EP0023334A1 - Wäscheweichspülmittel - Google Patents

Wäscheweichspülmittel Download PDF

Info

Publication number
EP0023334A1
EP0023334A1 EP80104269A EP80104269A EP0023334A1 EP 0023334 A1 EP0023334 A1 EP 0023334A1 EP 80104269 A EP80104269 A EP 80104269A EP 80104269 A EP80104269 A EP 80104269A EP 0023334 A1 EP0023334 A1 EP 0023334A1
Authority
EP
European Patent Office
Prior art keywords
alkyl
methyl
carbon atoms
cation
see diagramm
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80104269A
Other languages
English (en)
French (fr)
Other versions
EP0023334B1 (de
Inventor
Adolf Dr. May
Hans-Walter Dr. Bücking
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT80104269T priority Critical patent/ATE5662T1/de
Publication of EP0023334A1 publication Critical patent/EP0023334A1/de
Application granted granted Critical
Publication of EP0023334B1 publication Critical patent/EP0023334B1/de
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/645—Mixtures of compounds all of which are cationic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This is particularly the case when the laundry is done in the washing machine.
  • This undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts have been introduced for this purpose.
  • these products have the disadvantage that the treated tissue becomes hydrophobic when overdosed and the rewettability is thereby delayed.
  • the invention thus relates to fabric softeners in the form of an aqueous solution or dispersion which comprise 1 to 15, preferably 2 to 16% by weight of one or more compounds of the formulas I to III where R 1 is alkyl or alkenyl having 10-30 carbon atoms, preferably 8-14 carbon atoms, R 2 alkyl having 1-4 carbon atoms, preferably methyl, R 3 is methyl or hydrogen, m is a number from 1 to 15, preferably 1, and A.
  • Anion such as Cl (-) , Br (-) , R 2 OSO 3 (-) or R 2 OPO 3 (-) means and 0.01 - 4, preferably 0.5 - 2.5 wt .-% of a fatty acid ethanol amide polyglycol ether of formula IV where R 4 is C 4 -C 20 alkyl, preferably C 8 -C 16 alkyl, n is a number from 2 to 20, preferably 2 to 6, x and y are hydrogen or methyl, but x and y are not simultaneously methyl , contain.
  • This combination of compounds I, II and III with a compound of formula IV gives any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel.
  • the use as a laundry aftertreatment for terry cloth and underwear made of cotton is particularly advantageous.
  • These fabric softeners are produced by simply mixing or dispersing the individual components in water.
  • These fabric softeners according to the invention can either contain only one compound of the formulas I to III or they contain a mixture of two or more compounds of these formulas I to III within the limits specified. Is a mixture of two or more compounds of the formula 1 to III before, their mixing ratio with each other is completely uncritical and can take any value.
  • the fabric softener according to the invention can also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use, diluted fabric softener. These are substances or. Auxiliaries that have already been used in fabric softeners, e.g. cationic or nonionic surface-active substances, electrolytes, acidifying agents, organic complexing agents, optical brightening agents or solubilizers as well as colors and fragrances. They are used to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.
  • auxiliaries e.g. cationic or nonionic surface-active substances, electrolytes, acidifying agents, organic complexing agents, optical brightening agents or solubilizers as well as colors and fragrances. They are used to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Wäscheweichspülmittel in Form einer wässrigen Lösunc oder Dispersion, die 1 bis 15 Gew.-% einer oder mehrere Verbindungen der Formeln I bis III
Figure imga0001
Figure imga0002
Figure imga0003
wobei R1 Alkyl oder Alkenyl mit 10 - 30 Kohlenstoffatomen, R2 Alkyl mit 1 -4 Kohlenstoffatomen, R3 Methyl oder Wasserstoff, m eine Zahl von 1 bis 15, und A ein Anion bedeutet, 0,01 -4 Gew.-% eines Fettsäureethanolamidpolyglykolethers der Formel IV
Figure imga0004
wobei R4 C4-C20-Alkyl, n eine Zahl von 2 bis 20, x und y Wasserstoff oder Methyl bedeuten, wobei x und y jedoch nicht gleichzeitig Methyl bedeuten und weitere übliche Hilfs- und Zusatzstoffe enthalten.

Description

  • Es ist bekannt, daß gewaschene Textilien, besonders solche aus Cellulosefasern, nach dem Trocknen eine unangenehme Verhärtung aufweisen. Dies tritt insbesondere dann ein, wenn die Wäsche im Waschautomaten erfolgt. Diese unerwünschte Griffverhärtung kann man dadurch beseitigen, daß man die Textilien nach der Wäsche in einem Spülbad mit kationischen Substanzen behandelt, die mindestens zwei langkettige aliphatische Reste im Molekül enthalten. In der Praxis haben sich für diesen Zweck besonders die in Wasser dispergierbaren Dialkyldimethylammoniumsalze eingeführt. Diese Produkte haben jedoch den Nachteil, daß bei Überdosierung das behandelte Gewebe hydrophob und dadurch die Wiederbenetzbarkeit verzögert wird.
  • Es wurde nun gefunden, daß man diese Schwierigkeiten beseitigen kann, wenn man die als Wäscheweichspülmittel dienenden quaternären Ammoniumverbindungen mit einem Fettsäureethanolamidpolyglykolether kombiniert. Gegenstand der Erfindung sind somit Wäscheweichspülmittel in Form einer wäßrigen Lösung oder Dispersion, die 1 bis 15, vorzugsweise 2 bis 16 Gew.-% einer oder mehrerer Verbindungen der Formeln I bis III
    Figure imgb0001
    Figure imgb0002
    Figure imgb0003
    wobei R1 Alkyl oder Alkenyl mit 10 - 30 Kohlenstoffatomen, vorzugsweise 8 - 14 Kohlenstoffatomen, R2 Alkyl mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff, m eine Zahl von 1 bis 15, vorzugsweise 1, und A ein Anion wie z.B. Cl(-), Br(-), R2OSO3 (-) oder R2OPO3 (-) bedeutet und 0,01 - 4, vorzugsweise 0,5 - 2,5 Gew.-% eines Fettsäureethanolamidpolyglykolethers der Formel IV
    Figure imgb0004
    wobei R4 C4-C20-Alkyl, vorzugsweise C8-C16-Alkyl, n eine Zahl von 2 bis 20, vorzugsweise 2 bis 6, x und y Wasserstoff oder Methyl bedeuten, wobei x und y jedoch nicht gleichzeitig Methyl bedeuten, enthalten.
  • Diese Kombination der Verbindungen I, II und III mit einer Verbindung der Formel IV verleiht beliebigen Textilmaterialien, besonders solchen aus natürlicher oder regenerierter Cellulose, Wolle, Cellulose-acetat, -triacetat, Polyamid, Polyacrylnitril, Polyester, Polypropylen einen angenehmen und weichen Griff. Besonders vorteilhaft ist der Einsatz als Wäschenachbehandlungsmittel für Frottee- und Leibwäsche aus Baumwolle. Die Herstellung dieser Wäscheweichspülmittel erfolgt durch einfaches Vermischen oder Dispergieren der Einzelkomponenten in Wasser. Diese Wäscheweichspülmittel gemäß der Erfindung können entweder nur jeweils eine Verbindung der Formeln I bis III enthalten oder aber sie enthalten ein Gemisch aus zwei oder mehr Verbindungen dieser Formeln.I bis III innerhalb der angegebenen Grenzen. Liegt ein Gemisch aus zwei oder mehr Verbindungen der Formeln 1 bis III vor, so ist deren Mischungsverhältnis untereinander völlig unkritisch und kann jeden beliebigen Wert annehmen.
  • Darüberhinaus können die erfindungsgemäßen Wäscheweichspülmittel noch weitere Substanzen und Hilfsmittel enthalten, die entweder schon im Konzentrat des Wäscheweichspülmittels zugemischt oder dem gebrauchsfertigen, verdünnten Wäscheweichspülmittel gesondert zugesetzt werden. Hierbei handelt es sich um Substanzen oder. Hilfsmittel, die man bereits in Wäscheweichspülmitteln eingesetzt hat, wie z.B. kationische oder nichtionische oberflächenaktive Substanzen, Elektrolyte, Absäuerungsmittel, organische Komplexbildner, optische Aufhellungsmittel oder Lösungsvermittler sowie Farb- und Duftstoffe. Sie dienen zur zusätzlichen Beeinflussung des Warengriffs oder sonstiger Eigenschaften der zu behandelnden Textilien oder zur Viskositätseinstellung, zur pH-Regulierung oder zur Erhöhung der Kältestabilität.
  • Die Anwendung dieser Wäscheweichspülmittel erfolgt wie üblich, indem man sie im Anschluß an die Textilwäsche in das letzte Spülwasser gibt. Das so behandelte Textilmaterial wird dann getrocknet, wobei die Wiederbenetzbarkeit des Textilmaterials wesentlich verbessert ist im Vergleich zu handelsüblichen Mitteln.
  • In den folgenden Beispielen sind einige erfindungsgemäße Wäscheweichspülmittel beschrieben. Prozentangaben sind in allen Fällen Gewichtsprozente. Die Herstellung.dieser Wäscheweichspülmittel erfolgt in allen Fällen durch einfaches Verrühren in der Kälte von wässrigen Lösungen der einzelnen Komponenten.
    • Beispiel 1
  • Figure imgb0005
    Figure imgb0006
    • Beispiel 2
  • Figure imgb0007
    • Beispiel 3
  • Figure imgb0008
    • Beispiel 4 Vergleichs formulierung
  • Figure imgb0009
    Diese Wäscheweichspülmittel wurden auf ihren Einfluß auf die Wiederbenetzbarkeit nach der Steighöhenmethode (DIN 53 924) geprüft. Dabei werden glatte Baumwollgewebe mit den erfindungsgemäßen Mischungen behandelt. Zum Vergleich wurde ein handelsüblicher Weichmacher hinzugezogen (Beispiel 4). Nach dieser Prüfmethode wurden für die Mischungen der Beispiele 1 - 4 die in der nachfolgenden Tabelle aufgeführten Ergebnisse erhalten. Die Steighöhe nicht ausgerüsteter Gewebe wird dabei mit 100 % bezeichnet.
    Figure imgb0010
  • Die Ergebnisse zeigen, daß die erfindungsgemäßen Wäscheweichspülmittelkombinationen im Vergleich mit einem handelsüblichen Produkt ein verbessertes Saugvermögen aufweisen.

Claims (2)

1. Wäscheweichspülmittel in Form einer wässrigen Lösung oder Dispersion, die 1 bis 15 Gew.-% einer oder mehrerer Verbindungen der Formeln I bis III
Figure imgb0011
Figure imgb0012
Figure imgb0013
wobei R1 Alkyl oder Alkenyl mit 10 - 30 Kohlenstoffatomen,.vorzugsweise 8 - 14 Kohlenstoffatomen, R2 Alkyl mit 1 - 4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff, m eine Zahl von 1 bis 15, vorzugsweise 1, und A ein Anion wie z.B. Cl(-), Br(-), R2OSO3 (-) oder R2OPO3 (-) bedeutet, 0,01 - 4, vorzugsweise 0,5 - 2,5 Gew.-% eines Fettsäureethanolamidpolyglykolethers der Formel IV
Figure imgb0014
wobei R4 C4-C20-Alkyl, vorzugsweise C8-C16-Alkyl, n eine Zahl von 2 bis 20, vorzugsweise 2 bis 6, x und y Wasserstoff oder Methyl bedeuten, wobei x und y jedoch nicht gleichzeitig Methyl bedeuten, enthalten.
2. Wäscheweichspülmittel nach Anspruch 1 enthaltend 2 bis 6 Gew.-% einer oder mehrerer Verbindungen der Formel I, II oder III und 0,5 bis 2,5 Gew.-% eines Fettsäureethanolamid-polyglykolethers der Formel IV.
EP80104269A 1979-07-25 1980-07-19 Wäscheweichspülmittel Expired EP0023334B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80104269T ATE5662T1 (de) 1979-07-25 1980-07-19 Waescheweichspuelmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2930061 1979-07-25
DE19792930061 DE2930061A1 (de) 1979-07-25 1979-07-25 Waescheweichspuelmittel

Publications (2)

Publication Number Publication Date
EP0023334A1 true EP0023334A1 (de) 1981-02-04
EP0023334B1 EP0023334B1 (de) 1983-12-21

Family

ID=6076677

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80104269A Expired EP0023334B1 (de) 1979-07-25 1980-07-19 Wäscheweichspülmittel

Country Status (6)

Country Link
EP (1) EP0023334B1 (de)
JP (1) JPS5620677A (de)
AT (1) ATE5662T1 (de)
BR (1) BR8004626A (de)
CA (1) CA1153510A (de)
DE (2) DE2930061A1 (de)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0079643A2 (de) * 1981-11-17 1983-05-25 THE PROCTER & GAMBLE COMPANY Konzentriertes Textilweichmachmittel
EP0082457A2 (de) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Konzentrierte Wäscheweichspülmittel
EP0082456A2 (de) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Konzentrierte Vormischungen von Wäscheweichspülmitteln
EP0112719A2 (de) * 1982-12-23 1984-07-04 Unilever N.V. Weichmacherzusammensetzung für Textilien
EP0159922A2 (de) * 1984-04-19 1985-10-30 Unilever N.V. Wässrige Textilweichmacherzusammensetzung
EP0186967A1 (de) * 1984-11-30 1986-07-09 Thomas Swan And Co., Ltd. Quaternisierte Imidazolinderivate als Weichmacher für Textilmaterialien
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
EP0848103A2 (de) * 1996-12-11 1998-06-17 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
EP0861938A2 (de) * 1997-02-28 1998-09-02 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
US5908854A (en) * 1996-11-12 1999-06-01 Reckitt & Colman Inc. Mycobacterial compositions and methods for their use
EP0707059A3 (de) * 1994-10-14 2001-04-18 Kao Corporation Flüssige Weichspülerzusammensetzung, ihre Verwendung und Verfahren zur Herstellung eines quaternären Ammoniumsalzes
WO2002092740A1 (en) * 2001-05-15 2002-11-21 Ici Americas, Inc. Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58144175A (ja) * 1982-02-23 1983-08-27 ライオン株式会社 繊維製品処理用物品
JP7415563B2 (ja) 2020-01-07 2024-01-17 富士フイルムビジネスイノベーション株式会社 情報処理装置及びプログラム

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE545267A (de) *
CH461426A (de) * 1964-07-08 1968-08-31 Unilever Nv Handelsfähiges Textilhilfsmittel
DE2605502A1 (de) * 1976-02-12 1977-08-18 Exquisit Kosmetik Gmbh Fluessiges feinwaschmittel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE545267A (de) *
CH461426A (de) * 1964-07-08 1968-08-31 Unilever Nv Handelsfähiges Textilhilfsmittel
DE2605502A1 (de) * 1976-02-12 1977-08-18 Exquisit Kosmetik Gmbh Fluessiges feinwaschmittel

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0079643A2 (de) * 1981-11-17 1983-05-25 THE PROCTER & GAMBLE COMPANY Konzentriertes Textilweichmachmittel
EP0079643A3 (de) * 1981-11-17 1984-07-04 THE PROCTER & GAMBLE COMPANY Konzentriertes Textilweichmachmittel
EP0082457A3 (en) * 1981-12-18 1984-12-27 Hoechst Aktiengesellschaft Concentrated fabric-softening agents
EP0082457A2 (de) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Konzentrierte Wäscheweichspülmittel
EP0082456A2 (de) * 1981-12-18 1983-06-29 Hoechst Aktiengesellschaft Konzentrierte Vormischungen von Wäscheweichspülmitteln
EP0082456A3 (en) * 1981-12-18 1984-11-28 Hoechst Aktiengesellschaft Concentrated premixes of fabric-softening agents
EP0112719A3 (de) * 1982-12-23 1986-10-15 Unilever N.V. Weichmacherzusammensetzung für Textilien
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
EP0112719A2 (de) * 1982-12-23 1984-07-04 Unilever N.V. Weichmacherzusammensetzung für Textilien
EP0159922A2 (de) * 1984-04-19 1985-10-30 Unilever N.V. Wässrige Textilweichmacherzusammensetzung
US4622154A (en) * 1984-04-19 1986-11-11 Lever Brothers Company Aqueous fabric softening composition
US4627925A (en) * 1984-04-19 1986-12-09 Lever Brothers Company Aqueous concentrated fabric softening composition
EP0159922A3 (de) * 1984-04-19 1987-03-25 Unilever N.V. Wässrige Textilweichmacherzusammensetzung
EP0186967A1 (de) * 1984-11-30 1986-07-09 Thomas Swan And Co., Ltd. Quaternisierte Imidazolinderivate als Weichmacher für Textilmaterialien
EP0707059A3 (de) * 1994-10-14 2001-04-18 Kao Corporation Flüssige Weichspülerzusammensetzung, ihre Verwendung und Verfahren zur Herstellung eines quaternären Ammoniumsalzes
EP1445303A3 (de) * 1994-10-14 2004-10-20 Kao Corporation Flüssige Weichspülerzusammensetzung
US5908854A (en) * 1996-11-12 1999-06-01 Reckitt & Colman Inc. Mycobacterial compositions and methods for their use
EP0848103A3 (de) * 1996-12-11 1999-01-20 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
EP0848103A2 (de) * 1996-12-11 1998-06-17 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
EP0861938A2 (de) * 1997-02-28 1998-09-02 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
EP0861938A3 (de) * 1997-02-28 1999-01-20 Henkel Kommanditgesellschaft auf Aktien Mittel für die Avivage von Textil- und Keratinfasern
WO2002092740A1 (en) * 2001-05-15 2002-11-21 Ici Americas, Inc. Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants
US6635607B2 (en) 2001-05-15 2003-10-21 Ici Americas Inc. Mixed polyalkylene glycol hydroxyalkyl isostearamides as rheology adjuvants

Also Published As

Publication number Publication date
DE3065943D1 (en) 1984-01-26
EP0023334B1 (de) 1983-12-21
BR8004626A (pt) 1981-02-03
CA1153510A (en) 1983-09-13
DE2930061A1 (de) 1981-02-19
JPS5620677A (en) 1981-02-26
JPS6338470B2 (de) 1988-07-29
ATE5662T1 (de) 1984-01-15

Similar Documents

Publication Publication Date Title
EP0082457B1 (de) Konzentrierte Wäscheweichspülmittel
EP0043547B1 (de) Wäscheweichspülmittelkonzentrat
EP0023334B1 (de) Wäscheweichspülmittel
EP0082456B1 (de) Konzentrierte Vormischungen von Wäscheweichspülmitteln
DE2407708C2 (de) Wäßriges Textilweichmachungsmittel zur Anwendung in Spülbädern von Waschvorgängen
EP0413249B1 (de) Wäscheweichspülmittel
EP0085933B1 (de) Konzentrierte Wäscheweichspülmittel
DE3046352A1 (de) Grenzflaechenaktive quaternaere ammoniumverbindungen und deren verwendung zum behandeln von textil- und cellulosematerialien
EP0691396A2 (de) Wäscheweichspülmittelkonzentrate
DE2210087B2 (de) Imidazoliniumsalze und diese enthaltende Textüweichmachungsmittel
DE1195265B (de) Verfahren zur antistatischen, weichmachenden und baktericiden Ausruestung von Geweben
EP0023333B1 (de) Wäscheweichspülmittel
DE1619043B2 (de) Mittel zum weichmachen von textilien und gleichzeitigem vermitteln einer guten saugfaehigkeit
EP0094655B1 (de) Konzentrierte Wäscheweichspülmittel
EP0022555B1 (de) Wäscheweichspülmittel
DE2163003B2 (de) Weichmachungsmittel für Textilien
DE1935499A1 (de) Avivagemittel
DE3730444C2 (de)
DE1901194C3 (de) Detergens-verträgliches wäßriges Weichmachungsmittel und dessen Verwendung zum Weichmachen von Geweben während des Waschens oder während des Spiilens
DE3135013A1 (de) "waescheweichspuelmittel"
DE2243806C3 (de) Wässriges Mittel zum Weichmachen von Textilgut
DE1619182B2 (de) Verfahren zum weichmachen von textilien
DE2539310C2 (de)
DE1619081B2 (de) Avivagemittel fuer textilien
DE1619081C3 (de) Avivagemittel für Textilien

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

17P Request for examination filed

Effective date: 19810624

ITF It: translation for a ep patent filed

Owner name: ING. C. GREGORJ S.P.A.

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT LI NL SE

REF Corresponds to:

Ref document number: 5662

Country of ref document: AT

Date of ref document: 19840115

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3065943

Country of ref document: DE

Date of ref document: 19840126

ET Fr: translation filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 19840618

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19840621

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 19840630

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19840810

Year of fee payment: 5

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19840930

Year of fee payment: 5

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19860626

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19870731

Year of fee payment: 8

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19880719

Ref country code: AT

Effective date: 19880719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19880720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19880731

Ref country code: CH

Effective date: 19880731

Ref country code: BE

Effective date: 19880731

BERE Be: lapsed

Owner name: HOECHST A.G.

Effective date: 19880731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19890201

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
GBPC Gb: european patent ceased through non-payment of renewal fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19890331

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19890401

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

EUG Se: european patent has lapsed

Ref document number: 80104269.8

Effective date: 19890510