dyeing liquor is then carried out by including the bypass in the liquor cycle.
- This process can be carried out by means of pressure superimposition by, for example, compressed air, water vapor or an inert gas on the liquid surface of the dye solution, which is equipped with a compressed air supply in a heatable and pressure-tight sealable.
- Batch or storage vessel deposited which is connected to the fleet circuit directly or indirectly via a riser pipe with the interposition of a metering valve.
- the dosing of the dye solution in predetermined portions can be accomplished by appropriate control, for example a solenoid valve or a pneumatically controllable valve, manually or automatically, after certain times or distributed over a predetermined number of pumping cycles.
- the injector will then consist of an additional pump which conveys the dye solution into the pressurized dyeing system from a batch or storage vessel under atmospheric pressure.
- the dyeing described below was carried out in a yarn dyeing apparatus, which essentially consists of a pressure-tight dye container with carriers for the textile material to be dyed, a pipeline connected to form the liquor circuit and a circulation pump for the circulating liquor, the pipeline mentioned ( 1) contains a connection to the metering device shown in Fig. 1 for feeding the dye solution into the liquor circuit.
- This metering device is itself constructed from a batch or storage vessel (2) for the dye solution (3), which is equipped with a feed (4) for compressed air or a compressed gas, a closable pressure outlet (5) and a liquid emptying pipe (6) and with a Heating jacket (7) for controlling the temperature in the dye solution (3) is equipped.
- a riser pipe (8) reaching almost to the bottom of the vessel leads after an approximately right-angled bend out of the batch or storage vessel (2) and establishes the connection to the pipeline (1) of the liquor circulation system via a metering valve (9).
- the riser pipe (8) is provided for the portion-wise removal and transfer of the dye solution (3) from the batch or storage vessel (2) into the pipeline (1), which is achieved by applying relative overpressure to the liquid level of the dye solution (3) is, and expediently at dyeing temperature, ensures the uniform distribution of the dye solution (3) in the total dye liquor pulsating due to pump action with changing flow direction through the pipeline (1), the dyeing tank and the textile material or poor in dye.
- a blind liquor made of 320 liters of water had been filled into the dyeing container charged with the textile material to be dyed.
- the switching intervals were 4 minutes each .. from outside to inside and 3 minutes from inside to outside.
- the dye solution (3) was divided into 3 switching intervals and about 1/3 of the batch amount was added to the cycle of the entire fleet.
- the dye solution (3) was transferred with the aid of nitrogen, which was pressed into the batch vessel (2) and superimposed on the liquid level at a pressure of 5 bar. As soon as the metering valve (9) was opened, the dye solution rose in this riser pipe due to the increased pressure on the surface of the liquid outside the riser pipe (8) and in this way reached the circulating liquor.
- the dyeing system was cooled, the textile material was removed from the dyeing tank and only rinsed with water without reductive aftertreatment.
- a yarn dyeing apparatus similar to the description in Example 1 was used for the subsequent dyeing, but in this case the pipeline (1) used to form the liquor circuit is provided here with a metering device connected as a bypass according to FIG. 2.
- This metering device consists in that a shunt line (10a, 10b), which is installed between the sections (10a) and (10b) and equipped with a pressure outlet (5) which can be closed by a valve (3) passes through, branches off from the pipeline section (1a) and is fed back to this pipeline in section (1b) after a certain distance.
- a shunt line (10a, 10b) which is installed between the sections (10a) and (10b) and equipped with a pressure outlet (5) which can be closed by a valve (3) passes through, branches off from the pipeline section (1a) and is fed back to this pipeline in section (1b) after a certain distance.
- the dosing principle is based on the fact that hot, blind or dye-depleted liquor is removed in the flow direction of the pipelines at (1b) by suitable actuation of three-way cock (11b), over the distance (10b) through the batch or storage vessel (2 ) and is then returned via the line (10a) and the second three-way valve (11a) back into the pipeline at (1a).
- This measure causes the dye solution (3) to be carried in portions is then distributed evenly in the entire circulating fleet.
- the blind liquor of 20 l of water was adjusted to pH 5 by acidification and via the pipeline composed of sections (1a), (1c) and (1b) through the PES muff stored in the dyeing tank under the same treatment conditions as in Example 1 brought to circulation.
- the transfer of the dye solution (3) into the dyeing container was started.
- the hot fleet circulated 8 times briefly over the route (1b) - (11b) - (10b) - (2) - (10a) - (11a) - (1a) and took from the preparation vessel (2) each time with about 25 cm 3 of dye solution in the circulation stream.
- This dyeing was also ended after a dyeing time of 20 minutes, the dyed PES material with an aqueous bath with the addition of 3 cm 3 / l NaOH solution of 38 ° Be and 3 g / l sodium dithionite and 1 g / l of a nonionic detergent for 10 minutes after-treated at 85 ° C and then rinsed with water.
- the dyeing system used comprising the dyeing tank and the textile goods contained therein, was of the same type as in Example 1.
- a blind 20 liter liquor circulated through a 700 g PES fiber muff. This aqueous, 130 ° C warm liquor was mixed with 1 g / l of a dispersant and adjusted to pH 5.
- the dye solution was transferred into 8 portions. After the metering had ended, the dyeing operation was continued for a further 20 minutes and then ended.
- the yarn dyeing apparatus used here corresponds in principle to that of Example 1, but in this case the pipeline (1) provided to form the liquor circuit has a connection to the metering device shown in FIG. 3.
- This dosing device is composed of a batch or storage vessel (2) for the dye solution (3), containing a feed (4) for compressed air or compressed gas and is surrounded by a heating jacket (7) for controlling the temperature in the dye solution ( 3).
- a transfer line (12) branching off from the bottom of the vessel and provided with a metering valve (9) serves as a connection between the batch or storage vessel (2) and the pipeline (1) for the liquor circuit.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Coloring (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3210380A DE3210380C2 (de) | 1982-03-20 | 1982-03-20 | Verfahren zum gleichmäßigen Färben von hydrophoben synthetischen Fasern nach der Ausziehmethode |
DE3210380 | 1982-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0090272A2 true EP0090272A2 (fr) | 1983-10-05 |
EP0090272A3 EP0090272A3 (fr) | 1984-11-28 |
Family
ID=6158908
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83102623A Withdrawn EP0090272A3 (fr) | 1982-03-20 | 1983-03-17 | Procédé de teinture égale de fibres de polyester par la méthode d'épuisement |
Country Status (5)
Country | Link |
---|---|
US (1) | US4491995A (fr) |
EP (1) | EP0090272A3 (fr) |
JP (1) | JPS58169583A (fr) |
KR (1) | KR840004204A (fr) |
DE (1) | DE3210380C2 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0143077A1 (fr) * | 1983-11-15 | 1985-05-29 | Ciba-Geigy Ag | Procédé de teinture de matière textile hydrophobe |
EP0204656A1 (fr) * | 1985-05-14 | 1986-12-10 | Ciba-Geigy Ag | Procédé de teinture de matiére textile hydrophobe |
FR2658210A1 (fr) * | 1990-02-13 | 1991-08-16 | Champagne Teinturerie | Procede de traitement et de reajustement d'un bain de traitement (teinture) de produits textiles ainsi que dispositif utilise pour la mise en óoeuvre de ce procede. |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61252381A (ja) * | 1985-05-01 | 1986-11-10 | 株式会社 日阪製作所 | 低浴比染色における染液の供給方法 |
DE3720697A1 (de) * | 1987-06-23 | 1989-01-05 | Hoechst Ag | Verfahren zum faerben von textilen geweben oder gewirken aus polyesterfasern oder mischungen aus polyesterfasern mit anderen fasern in jet-faerbemaschinen |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1794193A1 (de) * | 1967-09-29 | 1971-05-06 | Ciba Geigy Ag | Verfahren zum Faerben von hydrophoben Textilmaterialien |
DE2337097A1 (de) * | 1972-09-01 | 1974-03-07 | Ciba Geigy Ag | Verfahren zum faerben von synthetischem fasermaterial und dessen mischungen mit natuerlichem fasermaterial |
LU70654A1 (fr) * | 1974-04-13 | 1974-12-10 | ||
DE2331669A1 (de) * | 1973-06-22 | 1975-01-23 | Hoechst Ag | Verfahren zum faerben von synthesefasern |
DE2534562A1 (de) * | 1975-08-02 | 1977-02-03 | Hoechst Ag | Verfahren zum gleichmaessigen, isothermischen hochtemperaturfaerben von hydrophoben synthetischen fasern mit dispersionsfarbstoffen |
DE2456250B2 (de) * | 1974-11-28 | 1979-09-27 | Rudolf Then, Faerbereimaschinenfabrik Gmbh, 7172 Schwaebisch Hall | Verfahren und Vorrichtung zum Färben von in einem Färbekessel im Pack- oder Aufstecksystem angeordnetem garn- oder faserförmigem Textilgut |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH555939A (fr) * | 1972-06-19 | 1974-11-15 | ||
DK514674A (da) * | 1974-05-22 | 1975-11-23 | Obermaier & Cie | Fremgangsmade til veskebehandling, navnlig til farvning af tekstilfibre, og apparat til gennemforelse af fremgangsmaden |
DE2534618C3 (de) * | 1975-08-02 | 1978-03-23 | Hoechst Ag, 6000 Frankfurt | Verfahren und Vorrichtung zum isothermischen Hochtemperaturfärben |
JPS5845519B2 (ja) * | 1976-07-16 | 1983-10-11 | 三井東圧化学株式会社 | 合成繊維の染色法 |
-
1982
- 1982-03-20 DE DE3210380A patent/DE3210380C2/de not_active Expired
-
1983
- 1983-03-09 US US06/473,757 patent/US4491995A/en not_active Expired - Fee Related
- 1983-03-17 EP EP83102623A patent/EP0090272A3/fr not_active Withdrawn
- 1983-03-18 JP JP58044527A patent/JPS58169583A/ja active Pending
- 1983-03-18 KR KR1019830001089A patent/KR840004204A/ko not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1794193A1 (de) * | 1967-09-29 | 1971-05-06 | Ciba Geigy Ag | Verfahren zum Faerben von hydrophoben Textilmaterialien |
DE2337097A1 (de) * | 1972-09-01 | 1974-03-07 | Ciba Geigy Ag | Verfahren zum faerben von synthetischem fasermaterial und dessen mischungen mit natuerlichem fasermaterial |
DE2331669A1 (de) * | 1973-06-22 | 1975-01-23 | Hoechst Ag | Verfahren zum faerben von synthesefasern |
LU70654A1 (fr) * | 1974-04-13 | 1974-12-10 | ||
DE2456250B2 (de) * | 1974-11-28 | 1979-09-27 | Rudolf Then, Faerbereimaschinenfabrik Gmbh, 7172 Schwaebisch Hall | Verfahren und Vorrichtung zum Färben von in einem Färbekessel im Pack- oder Aufstecksystem angeordnetem garn- oder faserförmigem Textilgut |
DE2534562A1 (de) * | 1975-08-02 | 1977-02-03 | Hoechst Ag | Verfahren zum gleichmaessigen, isothermischen hochtemperaturfaerben von hydrophoben synthetischen fasern mit dispersionsfarbstoffen |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0143077A1 (fr) * | 1983-11-15 | 1985-05-29 | Ciba-Geigy Ag | Procédé de teinture de matière textile hydrophobe |
EP0204656A1 (fr) * | 1985-05-14 | 1986-12-10 | Ciba-Geigy Ag | Procédé de teinture de matiére textile hydrophobe |
FR2658210A1 (fr) * | 1990-02-13 | 1991-08-16 | Champagne Teinturerie | Procede de traitement et de reajustement d'un bain de traitement (teinture) de produits textiles ainsi que dispositif utilise pour la mise en óoeuvre de ce procede. |
EP0443281A1 (fr) * | 1990-02-13 | 1991-08-28 | Teinturerie De Champagne | Procédé de traitement et de réajustement d'un bain de traitement (teinture) de produits textiles ainsi que dispositif utilisé pour la mise en oeuvre de ce procédé |
Also Published As
Publication number | Publication date |
---|---|
KR840004204A (ko) | 1984-10-10 |
EP0090272A3 (fr) | 1984-11-28 |
JPS58169583A (ja) | 1983-10-06 |
DE3210380A1 (de) | 1983-09-29 |
DE3210380C2 (de) | 1986-01-02 |
US4491995A (en) | 1985-01-08 |
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