EP0023334B1 - Wäscheweichspülmittel - Google Patents
Wäscheweichspülmittel Download PDFInfo
- Publication number
- EP0023334B1 EP0023334B1 EP80104269A EP80104269A EP0023334B1 EP 0023334 B1 EP0023334 B1 EP 0023334B1 EP 80104269 A EP80104269 A EP 80104269A EP 80104269 A EP80104269 A EP 80104269A EP 0023334 B1 EP0023334 B1 EP 0023334B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- methyl
- carbon atoms
- weight
- fabric softeners
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002979 fabric softener Substances 0.000 title claims abstract description 18
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 8
- 229910052739 hydrogen Chemical group 0.000 claims abstract description 6
- 239000001257 hydrogen Chemical group 0.000 claims abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 5
- 239000000194 fatty acid Substances 0.000 claims abstract description 5
- 229930195729 fatty acid Natural products 0.000 claims abstract description 5
- 229920000151 polyglycol Polymers 0.000 claims abstract description 5
- 239000010695 polyglycol Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 3
- 150000001450 anions Chemical class 0.000 claims abstract description 3
- 239000006185 dispersion Substances 0.000 claims abstract description 3
- 239000004094 surface-active agent Substances 0.000 claims abstract description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract 4
- 150000004665 fatty acids Chemical class 0.000 claims abstract 3
- 150000002431 hydrogen Chemical group 0.000 claims abstract 2
- -1 Cl (cation) Chemical class 0.000 abstract description 5
- 150000001768 cations Chemical class 0.000 abstract 4
- 239000004753 textile Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
- D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
- D06M2101/08—Esters or ethers of cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Definitions
- washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This is particularly the case when the laundry is done in the washing machine.
- This undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
- the water-dispersible dialkyldimethylammonium salts have been introduced for this purpose.
- these products have the disadvantage that the treated tissue becomes hydrophobic when overdosed and the rewettability is thereby delayed.
- the invention thus relates to fabric softeners in the form of an aqueous solution or dispersion which comprise 1 to 15, preferably 2 to 6% by weight of one or more compounds of the formulas 1 to III wherein R, is alkyl or alkenyl having 10-30 carbon atoms, preferably 8-14 carbon atoms, R 2 is alkyl having 1-4 carbon atoms, preferably methyl, R 3 is methyl or hydrogen m a number from 1 to 1 5, preferably 1, and A an anion such as B.
- Cl (-), Br (-), R 2 OSO 3 (-) or R 2 OPO 3 (-) means 0.01 ⁇ 4, preferably 0.5-2.5 wt .-% of a fatty acid ethanol amide polyglycol ether Formula IV where R 4 is C 4 ⁇ C 20 alkyl, preferably C8 ⁇ C 16 alkyl, n is a number from 2 to 20, preferably 2 to 6, x and y are hydrogen or methyl, but x and y are not simultaneously methyl, and in addition to 100% by weight of water and substances and auxiliaries customary in fabric softening agents, these substances and auxiliaries not being surfactants.
- This combination of compounds I, II and III with a compound of formula IV gives any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel.
- the use as a laundry aftertreatment for terry and underwear made of cotton is particularly advantageous.
- These fabric softeners are produced by simply mixing or dispersing the individual components in water.
- This fabric softener according to the invention can either only one compound of the formulas I to III contain or they contain a mixture of two or more compounds of these formulas to III within the specified limits. If a mixture of two or more compounds of the formulas I to 111 is present, their mixing ratio with one another is completely uncritical and can have any value.
- the fabric softener according to the invention may also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use, diluted fabric softener.
- substances or auxiliaries that have already been used in fabric softeners, such as. B. electrolytes, acidulants, organic complexing agents, optical brighteners or solvents as well as colors and fragrances. They are used to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Description
- Es ist bekannt, daß gewaschene Textilien, besonders solche aus Cellulosefasern, nach dem Trocknen eine unangenehme Verhärtung aufweisen. Dies tritt insbesondere dann ein, wenn die Wäsche im Waschautomaten erfolgt. Diese unerwünschte Griffverhärtung kann man dadurch beseitigen, daß man die Textilien nach der Wäsche in einem Spülbad mit kationischen Substanzen behandelt, die mindestens zwei langkettige aliphatische Reste im Molekül enthalten. In der Praxis haben sich für diesen Zweck besonders die in Wasser dispergierbaren Dialkyldimethylammoniumsalze eingeführt. Diese Produkte haben jedoch den Nachteil, daß bei Überdosierung das behandelte Gewebe hydrophob und dadurch die Wiederbenetzbarkeit verzögert wird.
- Es wurde nun gefunden, daß man diese Schwierigkeiten beseitigen kann, wenn man die als Wäscheweichspülmittel dienenden quaternären Ammoniumverbindungen mit einem Fettsäureethanolamidpolyglykolether kombiniert. Gegenstand der Erfindung sind somit Wäscheweichspülmittel in Form einer wäßrigen Lösung oder Dispersion, die 1 bis 15, vorzugsweise 2 bis 6 Gew.-% einer oder mehrerer Verbindungen der Formeln 1 bis III
- Diese Kombination der Verbindungen I, II und III mit einer Verbindung der Formel IV verleiht beliebigen Textilmaterialien, besonders solchen aus natürlicher oder regenerierter.Cellulose, Wolle, Cellulose-acetat, -triacetat, Polyamid, Polyacrylnitril, Polyester, Polypropylen einen angenehmen und weichen Griff. Besonders vorteilhaft ist der Einsatz als Wäschenachbehandlungsmittel für Frottee-und Leibwäsche aus Baumwolle. Die Herstellung dieser Wäscheweichspülmittel erfolgt durch einfaches Vermischen oder Dispergieren der Einzelkomponenten in Wasser. Diese Wäscheweichspülmittel gemäß der Erfindung können entweder nur jeweils eine Verbindung der Formeln I bis III enthalten oder aber sie enthalten ein Gemisch aus zwei oder mehr Verbindungen dieser Formeln bis III innerhalb der angegebenen Grenzen. Liegt ein Gemisch aus zwei oder mehr Verbindungen der Formeln I bis 111 vor, so ist deren Mischungsverhältnis untereinander völlig unkritisch und kann jeden beliebigen Wert annehmen.
- Darüber hinaus können die erfindungsgemäßen Wäscheweichspülmittel noch weitere Substanzen und Hilfsmittel enthalten, die entweder schon im Konzentrat des Wäscheweichspülmittels zugemischt oder dem gebrauchsfertigen, verdünnten Wäscheweichspülmittel gesondert zugesetzt werden. Hierbei handelt es sich um Substanzen oder Hilfsmittel, die man bereits in Wäscheweichspülmitteln eingesetzt hat, wie z. B. Elektrolyte, Absäuerungsmittel, organische Komplexbildner, optische Aufhellungsmittel oder Lösungsmittler sowie Farb- und Duftstoffe. Sie dienen zur zusätzlichen Beeinflussung des Warengriffs oder sonstiger Eigenschaften der zu behandelnden Textilien oder zur Viskositätseinstellung, zur pH-Regulierung oder zur Erhöhung der Kältestabilität.
- Die Anwendung dieser Wäscheweichspülmittel erfolgt wie üblich, indem man sie im Anschluß an die Textilwäsche in das letzte Spülwasser gibt. Das so behandelte Textilmaterial wird dann getrocknet, wobei die Wiederbenetzbarkeit des Textilmaterials wesentlich verbessert ist im Vergleich zu handelsüblichen Mitteln.
- In den folgenden Beispielen sind einige erfindungsgemäße Wäscheweichspülmittel beschrieben. Prozentangaben sind in allen Fällen Gewichtsprozente. Die Herstellung dieser Wäscheweichspülmittel erfolgt in allen Fällen durch einfaches Verrühren in der Kälte von wäßrigen Lösungen der einzelnen Komponenten.
-
-
-
-
- Dabei werden glatte Baumwollgewebe mit den erfindungsgemäßen Mischungen behandelt. Zum Vergleich wurde ein handelsüblicher Weichmacher hinzugezogen (Beispiel 4). Nach dieser Prüfmethode wurden für die Mischungen der Beispiele 1-4 die in der nachfolgenden Tabelle aufgeführten Ergebnisse erhalten. Die Steighöhe nicht ausgerüsteter Gewebe wird dabei mit 100% bezeichnet.
- Die Ergebnisse zeigen, daß die erfindungsgemäßen Wäscheweichspülmittelkombinationen im Vergleich mit einem handelsüblichen Produkt ein verbessertes Saugvermögen aufweisen.
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT80104269T ATE5662T1 (de) | 1979-07-25 | 1980-07-19 | Waescheweichspuelmittel. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2930061 | 1979-07-25 | ||
DE19792930061 DE2930061A1 (de) | 1979-07-25 | 1979-07-25 | Waescheweichspuelmittel |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0023334A1 EP0023334A1 (de) | 1981-02-04 |
EP0023334B1 true EP0023334B1 (de) | 1983-12-21 |
Family
ID=6076677
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80104269A Expired EP0023334B1 (de) | 1979-07-25 | 1980-07-19 | Wäscheweichspülmittel |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0023334B1 (de) |
JP (1) | JPS5620677A (de) |
AT (1) | ATE5662T1 (de) |
BR (1) | BR8004626A (de) |
CA (1) | CA1153510A (de) |
DE (2) | DE2930061A1 (de) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4439335A (en) * | 1981-11-17 | 1984-03-27 | The Procter & Gamble Company | Concentrated fabric softening compositions |
DE3150179A1 (de) * | 1981-12-18 | 1983-06-23 | Hoechst Ag, 6230 Frankfurt | Konzentrierte vormischungen von waescheweichspuelmitteln |
DE3150178A1 (de) * | 1981-12-18 | 1983-06-30 | Hoechst Ag, 6230 Frankfurt | "konzentrierte waescheweichspuelmittel" |
JPS58144175A (ja) * | 1982-02-23 | 1983-08-27 | ライオン株式会社 | 繊維製品処理用物品 |
US4497716A (en) * | 1982-12-23 | 1985-02-05 | Lever Brothers Company | Fabric softening composition |
GB8410319D0 (en) * | 1984-04-19 | 1984-05-31 | Unilever Plc | Aqueous fabric softening composition |
GB8410320D0 (en) * | 1984-04-19 | 1984-05-31 | Unilever Plc | Aqueous fabric softening composition |
GB8410321D0 (en) * | 1984-04-19 | 1984-05-31 | Unilever Plc | Aqueous concentrated fabric softening composition |
GB8430301D0 (en) * | 1984-11-30 | 1985-01-09 | Swan Thomas & Co Ltd | Compositions of matter for fabric softeners |
ES2227535T3 (es) * | 1994-10-14 | 2005-04-01 | Kao Corporation | Composicion suavizante liquida. |
GB2319180B (en) * | 1996-11-12 | 2001-01-17 | Reckitt & Colman Inc | Mycobacterial compositions |
DE19651447C1 (de) * | 1996-12-11 | 1997-10-02 | Henkel Kgaa | Mittel für die Avivage von Textil- und Keratinfasern und Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln |
DE19708133C1 (de) * | 1997-02-28 | 1997-12-11 | Henkel Kgaa | Mittel für die Avivage von Textil- und Keratinfasern sowie die Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln |
US6635607B2 (en) | 2001-05-15 | 2003-10-21 | Ici Americas Inc. | Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants |
JP7415563B2 (ja) | 2020-01-07 | 2024-01-17 | 富士フイルムビジネスイノベーション株式会社 | 情報処理装置及びプログラム |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE545267A (de) * | ||||
US3451927A (en) * | 1964-07-08 | 1969-06-24 | Lever Brothers Ltd | Fabric conditioner |
DE2605502A1 (de) * | 1976-02-12 | 1977-08-18 | Exquisit Kosmetik Gmbh | Fluessiges feinwaschmittel |
-
1979
- 1979-07-25 DE DE19792930061 patent/DE2930061A1/de not_active Withdrawn
-
1980
- 1980-07-19 AT AT80104269T patent/ATE5662T1/de not_active IP Right Cessation
- 1980-07-19 EP EP80104269A patent/EP0023334B1/de not_active Expired
- 1980-07-19 DE DE8080104269T patent/DE3065943D1/de not_active Expired
- 1980-07-24 BR BR8004626A patent/BR8004626A/pt unknown
- 1980-07-24 CA CA000356977A patent/CA1153510A/en not_active Expired
- 1980-07-24 JP JP10064180A patent/JPS5620677A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
DE2930061A1 (de) | 1981-02-19 |
BR8004626A (pt) | 1981-02-03 |
JPS5620677A (en) | 1981-02-26 |
DE3065943D1 (en) | 1984-01-26 |
CA1153510A (en) | 1983-09-13 |
EP0023334A1 (de) | 1981-02-04 |
JPS6338470B2 (de) | 1988-07-29 |
ATE5662T1 (de) | 1984-01-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0082457B1 (de) | Konzentrierte Wäscheweichspülmittel | |
EP0023334B1 (de) | Wäscheweichspülmittel | |
EP0082456B1 (de) | Konzentrierte Vormischungen von Wäscheweichspülmitteln | |
EP0043547B1 (de) | Wäscheweichspülmittelkonzentrat | |
DE2407708C2 (de) | Wäßriges Textilweichmachungsmittel zur Anwendung in Spülbädern von Waschvorgängen | |
DE2709463C2 (de) | Flüssiges, konzentriertes Wasch- und Reinigungsmittel | |
EP0413249B1 (de) | Wäscheweichspülmittel | |
EP0085933B1 (de) | Konzentrierte Wäscheweichspülmittel | |
DE2210087B2 (de) | Imidazoliniumsalze und diese enthaltende Textüweichmachungsmittel | |
EP0023333B1 (de) | Wäscheweichspülmittel | |
DE1619043B2 (de) | Mittel zum weichmachen von textilien und gleichzeitigem vermitteln einer guten saugfaehigkeit | |
DE69109579T2 (de) | Textilweichmacherzusammensetzung. | |
EP0094655B1 (de) | Konzentrierte Wäscheweichspülmittel | |
EP0022555B1 (de) | Wäscheweichspülmittel | |
DE2163003B2 (de) | Weichmachungsmittel für Textilien | |
DE1935499A1 (de) | Avivagemittel | |
DE3730444C2 (de) | ||
DE1901194C3 (de) | Detergens-verträgliches wäßriges Weichmachungsmittel und dessen Verwendung zum Weichmachen von Geweben während des Waschens oder während des Spiilens | |
DE2732985C2 (de) | ||
DE2243806C3 (de) | Wässriges Mittel zum Weichmachen von Textilgut | |
DE3135013A1 (de) | "waescheweichspuelmittel" | |
DE1619182B2 (de) | Verfahren zum weichmachen von textilien | |
DE2539310C2 (de) | ||
DE1619081B2 (de) | Avivagemittel fuer textilien | |
DE1619081C3 (de) | Avivagemittel für Textilien |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT NL SE |
|
17P | Request for examination filed |
Effective date: 19810624 |
|
ITF | It: translation for a ep patent filed | ||
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LI NL SE |
|
REF | Corresponds to: |
Ref document number: 5662 Country of ref document: AT Date of ref document: 19840115 Kind code of ref document: T |
|
REF | Corresponds to: |
Ref document number: 3065943 Country of ref document: DE Date of ref document: 19840126 |
|
ET | Fr: translation filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 19840618 Year of fee payment: 5 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 19840621 Year of fee payment: 5 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: BE Payment date: 19840630 Year of fee payment: 5 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 19840810 Year of fee payment: 5 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: SE Payment date: 19840930 Year of fee payment: 5 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed | ||
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: AT Payment date: 19860626 Year of fee payment: 7 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 19870731 Year of fee payment: 8 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Effective date: 19880719 Ref country code: AT Effective date: 19880719 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Effective date: 19880720 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Effective date: 19880731 Ref country code: CH Effective date: 19880731 Ref country code: BE Effective date: 19880731 |
|
BERE | Be: lapsed |
Owner name: HOECHST A.G. Effective date: 19880731 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Effective date: 19890201 |
|
NLV4 | Nl: lapsed or anulled due to non-payment of the annual fee | ||
GBPC | Gb: european patent ceased through non-payment of renewal fee | ||
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 19890331 |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Effective date: 19890401 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
EUG | Se: european patent has lapsed |
Ref document number: 80104269.8 Effective date: 19890510 |