EA202191028A1 - Катализаторы дегидрирования и способы их приготовления и использования - Google Patents

Катализаторы дегидрирования и способы их приготовления и использования

Info

Publication number
EA202191028A1
EA202191028A1 EA202191028A EA202191028A EA202191028A1 EA 202191028 A1 EA202191028 A1 EA 202191028A1 EA 202191028 A EA202191028 A EA 202191028A EA 202191028 A EA202191028 A EA 202191028A EA 202191028 A1 EA202191028 A1 EA 202191028A1
Authority
EA
Eurasian Patent Office
Prior art keywords
group
methods
catalysts
preparation
dehydration catalysts
Prior art date
Application number
EA202191028A
Other languages
English (en)
Inventor
Владимир З. Фридман
Жун Син
Мэтт Грини
Дэвид Лоуи
Клаус Дж. Лагмайр
Original Assignee
Клариант Интернэшнл Лтд
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Клариант Интернэшнл Лтд filed Critical Клариант Интернэшнл Лтд
Publication of EA202191028A1 publication Critical patent/EA202191028A1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/088—Decomposition of a metal salt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/10—Constitutive chemical elements of heterogeneous catalysts of Group I (IA or IB) of the Periodic Table
    • B01J2523/13—Potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/25—Barium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/31—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/32—Gallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/37—Lanthanides
    • B01J2523/3706—Lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/30—Constitutive chemical elements of heterogeneous catalysts of Group III (IIIA or IIIB) of the Periodic Table
    • B01J2523/37—Lanthanides
    • B01J2523/3712—Cerium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/41—Silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/80—Constitutive chemical elements of heterogeneous catalysts of Group VIII of the Periodic Table
    • B01J2523/82—Metals of the platinum group
    • B01J2523/828—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/58—Platinum group metals with alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
    • C07C2523/63—Platinum group metals with rare earths or actinides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Настоящее изобретение относится к катализаторам дегидрирования на основе одного или нескольких определенных элементов из группы 13 и группы 14, которые, кроме того, включают дополнительные металлические компоненты, к способам изготовления таких катализаторов и к способам дегидрирования углеводородов при использовании таких катализаторов. В одном аспекте изобретения предлагается прокаленный катализатор дегидрирования, который включает основной компонент P1, выбранный из группы, состоящей из Ga, In, Tl, Ge, Sn и Pb и их комбинаций; основной компонент P2, выбранный из лантанидов; промотор M1, выбранный из группы, состоящей из Ni, Pd и Pt; промотор M2, выбранный из группы, состоящей из Li, Na, K, Rb, Cs, Be, Mg, Ca, Sr и Ba, носителе и диоксида кремния-оксида алюминия.
EA202191028A 2018-10-30 2019-09-30 Катализаторы дегидрирования и способы их приготовления и использования EA202191028A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201862752380P 2018-10-30 2018-10-30
PCT/US2019/053725 WO2020091926A1 (en) 2018-10-30 2019-09-30 Dehydrogenation catalysts and methods for preparing and using them

Publications (1)

Publication Number Publication Date
EA202191028A1 true EA202191028A1 (ru) 2021-07-01

Family

ID=68470606

Family Applications (1)

Application Number Title Priority Date Filing Date
EA202191028A EA202191028A1 (ru) 2018-10-30 2019-09-30 Катализаторы дегидрирования и способы их приготовления и использования

Country Status (11)

Country Link
US (1) US10933405B2 (ru)
EP (1) EP3873662A1 (ru)
JP (2) JP2022512696A (ru)
KR (1) KR20210083280A (ru)
CN (1) CN113286653A (ru)
EA (1) EA202191028A1 (ru)
MX (1) MX2021004817A (ru)
SA (1) SA521421718B1 (ru)
SG (1) SG11202103845RA (ru)
TW (1) TWI838412B (ru)
WO (1) WO2020091926A1 (ru)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115427143A (zh) * 2020-05-01 2022-12-02 科莱恩国际有限公司 脱氢催化剂系统及其使用方法
WO2021250612A1 (en) * 2020-06-10 2021-12-16 Sabic Global Technologies B.V. Dehydrogenation catalyst
TW202216286A (zh) 2020-07-20 2022-05-01 瑞士商克萊瑞特國際股份有限公司 脫氫觸媒及其使用方法

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3198749A (en) 1960-10-10 1965-08-03 Exxon Research Engineering Co Silica-alumina-gallium oxide catalyst and method of preparation thereof
SE390781B (sv) 1974-12-12 1977-01-17 Asea Ab Kombination av en tyristorkoppling och en provanordning for tyristorerna i denna
IT1254252B (it) 1992-03-11 1995-09-14 Snam Progetti Procedimento per l'attivazione di precursori catalitici per la deidrogenazione di paraffine c2-c5 e composizione catalitica attivata con tale procedimento
US5346871A (en) 1993-03-09 1994-09-13 Exxon Research & Engineering Co. Catalyst for dehydrogenation of paraffins
IT1265047B1 (it) 1993-08-06 1996-10-28 Snam Progetti Procedimento per ottenere olefine leggere dalla deidrogenazione delle corrispondenti paraffine
DE69616789T2 (de) * 1995-06-16 2002-06-20 Institut Francais Du Petrole, Rueil-Malmaison Silizium enthaltende katalysatoren zur verwendung für die umwandlung von reaktionen von kohlenwasserstoffen
IT1295072B1 (it) * 1997-09-26 1999-04-27 Snam Progetti Procedimento per la produzione di stirene
FR2770421B1 (fr) * 1997-10-31 1999-12-10 Inst Francais Du Petrole Procede de preparation de catalyseurs utilisables dans les reactions de transformation de composes organiques
JP2000037628A (ja) * 1998-07-24 2000-02-08 Chiyoda Corp 脱水素触媒
JP4778656B2 (ja) * 2000-02-02 2011-09-21 ザ ダウ ケミカル カンパニー アルケニル置換芳香族化合物を製造するための統合された方法
US6756340B2 (en) * 2002-04-08 2004-06-29 Uop Llc Dehydrogenation catalyst composition
DE10333755A1 (de) * 2003-07-24 2005-03-31 Basf Ag Verfahren zur Dehydrierung von Carbonylverbindungen
DE102004015800A1 (de) * 2004-03-29 2005-10-20 Basf Ag Katalysator für die Oxidation von Wasserstoff, sowie Verfahren zur Dehydrierung von Kohlenwasserstoffen
US8200578B2 (en) 2008-07-09 2012-06-12 Hill Matthew D Methods and systems for account management and virtual agent design and implementation
EP2408558B1 (en) 2009-03-19 2017-06-28 Dow Global Technologies LLC Dehydrogenation process and catalyst
CN101773850B (zh) * 2010-01-28 2012-02-15 清华大学 一种低碳烷烃脱氢制烯烃催化剂及其应用
BR112013005637A2 (pt) * 2010-09-30 2019-09-24 Dow Global Technologies Llc processo melhorado para desidrogenação não oxidativa para conversão catalítica de uma corrente gasosa livre de oxigênio
CN102775262A (zh) * 2011-05-13 2012-11-14 中国石油天然气股份有限公司 一种低碳烷烃脱氢制备烯烃的方法
ITMI20112403A1 (it) * 2011-12-28 2013-06-29 Polimeri Europa Spa Composizione catalitica e procedimento per la deidrogenazione di buteni o miscele di butani e buteni a dare 1-3 butadiene
BR112014018119B1 (pt) * 2012-02-20 2020-09-29 Dow Global Technologies Llc Processo para desidrogenar compostos de alcano ou alquilaromáticose processo para preparar um catalisador
CN104755167B (zh) * 2012-08-28 2018-08-07 陶氏环球技术有限责任公司 催化剂组合物和用于烷烃脱氢的再活化方法
EP3036041A2 (en) * 2013-08-21 2016-06-29 Saudi Basic Industries Corporation Selective zeolite supported catalysts for propane and butane dehydrogenation
CN105813731B (zh) 2013-12-16 2019-08-30 陶氏环球技术有限责任公司 非均相烷烃脱氢催化剂
CN104289220A (zh) * 2014-09-18 2015-01-21 南京沃来德能源科技有限公司 一种高热稳定性低碳烷烃脱氢催化剂的制法和用途
CN105435782B (zh) * 2015-11-05 2019-03-26 中国海洋石油集团有限公司 一种性能可调的Pt基脱氢催化剂及提高其稳定性的方法
US10559965B2 (en) 2017-09-21 2020-02-11 Manufacturing Resources International, Inc. Display assembly having multiple charging ports
US10792646B2 (en) * 2017-10-30 2020-10-06 Clariant Corporation Dehydrogenation catalysts
EP3743206B1 (en) * 2018-01-26 2023-02-01 Clariant International Ltd Dehydrogenation catalysts and methods for preparing and using them

Also Published As

Publication number Publication date
TW202031353A (zh) 2020-09-01
SG11202103845RA (en) 2021-05-28
WO2020091926A1 (en) 2020-05-07
KR20210083280A (ko) 2021-07-06
SA521421718B1 (ar) 2024-07-15
EP3873662A1 (en) 2021-09-08
US10933405B2 (en) 2021-03-02
JP2024016087A (ja) 2024-02-06
TWI838412B (zh) 2024-04-11
MX2021004817A (es) 2021-06-15
US20200129961A1 (en) 2020-04-30
JP2022512696A (ja) 2022-02-07
CN113286653A (zh) 2021-08-20

Similar Documents

Publication Publication Date Title
EA202191028A1 (ru) Катализаторы дегидрирования и способы их приготовления и использования
BR112018070992A2 (pt) zeólita sintética compreendendo um metal catalítico
WO2020086647A8 (en) Ny-eso-1 t cell receptors and methods of use thereof
CR20190561A (es) ANTICUERPOS ANTI-GARP-TGF-ß
BR112021019334A2 (pt) Anticorpos de cadeia pesada que se ligam ao psma
UY36692A (es) Anticuerpos anti-cd40 y usos de los mismos
MY195443A (en) Tissue Factor Pathway Inhibitor Antibodies and uses Thereof
SA520412419B1 (ar) مُحفِّزات إزالة الهيدروجين وطرق لتحضيرها واستخدامها
AR112357A1 (es) Composiciones, procedimientos y/o kits que comprenden un dominio extracelular recombinante de cd38 humano
WO2019089753A3 (en) Cd137 antibodies and pd-1 antagonists and uses thereof
MX2019012606A (es) Celulas t que redirigen anticuerpos biespecificos para el tratamiento de canceres positivos a egfr.
EA202090153A1 (ru) Объединенный способ термического крекинга и дегидрирования для получения олефинов
EA201691715A1 (ru) Способ конверсии углеводородов в олефины
PE20230381A1 (es) Proteina de union a rgma
EA201990318A1 (ru) Добавки для катализаторов газофазной окислительной десульфуризации
MX2021008216A (es) Anticuerpos anti-tigit.
PH12020551270A1 (en) Botulinum neurotoxin biohybrid
MY189866A (en) Method for preparing dehydrogenation catalyst for straight chain-type light hydrocarbon using stabilized active material complex
MY190455A (en) Method for preparing dehydrogenation catalyst for linear chain light hydrocarbons with high regeneration efficiency
AR129305A2 (es) Catalizador híbrido para preparar parafinas c2 a c5
MX2023015028A (es) Nuevos aglutinantes del p2x7 disfuncional.
MY192190A (en) Catalyst composition and isomerisation process
Poleev Review of the book: ED Bakulina, AV Yablokov. Magical bracelet. Moscow, Detskaya Literatura, 1971.
AR114844A1 (es) Método de control de fusarium en papa usando alquilnaftaleno inferior
Akulinin et al. Strukturno-funktsional'nye posledstviya aktivatsii regenerativnykh protsessov golovnogo mozga belykh krys pri reperfuzii