EA201892697A1 - Одностадийный способ получения бутадиена - Google Patents

Одностадийный способ получения бутадиена

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Publication number
EA201892697A1
EA201892697A1 EA201892697A EA201892697A EA201892697A1 EA 201892697 A1 EA201892697 A1 EA 201892697A1 EA 201892697 A EA201892697 A EA 201892697A EA 201892697 A EA201892697 A EA 201892697A EA 201892697 A1 EA201892697 A1 EA 201892697A1
Authority
EA
Eurasian Patent Office
Prior art keywords
ethanol
catalyst
butadiene
acetaldehyde
stage method
Prior art date
Application number
EA201892697A
Other languages
English (en)
Inventor
Виталий Леонидович СУШКЕВИЧ
Андрей Валентинович СМИРНОВ
Ирина Игоревна ИВАНОВА
Original Assignee
Общество с ограниченной ответственностью "ЭТБ каталитические технологии" (ООО "ЭТБ КаТ")
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Общество с ограниченной ответственностью "ЭТБ каталитические технологии" (ООО "ЭТБ КаТ") filed Critical Общество с ограниченной ответственностью "ЭТБ каталитические технологии" (ООО "ЭТБ КаТ")
Publication of EA201892697A1 publication Critical patent/EA201892697A1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/12—Alkadienes
    • C07C11/16—Alkadienes with four carbon atoms
    • C07C11/167—1, 3-Butadiene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/76—Iron group metals or copper

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Изобретение относится к газофазному синтезу бутадиена из этанола или этанола в смеси с ацетальдегидом. Способ получения включает превращение этанола или смеси этанола с ацетальдегидом в присутствии катализатора, отличающийся тем, что взаимодействие проводят в присутствии твердофазного катализатора, включающего мезопористый Zr-содержащий цеолит со структурой BEA и металл в нулевой степени окисления, выбранный из группы: серебро, медь, золото и их комбинации. Заявленный способ пригоден для осуществления конденсации в условиях непрерывного потока в реакторе с неподвижным слоем катализатора. Изобретение позволяет обеспечить высокий выход бутадиена, селективность процесса и высокую стабильность работы катализатора.
EA201892697A 2017-03-31 2017-07-07 Одностадийный способ получения бутадиена EA201892697A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2017110879A RU2656602C1 (ru) 2017-03-31 2017-03-31 Одностадийный способ получения бутадиена
PCT/RU2017/000505 WO2018182450A1 (ru) 2017-03-31 2017-07-07 Одностадийный способ получения бутадиена

Publications (1)

Publication Number Publication Date
EA201892697A1 true EA201892697A1 (ru) 2020-02-14

Family

ID=62560417

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201892697A EA201892697A1 (ru) 2017-03-31 2017-07-07 Одностадийный способ получения бутадиена

Country Status (6)

Country Link
US (1) US11136276B2 (ru)
EP (1) EP3604260A4 (ru)
CN (1) CN109890782A (ru)
EA (1) EA201892697A1 (ru)
RU (1) RU2656602C1 (ru)
WO (1) WO2018182450A1 (ru)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10647625B2 (en) * 2017-02-07 2020-05-12 Battelle Memorial Institute Single step conversion of ethanol to butadiene
FR3090631B1 (fr) * 2018-12-21 2020-12-25 Ifp Energies Now Procédé de production de butadiène à partir d’éthanol avec régénération in situ du catalyseur de la deuxième étape réactionnelle
CN112479222A (zh) * 2019-09-11 2021-03-12 中国科学院大连化学物理研究所 多级孔纯硅沸石分子筛及其制备方法
CN112958146B (zh) * 2019-12-12 2022-04-19 中国科学院大连化学物理研究所 一种mfi分子筛纳米片负载的锆基催化剂及其在制备丁二烯反应中的应用
CN113289670B (zh) * 2021-04-14 2022-11-08 中山大学 一种制备1,3-丁二烯的催化剂及其制备方法
CN115518670B (zh) * 2021-06-24 2023-10-31 中国石油化工股份有限公司 烯烃化反应催化剂及其制备方法和应用
CN117460578A (zh) * 2021-07-29 2024-01-26 通伊欧轮胎株式会社 1,3-丁二烯用合成催化剂及其制备方法、以及1,3-丁二烯的制备方法
CN113996330B (zh) * 2021-11-12 2022-08-30 中国科学院大连化学物理研究所 一种球磨法制备的Zr基MFI分子筛催化剂及其应用

Family Cites Families (20)

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Publication number Priority date Publication date Assignee Title
FR665917A (fr) 1928-12-15 1929-09-25 Procédé pour obtenir des dioléfines directement des alcools
GB331482A (en) 1929-01-30 1930-06-30 Serge Vassiliewitsch Lebedev Improvements in or relating to the preparation of diolefines directly from alcohols
GB331402A (en) 1929-07-13 1930-07-03 Carl Franz Frauenberger Improvements in throw-off mechanism for platen presses
GB573631A (en) 1941-12-15 1945-11-29 Waclaw Szukiewicz Manufacture of butadiene
US2357855A (en) 1941-12-15 1944-09-12 Szukiewicz Waclaw Method for producing butadiene
US2374433A (en) 1942-06-08 1945-04-24 Universal Oil Prod Co Production of butadiene
US2438464A (en) 1944-08-30 1948-03-23 Rohm & Haas Catalytic process for producing butadiene
US2436125A (en) 1944-08-30 1948-02-17 Rohm & Haas Silica-zirconia catalysts and method of preparation
US2447181A (en) 1944-08-30 1948-08-17 Rohm & Haas Silica-magnesia catalyst and preparation thereof
JPS57102822A (en) 1980-12-16 1982-06-26 Takeda Chem Ind Ltd Preparation of butadiene
JPS5859928A (ja) 1981-10-02 1983-04-09 Takeda Chem Ind Ltd ブタジエンの製造法
RU2440962C1 (ru) * 2010-07-29 2012-01-27 Общество с ограниченной ответственностью "УНИСИТ" (ООО "УНИСИТ") Одностадийный способ получения бутадиена
KR101589140B1 (ko) 2012-10-19 2016-01-28 한국화학연구원 에탄올로부터 1,3-부타디엔 제조를 위한 규칙적인 메조세공 실리카계 촉매 및 이를 이용한 1,3-부타디엔의 제조방법
RU2514425C1 (ru) * 2012-11-16 2014-04-27 Открытое акционерное общество Научно-исследовательский институт "Ярсинтез" (ОАО НИИ "Ярсинтез") Катализатор для получения бутадиена превращением этанола
EP2994229B1 (en) * 2013-05-07 2016-10-19 Synthos S.A. Process for the production of 1,3-butadiene
JP6545157B2 (ja) * 2013-06-13 2019-07-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ブタジエンの製造方法
WO2014199348A2 (en) 2013-06-13 2014-12-18 Basf Se Metal doped silicate catalysts for the selective conversion of ethanol to butadiene
EP3207004B1 (en) * 2014-10-14 2024-01-17 GEVO, Inc. Methods for conversion of ethanol to functionalized lower hydrocarbons
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FR3038849B1 (fr) * 2015-07-13 2019-11-29 IFP Energies Nouvelles Catalyseur oxyde mixte mesoporeux comprenant du silicium

Also Published As

Publication number Publication date
EP3604260A4 (en) 2021-04-07
RU2656602C1 (ru) 2018-06-06
US11136276B2 (en) 2021-10-05
CN109890782A (zh) 2019-06-14
WO2018182450A1 (ru) 2018-10-04
EP3604260A1 (en) 2020-02-05
US20200317589A1 (en) 2020-10-08

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